Spinel Lherzolite Research Articles

Geochemistry of Rock-Forming Minerals in Mantle Xenoliths from Basalts of Sverre Volcano, Spitsbergen Archipelago

The paper reports the results of SIMS and SEM-EDS study of rock-forming minerals from melt pockets in the central part of a spinel peridotite xenolith taken from Quaternary alkaline basalts of Sverre Volcano in the northwestern part of West Spitsbergen Island. Olivine and clinopyroxene are analyzed to trace changes related to the metasomatic interaction between spinel lherzolite and a carbonate melt with formation of corresponding secondary minerals and silicate glass. It is established that the metasomatic interaction of the carbonate melt with minerals of host spinel lherzolite is accompanied by partial recrystallization of olivine and clinopyroxene, or crystallization of the second generation of these minerals. Percolating carbonate melt caused significant changes in the major, trace, and rare-earth element composition of the considered minerals, thus placing constraints on the use of the composition of these minerals for calculation of P–T parameters, estimating equilibrium, and modeling petrological processes in mantle.

Pargasite in fluid inclusions of mantle xenoliths from northeast Australia (Mt. Quincan): evidence of interaction with asthenospheric fluid

Three spinel lherzolite xenoliths from Mt. Quincan (Queensland, northeastern Australia) were studied with special attention to their enclosed fluid inclusions. The xenoliths are deformed, have porphyroclastic textures and overall show very similar petrographic features. The only significant difference is manifested in the abundance of fluid inclusions in the samples, mostly in orthopyroxene porphyroclasts. Xenolith JMTQ11 is fluid inclusion-free, whereas xenolith JMTQ20 shows a high abundance of fluid inclusions (fluid inclusion-rich). Xenolith JMTQ45 represents a transitional state between the previous two, as it contains only a small amount of fluid inclusions (fluid inclusion-bearing). Previous studies revealed that these xenoliths and the entrapped fluid inclusions represent a former addition of a MORB-type fluid to the pre-existing lithosphere, resulting from asthenosphere upwelling. There is a progressive enrichment in LREE, Nb, Sr and Ti from the fluid inclusion-free xenolith through the fluid inclusion-bearing one to the fluid inclusion-rich lherzolite. This suggests an increase in the extent of the interaction between the fluid-rich melt and the lherzolite wallrock. In addition, the same interaction is considered to be responsible for the formation of pargasitic amphibole as well.The presence of fluid inclusions indicates fluid migration at mantle depth, and their association with exsolution lamellae in orthopyroxene suggests fluid entrapment following the continental rifting (thermal relaxation) during cooling. A series of analyses, including microthermometry coupled with Raman spectroscopy, FTIR hyperspectral imaging, and Focused Ion Beam-Scanning Electron Microscopy (FIB-SEM) was carried out on the fluid inclusions. Based on the results, the entrapped high-density fluid is composed of 75–89 mol% CO2, 9–18 mol% H2O, 0.1–1.7 mol% N2 and ≤0.5 mol% H2S with dissolved trace elements (melt component).Our findings suggest that the metasomatic fluid phase could have been either a fluid/fluid-rich silicate melt released from the deeper asthenosphere, or a coexisting incipient fluid-rich silicate melt. Further cooling, possibly due to thermal relaxation and the upward migration of the fluid phase, caused the investigated lherzolites to reach pargasite stability conditions. We conclude that pargasite, even if only present in very limited modal proportions, can be a common phase at spinel lherzolite stability in the lithospheric upper mantle in continental rift – back-arc settings. Studies of fluid inclusions indicate that significant CO2 release from the asthenosphere in a continental rifting environment is resulting from asthenosphere upwelling and its addition to the lithospheric mantle together with fluid-rich melt – lherzolite interaction that leaves a CO2-rich fluid behind.

Petrogenesis of the Early Cretaceous Kada igneous rocks from Tethyan Himalaya: Implications for initial break‐up of eastern Gondwana

