Spin Structure Research Articles

Mechanisms of Electrical Switching of Ultrathin CoO/Pt Bilayers.

We study current-induced switching of the Néel vector in CoO/Pt bilayers to understand the underlying antiferromagnetic switching mechanism. Surprisingly, we find that for ultrathin CoO/Pt bilayers electrical pulses along the same path can lead to an increase or decrease of the spin Hall magnetoresistance signal, depending on the current density of the pulse. By comparing these results to XMLD-PEEM imaging of the antiferromagnetic domain structure before and after the application of current pulses, we reveal the details of the reorientation of the Néel vector in ultrathin CoO(4 nm). This allows us to understand how opposite resistance changes can result from a thermomagnetoelastic switching mechanism. Importantly, our spatially resolved imaging shows that regions where the current pulses are applied and regions further away exhibit different switched spin structures, which can be explained by a spin-orbit torque-based switching mechanism that can dominate in very thin films.

Machine-learning-based detection of spin structures

Machine-learning-based detection of spin structures

Magnetic structure of a multiferroic compound: Cu2OCl2.

The Cu2OCl2 compound has been shown to be a high-temperature spin-driven multiferroic system, with a linear magneto-electric coupling. In this paper we propose a complete study of its magnetic structure. We derive the low energy magnetic Hamiltonian using ab initio multi-reference configuration interaction and the spin structure using Monte-Carlo simulations. Among the three magnetic structures proposed in the literature from different experimental results, our calculations support the incommensurate cycloid magnetic structure with a q⃑ = (qa,0,0) propagation vector. Using symmetry analysis, we show that all experimental results (polarization, magnetic order, magneto-electric coupling) can be accounted for in the Fd'd'2 magnetic space group (2-fold axis along c⃑).

Experimental research progress of charge order of nickelate based superconductors

Ever since the discovery, nickelate superconductors have attracted great attention, declaring a “nickel age” of superconductivity. Currently, there are two types of nickelate superconductors: low-valence nickelate superconductors RE<sub><i>n</i>+1</sub>Ni<sub><i>n</i></sub>O<sub>2<i>n</i>+2</sub> (RE, rare earth; <i>n</i>, number of adjacent NiO<sub>2</sub> layers) and high-pressure nickelate superconductors La<sub>3</sub>Ni<sub>2</sub>O<sub>7</sub> and La<sub>4</sub>Ni<sub>3</sub>O<sub>10</sub>. Charge order plays a crucial role in studying the strongly correlated systems, especially the cuprate superconductors, in which potential correlation between charge order and superconductivity has been indicated. Thus, great efforts have been made to explore the charge order in nickelate superconductors. In the infinite-layer nickelate RENiO<sub>2</sub>, the evidence of charge order with in-plane wavevector of <i> <b>Q</b> </i><sub>//</sub> ≈ (1/3, 0) has been found in the undoped and underdoped regime but not in the superconducting samples. However, subsequent studies have indicated that this is not the true charge order inherent in the NiO<sub>2</sub> plane,which carries unconventional superconductivity, but rather originates from the ordered excess apical oxygen in the partially reduced impurity phases. On the other hand, the overdoped low-valence nickelate La<sub>4</sub>Ni<sub>3</sub>O<sub>8</sub> shows well-defined intertwined charge and magnetic order, with an in-plane wavevector of <i> <b>Q</b> </i><sub>//</sub> = (1/3, 1/3). Resonant X-ray scattering study has found that nickel orbitals play the most important role in the multi-orbital contribution of charge order formation in this material, which is significantly different from the cuprates with oxygen orbitals dominating the charge modulation. Although the spin order in La<sub>3</sub>Ni<sub>2</sub>O<sub>7</sub> has been well established, there is still controversy over its spin structure and the existence of coexisting charge order. In La<sub>4</sub>Ni<sub>3</sub>O<sub>10</sub>, intertwined charge and spin density waves have been reported, the origin and characteristics of which remain unknown. Owing to the research on the nickelate superconductors just starting, many questions have not yet been answered, and the exploration of charge order in nickelate superconductors will still be the center of superconductor research.

