Spin Reversal Research Articles

The effect of pressure on the physical properties of ScFe2 Laves phases

The physical properties of ScFe2 Laves phases with cubic (C15) and hexagonal (C14, C36) structures under ambient and high pressures are studied using the first-principles method and provide a comprehensive and in-depth analysis of the magnetic, elastic and dynamical properties. The spin magnetic moments of three structures decrease as pressure increases, and in the C36 structure, the spin reversal of Fe (6h) moment near 90 GPa is found. The critical pressures of magnetic collapse for the C14, C15 and C36 structures are 90, 160, and 170 GPa, respectively. The C15 structure is the most thermodynamically stable phase below 44.4 GPa, and a phase transition from C15 to C14 structure is observed. In the thermodynamic stability pressure range, with 0–44.4 GPa for C15 structure and 44.4–90 GPa for C14 structure, the C15 and C14 structures are both dynamically and mechanically stable. The C14 and C15 structures under high pressure are ductile structures with significant differences in elastic properties and anisotropy. Finally, the Debye temperature and sound velocity under high pressure are discussed in detail.

Alcohol-bridged dinuclear dysprosium single-molecule magnets

Herein we showcase triple-bridged symmetric dinuclear dysprosium complexes with the core structure of general chemical formula Dy2(L1)2(L2)2(R-OH) (R = Me, 1; Et, 2; iPr, 3; pHCH2, 4) involving bridging alcohol molecules. L1 and L2 represent the deprotonated form of oxazole 4‑tert‑butyl‑2-(7-methoxybenzo[d]oxazol-2-yl)phenol and Schiff-base (E)-2,4-di‑tert‑butyl‑6-((3,5-di‑tert‑butyl‑2-hydroxybenzylidene)amino)phenol, respectively. Single-crystal X-ray structural characterization revealed an unprecedented long Dy-O bond length for the benzyl alcohol analogue. The corresponding long Dy-O bond lengths in 1–4 are 2.7825, 2.6651, 2.6021 and 2.9955 Å, respectively. Alternating current magnetic susceptibility measurements at zero dc field revealed that all four complexes display clear frequency dependence signal peaks, indicating single-molecule magnet behavior. The spin reversal energy barrier heights for 1, 2 and 4 are 31.1, 27.6 and 17.4 K. The dynamic magnetic behavior is influenced by the different Dy-O bond lengths derived from the bridging alcohol molecules. Theoretical calculations were employed to establish magneto-structural correlations in 1–4. Magneto-structural correlations with respect to the alcohol molecule participating in triple-bridged symmetric dinuclear dysprosium complexes is established with the help of quantum-chemical calculations.

Modulating Magnetic Performance in DyIII Single Ion Magnets With N5O2 Ligands

ABSTRACT[Dy (LMe)(H2O)]CF3SO3·0.25H2O (1·0.25H2O), where H2LMe is the reported ligand 2,2′‐(((pyridine‐2,6‐diylbis (methylene))bis((pyridin‐2‐ylmethyl)azanediyl))bis (methylene))bis(4‐methylphenol), shows the DyIII ion in an N5O3 environment, with triangular dodecahedral geometry (D2d symmetry). 1·0.25H2O is a single ion magnet (SIM) with an energy barrier for spin reversal of 510 K, and open hysteresis loops up to 8 K. The magnetostructural comparison of 1·0.25H2O with some closely related complexes and with other eight‐coordinated SIMs with high energy barriers (> 300 K) allows to draw some conclusions to enhance the magnetic performance in these nanomagnets with non‐purely axial geometries. Ab initio calculations complement and support the experimental results.

Single-Ion Magnetism of the [DyIII(hfac)4]- Anions in the Crystalline Semiconductor {TSeT1.5}●+[DyIII(hfac)4]- Containing Weakly Dimerized Stacks of Tetraselenatetracene.