Early Cretaceous magmatic rocks associated with the Kerguelen mantle plume are widespread in the Comei area with a chronology concentrated from 134 to 130 Ma. However, less data for the earliest Early Cretaceous magmatic rocks cropping out in the Comei area have been reported. The earliest Early Cretaceous magmatic rocks from the Kada area comprise mafic rock (diabase) and felsic rocks (granite, dacite, and quartz monzonite). This paper presents a detailed LA‐ICP‐MS zircon U–Pb chronology with major and minor (trace) elements and Lu–Hf isotope data from Kada igneous rocks to identify the extent of the early activity of the Kerguelen mantle plume and the initial break‐up of eastern Gondwanaland. The LA‐ICP‐MS zircon U–Pb dates reveal that the age of Kada magmatic rocks range from 136.9 to 143.5 Ma. Kada mafic rocks exhibit both OIB (Samples KD3 and KD06) and N‐MORB (Sample KD7‐1) characteristics. The N‐MORB‐type mafic rocks were derived from partial melting of depleted spinel lherzolite. However, the OIB‐type mafic rocks were derived from partial melting (~60–80 km) of spinel + garnet lherzolite. Kada felsic rocks show obvious enrichment of light rare earth elements and negative Eu anomaly features. Among these, dacite and quartz monzonite rocks show flat heavy rare earth elements and clear Nb, Ta, P, and Ti negative anomalies with depleted εHf(t) characteristics (−11.0 to −21.0). This is indicative of partial melting of specific crustal rocks in an intraplate environment caused by underplating of coeval basaltic magmas. However, granite is characterized by high heavy rare earth element fractionation and high and dispersed εHf composition (−1.5 to +8.9), thus indicating that granite is derived from extensive fractional crystallization of mantle‐derived melts from an AFC process. The Kada felsic rocks show A‐type granitic characteristics in an extensional environment. Based on the evidence from palaeomagnetism reconstructions, Kada rocks and Bunbury basalts are both distributed in and influence the scope of the Kerguelen mantle plume. They are also coeval with the initial break‐up of eastern Gondwana. We suggest that Kada magmatic rocks in southern Tibet represent the earliest activity of the Kerguelen mantle plume and that they played a role in the initial break‐up of eastern Gondwana.

Trace element systematics and Nd, Sr and Pb isotopes of Pliocene flood basalt magmas (Ethiopian rift): A case for Afar plume-lithosphere interaction

We present high-precision trace element and Sr-Nd-Pb isotope data for Pliocene flood basalts located at Sire (eastern rift wall) and Chefe Donsa (western rift wall) sections from the main Ethiopian rift (MER). These basalts are tholeiitic to mildly alkaline and were derived by moderate degrees of melting (~10–20%) of a spinel lherzolite containing minor amounts of amphibole within the lithospheric mantle. Strontium, Nd and Pb isotopic compositions (87Sr/86Sr: 0.7040–0.7057, 143Nd/144Nd: 0.52164–0.51287, 206Pb/204Pb: 17.75–19.20, 207Pb/204Pb: 15.53–15.64 and 208Pb/204Pb: 38.12–38.86) are between the inferred composition of the Afar mantle plume and an unspecified enriched lithospheric component, suggesting interaction of melts from asthenospheric and lithospheric mantle domains rather than melting of homogeneous mixed sources or magma mixing. It is proposed that in the Oligocene the impinging Afar plume creates zones of metasomatically enriched mantle. Later, lithospheric thinning as a result of incipient rifting leads to decompression and melting of this metasomatically enriched mantle due to its lower solidus temperature. The chemistry of the Pliocene lavas therefore reflect two associated scenarios namely (i) upwelling plume material from the advancing Afar plume may have induced metasomatism in the lithospheric mantle (ii) mobilization and melting of this enriched lithospheric mantle material resulted in melts characterized by variable mixtures of the two mantle reservoirs.

Oxidation States of Fe in Constituent Minerals of a Spinel Lherzolite Xenolith from the Tariat Depression, Mongolia: The Significance of Fe3+ in Olivine

The oxidation states of Fe within olivine, orthopyroxene, clinopyroxene, and spinel in a spinel lherzolite xenolith from the Tariat Depression, Mongolia were investigated using 57Fe Mössbauer spectroscopy to evaluate the redox condition of the upper mantle from which the Tariat spinel lherzolite xenolith was derived. The purity of separated minerals for the Mössbauer spectroscopic analysis was examined using X-ray powder diffraction, Raman spectroscopy, and transmission electron microscopy. Average Fo and Fe contents of olivine at the core part of the xenolith are 89.9(4) mol % and 0.195(3) atoms per formula unit, respectively. The Fe3+/ΣFe values of the olivine, orthopyroxene, clinopyroxene, and spinel, determined by Mössbauer spectroscopic analysis, are 0.027(2), 0.15(1), 0.26(3), and 0.34(5), respectively. The Mössbauer spectrum of olivine consists of two doublets assigned to Fe2+ at the octahedral sites and one doublet, with I.S. of 0.40(2) mm/s and Q.S. of 0.69(3) mm/s assigned to Fe3+ at the octahedral site. Since the Tariat spinel lherzolite xenolith in this study shows no evidence of metasomatism or thermal alteration, the existence of a small amount of Fe3+ in olivine and the fairly high Fe3+ contents of clinopyroxene, orthopyroxene, and spinel imply that the upper mantle under the Tariat area was in a rather oxidized condition.

