Spectral Intensity Research Articles

Rational Control of Maximum EMI/CPL Intensity and Wavelength of Bora[6]helicene via Polarity and Vibronic Effects.

Solvent polarity control as an efficient methodology to regulate the chiroptical properties, including spectral shape, width, intensity, wavelength, etc., has emerged as a novel frontier in optical materials design. However, the underling relationship connecting polarity to the optical property remains unclear. Herein, using state-of-the-art computations and the FC|VG model, the solvent effect on the chiroptical properties of bora[6]helicene was accurately and systematically computed to shed light on this issue. It is found that the vibronic coupling is crucial in explaining the spectral shape, width, and relative intensity of different peaks. Moreover, the intensity and position of the emission (EMI) and circularly polarized luminescence (CPL) are closely related to the polarity of the solvent. Intriguingly, we got a series of good linear relationships between polarity and EMI|CPL (|r| ≥ 0.95). Thus, this parameter can be used as a potential descriptor to estimate the intensity and position of EMI|CPL, leading to new strategies for designing fully colored fluorescent materials.

Pure-quartic solitons with PT-symmetric nonlinearity

We propose a new, to the best of our knowledge, class of soliton based on the interaction of parity-time (PT) symmetric nonlinearity and quartic dispersion or diffraction. This novel kind of soliton is related to the recently discovered pure-quartic solitons (PQS), which arise from the balance of the Kerr nonlinearity and quartic dispersion, through a complex coordinate shift. We find that the PT-symmetric pure-quartic soliton presents important differences with respect to its Hermitian (Kerr) counterpart, including a nontrivial phase structure, a skewed spectral intensity, and a higher power for the same propagation constant. Further analysis reveals these solitons are linearly stable.

Temperature measurement method with line and continuum emissions in Ar-N2 DC arc

Abstract This study discusses a technique for accurate temperature measurement of thermal plasmas with a high-speed camera. Temperature of thermal plasmas is important parameter for plasma processes. High-speed cameras are useful to measure plasma temperatures in two dimensions. Measurements of plasma emission with a high-speed camera and band-pass filter provide only the spectral intensity of the entire transmitted wavelength range. Temperature measurements with high-speed cameras by Boltzmann plot method or Fowler-Milne method are less accurate. Theoretical consideration of the line and continuum emissions has improved the accuracy of plasma temperature measurement. The measurement target was a free burning arc in an argon and nitrogen atmosphere. Temperature errors were estimated based on the deviation from the true emission coefficient. The calculation and measurement errors were discussed as the factors of the deviation. Error estimation provides important insight into the selection of the measurement wavelength.

Holographic Multi-Notch Filters Recorded with Simultaneous Double-Exposure Contact Mirror-Based Method

This study presents a novel simultaneous double-exposure contact mirror-based method for fabricating holographic multi-notch filters with dual operational central wavelengths. The proposed method leverages coupled wave theory, the geometric relationships of K-vectors, and a reflection-type recording setup, incorporating additional reflecting mirrors to guide the recording beams. To validate the approach, a holographic notch filter was fabricated using photopolymer recording materials, resulting in operational wavelengths of 531.13 nm and 633.01 nm. The measured diffraction efficiencies at these wavelengths were ηs = 52.35% and ηp = 52.45% for 531.13 nm, and ηs = 67.30% and ηp = 67.40% for 633.01 nm. The component’s performance was analyzed using s- and p-polarized spectral transmission intensities at various reconstruction angles, revealing polarization-independent characteristics under normal incidence and polarization-dependent behavior under oblique incidence. The study also explored the relationships between recording parameters, such as incident angle, wavelength, emulsion expansion, and dispersion. The findings demonstrate that the first operational central wavelength is primarily influenced by the recording wavelength, while the second is primarily determined by the incident angle, covering a range from visible light to near-infrared. This method offers significant potential for cost-effective, mass-produced filters in optoelectronic applications.

Laser-induced plasma analysis of ammonia-oxygen and ammonia-oxygen-enriched-air flames at elevated pressures

This study employed Laser-induced breakdown spectroscopy (LIBS) to measure the fuel-oxidizer ratio (FOR) of ammonia combustion with oxygen-enriched air and pure oxygen flames at elevated pressures (100 - 300 kPa). The correlations between the spectral line intensity ratios of nitrogen (N), hydrogen (H), oxygen (O), and equivalence ratio were used to quantify the FOR of flames at various pressures. The effect of pressure on the stability and precision of the calibration profiles for the elemental intensity ratios in flames was investigated. It was observed that the H/O correlation decreases with pressure increase for both ammonia flames. N/O correlations decrease with elevated pressure for the ammonia-oxygen flame. Furthermore, the nitrogen (NII) spectral emission lines at 568 nm and 595 nm were used to estimate the plasma temperature, while the hydrogen (Hα) line at 656 nm was used for electron number density measurements.