The oxidation of tetraselenatetracene (TSeT) by tetracyanoquinodimethane in the presence of dysprosium(III) tris(hexafluoroacetylacetonate), DyIII(hfac)3, produces black crystals of {TSeT1.5}●+[DyIII(hfac)4]- (1) salt, which combines conducting and magnetic sublattices. It contains one-dimensional stacks composed of partially oxidized TSeT molecules (formal averaged charge is +2/3). Dimers and monomers can be outlined within these stacks with charge and spin density redistribution. The spin triplet state of the dimers is populated above 128 K with an estimated singlet-triplet energy gap of 542 K, whereas spins localized on the monomers show paramagnetic behavior. A semiconducting behavior is observed for 1 with the activation energy of 91 meV (measured by the four-probe technique for an oriented single crystal). The DyIII ions coordinate four hfac- anions in [DyIII(hfac)4]-, providing D2d symmetry. Slow magnetic relaxation is observed for DyIII under an applied static magnetic field of 1000 Oe, and 1 is a single-ion magnet (SIM) with spin reversal barrier Ueff = 40.2 K and magnetic hysteresis at 2 K. Contributions from DyIII and TSeT●+ paramagnetic species are seen in EPR. The DyIII ion rarely manifests EPR signals, but such signal is observed in 1. It appears due to narrowing below 30 K and has g4 = 6.1871 and g5 = 2.1778 at 5.4 K.

Unipolar spin diodes and unipolar spin switches by Spin-Transfer torque in doped graphether

Spin switches are a fundamental component in the majority of spintronic devices, and have found extensive application in data storage, logical data manipulation, and signal processing. An essential aspect of constructing a spin switch is determining a stable two-dimensional material, which is easy to control and produce. Theoretical studies have shown that graphether is particularly promising due to its exceptionally high melting point and outstanding air stability. The band structure can be modified by doping, making it an important material for spin switch applications. In this paper, we have calculated the electromagnetic properties of doped graphether by first principles. Then we select a modified graphether with P-type and N-type doping configurations to construct magnetic tunnel junctions (MTJ). The results show that the MTJ exhibits perfect highly efficient spin switch as a result of spin reversal induced by spin-transfer torque (STT). In addition, our designed MTJ shows a remarkable rectification effect and spin filtering effect (SFE). According to our calculations, the modified graphether materials also show promise as two-dimensional spintronics materials.

Spin switching in Er1-xSmxFeO3 (x = 0, 0.2) single crystals

We investigated spin-switching transitions in Er1-xSmxFeO3 (x = 0, 0.2) single crystals and variations in spin configurations with the applied field. The crystals were grown using the optical floating zone technique, and the magnetic properties were measured under field-cooled cooling (FCC) and field-cooled warming (FCW) protocols. The crystals exhibit field-dependent variation in the spin-switching temperature. In FCC, spin switching temperature increases with a magnetic field. However, in FCW, the spin-switching temperature (TSSW) rises initially with an increasing magnetic field, reaches a maximum value and later decreases when field strengths are high. We observe that spin switching depends not only on the magnitude of the externally applied magnetic field but also on the starting temperature of FCC. The magnetic and thermal history of the sample has a critical role in this phenomenon. A phase diagram (magnetic field-TSSW) constructed using the FCC and FCW data helps to illustrate various magnetic configurations. The FCC and FCW measurements in the a-direction of ErFeO3 at high fields (2T, 3T) suggest that spin switching, which involves the reversal of spins, does not occur. Instead, there is a change in the magnitude of the weak ferromagnetic moment, and rare earth spins below the compensation temperature (Tcomp).

Coercive Fields Exceeding 30 T in the Mixed-Valence Single-Molecule Magnet (CpiPr5)2Ho2I3.

Mixed-valence dilanthanide complexes of the type (CpiPr5)2Ln2I3 (CpiPr5 = pentaisopropylcyclopentadienyl; Ln = Gd, Tb, Dy) featuring a direct Ln-Ln σ-bonding interaction have been shown to exhibit well-isolated high-spin ground states and, in the case of the Tb and Dy variants, a strong axial magnetic anisotropy that gives rise to a large magnetic coercivity. Here, we report the synthesis and characterization of two new mixed-valence dilanthanide compounds in this series, (CpiPr5)2Ln2I3 (1-Ln; Ln = Ho, Er). Both compounds feature a Ln-Ln bonding interaction, the first such interaction in any molecular compounds of Ho or Er. Like the Tb and Dy congeners, both complexes exhibit high-spin ground states arising from strong spin-spin coupling between the lanthanide 4f electrons and a single σ-type lanthanide-lanthanide bonding electron. Beyond these similarities, however, the magnetic properties of the two compounds diverge. In particular, 1-Er does not exhibit observable magnetic blocking or slow magnetic relaxation, while 1-Ho exhibits magnetic blocking below 28 K, which is the highest temperature among Ho-based single-molecule magnets, and a spin reversal barrier of 556(4) cm-1. Additionally, variable-field magnetization data collected for 1-Ho reveal a coercive field of greater than 32 T below 8 K, more than 6-fold higher than observed for the bulk magnets SmCo5 and Nd2Fe14B, and the highest coercive field reported to date for any single-molecule magnet or molecule-based magnetic material. Multiconfigurational calculations, supported by far-infrared magnetospectroscopy data, reveal that the stark differences in magnetic properties of 1-Ho and 1-Er arise from differences in the local magnetic anisotropy of the lanthanide centers.

