ABSTRACT This work illustrates the effectiveness of hyperspectal image spectroscopy and lab spectroscopy in identiûcation techniques of minerals in alteration zone of ore body. The adopted procedure involves testing of Hyperion image spectra, their processing for noise, spectral matching and spectral similarity measurement with selected library spectra. Average weighted spectral similarity; visual and statistical matching techniques were used to select end-members from image spectra. Minimum noise fraction and pixel purity index technique were used to retrieve end-member spectra from hyperion image. Hyperspectral image like hyperion has the capability to deliver laboratory standard spectroscopic result. This paper illustrates the capability of hyperion image spectra in copper ore identification and mapping of chalcopyrite outcrop. A systematic approach has been made in this paper. This approach describes how image end member spectra and laboratory spectra can be co-related to fetch accurate spectral form of chalcopyrite ores. Thus, statistical and graphical comparison has been carried out between image derived end member spectra and laboratory spectra of chalcopyrite for better accuracy. The visual measurements is satisfactory, R = 0.973 for fine and 0.976 for medium grained chalcopyrite ore. Excellent statistical signiûcance levels (90–97%) are found while comparing these spectra. There are many success stories of sub-pixel and N-dimensional feature space methods to separate the hydrothermal alteration zones from iron oxide mixed ore bodies. Thus, unmixing methods are very useful for mapping of most dominating mineral parts of a pixel from hyperspectral images which have coarse spatial resolution. Finally, mapping of mineralized zone has been achieved through sub-pixel based classifiers like spectral angle mapper (SAM), constrained energy minimization (CEM) and adaptive coherence estimator (ACE) techniques.