Spectroscopic Confirmation Research Articles

Early Results from GLASS-JWST. XIV. A Spectroscopically Confirmed Protocluster 650 Million Years after the Big Bang

We present the spectroscopic confirmation of a protocluster at z = 7.88 behind the galaxy cluster Abell 2744 (hereafter A2744-z7p9OD). Using JWST NIRSpec, we find seven galaxies within a projected radius of 60 kpc. Although the galaxies reside in an overdensity around ≳20× greater than a random volume, they do not show strong Lyα emission. We place 2σ upper limits on the rest-frame equivalent width <16–28 Å. Based on the tight upper limits to the Lyα emission, we constrain the volume-averaged neutral fraction of hydrogen in the intergalactic medium to be x HI > 0.45 (68% C i). Using an empirical M UV–M halo relation for individual galaxies, we estimate that the total halo mass of the system is ≳4 × 1011 M ⊙. Likewise, the line-of-sight velocity dispersion is estimated to be 1100 ± 200 km s−1. Using an empirical relation, we estimate the present-day halo mass of A2744-z7p9OD to be ∼2 × 1015 M ⊙, comparable to the Coma cluster. A2744-z7p9OD is the highest redshift spectroscopically confirmed protocluster to date, demonstrating the power of JWST to investigate the connection between dark-matter halo assembly and galaxy formation at very early times with medium-deep observations at <20 hr total exposure time. Follow-up spectroscopy of the remaining photometric candidates of the overdensity will further refine the features of this system and help characterize the role of such overdensities in cosmic reionization.

The Pan-STARRS1 z > 5.6 Quasar Survey. II. Discovery of 55 Quasars at 5.6 < z < 6.5

The identification of bright quasars at z ≳ 6 enables detailed studies of supermassive black holes, massive galaxies, structure formation, and the state of the intergalactic medium within the first billion years after the Big Bang. We present the spectroscopic confirmation of 55 quasars at redshifts 5.6 < z < 6.5 and UV magnitudes −24.5 < M 1450 < −28.5 identified in the optical Pan-STARRS1 and near-IR VIKING surveys (48 and 7, respectively). Five of these quasars have independently been discovered in other studies. The quasar sample shows an extensive range of physical properties, including 17 objects with weak emission lines, 10 broad absorption line quasars, and 5 objects with strong radio emission (radio-loud quasars). There are also a few notable sources in the sample, including a blazar candidate at z = 6.23, a likely gravitationally lensed quasar at z = 6.41, and a z = 5.84 quasar in the outskirts of the nearby (D ∼ 3 Mpc) spiral galaxy M81. The blazar candidate remains undetected in NOEMA observations of the [C ii] and underlying emission, implying a star formation rate <30–70 M ⊙ yr−1. A significant fraction of the quasars presented here lies at the foundation of the first measurement of the z ∼ 6 quasar luminosity function from Pan-STARRS1 (introduced in a companion paper). These quasars will enable further studies of the high-redshift quasar population with current and future facilities.

CEERS Key Paper. I. An Early Look into the First 500 Myr of Galaxy Formation with JWST

We present an investigation into the first 500 Myr of galaxy evolution from the Cosmic Evolution Early Release Science (CEERS) survey. CEERS, one of 13 JWST ERS programs, targets galaxy formation from z ∼ 0.5 to >10 using several imaging and spectroscopic modes. We make use of the first epoch of CEERS NIRCam imaging, spanning 35.5 arcmin2, to search for candidate galaxies at z > 9. Following a detailed data reduction process implementing several custom steps to produce high-quality reduced images, we perform multiband photometry across seven NIRCam broad- and medium-band (and six Hubble broadband) filters focusing on robust colors and accurate total fluxes. We measure photometric redshifts and devise a robust set of selection criteria to identify a sample of 26 galaxy candidates at z ∼ 9–16. These objects are compact with a median half-light radius of ∼0.5 kpc. We present an early estimate of the z ∼ 11 rest-frame ultraviolet (UV) luminosity function, finding that the number density of galaxies at M UV ∼ −20 appears to evolve very little from z ∼ 9 to 11. We also find that the abundance (surface density [arcmin−2]) of our candidates exceeds nearly all theoretical predictions. We explore potential implications, including that at z > 10, star formation may be dominated by top-heavy initial mass functions, which would result in an increased ratio of UV light per unit halo mass, though a complete lack of dust attenuation and/or changing star formation physics may also play a role. While spectroscopic confirmation of these sources is urgently required, our results suggest that the deeper views to come with JWST should yield prolific samples of ultrahigh-redshift galaxies with which to further explore these conclusions.

