Specific Strength Research Articles

Advances in carbon-fiber reinforced polymers and composites for sustainable concrete structures

Sustainable materials that are characterised with cost-effectiveness, high durability and low density are typically required in the civil engineering markets to survive unfavourable severe loading and harsh environmental circumstances. Because of this, new applications in building and construction works have made the use of sophisticated composite materials as reinforcing for a wide spectrum of building structures. Carbon fibre reinforced polymers (CFRP) which possess remarkable attributes like high specific strength, stiffness, and lightweight nature, have garnered significant interest in the repairing and reinforcement of concrete structures. Improving the intrinsic material qualities of any construction material, like CFRP, is the most straightforward approach to make it better. Many of the restrictions associated with using materials can be overcome once the qualities of CFRP can be improved. This review, therefore, gives a thorough summary of the features and applications of CFRP in different building structural parts, including concrete slabs, columns, beams among others. Different fabrication techniques and surface modifications of CFRP to provide insight into their capabilities and possible drawbacks are highlighted. Moreover, sustainability issues surrounding CFRP as well as their recycling potentials in the circular economy are discussed. We conclude by providing outlook and challenges regarding the usage of CFRP composites in civil engineering applications.

Ceramic/metal composites fabricated via 3D printing and ultrasonic-assisted infiltration for high specific strength and energy absorption

To address the strength-toughness dilemma, ceramic/metal interpenetrating phase composites (IPCs), fabricated through metal infiltration into ceramic perform, have been investigated. However, infiltrating metal into porous ceramic scaffold with high volume fraction remains a significant challenge. Herein, we propose a novel method to fabricate highly dense Al2O3/AlSi10Mg (Al) interpenetrating phase composites through ultrasonic-assisted pressureless infiltration into 3D printed ceramic scaffolds. Experimental results indicate that the as-fabricated Al2O3/Al IPCs exhibit excellent quasi-static and dynamic mechanical properties. Specifically, the materials can achieve high specific compressive strengths of 148.6 ± 5.2 MPa/(g/cm3) under quasi-static compression and 228.6 ± 4.5 MPa/(g/cm3) under dynamic compression while also exhibiting high specific energy absorption of 33.6 ± 0.9 J/g under quasi-static compression and 37.7 ± 1.1 J/g under dynamic compression. The specific compressive strength and specific energy absorption of the as-fabricated Al2O3/Al IPCs outperform those of the literature-reported ceramic/metal IPCs. This work provides an innovative approach to fabricate strong and tough ceramic composites.

Systematic Evaluation of Isometric Maximal Muscle Strength in an Orthopaedic Cohort.

Although the lower extremities are essential for movement function and human gait, no normalized isometric maximum strength values, which include the factors gender, age, weight, height, and body mass index (BMI), have been defined to date for orthopaedic patients. To systematically analyze the isometric maximal muscle strength of a cohort in an orthopaedic outpatient clinic and to evaluate its relation to gender, age, weight, height, BMI, and the differences between diseases. Cross-sectional study. Level 4. Isometric maximal muscle strength of knee extension, knee flexion, hip abduction, and hip adduction was measured in orthopaedic patients of an outpatient clinic using a specific muscle strength measurement device. Correlation analysis was performed for age, gender, height, weight, and BMI. Patients were grouped by disease characteristics. The cohort consisted of 311 subjects (sex: 164 male, 147 female; age: 48.63 years, SD = 16.595; BMI: 26.56 kg/m², SD = 4.9). Age correlated significantly with maximal isometric muscle strength. At the age of 54 years onward, based on 133 patients, a decline in maximum isometric muscle strength was detected. Gender showed a strong influence on maximal isometric muscle strength, with significantly higher values for male patients. Furthermore, weight and height, but not BMI, correlated significantly with muscle strength. For clinical studies comparing different evidence-based training interventions for rehabilitation, it is important to consider determinants such as gender, age, weight, and height for isometric maximum strength measurement. For further validation, follow-up examinations taking into account the performance level, other target groups, and other muscle groups are required to avoid the wide dispersion of isometric maximum strength values. These results and associated determinants are highly clinically relevant and can be used as a reference for further studies in the field of musculoskeletal regeneration.

