The secondary defects introduced by quenching of Al-Zn alloys were investigated by means of transmission electron microscopy, with particular attension to the effect of the quenching rates and the solute concentrations.Two different methods of quenching were employed in this experiments. One was a fast quenching at the quenching rate of 1×104 deg C/sec, and the other a slow quenching at the rate of 1×103 deg C/sec.The type, size and density of secondary defects were sensitive to the quenching rates and the solute concentrations. The types of secondary defects observed in quenched Al-Zn alloys were the Frank sessile loop, prismatic loop, helical dislocation and black spot defect. Frank sessile loops were observed only in pure Al by the fast quenching and in the alloys containing less than 1.9 at%Zn by the slow quenching. Helical dislocations were observed in the alloys containing above 7.0 at%Zn by the fast quenching but in alloys of more than 1.6 at%Zn by the slow quenching. Black spot defects were found in the alloys containing above 0.5 at%Zn by the fast quenching and in alloys of more than 7.0 at%Zn by the slow quenching. Judging from the various experimental results, the black spot defects found in the quenched Al-Zn alloys were thought to be the three dimensional vacancy clusters.The initial vacancy concentrations estimated roughly from the size and density of secondary defects in the quenched alloys were much larger than in pure Al. This may indicate that the presence of Zn in Al lowers the activation energy to form a vacancy.