A novel survey for young substellar objects with the W-band filter IV: detection and characterization of low-mass brown dwarfs in Serpens Core

ABSTRACT We present spectroscopic confirmation of nine M5 or later Serpens Core candidate members, identified using a combination of CFHT WIRCam photometry and IRTF SpeX spectroscopy. Through spectral fitting, we find that the latest of these nine candidate members is best fit by an L0 spectral standard (in the range of M8–L2), implying a mass of ∼0.01–0.035M⊙. If confirmed as a cluster member, this would be one of the lowest mass Serpens Core objects ever discovered. We present analysis of the physical properties of the sample, as well as the likely membership of the candidate Serpens Core members.

When Spectral Modeling Meets Convolutional Networks: A Method for Discovering Reionization-era Lensed Quasars in Multiband Imaging Data

Over the last two decades, around 300 quasars have been discovered at z ≳ 6, yet only one has been identified as being strongly gravitationally lensed. We explore a new approach—enlarging the permitted spectral parameter space, while introducing a new spatial geometry veto criterion—which is implemented via image-based deep learning. We first apply this approach to a systematic search for reionization-era lensed quasars, using data from the Dark Energy Survey, the Visible and Infrared Survey Telescope for Astronomy Hemisphere Survey, and the Wide-field Infrared Survey Explorer. Our search method consists of two main parts: (i) the preselection of the candidates, based on their spectral energy distributions (SEDs), using catalog-level photometry; and (ii) relative probability calculations of the candidates being a lens or some contaminant, utilizing a convolutional neural network (CNN) classification. The training data sets are constructed by painting deflected point-source lights over actual galaxy images, to generate realistic galaxy–quasar lens models, optimized to find systems with small image separations, i.e., Einstein radii of θ E ≤ 1″. Visual inspection is then performed for sources with CNN scores of P lens > 0.1, which leads us to obtain 36 newly selected lens candidates, which are awaiting spectroscopic confirmation. These findings show that automated SED modeling and deep learning pipelines, supported by modest human input, are a promising route for detecting strong lenses from large catalogs, which can overcome the veto limitations of primarily dropout-based SED selection approaches.

A novel paper‐based microfluidic device and UV‐visible spectroscopy coupled method for the field detection and analysis of seized marijuana samples

AbstractCannabis is recorded to be the most used drug in the world. This causes a lot of difficulties for developing countries to curb the illegal cultivation, sale, and use of cannabis. The main psychoactive component of the cannabis plant is D9‐tetrahydrocannabinol (THC). The introduction of mobile forensic labs has greatly increased the testing efficiency of psychotropic substances, but the traditional methods of analysis might seem to be cumbersome for the individual experimenting with the scene of seizure. The incorporation of portable analytical devices in forensic field analysis is the approach in the right direction for the testing of drugs. In this paper, we introduce a paper‐based microfluidic device for the onsite detection of marijuana. The device comprises the fast blue B reagent (FBB) as the main reagent. The µPAD was used for the successful detection of seized marijuana. The µPAD‐based detection was combined with a UV‐Vis spectroscopic confirmation. The computational modeling of the absorbance spectra gave further insights into the product formation during the reaction of THC and FBB. This novel method helps in a faster analysis of marijuana, at a considerably lower cost; which is a great boost to the forensic community and the law enforcement authority.