Energy Balance From a Mantle Pseudotachylyte, Balmuccia, Italy

AbstractIn the Balmuccia massif (NW Italy), a pseudotachylyte vein network (N068 trending) in a spinel lherzolite is interpreted as the product of frictional melting during a single Mw > 6 earthquake. The subvertical fault underwent a metric dextral coseismic displacement, raking 60°SW. The average width of the main slip surface is ~ 5 mm. A dense network of thin (20–200 μm) injection and ultramylonite‐like veins decorates the fault walls. In the injection veins, Raman microspectrometry mapping reveals pockets of still preserved amorphous silicate, containing ≈ 1% of structurally bound H2O. In the ultramylonite‐like veins, electron backscattered diffraction mapping reveals that ultrafine (0.2–2 μm) olivine grains exhibit a strong fabric with (010) planes parallel to shearing, consistent with temperatures above 1250°C during deformation and suggesting fast recrystallization from the frictional melt. The veins also exhibit pyroxene and recrystallized spinel, which proves that the earthquake occurred at a minimum depth of 40 km. The energy balance demonstrates that complete fault lubrication must have occurred during coseismic sliding (i.e., dynamic friction coefficient ≪ 0.1). Because of the low viscosity of slightly hydrated ultramafic liquids (≈ 1 Pa·s), we argue that lubrication was only transient, as the melt could rapidly flow into tensile fractures, which led to rapid cooling and promoted strength recovery and sliding arrest. Combined together, our observations suggest that this pseudotachylyte is the frozen record of a deep (>40 km) earthquake of 6 < Mw < 7. Its focal mechanism is deduced from the crystal preferred orientation due to late coseismic creep in ultramylonite‐like veins and deciphered by electron backscattered diffraction.

Spinel and plagioclase peridotites of the Nain ophiolite (Central Iran): Evidence for the incipient stage of oceanic basin formation

The Nain ophiolites crop out along the western border of the central East Iran Microcontinent (CEIM) and consist of an ophiolitic mélange in which pargasite-bearing spinel and plagioclase mantle lherzolites are largely represented. Whole-rock and mineral chemistry data suggest that these rocks record the complex history of the asthenospheric and lithospheric mantle evolution. The spinel lherzolites have experienced low-degree (~5%) partial melting and contain clinopyroxenes with positive Eu anomalies (Eu/Eu⁎ = 1.10–1.48) suggesting that the partial melting occurred under oxidized conditions (fayalite–magnetite–quartz −0.8 to +1.3). The pargasite and coexisting clinopyroxene in these rocks are depleted in light rare earth elements (LREE) (mean chondrite-normalized CeN/SmN = 0.045). The depleted chemistry of this amphibole reflects metasomatism during interaction with H2O-rich subalkaline mafic melts, most likely concurrently with or after the partial melting of the spinel lherzolites. The plagioclase lherzolites were subsequently formed by the subsolidus recrystallization of spinel lherzolites under plagioclase facies conditions as a result of mantle uprising, as evidenced by: (1) the development of plagioclase rims around the spinels; (2) plagioclase + orthopyroxene exsolution textures within some clinopyroxene grains; (3) an increase in plagioclase modal content coupled with an increase in modal olivine and a decrease in modal pyroxene and pargasite; (4) coincident decreases in Al, Mg, and Ni, and increases in Cr, Ti, and Fe in spinel, as well as decreases in Al and Ca, and increases in Cr and Ti in pyroxene and pargasite; and (5) the identical whole rock compositions of the spinel and plagioclase lherzolites, which rules out a magmatic origin for the plagioclase in these units.The Nain lherzolites have similar whole-rock and mineral geochemical compositions to subcontinental peridotites that are typically representative of Iberia-type rifted continental margins and ocean–continent transition zones (OCTZ), suggesting that they formed during the early stages of the evolution of the Nain oceanic basin. This means that the Nain lherzolites represent the Triassic–Jurassic western border of the CEIM or alternatively an associated OCTZ.

118–115 Ma magmatism in the Tethyan Himalaya igneous province: Constraints on Early Cretaceous rifting of the northern margin of Greater India