Orchestrating time and color: a programmable source of high-dimensional entanglement

High-dimensional encodings based on temporal modes (TMs) of photonic quantum states provide the foundations for a highly versatile and efficient quantum information science (QIS) framework. Here, we demonstrate a crucial building block for any QIS applications based on TMs: a programmable source of maximally entangled high-dimensional TM states. Our source is based on a parametric downconversion process driven by a spectrally shaped pump pulse, which facilitates the generation of maximally entangled TM states with a well-defined dimensionality that can be chosen programmatically. We characterize the effective dimensionality of the generated states via measurements of second-order correlation functions and joint spectral intensities, demonstrating the generation of bi-photon TM states with a controlled dimensionality in up to 20 dimensions.

Thermal experiment study on the self-luminous properties of metallic iron during solid–liquid phase transition

According to the thermal experiment study of the self-luminescence spectrum of industrially pure iron (DT8) at a heating and cooling rate of 5 °C/min, at the moment of 0 (800 °C), DT8 had no significant self-luminescence characteristics in the wavelength range of 200–1100 nm. At the same time, the first-order differentiation of the spectral intensity versus time was equal to zero at the beginning and end moments of the solid-liquid phase transition. When the solid-liquid melt temperatures are equal (i.e. 1531 °C), there are two sharp peaks at wavelengths of 589.1 nm and 766.7 nm of the self-luminous spectrum in the pure liquid state compared to the self-luminous spectrum in the pure solid state. The intensity of the spectrum decreases significantly as the metallic iron changes from the pure solid phase to the pure liquid phase, with a reduction rate greater than 20%. The appearance of the fitted peaks at 589.1 nm and 769 nm was found by XPS fitting analysis to be a significant feature of the difference in the auto-luminescence spectra of pure solid phase and pure liquid phase metallic iron at a constant melt pool temperature. After the transformation of pure solid phase into pure liquid phase, the decay rate of the self-luminous spectrum in the long-wave direction at wavelengths greater than 762 nm is greater than that in the short-wave direction at wavelengths less than 625 nm.

Lanthanide detection by novel arylether based receptor with imine functional groups: synthetic, photophysical, electrochemical and computational elucidation

AbstractThe present research discloses a novel chemical sensor (TEI) [1-((E)-(2-(3-(2-((E)-(2-hydroxynaphthalene-1-yl)methyleneamino)phenoxy)phenoxy)phenylimino)methyl)naphthalene-2-ol] for the detection of rare earth element cerium (III) in which spectrophotometric and voltametric sensor techniques were used with a versatile combination of ether and imine group. Various lanthanide ions were checked for the binding in a solution of TEI under identical conditions, including Ce(III), Dy(III), Ho(III), La(III), Sm(III), Eu(III), Gd(III), Tb(III), Er(III), Yb(III), Tm(III), Pr(III) and Nd(III). As observed in absorption studies, the enhancement of spectral intensity at 310 nm caused by Ce(III) was expected over other lanthanide ions. Cyclic and differential pulse voltammograms were also drawn for TEI receptor with and without Ce3+ ions With incremental addition of Ce3+ ions the anodic peak at 0.68 V oxygen gets completely diminished. Another anodic peak at 0.75 V which was due to complete oxidation of ether group and re-oxidation of reduced imine group, got reduced. In case of cathodic peak (due to reduction of imine group) at 0.6 V, there was hardly any decrease in current. This leads to the confirmation that there was no involvement of imine group in binding in the complex. Detection limit obtained by this sensor is 5 × 10–7 M without any interference which makes it a potent sensor for cerium detection.

Multi-modal and multi-level structure-specific spectral intensity measures for seismic evaluation of reinforced concrete frames

Multi-modal and multi-level structure-specific spectral intensity measures for seismic evaluation of reinforced concrete frames

Statistical properties of circular and rectangular multi-sinc Schell-model beams propagating in uniaxial crystals

With the extended Huygens–Fresnel principle, we derive the expressions for the spectral intensity, coherence, and effective beam width of circular and rectangular multi-sinc Schell-model (MSSM) beams propagating through uniaxial crystals. Numerical simulations are employed to extensively explore how beam and crystal parameters modulate the optical field. The results reveal that the propagating field exhibits multiple ring-shaped and array-like intensity distributions, with adjustable features such as the number of concentric rings, central brightness, array dimensions, and the morphology and diversity of sub-beams. Additionally, the spectral coherence displays an oscillatory distribution that evolves into a Gaussian distribution as the transmission distance increases. The anisotropy of uniaxial crystals not only influences the morphology of intensity distribution but also affects the evolution rate of coherence and the expansion rate of effective beam width. Our work contributes to optimizing beam propagation through uniaxial crystals, potentially benefiting precision optical systems in laser technology.

