The lattice Boltzmann (LB) method has been extensively applied to the simulation of various fluid flows. Nonetheless, the standard LB model in rectangular coordinates faces some challenges when attempts are made to use it to simulate single-phase liquid flows involving super-hydrophobic cylindrical surfaces with a large slip length. Therefore, in this paper, boundary conditions for an axisymmetric LB model are proposed for the simulation of liquid slip at both convex and concave cylindrical surfaces. Based on the Navier slip boundary conditions, an equilibrium–nonequilibrium boundary scheme is developed to obtain the liquid slip in the azimuthal direction, with a combined bounce-back and specular-reflection boundary condition being developed to obtain the liquid slip in the axial direction. These boundary schemes are verified by simulating several established cases, namely, cylindrical Couette flow, harmonic oscillatory cylindrical Couette flow, Hagen–Poiseuille flow, and annular Poiseuille flow. The results are in excellent agreement with analytical results. Furthermore, some more complex flows involving super-hydrophobic cylindrical surfaces, such as stepwise oscillatory cylindrical Couette flow, are also simulated and studied using the proposed LB model. The axisymmetric LB model presented here overcomes the inability of standard LB models to accurately and efficiently simulate single-phase liquid flows involving super-hydrophobic cylindrical surfaces with a large slip length.