Understanding the dynamics of Large Igneous Provinces (LIPs) is critical to deciphering processes associated with rupturing continental lithosphere. Microcontinental calving, the rifting of microcontinents from mature continental rifted margins, is particularly poorly understood. Here we present new insights into these processes from geochronological and geochemical analyses of igneous rocks from the Tethyan Himalaya. Early Cretaceous mafic dikes are widely exposed in the eastern and western Tethyan Himalaya, but no such rocks have been reported from the central Tethyan Himalaya. Here we present an analysis of petrological, geochronological, geochemical, and Sr–Nd–Hf–Os isotopic data for bimodal magmatic rocks from the center-east Tethyan Himalaya. Zircon U–Pb dating yields six weighted-mean concordant 206Pb/238U ages of 118±1.2 to 115±1.3 Ma. Mafic rocks display MORB-like compositions with flat to depleted LREE trends, and positive εNd(t) (+2.76 to +5.39) and εHf(t) (+8.0 to +11.9) values. The negative Nb anomalies and relatively high 187Os/188Os ratios (0.15–0.19) of these rocks are related to variable degrees (up to 10%) of crustal contamination. Geochemical characteristics indicate that mafic rocks were generated by variable degrees (2–20%) of partial melting of spinel lherzolites in shallow depleted mantle. Felsic rocks are enriched in Th and LREE, with negative Nb anomalies and decoupling of Nd (εNd(t) = −13.39 to −12.78) and Hf (εHf(t) = −4.8 to −2.0), suggesting that they were derived mainly from garnet-bearing lower continental crust. The geochemical characteristics of the bimodal magmatic associations are comparable to those of associations that form in a continental rift setting. Results indicate that Early Cretaceous magmatism occurred across the whole Tethyan Himalaya, named here as the “Tethyan Himalaya igneous province”. Separation of the Tethyan Himalaya from the Indian craton may have occurred during ongoing Early Cretaceous extension related to the Kerguelen mantle plume during the nascent stages of a global plate-reorganization event. If this is the case, our findings provide clues to the nature of the Tethyan Himalaya, challenging traditional view of the India–Asia single-stage collision model.

Experimental constraints on metasomatism of mantle wedge peridotites by hybridized adakitic melts

In this study, a series of high-pressure (1.5 GPa) and high-temperature (1000–1300 °C) experiments were performed to investigate the petrological imprints of adakitic metasomatism on mantle wedge peridotites. Reaction couples were prepared using a powdered adakite from Cerro Pampa, Argentina (Mg# ~0.7) placed in contact with a cored sample of medium-grained protogranular depleted spinel lherzolite from Pali Aike (Chile). Textural and chemical analyses of the run products allow us to identify key features of modal metasomatism by hybridized adakitic melts. The main changes in phase relations are associated with the following metasomatic reactions: incongruent dissolution of olivine and associated precipitation of secondary orthopyroxene, dissolution of primary spinel and subsequent replacement by secondary high-Cr spinel. In experiments with high water contents (9–12 wt%), precipitation of pargasitic amphibole also occurred, possibly at the expense of primary clinopyroxene. Neither phlogopite nor Ti-oxides were precipitated in any of these experiments. As expected, primary pyroxenes do not show evidence of being significantly altered following the interaction with the produced siliceous melts. Within the adakitic portion of the experimental charge, it was also observed the crystallization of secondary Ti-rich, Cr- and Na-poor diopsidic clinopyroxene, andesine plagioclase and, at low temperature, Fe-enriched secondary orthopyroxene. Considering textural criteria, we interpreted the formation of these minerals as crystallization products of the adakite component and not as true products of metasomatic reactions. The experimental results are used to discuss some of the petrological evidences presented to support modal metasomatism by slab-derived melts of mantle xenoliths extracted from several suprasubduction settings located around the Pacific Ring of Fire.

Geology and Petrology of the Intraplate Cenozoic Continental Basalts in the Transcaucasian Intermountain Area (Georgia)

ABSTRACT The Transcaucasian intermountain area is part of the Caucasus segment of the Alpine-Mediterranean mountain belt. The continental intraplate basalts of the study area range in age from 6.10 ± 0.20 to 6.40 ± 0.20 Ma. The basalt erupted from monogenetic volcanoes are formed by lava flows and their pyroclastic equivalents. They are generally characterized by low volumes, are predominantly subalkalic with minor alkaline composition. The ultramafic xenoliths have not been identified in the basalts. The basalts may be subdivided into porphyritic and oligophyric groups. Fractional crystallization plays an important role in the petrogenesis of basalts. Almost all the studied samples showed different degrees of fractionation of olivine ± plagioclase ± clinopyroxene. No significant contamination of basalts with upper continental crustal material was confirmed by Rb/Sr and Rb/Ba ratios or by Sr, Nd isotopic and geochemical composition (87Sr/86Sr = 0.703683-0.704531±2; 143Nd/144Nd = 0.512788-0.512848 ±10; 147Sm/144Nd = 0.1036-0.1144 ±2-3). The studied basalts display, compared to heavy rare earth elements (HREE), highly fractionated light rare earth elements (LREE) with La/Yb=9.25-24.00. This makes them similar to ocean island basalts (OIB), which is also evidenced by Ce/Pb, La/Nb, Zr/Nb, Zr/Y ratios. The Dy/Yb-La/Yb and Yb-La/Yb and 87Sr/86Sr-143Nd/144Nd ratios indicating a “mixed” evolution of basalt-forming magmas. The basalt feeding magma chambers of the Transcaucasian inter-mountain area seem to be formed from a mixture of partial melting of Normal-MORB (Mid-Ocean Ridge Basalt) type upper mantle (garnet and spinel lherzolite) and EMII type components with strong ocean island basalts (OIB)-like signature.

