Abstract Ship exhaust emissions contain a large amount of sulfur oxides and nitrogen oxides, which have attracted widespread attention from the international community for their pollution of the atmospheric environment. In order to reduce the emissions of these pollutants, the International Maritime Organization (IMO) and other national institutions have established strict emission standards and promoted the research and application of ship exhaust desulfurization and denitrification technology. Experimental and simulation analyses were conducted on the denitrification effect of Mg(OH)2/NaClO2 solution using a cyclic spray method. Simulation analysis was carried out using cyclic spraying. The experiment compared the reaction degree and reaction time of NO in NaClO2 seawater, NaClO2 water, and Mg(OH)2/NaClO2 marine solution. The experimental result is that in the process of cyclic spray, the removal rate of NO by these three solutions can reach 100%. The reaction time of NO is 71, 86, and 90 minutes, respectively. Under the same conditions, the simulation results showed that the reaction rate of NaClO2 water solution with NO was faster, followed by NaClO2 seawater solution. The reaction rate of Mg(OH)2/NaClO2 seawater solution with NO was the slowest of the three. When the pH value exceeds 7, it effectively inhibits the production of ClO2 gas by NaClO2. The removal rate of Mg(OH)2/NaClO2 seawater solution is directly proportional to the initial concentration of NaClO2. In addition, it could be seen from the simulation cloud diagram that the removal speed of NO in the spray reactor slows down as the concentration of NO increases.
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