МОЛЕКУЛЯРНЫЙ ИОН ВОДОРОДА𝑯𝟐+. МАГНИТНЫЕ M1 ПЕРЕХОДЫ

The magnetic dipole transitions in the homonuclear molecular ion 𝐻2+are obtained for a range ofand L, vibrational and total orbital momentum quantum numbers, respectively. Calculations are performed in the nonrelativistic approximation. The effects of the ion spin structure on M1 transitions are also considered. Numerical calculations were carried out on the basis of “exponential” variational expansion. One of the simplest and most fully developed areas of application of quantum mechanics is the theory of atoms with one or two electrons. For hydrogen and hydrogen-like ions, calculations can be performed strictly in both Schrödinger's non-relativistic wave mechanics and Dirac's relativistic electron theory. The exact calculations are rigorous for an electron at a fixed Coulomb potential. Therefore, the hydrogen-like atom provides an excellent material for testing the validity of quantum mechanics. For such an atom, the correction terms that take into account the motion and structure of the atomic nucleus, as well as quantum electrodynamic effects, are small and can be calculated with great accuracy. Since the energy levels of hydrogen and hydrogen-like atoms can be experimentally studied with anamazing degree of accuracy, it turns out that it is possible to test the correctness of quantum electrodynamics to some extent accurately.

A nested spin structure and single molecule magnet behaviour in an Fe8Dy12 heterometallic cyclic coordination cluster.

The 20-nuclearity compound [Fe8Dy12(tea)8(teaH)12(NO3)12]·8MeCN (where teaH3 = triethanolamine) was synthesised and characterised through single crystal X-ray diffraction and magnetic measurements. The shape of the magnetic hysteresis in the microSQUID measurements was rationalised using the MAGELLAN program.

Introducing antiferromagnetic ordering on the surface states of a Bi2Se3 topological insulator by europium doping

Topological insulators (TIs) are materials with an insulating bulk characterized by a gapped band structure, along with gapless metallic surface states having a Dirac cone with a helical spin structure in momentum space.

Preparation, Magnetic and Transport Properties of Mn3Sn Single Crystal

Topological antiferromagnetic Mn3Sn crystals exhibit notable magnetic and transport properties, comparable to ferromagnets, and undergo various intriguing magnetic phase transitions during heating or cooling. The spin structures of Mn3Sn crystals...

Coherent spin-control of S = 1 vanadium and molybdenum complexes.

The burgeoning field of quantum sensing hinges on the creation and control of quantum bits. To date, the most well-studied quantum sensors are optically active, paramagnetic defects residing in crystalline hosts. We previously developed analogous optically addressable molecules featuring a ground-state spin-triplet centered on a Cr4+ ion with an optical-spin interface. In this work, we evaluate isovalent V3+ and Mo4+ congeners, which offer unique advantages, such as an intrinsic nuclear spin for V3+ or larger spin-orbit coupling for Mo4+, as optically addressable spin systems. We assess the ground-state spin structure and dynamics for each complex, illustrating that all of these spin-triplet species can be coherently controlled. However, unlike the Cr4+ derivatives, these pseudo-tetrahedral V3+ and Mo4+ complexes exhibit no measurable emission. Coupling absorption spectroscopy with computational predictions, we investigate why these complexes exhibit no detectable photoluminescence. These cumulative results suggest that design of future V3+ complexes should target pseudo-tetrahedral symmetries using bidentate or tridentate ligand scaffolds, ideally with deuterated or fluorinated ligand environments. We also suggest that spin-triplet Mo4+, and by extension W4+, complexes may not be suitable candidate optically addressable qubit systems due to their low energy spin-singlet states. By understanding the failures and successes of these systems, we outline additional design features for optically addressable V- or Mo-based molecules to expand the library of tailor-made quantum sensors.

Angular-dependent magnetoresistance modulated by interfacial magnetic state in Pt/LSMO heterostructures.

The interfaces between heavy metals and antiferromagnetic materials have garnered significant attention due to their interesting physical properties. La0.35Sr0.65MnO3 (LSMO), as a typical manganite, exhibits an antiferromagnetic ground state that can be controlled through epitaxial strain and interfacial spin-orbit coupling. In this work, we reported the diverse magnetoresistance, influenced by the interfacial magnetic state, in Pt (3 nm)/LSMO (6-20 nm) heterostructures. The strong spin-orbit coupling of Pt and Dzyaloshinskii-Moriya interaction alter the spin structure and enhance the electron scattering at the Pt/LSMO interface, resulting in positive magnetoresistance. The interfacial angular-dependent magnetoresistance modulated by the interfacial magnetic states was also observed in the Pt/LSMO (20 nm) heterostructures. Our findings contribute to a broader understanding of interfacial properties between heavy metals and antiferromagnetic manganites.