Core and surface structure and magnetic properties of mechano-synthesized LaFeO3 nanoparticles and their Eu3+-doped and Eu3+/Cr3+-co-doped variants

The core and surface structure and magnetic properties of mechano synthesized LaFeO3 nanoparticles (30–40 nm), their Eu3+-doped (La0.70Eu0.30FeO3), and Eu3+/Cr3+ co-doped (La0.70Eu0.30Fe0.95Cr0.05O3) variants are reported. Doping results in a transition from the O′-type to the O-type distorted structure. Traces of reactants, intermediate phases, and a small amount of Eu2+ ions were detected on the surfaces of the nanoparticles. The nanoparticles consist of antiferromagnetic cores flanked by ferromagnetic shells. The Eu3+ dopant ions enhance the magnetization values relative to those of the pristine nanoparticles and result in magnetic susceptibilities compatible with the presence of Eu3+ van Vleck paramagnetism of spin–orbit coupling constant (λ = 363 cm−1) and a low temperature Curie–Weiss like behavior associated with the minority Eu2+ ions. Anomalous temperature-dependent magnetic hardening due to competing magnetic anisotropy and magnetoelectric coupling effects together with a temperature-dependent dopant-sensitive exchange bias, caused by thermally activated spin reversals at the core of the nanoparticles, were observed.

Giant gate modulation of antiferromagnetic spin reversal by the magnetoelectric effect

In this study, using the Pt/Cr2O3/Pt epitaxial trilayer, we demonstrate the giant voltage modulation of the antiferromagnetic spin reversal and the voltage-induced 180° switching of the Néel vector in maintaining a permanent magnetic field. We obtained a significant modulation efficiency of the switching field, Δμ0HSW/ΔV (Δμ0HSW/ΔE), reaching a maximum of −500 mT/V (−4.80 T nm/V); this value was more than 50 times greater than that of the ferromagnetic-based counterparts. From the temperature dependence of the modulation efficiency, X-ray magnetic circular dichroism measurements and first-principles calculations, we showed that the origin of the giant modulation efficiency relied on the electric field modulation of the net magnetization due to the magnetoelectric effect. From the first-principles calculation and the thickness effect on the offset electric field, we found that the interfacial magnetoelectric effect emerged. Our demonstration reveals the energy-efficient and widely applicable operation of an antiferromagnetic spin based on a mechanism distinct from magnetic anisotropy control.

Investigation of the properties of photonic crystal resonant cavities based on valley spin reversal

Resonators have been treated as essential elements in optics because of their capacity to store and enhance light and exhibit a wide range of applications such as semiconductor lasers and optical communication components. In this article, we reveal a new mechanism of light field confinement in an optical cavity composed of different valley photonic crystals. The electromagnetic field of light is localized because of the valley spin states contrasted between the inner and outer regions, which leads a high Q-factor and a small model volume of the resonator. Furthermore, the whispering-gallery-mode modulated vortex phase distribution is demonstrated in the proposed structure, which offers a new method for manipulating the light field. The energy spectrum as well as the light field distributions show the simultaneous appearance of both bulk and edge states. Such effect becomes pronounced or diminished when the domain wall changes, and can be explained by the location of the edge states in the shared bandgap. Our findings offer a novel mechanism of light field confinement and phase modulation, which may pave the way for a new type of topological device and provide broad applications in the areas of micro-lasers, optical communications, and other light-matter interaction systems.

Oxygen-Donor Metalloligands Induce Slow Magnetization Relaxation in Zero Field for a Cobalt(II) Complex with {CoO4} Motif.