Application of Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy in Human Sera: Validate the method for contributing effective strategy for the storage and preservation

The serum is one of the biological specimens that have been extensively studied as biomarkers and is recognized as an effective tool for screening and diagnosing a variety of diseases. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) is a practical technique utilized in investigating characteristic spectra in infectious diseases cancer, and metabolic status. However, the pre-analytical procedure as storage condition is a crucial phase that directly impacts the accuracy of the result. In this study, we intend to investigate the effects of serum stabilization under both identical and distinct storage conditions on the FTIR spectral patterns, intensity variations, and macromolecule composition. The ten serum samples were stored in 3 different conditions including 4 °C, −20°C, and −80°C for six different time intervals (7, 14, 21, 28, 56, and 84 days). The spectra were obtained by ATR-FTIR spectroscopy. The serum stabilization was studied in two investigations: one focusing on the stability of serum under identical conditions over six different time intervals, and the other examining the stability of serum stored under three distinct conditions. Principal Component Analysis (PCA) and Area Under the Peak (AUP) were used to investigate clusters in different sets of data across five spectral ranges. The macromolecule composition was identified in conjunction with the intensity measurements. The results showed that the same conditions remained stable across six different time intervals, as indicated by the consistent PCA results. In contrast, the stabilization of serum under different temperature condition showed different major intensities across the five selected positive bands, including 1781 cm−1, 1740 cm−1 1727 cm−1 corresponding to lipid region (1800–1700 cm−1), and Amide region (1700 −1500 cm−1) at 1646 cm−1, and 1632 cm−1, when the serum was stored over 28 days. This might involve lipid peroxidation-induced changes in the secondary structure of proteins. Our findings indicated that serum should be stored at −80°C to ensure stabilization and achieve the highest intensity. Additionally, preserving serum under consistent conditions was crucial to minimize variability and prevent external factors from affecting the results.

Improvement of optical noise in optical-injection-locked quantum dot lasers epitaxially grown on silicon by reducing external carrier noise

Abstract This study theoretically investigates the impact of external carrier noise from pumping sources on the optical noise of epitaxial quantum dot (QD) lasers on silicon. The findings indicate that the spectral linewidth and relative intensity noise (RIN) of silicon-based QD lasers using a quiet pump are significantly reduced. At 5.5 times the threshold current, the spectral linewidth decreases from 337.2 kHz to 213.2 kHz, and the RIN decreases from −141.3 dB Hz−1 to −168.8 dB Hz−1. This reduction is attributed to the lower external carrier noise level of the quiet pump, which also suppresses the spectral linewidth rebroadening effect at a high bias current. Moreover, when external optical injection locking is applied, the spectral linewidth further decreases to 24 kHz at an injection ratio of −70 dB and to 1.8 mHz at 0 dB. The RIN also slightly decreases to −172.4 dB Hz−1 with an injection ratio of 10. These results demonstrate that using a quiet pump is an effective and manageable strategy for significantly reducing both the spectral linewidth and RIN of QD lasers, thereby facilitating their application in next-generation photonic integrated circuits, continuous-variable quantum key distribution, quantum computing and ultra-precise quantum sensing.

Calibration and Release of Magnetograms/Dopplergrams Obtained at the Mt. Wilson 150-Foot Tower Telescope (MWO)

The Mt. Wilson Observatory archive of observations of solar disk magnetic fields, Doppler velocities, and spectral line intensities is a resource for studying the Sun’s state from 1967 to 2013. Instrument changes/upgrades during this time must be considered when interpreting this record. Portions of this record have been previously released. This publication documents the data record in order to allow its independent interpretation. The archive is available through two directory trees which can be accessed at http://sha.stanford.edu/mwo/msm.html. The calibration of the observations is impacted by the solar surface convective flows, which produce offsets for both differential rotation and meridional circulation functions. The effects of these offsets have been reduced in this and other publications by temporal averaging.