From mantle peridotites to hybrid troctolites: Textural and chemical evolution during melt-rock interaction history (Mt. Maggiore, Corsica, France)

Recent studies investigate the replacive formation of hybrid troctolites from mantle peridotites after multiple stages of melt-rock reaction. However, these studies are not conducted in a field-controlled geological setting displaying the clear evolution from the protolith to the end-product of the reactions. The Mt. Maggiore peridotitic body exposes a clear evolution from spinel lherzolite to plagioclase-bearing lithotypes (plagioclase peridotites, olivine-rich troctolites and troctolites) during two continuous episodes of melt-rock interaction. In the spinel facies, the reactive percolation of a LREE-depleted melt leads to the dissolution of mantle pyroxenes and the growth of olivine crystals, forming replacive spinel dunites. The progressive evolution from spinel lherzolite to harzburgite to replacive dunite is accompanied by a change of olivine Crystallographic Preferred Orientation (CPO), from axial-[100] in the lherzolite to axial-[010] olivine CPO in the dunites, indicative of deformation in presence of melt. The initial percolating melt composition is consistent with single melt increments after 6% partial melting of a depleted mantle source. Reactive melt percolation leads to a progressive enrichment in the melt M-HREE absolute concentrations, while preserving its LREE depletion, consistent with the enriched analyzed HREE composition of olivine in the spinel dunite.In the shallower plagioclase facies, the melts modified by reactive melt percolation impregnate the spinel-facies lithotypes, leading to the dissolution of olivine and crystallization of plagioclase and orthopyroxene in the peridotites. This impregnation stage is also observed in the spinel dunites, forming hybrid olivine-rich troctolites and troctolites. The dissolution-precipitation reactions forming hybrid troctolites cause a progressive textural evolution of the olivine matrix, with the disruption of deformed coarse grains into undeformed small rounded grains. This textural evolution is not accompanied by clear changes in the olivine CPO, indicating low instantaneous melt/rock ratios during the impregnation process. Olivine, plagioclase and clinopyroxene REE compositions analyzed in troctolite fit a process of impregnation with a progressive closure of the porosity (at decreasing melt mass), leading to the crystallization of trapped melt and REE enrichments during the last crystallization increments.

Petrology of spinel lherzolite xenoliths from Youkou volcano, Adamawa Massif, Cameroon Volcanic Line: mineralogical and geochemical fingerprints of sub-rift mantle processes

The basaltic maar of Youkou, situated in the Adamawa Volcanic Massif in the eastern branch of the continental segment of the Cameroon Volcanic Line, contains mantle-derived xenoliths of various types in pyroclastites. Spinel-bearing lherzolite xenoliths from the Youkou volcano generally exhibit protogranular textures with olivine (Fo89.4−90.5), enstatite (En89 − 91Fs8.7−9.8Wo0.82−1.13), clinopyroxene, spinel (Cr#Sp = 9.4–13.8), and in some cases amphibole (Mg# = 88.5–89.1). Mineral equilibration temperatures in the lherzolite xenoliths have been estimated from three–two pyroxene thermometers and range between 835 and 937 °C at pressures of 10–18 kbar, consistent with shallow mantle depths of around 32–58 km. Trends displayed by bulk-rock MgO correlate with Al2O3, indicating that the xenoliths are refractory mantle residues after partial melting. The degree of partial melting estimated from spinel compositions is less than 10%: evidences for much higher degrees of depletion are preserved in one sample, but overprinted by refertilization in others. Trace element compositions of the xenoliths are enriched in highly incompatible elements (LREE, Sr, Ba, and U), indicating that the spinel lherzolites underwent later cryptic metasomatic enrichment induced by plume-related hydrous silicate melts. The extreme fertility (Al2O3 = 6.07–6.56 wt% in clinopyroxene) and the low CaO/Al2O3 ratios in the spinel lherzolites suggest that they could not be a simple residue of partial melting of primitive mantle and must have experienced refertilization processes driven by the infiltration of carbonatite or carbonated silicate melts.