Most 3d metal-based single-molecule magnets (SMMs) use N-ligands or ligands with even softer donors to impart a particular coordination geometry and increase the zero-field splitting parameter |D|, while complexes with hard O-donor ligands showing slow magnetization relaxation are rare. Here, we report that a diamagnetic NiII complex of a tetradentate ligand featuring two N-heterocyclic carbene and two alkoxide-O donors, [LO,ONi], can serve as a {O,O'}-chelating metalloligand to give a trinuclear complex [(LO,ONi)Co(LO,ONi)](OTf)2 (2) with an elongated tetrahedral {CoIIO4} core, D = -74.3 cm-1, and a spin reversal barrier Ueff = 86.9 cm-1 in the absence of an external dc field. The influence of diamagnetic NiII on the electronic structure of the {CoO4} unit in comparison to [Co(OPh)4]2- (A) has been probed with multireference ab initio calculations. These reveal a contrapolarizing effect of the NiII, which forms stronger metal-alkoxide bonds than the central CoII, inducing a change in ligand field splitting and a 5-fold increase in the magnetic anisotropy in 2 compared to A, with an easy magnetization axis along the Ni-Co-Ni vector. This demonstrates a strategy to enhance the SMM properties of 3d metal complexes with hard O-donors by modulating the ligand field character via the coordination of diamagnetic ions and the benefit of robust metalloligands in that regard.

Measurements and linearized models for golf ball bounce on a green

A detailed set of experiments are described that capture over a 1000 different instances of the bounce of a golf ball on a green. Video analysis was used to capture ball’s velocity and spin just before and after each bounce for a wide variety of landing conditions. Data are presented from two different turfs; one artificial and one from a typical tee. Measurement errors and repeatability are analysed. The data are compared to predictions from models of rigid bounce with friction, including Penner’s modification to account for elasto-plasticity. Coefficients of restitution and friction, and Penner’s effective contact angle are fit from the data. A better fit to the data is found using a non-physical piecewise-affine landing to lift-off relationship, which distinguishes between cases that bounce in pure slip from those that undergo rolling. Nevertheless, even balls that undergo rolling are typically found to lift-off slipping, having undergone spin reversal. The findings suggest that further effort needs to be spent on finding simple physics-based models of golf ball bounce on a green.

Mechanisms of linear control of exchange bias in Fe/FeO bilayer

The microscopic nature of pinning uncompensated moment interface, how it is pinned by an antiferromagnet, and how the mechanism with this coupling drives exchange bias remain outstanding challenges. In this work, the Fe/FeO ferromagnet/antiferromagnet bilayer with an ultrathin FeO layer is modeled and the correlation between exchange bias and microscopically uncompensated antiferromagnetic magnetization is studied, based on first-principles calculations and modified Monte-Carlo simulations, where spin energies are exactly calculated and energy barriers are detectable to avoid the occurrence of unphysical tunneling during spin reversals. The linear dependence of exchange bias on uncompensated antiferromagnetic magnetization in Fe/FeO bilayer experimentally is reproduced and interpreted by exploring the monolayer-resolved magnetization behavior in the FeO layer, which depends on antiferromagnetic anisotropy, cooling field, fraction of Fe atoms permeated in the FeO layer, and magnetic frustration effect. It is evidenced that this linear dependence requires plenty of controllable pinning uncompensated antiferromagnetic spins located in the layer depths close to but not in contact with the ferromagnetic layer.

Sublattice spin reversal and field induced Fe3+ spin-canting across the magnetic compensation temperature in Y1.5Gd1.5Fe5O12 rare-earth iron garnet

In the present work Fe3+ sublattice spin reversal and Fe3+ spin-canting across the magnetic compensation temperature (T) are demonstrated in polycrystalline Y1.5Gd1.5Fe5O12 (YGdIG) by means of in-field Mössbauer spectroscopy measurements. Corroborating in-field Mössbauer measurements, both Fe3+ & Gd3+ sublattice spin reversal has also been manifested in hard x-ray magnetic circular dichroism (XMCD) measurements. From in-field 57 Fe Mössbauer measurements, estimation and analysis of effective internal hyperfine field (H), relative intensity of absorption lines in a sextet elucidated unambiguously the signatures of Fe3+ spin reversal and field induced spin-canting of Fe3+ sublattices across T. Gd L3-edge XMCD signal is observed to consist of an additional spectral feature, identified as Fe3+ magnetic contribution to XMCD spectra of Gd L3-edge, enabling us the extraction of both the sublattices (Fe3+ & Gd3+) information from a single absorption edge analysis. The evolution of the XMCD amplitudes, which is proportional to magnetic moments, as a function of temperature for both magnetic sublattices extracted at the Gd L3-edge reasonably match with values that are extracted from bulk magnetization data of YGdIG and YIG (Y3Fe5O12) and corresponding Fe K-edge XMCD amplitudes for Fe contribution. These measurements pave new avenues to investigate how the magnetic behavior of such complex system acts across the compensation point.