3He and Fe Spectral Properties in 3He-rich Solar Energetic Particle Events

We have surveyed 3He-rich events on the Solar Orbiter mission from 2020 April to 2024 April, selecting isolated injections whose rollover 3He spectral shape is presumed to represent the initial acceleration state, unprocessed by subsequent activity such as coronal mass ejections or jets. A main goal has been to find relationships between the spectra of 3He and heavy ions C–Fe, in order to explore a common acceleration mechanism in spite of the fact that these events show 3He enrichments of up to ∼104, while the heavy-ion enrichment is rarely larger than ∼10. Selecting 34 3He injections, we find that heavy ions are always present, and arrive at the same time as the 3He signaling a common origin. Concentrating on Fe since it is a minor ion but with higher abundance than many others, we find its spectral shape and intensity is similar to 3He. In ∼two-thirds of the cases, if the 3He spectrum is shifted to lower energy by a factor 3.0 ± 1.3, it nearly coincides with the Fe spectrum, illustrating their close connection. Several plasma wave turbulence models have calculated spectra that also show the ion rollovers around 1 MeV nucleon−1. The unique mass-to-charge ratio of 3He allows it to interact more efficiently with the turbulence, thereby gaining several times more energy per nucleon than the other heavy ions. In the spectral rollover region this can lead to the observed enormous enhancements of 3He. The acceleration appears to be associated with magnetic reconnection in emerging flux regions on the Sun.

Double perovskite CaSrMSbO6(M = La, Gd, Y): Bi3+ phosphors for multifunctional application

Bi3+-doping luminescent materials have recently evoked considerable interest in versatile applications. In this work, we have developed a series of Bi3+-activated CaSrMSbO6(M = La, Gd, Y) phosphors with double perovskite structures, exhibiting blue emission from 350 nm to 500 nm. The emission spectral position and intensity of Bi3+ ions can be tuned by changing excitation wavelength and doping concentrations. The relationship between the local crystal field environment and the luminescence properties is comprehensively analyzed. Importantly, optical temperature properties of CaSrLaSbO6: Bi3+ were investigated and were found to reach a maximum relative sensitivity of 4.57 % K−1 at 298 K. Furthermore, the anti-counterfeiting ink was prepared using CaSrLaSbO6: Bi3+ phosphors, and it showed tunable emission under different light stimulation. These results indicate that CaSrLaSbO6: Bi3+ phosphors have application potential in optical temperature sensing and anti-counterfeiting.

Experimental investigation of OH* emission spectrum characteristics and transient ignition dynamics in methane and coal dust mixtures explosions

Combustible gases, dusts and their mixtures are widely present in human production and life，and the fire and explosion disasters caused by them pose a serious threat to the field of energy security applications. Studying the ignition process of mixtures is essential for disaster risk assessment and safety protection. In this work, the explosion characteristics and OH* emission spectra of the mixtures were experimentally tested by varying the fuel equivalence ratio ( ER ≈ 0.79 ~ 1.71), and the evolution of the transient flow field structure during the ignition process was quantitatively analyzed using the schlieren image velocimetry method. The results indicate that the emission spectrum of OH* is closely correlated with the maximum explosion pressure, and the spectral intensity of OH* at 306.4nm is consistent with the maximum rate of explosion pressure rise. The flow field during the ignition process of the mixtures shows that a small amount of coal dust (concentration≤30g/m3) can significantly promote flame acceleration and instability as the methane concentration is in lean combustion or stoichiometric ratio. However, when the concentration of coal dust increases (concentration≥40g/m3), coal dust will suppress flame acceleration and instability. For methane concentration in fuel-rich combustion state, coal dust always suppresses flame acceleration and instability. The experimental results contribute to a further understanding of gas and coal dust mixed explosions and provide a verification database for the construction of chemical kinetic mechanisms.

Study on the Impact of Air Pressure on the Laser-Induced Breakdown Spectroscopy of Intumescent Fireproof Coatings

Intumescent fireproof coatings protect steel structures and cables by forming a thick, fire-resistant layer under high temperatures. These coatings can deteriorate over time, impacting their fire resistance. Current testing methods are largely lab-based, lacking in-service evaluation platforms. Laser-Induced Breakdown Spectroscopy (LIBS) is emerging as a promising in situ detection technology but is influenced by low air pressure in high-altitude areas. This study investigates how air pressure affects LIBS signals in intumescent coatings on galvanized steel. Using pressures between 35 and 101 kPa, a linear model was developed to correlate laser pulses to ablation depth for characterizing coating thickness. Results show that spectral intensity decreases with lower air pressure. However, a strong linear relationship persists between laser pulses and ablation depth, with a fitting accuracy above 0.9. The coating thickness is identified by the number of laser pulses required to detect the Zn spectral line from the underlying galvanized steel. As air pressure decreases, the ablation depth increases. The study effectively models and corrects for air pressure effects on LIBS data, enabling its application for field detection of fireproof coatings. This advancement enhances the reliability of LIBS technology in assessing the fire performance of these materials, providing a reference for their in situ evaluation and ensuring better fire safety standards for building steel structures and cables.