Petrogenesis of pillow basalts in West Junggar, NW China: Constraints from geochronology, geochemistry, and Sr–Nd–Pb isotopes

West Junggar is located at the southwest margin of the Central Asian Orogenic Belt and includes Silurian pillow basalts of the Mayilashan Formation. The petrogenesis and tectonic setting of these pillow basalts are important for the understanding of the tectonic evolution and metallogeny of the West Junggar area. This paper presents geochronological, geochemical, and whole‐rock Sr–Nd–Pb isotope data from the pillow basalts of the Mayilashan Formation. Zircon LA‐ICP‐MS U–Pb dating of a pillow basalt, which is in conformable contact with the chert, suggests that they were erupted at 437.2 ± 2.2 Ma marking the timing of generation of these rocks as Middle Silurian. Geochemically, all the pillow basalts bear the signature of ocean island basalt (OIB), and are characterized by alkaline affinity with high concentrations of TiO2 (3.28–4.12 wt.%), LILE and LREE enrichment and HREE depletion ((La/Yb)N = 5.5–7.3), with very weak Eu anomalies (Eu/Eu* = 0.96–1.06), and no obvious Nb, Ta, or Ti negative anomalies. Their Sr–Nd–Pb isotopic compositions ((87Sr/86Sr)I = 0.7037–0.7051, εNd(t) = 1.9–2.9, 206Pb/204Pbi = 17.74–18.22, 207Pb/204Pbi = 15.48–15.52, and 208Pb/204Pbi = 36.49–37.86) show Dupal‐like isotopic signature of ophiolites in the southern Paleo‐Asian Ocean. These characteristics indicate that the magmas were derived from a deep OIB reservoir, that is, a depleted but slightly heterogeneous asthenospheric mantle source with ~5–15% partial melting of garnet and spinel lherzolite. Our obtained results, in conjunction with previous published data, allow us to suggest that the alkaline pillow basalts formed in a seamount within an intraoceanic setting, where a larger number of seamounts with different ages occurred in the Paleo‐Asian Ocean.

Fluid‐Enhanced Annealing in the Subcontinental Lithospheric Mantle Beneath the Westernmost Margin of the Carpathian‐Pannonian Extensional Basin System

AbstractMantle xenoliths from the Styrian Basin Volcanic Field (Western Pannonian Basin, Austria) are mostly coarse granular amphibole‐bearing spinel lherzolites with microstructures attesting for extensive annealing. Olivine and pyroxene CPO (crystal‐preferred orientation) preserve nevertheless the record of coeval deformation during a preannealing tectonic event. Olivine shows transitional CPO symmetry from [010]‐fiber to orthogonal type. In most samples with [010]‐fiber olivine CPO symmetry, the [001] axes of the pyroxenes are also dispersed in the foliation plane. This CPO patterns are consistent with lithospheric deformation accommodated by dislocation creep in a transpressional tectonic regime. The lithospheric mantle deformed most probably during the transpressional phase after the Penninic slab breakoff in the Eastern Alps. The calculated seismic properties of the xenoliths indicate that a significant portion of shear wave splitting delay times in the Styrian Basin (0.5 s out of approximately 1.3 s) may originate in a highly annealed subcontinental lithospheric mantle. Hydroxyl content in olivine is correlated to the degree of annealing, with higher concentrations in the more annealed textures. Based on the correlation between microstructures and hydroxyl content in olivine, we propose that annealing was triggered by percolation of hydrous fluids/melts in the shallow subcontinental lithospheric mantle. A possible source of these fluids/melts is the dehydration of the subducted Penninic slab beneath the Styrian Basin. The studied xenoliths did not record the latest large‐scale geodynamic events in the region—the Miocene extension then tectonic inversion of the Pannonian Basin.

Geochronology and geochemistry of the Huilvshan gabbro in west Junggar (NW China): Implications for magma process and tectonic regime

Gabbro plutons, consisting of clinopyroxene and plagioclase with trace amounts of magnetite, titanite, and apatite, intruded into Early Carboniferous volcanic-sedimentary strata in the Huilvshan gold mining region (west Junggar, China). Samples collected from two gabbro bodies are tholeiitic in composition with low concentrations of Na2O + K2O, showing weak depletions of light rare earth elements with insignificant Eu, Nb, and Ti anomalies. Zircon U-Pb analyses yield a weighted average U-Pb age of 296.1 ± 2.7 Ma (MSWD = 0.98), which could represent the time corresponding to mafic magma emplacement in the Huilvshan region. Geochemical calculations suggest that this mafic magma was derived from a depleted mantle source in a post-collisional tectonic setting corresponding to ~ 4% partial melting of spinel lherzolite.

Composition of the lithospheric mantle in the northern part of Siberian craton: Constraints from peridotites in the Obnazhennaya kimberlite