A Candidate for the Least-massive Black Hole in the First 1.1 Billion Years of the Universe

We report a candidate of a low-luminosity active galactic nucleus (AGN) at z = 5 that was selected from the first near-infrared images of the JWST CEERS project. This source, named CEERS-AGN-z5-1 at absolute 1450 Å magnitude M 1450 = −19.5 ± 0.3, was found via a visual selection of compact sources from a catalog of Lyman break galaxies at z > 4, taking advantage of the superb spatial resolution of the JWST/NIRCam images. The 20 photometric data available from CFHT, Hubble Space Telescope, Spitzer, and JWST suggest that the continuum shape of this source is reminiscent of that for an unobscured AGN, and there is a clear color excess in the filters where the redshifted Hβ+[O iii] and Hα are covered. The estimated line luminosity is L Hβ+[O III] = 1043.0 erg s−1 and L Hα = 1042.9 erg s−1 with the corresponding rest-frame equivalent width EWHβ+[O III] = 1100 Å and EWHα = 1600 Å, respectively. Our spectral energy distribution fitting analysis favors the scenario that this object is either a strong broad-line emitter or even a super-Eddington accreting black hole (BH), although a possibility of an extremely young galaxy with moderate dust attenuation is not completely ruled out. The bolometric luminosity, L bol = 2.5 ± 0.3 × 1044 erg s−1, is consistent with those of z < 0.35 broad-line AGNs with M BH ∼ 106 M ⊙ accreting at the Eddington limit. This new AGN population in the first 1.1 billion years of the universe may close the gap between the observed BH mass range at high redshift and that of BH seeds. Spectroscopic confirmation is awaited to secure the redshift and its AGN nature.

Early Results from GLASS-JWST. IX. First Spectroscopic Confirmation of Low-mass Quiescent Galaxies at z > 2 with NIRISS

How passive galaxies form, and the physical mechanisms which prevent star formation over long timescales, are some of the most outstanding questions in understanding galaxy evolution. The properties of quiescent galaxies over cosmic time provide crucial information to identify the quenching mechanisms. Passive galaxies have been confirmed and studied out to z ∼ 4, but all of these studies have been limited to massive systems (mostly with ). Using JWST-NIRISS grism slitless spectroscopic data from the GLASS-JWST Early Release Science program, we present spectroscopic confirmation of two quiescent galaxies at and (3σ errors) with stellar masses of and (corrected for magnification factors of μ = 2.0 and μ = 2.1, respectively). The latter represents the first spectroscopic confirmation of the existence of low-mass quiescent galaxies at cosmic noon, showcasing the power of JWST to identify and characterize this enigmatic population.

An upper limit on [O III] 88 μm and 1.2 mm continuum emission from a JWSTz ≈ 12–13 galaxy candidate with ALMA

A number of newz &gt; 11 galaxy candidates have recently been identified based on publicJames WebbSpace Telescope (JWST) NIRCam observations. Spectroscopic confirmation of these candidates is necessary to robustly measure their redshift and put them in the context of our understanding of the buildup of galaxies in the early Universe. GLASS-z13 is one of these candidates, with a reported photometric redshiftz &gt; 11.9. I present publicly available Atacama Large Millimeter/submillimeter Array (ALMA) band 6 Director’s Discretionary Time observations (project 2021.A.00020.S; PI T. Bakx), taken to acquire a spectroscopic redshift for GLASS-z13 by searching for [O III] 88 μm line emission in the redshift rangez = 11.9 − 13.5. No [O III] 88 μm emission is detected in integrated spectra extracted within an aperture around GLASS-z13, nor when using an automated line finding algorithm (applying different uv-weighting strategies for the imaging). In addition, 1.2 mm continuum emission associated with GLASS-z13 is not detected either. If GLASS-z13 is atz ≈ 12 − 13, this implies a 3-σupper limit on the [O III] 88 μm and rest-frame ∼90 μm continuum emission of ∼1 × 108 L⊙and 10.8 μJy, respectively. The non-detection of [O III] 88 μm and continuum emission does not necessarily imply that GLASS-z13 is not atz ≈ 12 − 13. It can also be explained by a low metallicity (∼0.2 Z⊙or lower) and/or high-density (at least 100 cm−3) interstellar medium. This work demonstrates the synergy between ALMA and JWST to study the properties of the first galaxies; although, JWST/NIRSpec spectroscopy will be necessary to confirm or reject the high photometric redshift of GLASS-z13.