Electrically triggered spin reversal and precise control of spin polarization for electron transport at the single-molecule level

Different from conventional ferromagnetic methods, producing a spin-polarized current through electrical ways in spintronic devices can greatly increase operating speed, reduce power consumption, and improve device integration. Inspired by recent experimental progress on the synthesis of a heptauthrene molecule, we investigate its spin-dependent transport contacted with Au electrodes through first-principles calculations. By applying a gate voltage, the transmission can be switched between completely spin-up and spin-down polarized states, achieving an electrically controlled dual-spin filter. Furthermore, a fine tuning on the spin polarization, between 100% and −100%, can also be realized, where the transport with any ratio of spin-up to spin-down electron quantities can be realized beyond the traditional devices. The peculiar transmission spectra and their shift are found to play crucial roles, where transmission peaks distribute on both sides of the Fermi level with opposite spin components. Such a spin-polarization modulating effect is found to be robust to the molecule-electrode contacting site, indicating it is an intrinsic feature of such systems. Moreover, the dimension of the device is at the single-molecule level, suggesting great application potential.

Magnetic properties of SmMn1-xCoxO3 and Sm1-yRyMn0.6Co0.4O3

Polycrystalline SmMn1-xCoxO3 and Sm1-yRyMn0.6Co0.4O3, which have a single orthorhombic perovskite-type structure without any impurities, were prepared by complex polymerization to investigate the effects of A- and B-site element substitutions on the crystal structure and magnetic properties. The unit-cell volume of SmMn1-xCoxO3 decreased with increasing x and that of Sm1-yRyMn0.6Co0.4O3 increased with increasing average radius of A-site ions ⟨rR⟩, and the chemical pressure due to element substitution was observed in these two systems. At 0.0 ≤ x ≤ 0.4 in SmMn1-xCoxO3, a marked increase in the field-cooled magnetization MFC and an increase in the canted-antiferromagnetic transition temperature Tc were observed with increasing x, but they decreased for 0.5 ≤ x ≤ 1.0. However, no specific spin reversal phenomenon was observed, unlike in other RMnO3 compounds. The magnetic susceptibility of both compounds obeyed the Curie–Weiss law with constant susceptibility above 200 K, which was not common in other Sm compounds, and the effective magnetic moment Peff could be easily evaluated. By analyzing Peff of SmMn1-xCoxO3, we determined the electronic states of the ions constituting the sample as Mn3+(high spin, HS), Mn4+, and Co2+(HS) at 0 < x ≤ 0.5 and Mn4+, Co3+(low spin), and Co2+(HS) at 0.5 < x ≤ 0.9. The MFC of Sm1-yRyMn0.6Co0.4O3 decreased with increasing Y and Lu concentrations and increased with La concentration. The Tc and Weiss temperature of Sm1-yRyMn0.6Co0.4O3, both of which increased linearly with increasing ⟨rR⟩, could be attributed to the effects of chemical pressure. Although M − H measurements showed that Sm3+ in Sm1-yRyMn0.6Co0.4O3 was paramagnetic, the Peff analysis results suggested that the excited state of Sm3+ was affected.

Microscopic description of magnetic nonequilibrium phenomena in erbium orthoferrite

A model of nonequilibrium thermodynamics of erbium orthoferrite is presented. The quantum-mechanical effects in arbitrary magnetic fields, related both to the direction of a general quantization axis and an influence of anisotropic exchange interactions on the magnetic structure, spin-reorientation phase transition, spin reversals, and hysteresis, are considered. Based on recent experimental data on temperature-induced spin switching [Phys. Rev. B 105, 094424 (2022)], a possible mechanism for the exchange bias of magnetic hysteresis loops is proposed. The main parameters of the model Hamiltonian are determined, which point out a strongly competitive character of exchange interactions in erbium orthoferrite.