The character of the lithospheric mantle of the northern Siberian craton is not well established; nearly all published data are for mantle xenoliths from a single kimberlite in the center of the craton (Udachnaya). We report major elements of the whole rock, trace elements data of clinopyroxene and Re-Os isotope and PGE concentration of mantle xenoliths from the Obnazhennaya kimberlite pipe (160Ma) in the northern part of Siberian craton. The Obnazhennaya mantle xenoliths include spinel harzburgites, spinel dunites, spinel lherzolites and spinel-garnet lherzolite. The spinel harzburgites and dunites have refractory compositions, with 0.23–1.35wt% Al2O3, 0.41–3.11wt% CaO and 0.00–0.09wt% TiO2, whereas the lherzolites (both spinel- and spinel-garnet-) have more fertile compositions, containing 2.16–6.55wt% Al2O3, 2.91–7.55wt% CaO and 0.04–0.15wt% TiO2. The trace element compositions and mineralogical textures of the Obnazhennaya xenoliths indicate the occurrence of metasomatic enrichments, including carbonatite melts, basaltic melts from Siberian Trap and kimberlitic melts. The spinel harzburgites and dunites have 187Os/188Os of 0.11227–0.11637, giving a TRD age of 1.6–2.2Ga. This suggests that old cratonic mantle still existed beneath the Obnazhennaya. In contrast, both spinel and spinel-garnet lherzolites have more radiogenic 187Os/188Os ratios (0.11931–0.17627), enriched P-PGEs. But the higher Al2O3 and Os character of these lherzolites suggest that they were not juvenile mantle but the refertilized ancient mantle. Therefore, our results suggest that the cratonic mantle beneath the northern part of Siberian craton contain both ancient and reworked lithospheric mantle, and the metasomatism may not be effective at overprinting/eroding the pre-existing lithosphere.

Lithospheric magma dynamics beneath the El Hierro Volcano, Canary Islands: insights from fluid inclusions

At active volcanoes, petrological studies have been proven to be a reliable approach in defining the depth conditions of magma transport and storage in both the mantle and the crust. Based on fluid inclusion and mineral geothermobarometry in mantle xenoliths, we propose a model for the magma plumbing system of the Island of El Hierro (Canary Islands). The peridotites studied here were entrained in a lava flow exposed in the El Yulan Valley. These lavas are part of the rift volcanism that occurred on El Hierro at approximately 40–30 ka. The peridotites are spinel lherzolites, harzburgites, and dunites which equilibrated in the shallow mantle at pressures between 1.5 and 2 GPa and at temperatures between 800 and 950 °C (low-temperature peridotites; LT), as well as at higher equilibration temperatures of 900 to 1100 °C (high-temperature peridotites; HT). Microthermometry and Raman analyses of fluid inclusions reveal trapping of two distinct fluid phases: early type I metasomatic CO2-N2 fluids (X N2 = 0.01–0.18; fluid density (d) = 1.19 g/cm3), coexisting with silicate-carbonate melts in LT peridotites, and late type II pure CO2 fluids in both LT (d = 1.11–1.00 and 0.75–0.65 g/cm3) and HT (d = 1.04–1.11 and 0.75–0.65 g/cm3) peridotites. While type I fluids represent metasomatic phases in the deep oceanic lithosphere (at depths of 60–65 km) before the onset of magmatic activity, type II CO2 fluids testify to two fluid trapping episodes during the ascent of xenoliths in their host mafic magmas. Identification of magma accumulation zones through interpretation of type II CO2 fluid inclusions and mineral geothermobarometry indicate the presence of a vertically stacked system of interconnected small magma reservoirs in the shallow lithospheric mantle between a depth of 22 and 36 km (or 0.67 to 1 GPa). This magma accumulation region fed a short-lived magma storage region located in the lower oceanic crust at a depth of 10–12 km (or 0.26–0.34 GPa). Following our model, the 40–30-ka-old volcanic activity of El Hierro is related to this mantle-based magma system, a system that we propose fed the recent 2011–2012 eruption.

Geochemistry and geochronology of the Mesozoic Lanong ophiolitic mélange, northern Tibet: Implications for petrogenesis and tectonic evolution

The Lanong ophiolitic mélange is a typical ophiolitic mélange in the middle section of the Bangong–Nujiang suture zone in northern Tibet. It mainly consists of ultramafic and mafic rocks, and its tectonic setting and formation age remain poorly constrained. In this paper, new geochemical and LA–ICP–MS (laser ablation–inductively coupled plasma mass spectrometer) zircon U–Pb age data obtained from gabbro, gabbro–dolerite, dolerite and basalt of the Lanong ophiolitic mélange are provided. The pillow basalts exhibit N-MORB (normal mid-ocean ridge basalt)-like geochemical features with a zircon U–Pb age of 147.6±2.3Ma. They were generated by ~20–30% partial melting of a depleted mantle source composed of spinel lherzolite. The gabbro, massive basalt and gabbro–dolerite samples are characterised by more depleted and “V”-shaped REE (rare earth element) patterns, and they exhibit variable degrees of boninite-like geochemical characteristics, with a zircon U–Pb age of 149.1±1.2Ma (gabbro-dolerite). They were derived from the remelting of a significantly refractory mantle source following one or more episodes of previous basaltic melt extraction. Geochemical data of these mafic rocks indicate that they were developed in a continental fore-arc setting, and magmas were derived from depleted mantle sources modified by subducted slab-derived fluids and melts with minor crustal contamination. On the other hand, the dolerites show distinct OIB (oceanic island basalt)-like geochemical features, with a zircon U–Pb age of 244.1±3.0Ma. They were formed in a rift setting on a continental shelf-slope and originated from a low degree of partial melting of a depleted asthenospheric magma source mixed with some ancient sub-continental lithospheric mantle materials. The signatures presented here, combined with the results of previous studies, suggest that the Lanong ophiolitic mélange probably developed in a convergent plate margin under the southward subduction of the Bangong–Nujiang Tethys Ocean beneath the Lhasa terrane during the Middle Triassic–Early Cretaceous. Namely, the OIB-like dolerites likely reflect an extensional rift setting featuring thin continental crust in the Middle Triassic, and the gabbros, gabbro–dolerites and basalts represent a later stage of a fore-arc basin during the Late Jurassic–Early Cretaceous.