Spectroscopic Confirmation of a Population of Isolated, Intermediate-mass Young Stellar Objects

Wide-field searches for young stellar objects (YSOs) can place useful constraints on the prevalence of clustered versus distributed star formation. The Spitzer/IRAC Candidate YSO (SPICY) catalog is one of the largest compilations of such objects (∼120,000 candidates in the Galactic midplane). Many SPICY candidates are spatially clustered, but, perhaps surprisingly, approximately half the candidates appear spatially distributed. To better characterize this unexpected population and confirm its nature, we obtained Palomar/DBSP spectroscopy for 26 of the optically bright (G < 15 mag) “isolated” YSO candidates. We confirm the YSO classifications of all 26 sources based on their positions on the Hertzsprung–Russell diagram, H and Ca ii line emission from over half the sample, and robust detection of infrared excesses. This implies a contamination rate of <10% for SPICY stars that meet our optical selection criteria. Spectral types range from B4 to K3, with A-type stars being the most common. Spectral energy distributions, diffuse interstellar bands, and Galactic extinction maps indicate moderate-to-high extinction. Stellar masses range from ∼1 to 7 M ⊙, and the estimated accretion rates, ranging from 3 × 10−8 to 3 × 10−7 M ⊙ yr−1, are typical for YSOs in this mass range. The 3D spatial distribution of these stars, based on Gaia astrometry, reveals that the “isolated” YSOs are not evenly distributed in the Solar neighborhood but are concentrated in kiloparsec-scale dusty Galactic structures that also contain the majority of the SPICY YSO clusters. Thus, the processes that produce large Galactic star-forming structures may yield nearly as many distributed as clustered YSOs.

Evaluating Lyα Emission as a Tracer of the Largest Cosmic Structure at z ∼ 2.47

The discovery and spectroscopic confirmation of Hyperion, a protosupercluster at z ∼ 2.47, provides an unprecedented opportunity to study distant galaxies in the context of their large-scale environment. We carry out deep narrowband imaging of a ≈1° × 1° region around Hyperion and select 157 Lyα emitters (LAEs). The inferred LAE overdensity is δ g ≈ 40 within an effective volume of 30 × 20 × 15 cMpc3, consistent with the fact that Hyperion is composed of multiple protoclusters and will evolve into a supercluster with a total mass of M tot ≈ 1.4 × 1015 M ⊙ at z = 0. The distribution of LAEs closely mirrors that of known spectroscopic members, tracing the protocluster cores and extended filamentary arms connected to them, suggesting that they trace the same large-scale structure. By cross-correlating the LAE positions with H i tomography data, we find weak evidence that LAEs may be less abundant in the highest H i regions, perhaps because Lyα is suppressed in such regions. The Hyperion region hosts a large population of active galactic nuclei (AGNs) ≈ 12 times more abundant than that in the field. The prevalence of AGNs in protocluster regions hints at the possibility that they may be triggered by physical processes that occur more frequently in dense environments, such as galaxy mergers. Our study demonstrates LAEs as reliable markers of the largest cosmic structures. When combined with ongoing and upcoming imaging and spectroscopic surveys, wide-field narrowband imaging has the potential to advance our knowledge in the formation and evolution of cosmic structures and of their galaxy inhabitants.

COSMOS2020: UV-selected galaxies atz ≥ 7.5

This paper presents a new search forz ≥ 7.5 galaxies using the COSMOS2020 photometric catalogues. Finding galaxies at the reionisation epoch through deep imaging surveys remains observationally challenging. The larger area covered by ground-based surveys such as COSMOS enables the discovery of the brightest galaxies at these high redshifts. Covering 1.4 deg2, our COSMOS catalogues were constructed from the latest UltraVISTA data release (DR4) combined with the finalSpitzer/IRAC COSMOS images and the Hyper-Suprime-Cam Subaru Strategic Program DR2 release. We identified 17 new 7.5 &lt; z &lt; 10 candidate sources, and confirm 15 previously published candidates. Using deblended photometry extracted by fitting surface brightness models on multi-band images, we selected four candidates which would be rejected using fixed aperture photometry. We tested the robustness of all our candidates by comparing six different photometric redshift estimates. Finally, we computed the galaxy UV luminosity function in three redshift bins centred atz = 8, 9, 10. We find no clear evolution of the number density of the brightest galaxiesMUV &lt; −21.5, in agreement with previous works. Rapid changes in the quenching efficiency or attenuation by dust could explain such a lack of evolution betweenz ∼ 8 andz ∼ 9. A spectroscopic confirmation of the redshifts, already planned with JWST and the Keck telescopes, will be essential to confirm our results.