Crystal structure and magnetic properties ferrites Ba-Fe-O, Bi-Fe-O, synthesized in NGO “Physics-Sun”

Alloys based on Ba-Fe-O have been synthesized in a large solar furnace NGO “Physics-Sun”. The obtained barium hex ferrite with magnetic characteristics suitable for solving technical problems for the manufacture of protective coatings. The experimentally observed increase in the specific magnetization of BiFe0.75Ni0.25O3 with respect to the data obtained in nominally pure bismuth ferrite is associated both with the suppression of the cycloidal spin structure due to the partial substitution of nickel cations for iron cations and with the establishment of ferromagnetic exchange interaction between neighboring Fe3+ and Ni3+ ions. The results of ab initio (LSDA + U approximation of the DFT method) calculations of the band structure suggest that in the ground state BiFe0.75Ni0.25O3 is a semiconductor with a band gap of 1.94 eV.

Exploring the spin structure of the nucleon at STAR

Understanding the internal spin structure of the nucleon remains a challenge in strong interaction physics. The unique capability of RHIC opened new avenues in studying the internal structure of the proton with unprecedented depth and precision. Significant progress has been made in the last few years through various measurements at STAR. The longitudinal spin measurements have contributed significantly to our understanding of the quark and gluon helicity distributions inside the proton. The longitudinal double-spin asymmetry, ALL, from STAR inclusive jet and dijet measurements provides the first evidence of a positive gluon polarization with partonic momentum fraction x > 0.05. The reconstruction of W±/Z in longitudinally polarized proton-proton collisions indicates that there is a flavor separation of the light sea quark helicity distributions. In transversely polarized proton collisions, W±/Z-bosons provide the first constraint on the sea-quark Sivers function and contributes to the tests of the predicted sign change. The tilt of the dijet opening angle provides a direct access to the first Mellin momentum of the Sivers function and avoids the spin-correlated fragmentation contributions. The novel measurements of the azimuthal distributions of identified hadrons in jets and spin-dependent dihadron correlations directly probe the collinear quark transversity in the proton, with the former coupled to the transverse momentum dependent (TMD) Collins fragmentation function and the latter to the dihadron interference fragmentation function. These measurements shed lights on Sivers function, quark transversity and spin-dependent fragmentation functions in both collinear and TMD formalism. In this proceeding, recent jet results on both the longitudinal and transverse spin structure of the proton from STAR are presented.

Binuclear methylphosphinidine complexes of cyclopentadienylruthenium carbonyls: effects of the higher ligand field strength of ruthenium derivatives relative to iron derivatives.

The structures and energetics of the binuclear methylphosphinidene complexes of cyclopentadienylruthenium carbonyls of the type [MePRu2(CO)nCp2] (n = 4, 3, 2, 1) have been investigated for comparison with their previously studied iron analogues. For the tetracarbonyls and tricarbonyls [MePM2(CO)nCp2] (n = 4, 3) substituting ruthenium for iron has relatively little effect on the energetically preferred structures. Thus such structures have two-electron donor bridging MeP groups with no metal-metal bond for the tetracarbonyls and a metal-metal single bond for the tricarbonyls. This leads to favored 18-electron configurations for both ruthenium atoms in all cases. However, the higher ligand field strengths of ruthenium complexes relative to analogous iron complexes have major effects on the energetically preferred structures for the dicarbonyls and monocarbonyls [MePM2(CO)nCp2] (M = Fe, Ru; n = 2, 1). Thus the 11 lowest energy structures for the dicarbonyl [MePFe2(CO)2Cp2] are triplet or quintet spin state structures whereas the 6 lowest energy structures for the ruthenium analogue [MePRu2(CO)2Cp2] are all singlet structures. These low-energy singlet [MePRu2(CO)2Cp2] structures include species in which both ruthenium atoms attain the favored 18-electron configurations in different ways: either by a Ru-Ru single bond and an agostic C-H-Ru interaction from the methyl group, a Ru-Ru single bond and a four-electron donor bridging MeP ligand with PRu double bonds, or a formal RuRu double bond with a two-electron donor bridging MeP ligand. The 8 lowest energy structures for the diiron monocarbonyl [MePFe2(CO)Cp2] are all triplet or quintet spin structures whereas the lowest energy structure for the diruthenium monocarbonyl [MePRu2(CO)Cp2] by more than 20 kcal mol-1 is a singlet structure with a formal RuRu double bond and bridging CO and four-electron donor MeP groups. Thermochemical information predicts such monocarbonyl derivatives to be the dominant binuclear decarbonylation products of the tricarbonyls [RPRu2(CO)3Cp2] by thermal or photochemical methods.