Probabilistic investigation of piezoelectric application for reliability enhancement of composite laminates under edge delamination

In this research a novel probabilistic numerical approach is developed to investigate the effectiveness of piezoelectric (PZT) materials to enhance the reliability of composite laminates under edge delamination onset (EDO). To achieve this, finite element (FE) modeling is employed as an implicit limit state function (LSF) based on a quadratic failure criterion and the concept of critical length. An interactive interface that integrates FE analysis and reliability analysis is then established to execute both processes simultaneously until the convergence condition of the reliability index is satisfied. To validate current FE analysis, the interlaminar stress peaks, and resulting edge delamination probability obtained in this study are compared with available data. Subsequently, the probability of EDO in angle-ply composite laminates under applied longitudinal strain and an applied electric field on the PZT layer is assessed using both the first-order reliability method (FORM) and the second-order reliability method (SORM). The Monte Carlo simulation (MCS) is employed to verify the numerical results. Findings reveal that employment of PZT reduces EDO probability. Moreover, as the applied voltage increases, the critical strain required for definitive EDO also increases, and the positive influence of PZT on enhancing reliability becomes more pronounced, particularly with increased thickness under higher applied strain.

Design and characterization of novel Ti-8Mo-xFe-yCu alloys as implant materials: Evaluation of biocompatibility, mechanical properties, and antibacterial potential

Titanium and its alloys are highly desirable materials for biomedical metallic implants due to their superior specific strength, excellent corrosion resistance, and exceptional biocompatibility. Among these alloys, Ti6Al4V is widely used in practical biomedical applications because it offers an excellent combination of strength, fracture toughness, and corrosion resistance. However, recent research has revealed limitations in its biocompatibility attributed to the presence of toxic elements such as Al and V. In addition, it has been reported that Ti6Al4V is costly due to the addition of Vanadium and has the potential for post-implant inflammation. As a result, researchers have been investigating new biomedical beta-Ti alloys using biocompatible, affordable, and easily accessible beta-stabilizers like Mo, Fe, and Cu, to achieve similar performance as Ti6Al4V alloys. The present study aims to develop a novel biomedical alloy through the arc melting method, to obtain an implant material possessing low elastic moduli, biocompatibility, and antibacterial properties to mitigate the risk of post-implant inflammation. Microstructural analysis was conducted using microscopy and x-ray diffraction, while the mechanical properties were evaluated through micro vickers hardness testing machine and elastic moduli measurement utilizing the impulse excitation technique. Cytotoxicity assessment was performed using the (Cell Counting Kit-8) CCK-8 method, followed by an examination of the alloy's antibacterial properties using the point counting method. β-Ti single phase was obtained in this study with the addition of ≥1% Fe and ≥1% Cu. The Ti-8Mo-2Fe-2Cu alloy was found to have the lowest elastic moduli of 95 GPa. Electrochemical measurements show that the Ti-8Mo- xFe- yCu alloys have a lower corrosion current density of around 0.319–2.317 µA/cm2 compared to Ti6Al4V of 16.543 µA/cm2. The Ti-8Mo-1Fe-3Cu, Ti-8Mo-3Fe-1Cu, and Ti-8Mo-3Fe-3Cu alloys have comparable biocompatibility with Ti6Al4V with the viability of mesenchymal stem cells (MSCs) above 75% and have a positive antibacterial response. Ti-8Mo-3Fe-3Cu alloy demonstrates the most favorable blend of microstructure, mechanical attributes, corrosion resistance, cell viability, and antibacterial properties as an alternate biomaterial for implant applications.