Grantecan spectroscopic observations and confirmations of planetary nebulae candidates in the Northern Galactic Plane

ABSTRACT We present Gran Telescopio Canarias (GTC) spectroscopic confirmations of 55 faint Planetary Nebulae (PNe) candidates discovered largely in the INT Photometric H α Survey (IPHAS) of the Northern Galactic Plane by our pro-am collaboration. We confirm 46 of them as ‘True’ (T), 4 as ‘Likely’ (L), and 5 as ‘Possible’ (P) PNe and including 5 new PNe central star (CSPN) discoveries. This was from observations of 62 new candidates yielding a maximum PN discovery success rate of 89 per cent. The sensitivity and longer wavelength coverage of IPHAS allows PNe to be found in regions of greater extinction and at these lower Galactic latitudes, including PNe in a more advanced evolutionary state and at larger distances compared to previously known Galactic PNe. We use a holistic set of observed characteristics and optical emission-line diagnostics to confirm candidates. Plasma properties have been determined in a self-consistent way using pyneb. This work is facilitated by the functionality of our powerful, multiwavelength database ‘HASH’ (Hong Kong, Australian Astronomical Observatory, Strasbourg Observatory H-alpha Planetary Nebula catalogue) that federates known imaging, spectroscopy, and other pertinent data for all Galactic T, L, P PNe, and the significant numbers of mimics. Reddenings, corrected radial velocities, and PNe electron density and temperature estimates are provided for these new PNe wherever possible.

Rogue Planets and Brown Dwarfs: Predicting the Populations Free-floating Planetary Mass Objects Observable with JWST

Free-floating (or rogue) planets are planets that are liberated (or ejected) from their host systems. Although simulations predict their existence in substantial numbers, direct observational evidence for free-floating planets with masses below ∼5 M Jup is still lacking. Several cycle-1 observing programs with JWST aim to hunt for them in four different star-forming clusters. These surveys are designed to be sensitive to masses of 1–15 M Jup (assuming a hot-start formation), which corresponds to spectral types of early L to late T for the ages of these clusters. If the existing simulations are not wide off the mark, we show here that the planned programs are likely to find up to 10–20 giant rogue planets in moderate density clusters like NGC1333 or IC348, and several dozen to ∼100 in high-density regions like NGC2024 and the Orion Nebula Cluster. These numbers correspond to 1%–5% of the total cluster population; they could be substantially higher if stars form multiple giant planets at birth. In contrast, the number of free-floating brown dwarfs, formed from core collapse (like stars) is expected to be significantly lower, only about 0.25% of the number of stars, or 1–7 for the clusters considered here. Below 10 M Jup that number drops further by an order of magnitude. We also show that the planned surveys are not at risk of being significantly contaminated by field brown dwarfs in the foreground or background, after spectroscopic confirmation. Taken together, our results imply that if a population of L and T dwarfs were to be found in these JWST surveys, it is expected to be predominantly made up of rogue planets.

Screening of microplastics in water and sludge lines of a drinking water treatment plant in Catalonia, Spain