Realism, irrationality, and spinor spaces

Mathematics, as Eugene Wigner noted, is unreasonably effective in physics. The argument of this paper is that the disproportionate attention that philosophers have paid to discrete structures such as the natural numbers, for which a nominalist construction may be possible, has deprived us of the best argument for Platonism, which lies in continuous structures—in fields and their derived algebras, such as Clifford algebras. The argument that Wigner was making is best made with respect to such structures—in a loose sense, with respect to geometry rather than arithmetic. The purpose of the present paper is to make this connection between mathematical realism and geometrical entities. It thus constitutes an argument against formalism, for which mathematics is merely a game with humanly set rules; and nominalism, in which whatever mathematics is used is eliminable in the final analysis, by often insufficiently specified means. The hope is that light may be cast on the stubborn mysteries of the nature of quantum mechanics and its mathematical formulation, with particular reference to spinor representations—as they have been developed by Andrej Trautman. Thus, according to our argument, quantum mechanics (QM) may appear more natural, as we have better reasons to take spinor structures as irreducibly real, a view consonant with the work of Trautman and Penrose in particular.

Origin of the Magnetic Exciton in the van der Waals Antiferromagnet NiPS_{3}.

An ultrasharp photoluminescence line intimately related to antiferromagnetic order has been found in NiPS_{3}, a correlated van der Waals material, opening prospects for magneto-optical coupling schemes and spintronic applications. Here we unambiguously clarify the singlet origin of this excitation, confirming its roots in the spin structure. Based on a comprehensive investigation of the electronic structure using angle-resolved photoemission and q-dependent electron energy loss spectroscopy as experimental tools we develop, in a first step, an adequate theoretical understanding using density functional theory (DFT). In a second step the DFT is used as input for a dedicated multiplet theory by which we achieve excellent agreement with available multiplet spectroscopy. Our Letter connects the understanding of the electronic structure and of optical processes in NiPS_{3} and related materials as a prerequisite for further progress of the field.

Singular spin structures and superstrings

There are two main problems in finding the higher genus superstring measure. The first one is that for g ≥ 5 the super moduli space is not projected. Furthermore, the supermeasure is regular for g ≤ 11, a bound related to the source of singularities due to the divisor in the moduli space of Riemann surfaces with even spin structure having holomorphic sections, such a divisor is called the θ-null divisor. A result of this paper is the characterization of such a divisor. This is done by first extending the Dirac propagator, that is the Szegö kernel, to the case of an arbitrary number of zero modes, that leads to a modification of the Fay trisecant identity, where the determinant of the Dirac propagators is replaced by the product of two determinants of the Dirac zero modes. By taking suitable limits of points on the Riemann surface, this holomorphic Fay trisecant identity leads to identities that include points dependent rank 3 quadrics in ℙg−1. Furthermore, integrating over the homological cycles gives relations for the Riemann period matrix which are satisfied in the presence of Dirac zero modes. Such identities characterize the θ-null divisor. Finally, we provide the geometrical interpretation of the above points dependent quadrics and show, via a new θ-identity, its relation with the Andreotti-Mayer quadric.

Quantum criticality features in the Co,Fe doped MnSi

An universal line revealing an independence of spin fluctuation contributions to the heat capacity on impurity content and its nature is discovered in the helical phase of Mn(Co,Fe)Si. This situation declares an invariance of the heat capacity of spin subsystem under doping, which probably arises as a result of relative stiffness of the helical spin structure in respect to the impurity spins. On the other hand the situation drastically changes at the helical fluctuation region when no long range spin order exists. At low temperatures the spin fluctuation contributions to the heat capacity for a whole set of compositions of Mn(Co,Fe)Si are described by a single power expression with an exponent less then unity, which implies divergence of the ratio Cp/T at T→0. The current data are revealing that a singular quantum critical point does not exist in the system under study. In its place, one can see some sort of a quantum critical cloud covering a significant range of dopant concentrations.