Single-Ion Magnetism in a Three-Dimensional Thiocyanate-Bridged Dysprosium(III) Framework

New three-dimensional (3D) lanthanide framework compounds supported by bridging thiocyanate ligand and K+ cations, K4[Ln(NCS)4(H2O)4](NCS)3(H2O)2(1: Ln = Dy, 2: Ln = Tb, 3: Ln = Gd) have been synthesized. A single-crystal X-ray diffraction study showed that all three compounds were isostructural and crystallized in the I 2/a space group. The K+ ion form 2D layers with thiocyanates which are further linked by [Ln(NCS)4(H2O)4]- complexes and additional thiocyanate ions to generate an interesting 3D framework structure. Compound 1 shows slow magnetic relaxation behavior under a zero direct current (DC) field, indicating that 1 behaves as a single-ion magnet (SIM). As estimated from AC magnetic measurements, the effective energy barrier for spin reversal in 1 was Ueff = 42 cm–1. Slow relaxation of magnetization under a small external DC field was also detected for 2 and 3 at 1.8 K.

Thermodynamics and a definite large half-metallic spin gap along with a magnetic anisotropy in La-doped Ba[formula omitted]NiIrO[formula omitted

Electron doping (i. e., by replacing Ba+2 with La+3) impact on the electronic and magnetic properties of Ba2NiIrO6 system is investigated using ab-initio calculations with the inclusion of Hubbard parameter U along with spin–orbit coupling effects. The calculated formation energies affirm the experimental realization of all motifs at ambient conditions. Whereas, the elastic properties confirm the mechanical stability, ductility, and thermal conductivity of all the structures. It is revealed that anti-ferromagnetic/ferromagnetic (FM) interaction between Ni and Ir ions are energetically stable in pristine motif having an energy band gap (Eg) of 0.70/0.35 eV using the GGA+U method without/with the inclusion of SOC effects, which is in good agreement with the recent experimental results (Feng et al., 2021). Interestingly, La-doped structures depict the half-metallic FM behavior except for 50% concentration, which results in conductivity of the spin-minority channel owing to the admixture of Ir 5d states. On the other hand, the spin-majority channels exhibit an insulating nature having a large Eg of 2.53/2.63/2.49 eV for 12.5%/25%/37.5%, which looks sufficient to restrict the spin reversal and assure high spin filtering efficiency. Moreover, La-doping leads to the existence of mixed-valence state of ＋6/＋5 having a configuration 5d3 (t2g3↑t2g0↓eg0↑eg0↓)/5d4 (t2g3↑t2g1↓eg0↑eg0↓) for Ir ion. Finally, a reasonable magneto-crystalline anisotropic constant of ∼×106 erg/cm3 in all La-doped Ba2NiIrO6 systems is predicted, which is a good signal for their potential utilization in data storage devices.

Hole doping in compositionally complex correlated oxide enables tunable exchange biasing

Magnetic interfaces and the phenomena arising from them drive both the design of modern spintronics and fundamental research. Recently, it was revealed that through designing magnetic frustration in configurationally complex entropy stabilized oxides, exchange bias can occur in structurally single crystal films. This eliminates the need for complex heterostructures and nanocomposites in the design and control of magnetic response phenomena. In this work, we demonstrate through hole doping of a high entropy perovskite oxide that tuning of magnetic responses can be achieved. With detailed magnetometry, we show magnetic coupling exhibiting a variety of magnetic responses including exchange bias and antiferromagnetic spin reversal in the entropy stabilized ABO3 perovskite oxide La1−xSrx(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3 family. We find that manipulation of the A-site charge state can be used to balance magnetic phase compositions and coupling responses. This allows for the creation of highly tunable exchange bias responses. In the low Sr doping regime, a spin frustrated region arising at the antiferromagnetic phase boundary is shown to directly couple to the antiferromagnetic moments of the film and emerges as the dominant mechanism, leading to a vertical shift of magnetization loops in response to field biasing. At higher concentrations, direct coupling of antiferromagnetic and ferromagnetic regions is observed. This tunability of magnetic coupling is discussed within the context of these three competing magnetic phases, revealing critical features in designing exchange bias through exploiting spin frustration and disorder in high entropy oxides.