Microplastics (MPs) are emerging pollutants detected everywhere in the environment, with the potential to harm living organisms. The present study investigated the concentration, morphology, and composition of MPs, between 20 μm and 5 mm, in a drinking water treatment plant (DWTP) located close to Barcelona (Catalonia, NE Spain). The sampling included different units of the DWTP, from influent to effluent as well as sludge line. Sampling strategy, filtration, allows sampling of large volumes of water avoiding sample contamination, and during 8 h in order to increase the representativeness of MPs collected. The pre-treatment of the samples consisted of advanced oxidation with Fenton's reagent and hydrogen peroxide, followed by density separation of the particles with zinc chloride solution. Visual identification was performed with an optical and stereoscopic microscope with final Fourier-transform infrared spectroscopic (FTIR) confirmation. MPs were found in all DWTP samples, with concentrations from 4.23 ± 1.26 MPs/L to 0.075 ± 0.019 MPs/L in the influent and effluent of the plant, respectively. The overall removal efficiency of the plant was 98.3%. The most dominant morphology was fibers followed by fragments and films. Twenty-two different polymer types were identified and synthetic cellulose, polyester, polyamide, polypropylene, polyethylene, polyurethane, and polyacrylonitrile were the most common. Although MPs could be incorporated from the distribution network, MPs intake from drinking water from this DWTP was not an important route compared to fish and seafood ingestion.

The AGEL Survey: Spectroscopic Confirmation of Strong Gravitational Lenses in the DES and DECaLS Fields Selected Using Convolutional Neural Networks

We present spectroscopic confirmation of candidate strong gravitational lenses using the Keck Observatory and Very Large Telescope as part of our ASTRO 3D Galaxy Evolution with Lenses (AGEL) survey. We confirm that (1) search methods using convolutional neural networks (CNNs) with visual inspection successfully identify strong gravitational lenses and (2) the lenses are at higher redshifts relative to existing surveys due to the combination of deeper and higher-resolution imaging from DECam and spectroscopy spanning optical to near-infrared wavelengths. We measure 104 redshifts in 77 systems selected from a catalog in the DES and DECaLS imaging fields (r ≤ 22 mag). Combining our results with published redshifts, we present redshifts for 68 lenses and establish that CNN-based searches are highly effective for use in future imaging surveys with a success rate of at least 88% (defined as 68/77). We report 53 strong lenses with spectroscopic redshifts for both the deflector and source (z src > z defl), and 15 lenses with a spectroscopic redshift for either the deflector (z defl > 0.21) or source (z src ≥ 1.34). For the 68 lenses, the deflectors and sources have average redshifts and standard deviations of 0.58 ± 0.14 and 1.92 ± 0.59 respectively, and corresponding redshift ranges of z defl = 0.21–0.89 and z src = 0.88–3.55. The AGEL systems include 41 deflectors at z defl ≥ 0.5 that are ideal for follow-up studies to track how mass density profiles evolve with redshift. Our goal with AGEL is to spectroscopically confirm ∼100 strong gravitational lenses that can be observed from both hemispheres throughout the year. The AGEL survey is a resource for refining automated all-sky searches and addressing a range of questions in astrophysics and cosmology.

KIC 10417986: Spectroscopic Confirmation of the Nature of the Binary System with a δ Scuti Component

KIC 10417986 is a short orbital period (0.0737 day) ellipsoidal variable star with a δ Sct and γ Dor hybrid pulsation component discovered by Kepler. The ground-based spectroscopic observations were carried out in the winters of 2020 and 2021 to investigate the binary nature of this star. We derive the orbital parameters using the rvfit code with a result of K 1 = 29.7 ± 1.5 km s−1, γ = −18.7 ± 1.7 km s−1, and confirm an orbital period of 0.84495 day instead of the result given by Kepler. The atmospheric parameters of the primary are determined by the synthetic spectral fitting technique with the estimated values of T eff = 7411 ± 187 K, log g = 4.2 ± 0.3 dex, [M/H] = 0.08 ± 0.09 dex and vsini = 52 ± 11 km s−1. KIC 10417986 is a circular orbit binary system. From the single-lined nature and mass function of the star, the derived orbital inclination is 26° ± 6°, and the mass of the secondary is M ⊙, which should be a late-K to early-M type star. Fourteen frequencies are extracted from Kepler light curves, of which six independent frequencies in the high-frequency region are identified as the p-mode pulsations of δ Sct star, and one independent frequency in the low-frequency region (f 2 = 1.3033 cd−1) is probably the rotational frequency due to the starspots rather than the ellipsoidal effect.