Prediction method for re-damage behavior of the repaired CFRP bolted joint

Composite materials are widely used in various aircraft due to their high specific strength, stiffness, corrosion resistance, and robust design flexibility. However, when subjected to complex loading conditions, composite structures are susceptible to damage, necessitating prompt repair upon aircraft return. Analyzing the re-damage process of repaired structures is crucial for assessing aircraft structural reliability, lifespan, and determining whether a repeat flight is warranted. In this study, a prediction method was proposed for re-damage behavior through meso-modeling and energy analysis of the repaired composite bolted joint. First, this article established a meso-mechanical model for composite laminates, analyzed force transfer characteristics at the fiber − matrix interface, and derived equations for stress field. Additionally, a strain energy distribution model was developed for composite bolted repaired joint near fibers and repaired area, proposing a damage prediction method based on the strain energy criterion. This method could anticipate the location, type, sequence, and magnitude of damage. Finally, simulation calculations yielded mechanical characteristics of the repaired area under typical load conditions, while loading tests verified the feasibility of the prediction method. This study offered an effective means of predicting performance degradation in composite structures and provided a vital direction for optimal spacecraft structure repairing methods and parameters.

Enhancement of mechanical properties and machinability of aluminium composites by cupola slag reinforcements

AbstractRapid evolution in engineering and manufacturing demands light weight material with enhanced mechanical properties. Aluminium metal matrix composites with ceramic reinforcement particulates serve this demand due to their reduced density, improved strength and hardness along with higher resistance to wear and corrosion. However, the material cost and reduced machinability hinders the full potential of utilization. To overcome these challenges, in this work cupola slag, an industrial waste generated as by product of cast iron production, has been incorporated as reinforcement of aluminium composites using low cost stir casting method. The enhancement of material properties and machinability by cupola slag inclusion on base alloy has been investigated in detail. Moreover, introspection about the underlying mechanisms responsible for the improvement in material properties has been studied using detailed microstructure and fractographic analysis. The results show improvement of in material properties and machinability up to 7 wt.–% cupola slag inclusion, beyond which the reduced wettablity prohibits sound castings. The ultimate tensile strength and specific strength observed to be improved by 18.20 % and 33.23 % respectively for 7 wt.–% slag reinforced composites when compared with base alloy. This work can be a successful addition to the knowledge pool of ongoing research on low‐cost novel material with enhanced properties.

Microstructure, Mechanical, and Tribological Properties of Nb-Doped TiAl Alloys Fabricated via Laser Metal Deposition.

TiAl alloys possess excellent properties, such as low density, high specific strength, high elastic modulus, and high-temperature creep resistance, which allows their use to replace Ni-based superalloys in some high-temperature applications. In this work, the traditional TiAl alloy Ti-48Al-2Nb-2Cr (Ti4822) was alloyed with additional Nb and fabricated using laser metal deposition (LMD), and the impacts of this additional Nb on the microstructure and mechanical and tribological properties of the as-fabricated alloys were investigated. The resulting alloys mainly consisted of the γ phase, trace β0 and α2 phases. Nb was well distributed throughout the alloys, while Cr segregation resulted in the residual β0 phase. Increasing the amount of Nb content increased the amount of the γ phase and reduced the amount of the β0 phase. The alloy Ti4822-2Nb exhibited a room-temperature (RT) fracture strength under a tensile of 568 ± 7.8 MPa, which was nearly 100 MPa higher than that of the Ti4822-1Nb alloy. A further increase in Nb to an additional 4 at.% Nb had little effect on the fracture strength. Both the friction coefficient and the wear rate increased with the increasing Nb content. The wear mechanisms for all samples were abrasive wear with local plastic deformation and oxidative wear, resulting in the formation of metal oxide particles.