Model' spinovogo stekla dlya kvantovykh yam GaAs/AlGaAs, legirovannykh nemagnitnymi primesyami, vblizi perekhoda metall–izolyator

In a previous report, we presented experiments which suggested that ferromagnetic ordering of the spins of localized holes in GaAs/AlGaAs quantum wells could be observed when doped with shallow (Be) acceptors at impurity concentrations near the metal-insulator transition. The compensating impurity (Si) was introduced into a narrow region at the center of the barriers [4]. In this paper, we present results from magnetotransport experiments performed on similar structures, but without the compensating impurity (Si). In these samples, the compensation degree is expected to be controlled by the background defects located at the edges of the quantum wells and within the barriers. At low temperatures T ≤ 10 K, we observed isotropic, linear magnetoresistance, anomalous behavior of the Hall effect as a function of the magnetic field, and slow relaxation of resistance after the application of a magnetic field. We explain this anomalous magnetotransport as the manifestation of a ferromagnetic transition or spin glass, originating from indirect spin exchange between localized holes on impurities near the metal-insulator transition. However, we note that perfect disorder, including signs of interspin interactions, leads to unstable configurations. In what follows, we present a model in which we start with this perfect disorder, but apply a procedure to obtain a stable configuration. We show that the resulting spin structure, a “closely packed” structure of “droplets,” can reproduce the features observed in the experiment, particularly isotropic, linear magnetoresistance.

CO2‐Induced Strong Room‐Temperature Ferromagnetism in BiFeO3

AbstractWith humongous demand for data storage and processing, two‐dimensional (2D) ferromagnetic‐based materials, is emerged as the next‐generation nanoelectronic devices due to their low power consumption and optimal memory and processing capabilities. BiFeO3 as a single‐phase multiferromagnetic material is expected to find potential applications in electromagnetic devices. Herein, 2D room‐temperature ferromagnetic BiFeO3 is obtained with the help of supercritical carbon dioxide (SC CO2). The rhombic phase of BiFeO3 is converted to cubic with the creation of Ov and Fe2+ defects over the SC CO2 treatment, leading to significant ferromagnetic enhancement. More importantly, it is found that SC CO2 can destroy the cycloidal spin structure of BiFeO3 leading to an increase in the Fe─O─Fe bond angle, which generates stronger superexchange interactions. Ultimately, the saturation magnetization strength of BiFeO3 is increased by nearly 23 times. A new strategy is provided for ferromagnetic induction in 2D materials, which is favorable for promoting their practical applications on device architectures in the future.

Large Room-Temperature Magnetoresistance in a High-Spin Donor-Acceptor Conjugated Polymer.

Open-shell conjugated polymers (CPs) offer new opportunities for the development of emerging technologies that utilize the spin degree of freedom. Their light-element composition, weak spin-orbit coupling, synthetic modularity, high chemical stability, and solution-processability offer attributes that are unavailable from other semiconducting materials. However, developing an understanding of how electronic structure correlates with emerging transport phenomena remains central to their application. Here, the first connections between molecular, electronic, and solid-state transport in a high-spin donor-acceptor CP, poly(4-(4-(3,5-didodecylbenzylidene)-4H-cyclopenta[2,1-b:3,4-b']dithiophen-2-yl)-6,7-dimethyl-[1,2,5]-thiadiazolo[3,4-g]quinoxaline), are provided. At low temperatures (T < 180 K), a giant negative magnetoresistance (MR) is achieved in a thin-film device with a value of -98% at 10 K, which surpasses the performance of all other organic materials. The thermal depopulation of the high-spin manifold and negative MR decrease as temperature increases and at T > 180 K, the MR becomes positive with a relatively large MR of 13.5% at room temperature. Variable temperature electron paramagnetic resonance spectroscopy and magnetic susceptibility measurements demonstrate that modulation of both the sign and magnitude of the MR correlates with the electronic and spin structure of the CP. These results indicate that donor-acceptor CPs with open-shell and high-spin ground states offer new opportunities for emerging spin-based applications.