Mesozoic decratonization of the North China Craton by lithospheric delamination: Evidence from Sr-Nd-Hf-Os isotopes of mantle xenoliths of Cenozoic alkaline basalts in Yangyuan, Hebei Province, China

Mineral compositions, clinopyroxene trace-element and Sr-Nd-Hf isotopic compositions, whole-rock major element and platinum group element (PGE) contents, and Re-Os isotopes are reported for peridotite xenoliths in the Cenozoic alkali basalts from Yangyuan, Hebei Province (China), in order to constrain the nature of the subcontinental lithospheric mantle beneath the central part of the North China Craton, and further to investigate the mechanism of decratonization. The xenoliths mainly consist of spinel lherzolites and minor spinel pyroxenites and spinel harzburgites with equilibration temperatures of 890–1060°C. The olivine in these xenoliths have Mg number (%Fo) ranging from 88.2 to 91.6. According to the chemical characteristics, two groups of peridotites can be identified, i.e., group 1 are spinel lherzolites and spinel harzburgite that are depleted in Pt, Pd and Re (i.e., P-PGEs) relative to Os, Ir and Ru (i.e., I-PGEs) and their clinopyroxenes are depleted in light rare earth elements (LREEs), whereas, Group II are spinel lherzolites that are enriched in P-PGEs relative to I-PGEs and their clinopyroxenes are enriched in LREEs relative to HREEs. The spinel lherzolites have radiogenic 187Os/188Os ratios ranging from 0.1182 to 0.1262, whereas, the spinel harzburgites have relatively low 187Os/188Os ratios with Proterozoic model ages. Clinopyroxenes in the peridotite xenoliths have variable but relatively unradiogenic Sr (87Sr/86Sr=0.7026–0.7046) and radiogenic Nd (εNd=+2.0 to +14.7) and Hf (εHf=+8.8 to +37.9) isotopic compositions. All these geochemical features indicate that the subcontinental lithospheric mantle beneath Yangyuan had experienced variable degrees of melt extraction and mantle metasomatism by the silicate melts represented by spinel pyroxenites. The spinel pyroxenites are enriched in LREEs and P-PGEs relative to HREEs and I-PGEs. Clinopyroxenes in pyroxenite xenoliths have high 87Sr/86Sr ratios of 0.7054–0.7063, negative εNd (−3.4 to −15.8) and εHf (−2.0 to −22.0) values, and high 187Os/188Os ratios of 0.2196–0.3343, indicating that the silicate melts were derived from ancient lower continental crustal materials. Our data suggest that the lithospheric mantle beneath Yangyuan had been metasomatized by silicate melts derived from recycled ancient lower crust, indicating that decratonization of the North China Craton was possibly induced by delamination of the lower crust and lithospheric mantle.

Geochemistry and tectonic setting of triassic magmatism from the Lercara Basin (Sicily, Italy)

Petrological and geochemical data of Triassic magmatic rocks from Lercara Basin (Central Sicily), are discussed to provide new information about the intraplate volcanism related to the Pangea break up. The magmatic rocks crop out as subvolcanic bodies and are packed in several Lower Triassic clayey lithologies correlated to the sedimentation into the Imerese and Sicano domains. The samples were divided in two groups. The first group includes transitional to alkaline basalts, with crystalline sub - ophitic texture mainly characterized by plagioclase, clino- and orthopyroxene, and olivine crystals. The second group includes more altered rocks, with porphyritic texture, showing alkali basaltic to phonolitic compositions. Major and trace element data of single groups show small variations indicating fractional crystallization processes. Abundances and ratios of incompatible trace elements indicate that rocks were formed in an intraplate continental environment from different mantle sources with E-MORB to OIB-type compositions. Low degrees of partial melting at the transition between spinel and garnet lherzolite fields can be hypothesized for parental magmas of the Lercara Basin. Magmas ascended to the surface as various batches of magmas along lithospheric fractures originated by flexure and uplift of the Mesozoic Pangea supercontinent.