Fracture properties and acoustic emission characteristics of manufactured sand recycled fine aggregate concrete

To promote the application of recycled fine aggregates, fracture characteristics of concrete beams containing manufactured sand (MS) and recycled fine aggregate (RFA) were investigated. The fracture properties and acoustic emission (AE) characteristics of manufactured sand recycled fine aggregate concrete (MSRFAC) with 0 %, 25 %, 50 %, 75 % and 100 % RFA replacement rates were evaluated by three-point bending test of single-sided notched beams. The fracture mechanisms of MSRFAC beams were explored using AE and digital image correlation (DIC) techniques, and fracture process zone (FPZ) was qualitatively and quantitatively analyzed. The results indicated that the critical nominal stiffness, initial fracture toughness, fracture energy and characteristic length of MSRFAC decreased significantly with the increase of RFA replacement rate, up to 20.2 %, 37.7 %, 22.8 %, and 26.6 %, respectively, while the unstable fracture toughness was insensitive to the variation of RFA. Moreover, the AE activity, the tensile crack, large-scale crack, high amplitude, and high peak frequency in MSRFAC increased with increasing RFA replacement rate. According to the FPZ characteristics of MSRFAC, its FPZ length increased with the increase of RFA replacement rate, while the FPZ width decreased with the increase of RFA replacement rate. The critical FPZ lengths of MSRFAC with different RFA replacement rates were about 20.2–30.0 mm, and the maximum FPZ widths were about 26.0–36.7 mm. The RFA weakened the friction mechanism and interlocking effect between aggregates of MSRFAC, resulting in a faster FPZ propagation rate and smaller damage width of MSRFAC than normal manufactured sand concrete.

Research Progress on the Microstructure Evolution Mechanisms of Al-Mg Alloys by Severe Plastic Deformation.

Al-Mg alloys are widely used as important engineering structural materials in aerospace engineering, transportation systems, and structural constructions due to their low density, high specific strength, corrosion resistance, welding capability, fatigue strength, and cost-effectiveness. However, the conventional Al-Mg alloys can no longer fully satisfy the demands of practical production due to difficulties caused by many defects. The high strength of Al-Mg alloys as non-heat treatment precipitation-strengthened alloys is achieved primarily by solid solution strengthening along with work hardening rather than precipitation strengthening. Therefore, severe plastic deformation (SPD) techniques can be often used to produce ultrafine-grained structures to fabricate ultra-high strength aluminum alloys. However, this approach often achieves the strengthening of material at the cost of reduced ductility. This paper comprehensively summarizes the various approaches of ultrafine/nanocrystalline materials for enhancing their plasticity, elaborates on the creation of a bimodal microstructure within the alloy, and discusses the formation of a nanotwin microstructure within the alloy and the incorporation of dispersed nanoparticles. The mechanisms underlying both the strengthening and toughening during large plastic deformation in aluminum alloys are summarized, and the future research direction of high-performance ultrafine crystalline and nanocrystalline Al-Mg aluminum alloys is prospected.

Critical crack length during fracture.

Through controlled numerical simulations in a one-dimensional fiber bundle model with local stress concentration, we established an inverse correlation between the strength of the material and the cracks which grow inside it-both the maximum crack and the one that sets in instability within the system, defined to be the critical crack. Through the Pearson correlation function as well as probabilistic study of individual configurations, we found that the maximum and the critical crack often differ from each other unless the disorder strength is extremely low. A phase diagram on the plane of disorder vs system size demarcates between the regions where the largest crack is the most vulnerable one and where they differ from each other but still show moderate correlation.

Applying a thermodynamic-based method to reveal the failure laws of CFRP stiffened plates

The high specific strength and stiffness of carbon fiber-reinforced polymer (CFRP) stiffened plates make them popular in aerospace and other fields. Nevertheless, CFRP stiffened plates have unique characteristics and complicated and diversified failure patterns, so it is impossible to determine its failure law with a uniform failure criterion accurately. Its load-carrying capacity has always been calculated on the conservative side of empirical estimation. This work uses the stressing state theory to investigate the stressing state evolution of composite stiffened plates under axial loading. It conducts three CFRP stiffened plates of the same configuration from a thermodynamic perspective. By equating stiffened plates to thermodynamic systems, the measured strain data are modeled as state variables, and renormalization and clustering algorithms are applied to determine the phase transition loads of the structure, while the characteristic points before and after normalization are verified for their reasonableness and stability. Accordingly, this work reveals the failure laws of CFRP stiffened plates by applying a thermodynamic-based method. It characterizes the structural failure features by defining catastrophe points throughout the failure process, which provides a new reference for the failure analysis and strength design of CFRP stiffened plates.