Counterparts of candidate dusty starbursts at z &amp;gt; 6

ABSTRACT We present an analysis of the optical-to-near-infrared (IR) counterparts of a sample of candidate dusty starbursts at z &amp;gt; 6. These objects were pre-selected based on the rising trend of their far-IR-to-sub-millimeter spectral energy distributions and the fact that they are radio-weak. Their precise positions are available through millimeter and/or radio interferometry, which enable us to search for their counterparts in the deep optical-to-near-IR images. The sample includes five z &amp;gt; 6 candidates. Three of them have their counterparts identified, one is still invisible in the deepest images, and one is a known galaxy at z = 5.667 that is completely blocked by a foreground galaxy. The three with counterparts identified are analysed using population synthesis model, and they have photometric redshift solutions ranging from 7.5 to 9.0. Assuming that they are indeed at these redshifts and that they are not gravitationally lensed, their total IR luminosities are $10^{13.8-14.1}\, {\rm L}_\odot$ and the inferred star formation rates are 6.3–13 $\times 10^3\, {\rm M}_\odot$ yr−1. The existence of dusty starbursts at such redshifts would imply that the Universe must be forming stars intensely very early in time in at least some galaxies, otherwise there would not be enough dust to produce the descendants observed at these redshifts. The inferred host galaxy stellar masses of these three objects, which are at $\gtrsim 10^{11}\, {\rm M}_\odot$ (if not affected by gravitational lensing), present a difficulty in explanation unless we are willing to accept that their progenitors either kept forming stars at a rate of $\gtrsim 10^3\, {\rm M}_\odot$ yr−1 or were formed through intense instantaneous bursts. Spectroscopic confirmation of such objects will be imperative.

Structural and Spectroscopic Characterization of a Zinc-Bound N-Oxyphthalimide Radical.

Thermolysis of a 1:1:1 mixture of MeLH (MeL = {(2,6-iPr2C6H3)NC(Me)}2CH), N-hydroxyphthalimide (HOPth), and diethylzinc in toluene at 77 °C provided [MeLZn(OPth)] (1) in good yield after workup. The subsequent reduction of 1 with 1.3 equiv of KC8 and 1 equiv of 2.2.2-cryptand, in tetrahydrofuran, provided [K(2.2.2-cryptand)][MeLZn(OPth)] (2) in 74% yield after workup. Characterization of 2 via X-ray crystallography and electron paramagnetic resonance spectroscopy reveals the presence of an S = 1/2 radical on the N-oxyphthalimide ligand. Importantly, these data represent the first structural and spectroscopic confirmation of the redox activity of a metal-bound N-oxyphthalimide fragment, expanding the range of structurally characterized redox-active ligands.

New Spectroscopic Confirmations of Lyα Emitters at Z ∼ 7 from the LAGER Survey

We report spectroscopic confirmations of 15 Lyα galaxies at z ∼ 7, implying a spectroscopic confirmation rate of ∼80% on candidates selected from the Lyα Galaxies in the Epoch of Reionization (LAGER), which is the largest (24 deg2) survey aimed at finding Lyα emitters (LAEs) at z ∼ 7 and uses deep narrowband imaging from the Dark Energy Camera at CTIO. LAEs at high redshifts are sensitive probes of cosmic reionization, and narrowband imaging is a robust and effective method for selecting a large number of LAEs. In this work, we present results from the spectroscopic follow-up of LAE candidates in two LAGER fields, COSMOS and WIDE-12, using observations from Keck/LRIS. We report the successful detection of Lyα emission in 15 candidates. Three of these in COSMOS have matching confirmations from a previous spectroscopic follow-up and are part of the overdense region, LAGER-z7OD1. Two other candidates that were not detected with LRIS have prior spectroscopic confirmations from Magellan. Including these, we obtain a spectroscopic confirmation success rate of ∼80% for LAGER LAE candidates. Thorough checks were performed to reject the possibility of these detections being foreground emission resulting with a probability of, at most, one contaminant. We do not detect any other UV nebular lines in our LRIS spectra, apart from Lyα. We estimate a 2σ upper limit for the ratio of N v/Lyα, f NV/f Lyα ≲ 0.27. Including confirmations from this work, a total of 33 LAE sources from LAGER are now spectroscopically confirmed. LAGER has more than doubled the sample of spectroscopically confirmed LAE sources at z ∼ 7.