Ozone production in nanosecond pulsed dielectric barrier discharge in synthetic air: the Effect of Pulse Width

This work investigates the effect of pulse width on the characteristics of electrical discharge, optical emission spectra and ozone production in a water electrode DBD using a modulable nanosecond pulsed power supply. Results show that the increase of pulse width tpw slightly increases the spectral intensity and the rotational temperature Trot, with a typical Trot of 299 ± 5 K at an applied peak voltage Vp of 18.6 kV and a tpw of 400 ns. The electronic excitation temperature Texc increases linearly with Vp and gradually with tpw, while the electron density ne shows a non-linear relationship with tpw. Results also show that an increase in tpw slightly increases the energy density. At low energy densities (SIE < 50 J/L), increasing tpw can improve ozone generation efficiency, reaching a maximum of 99.64 ± 0.87 g/kWh at 33.60 ± 1.53 J/L at a tpw of 900 ns. This investigation provides substantial insight into the nanosecond pulsed ozone production.

Enhancing silicon spectral emission in LIBS using Tesla coil discharge

Abstract Laser-induced breakdown spectroscopy (LIBS) is a powerful technique for elemental analysis, offering rapid analysis, minimal sample preparation, wide elemental coverage, and portability. To enhance the detection sensitivity of LIBS, increasing the spectral emission intensity is crucial. This paper explores the use of Tesla coil (TC) discharge as an alternative to spark discharge in silicon LIBS. The study examines the influence of TC discharge on both time-integrated and time-resolved spectra, with and without TC discharge; the corresponding electron temperature and density are obtained. The results show that TC discharge significantly amplifies the spectral intensity, improving signal sensitivity in LIBS analysis. Specifically, in the laser energy range from 7.4 to 24.0 mJ, TC discharge increased the average spectral line intensities of Si (II) 385.60 nm and Si (I) 390.55 nm by factors of 8.4 and 5.1, respectively. Additionally, the average electron temperature and density were enhanced by approximately 3.2% and 4.2%, respectively, under TC discharge. The advantages of TC discharge include higher energy deposition, extended discharge duration, reduced electrode erosion, and enhanced safety. This research contributes to advancing LIBS technology and expanding its applications in various fields.

A spectral bias-error stepwise correction method of plasma image-spectrum fusion based on deep learning for improving the performance of LIBS

Poor spectral stability seriously hinders the wide application of laser-induced breakdown spectroscopy (LIBS), so how to improve its stability is the focus, hotspot, and difficulty of current research. In this study, to achieve high precision quantitative analysis under complex detection conditions, utilizing the fusion of multi-dimensional plasma information and the integration of physical models and algorithmic models, a spectral bias-error stepwise correction method of plasma image-spectrum fusion based on deep learning (SBESC-PISF) was proposed. In this method, based on the statistical properties of LIBS spectra, the actual obtained spectra were decomposed into three parts: the ideal spectral intensity related only to the element concentration, and the spectral bias and spectral error caused by the fluctuation of complex high-dimensional plasma parameters. Further, the deep learning methods were used to fully excavate all the effective features in the plasma images and spectra to invert the complex high-dimensional plasma parameters according to the physical models. Finally, the estimation models of spectral bias and spectral error were established based on these features, to realize the high-precision correction of spectral intensity. To verify the feasibility of SBESC-PISF, the spectra of aluminum alloy samples obtained under three complex detection conditions were used for analysis. Under the experimental condition of laser energy fluctuation, after correction by SBESC-PISF, R2 of the three calibration curves was all increased to 0.999, RMSE and STD of the validation set (RMSEV, STDV) were reduced by 55.246 % and 50.167 %, respectively. Under the experimental condition of defocusing amount fluctuation, R2 was also all increased to 0.999, RMSEV and STDV were decreased by 58.201 % and 51.006 %, respectively. When the laser energy and defocusing amount fluctuate simultaneously, R2 was increased to 0.999, 0.996 and 0.988, RMSEV and STDV were reduced by 58.776 % and 54.397 %, respectively. These experimental results demonstrate that the spectral fluctuation correction of SBESC-PISF under complex detection conditions is effective and has wide applicability.