The work is devoted to the theoretical study of the energy spectrum and low-temperature magnetic properties of the decorated spin-ladder model with the polyacene topology and the three types of the site spins. On the base of cluster expansion technique an approximate analytical treatment of lowest part of the energy spectra of two isomeric ladder structures was given. It is shown that the ladder model with singlet ground state is more stable than its isomeric analog with the macroscopic ground state spin. In addition, the numerical study of field dependence of low-temperature magnetization of 8- spin clusters of both ladder models was performed by means of exact diagonalization method. On the base of these results, it was shown the presence of an intermediate plateau in low-temperature magnetization profile of the above spin ladder models.
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