Elastic–Plastic Buckling of Scaled Model of Radial Ring-Stiffened Shallow Spherical Shells Based on Energy Method

Stiffened shallow spherical shell has the advantages including high strength and light weight, which allows it to be widely applied in areas including aerospace, submarine and civil engineering. For the design of scaled model for elastic–plastic buckling of a large radially–circumferentially stiffened shallow spherical shell under uniformly distributed pressure and for the purpose of similarity prediction, the similarity relation of the elastic–plastic buckling coefficient of the shell is derived; then by using the dense stiffening theory and considering the dual nonlinearity of geometry and materials, the energy increment formula for the structure under uniformly distributed external pressure is established; next, based on the similarity transformation of the energy increment of the structural system, the generalized similarity condition and similarity relation of elastic–plastic buckling of the structure under uniformly distributed external pressure are identified. Based on the scaling and equivalence of tensile–compressive stiffness and bending stiffness, the distortion scaled model for the prototype is designed. Through numerical simulation, the distortion similarity prediction for elastic–plastic buckling under uniformly distributed pressure of the radially–circumferentially stiffened shallow spherical shell that has square-shaped dimple defects has been conducted; based on the derived similarity relation of elastic–plastic buckling of stiffened plate, the similarity prediction for the elastic–plastic buckling of orthogonally stiffened plate in the plane under unidirectional uniformly distributed pressure has been conducted. The results indicate that the load–displacement curve, buckling load, and buckling mode of the distortion similarity scaled model, combined with the established radial displacement scaling factor expression, the scaling relation of tension–compression stiffness, and the similarity relation of buckling mode, can effectively predict the elastic–plastic buckling characteristics of its prototype structure. The research results can provide theoretical reference for the design and test of the scaled model with distortion of elastic–plastic buckling of similar stiffened large shell structures.

Wire-arc additive manufacturing of Mg-Gd-Y-Zn-Zr alloy: Microstructure and mechanical properties

Mg-Gd-Y-Zn-Zr alloy is an essential high strength weight ratio material in the aerospace field. It has been fabricated gradually using wire-arc additive manufacturing (WAAM), a key integrated preparation technology for large-scale parts. In this investigation, a Mg-9.4Gd-3.3Y-1.75Zn-0.38Zr (wt.%) alloy was prepared by WAAM based in the cold metal transfer (CMT) process. Investigations were conducted into the microstructural evolution and mechanical properties during the solution and aging heat treatment. With an average grain size of 18.30 ± 9.89 μm, the as-deposited Mg-Gd-Y-Zn-Zr alloy is mainly composed of α-Mg matrix, (Mg,Zn)3(Gd,Y) eutectic phase, RE-rich particles, and rare-earth (RE) segregation zone. Following a 12-h heat treatment at 500 °C, the average grain size of the α-Mg matrix showed no appreciable changes. The α-Mg matrix also dissolved the (Mg, Zn)3(Gd, Y) phases, which led to the production of long period stacking ordered (LPSO) phases and the disappearance of the RE-segregation zone. The appearance of the nanoscale β′ phase following aging heat treatment. The deposited alloys had the following tensile properties: 196.5 ± 24 MPa for ultimate tensile strength (UTS), 157.2 ± 14 MPa for yield strength (YS), and 2.08 ± 0.8% for elongation (EL). The formation of LSPO phase can improve the ductility while the formation of nanoscale β′ phase can improve the strength of Mg-Gd-Y-Zn-Zr alloy. Thus, after heat treatment at 500 °C for 12 h, the alloy's EL rose to 9.27 ± 0.94%. After further aging heat treatment for 225 °C at 24h, the alloy's YS rose to 234±3 MPa and its EL was 4.56 ± 0.25%.

Growth mechanism and performance of MAO-AO composite coating obtained by two-stage process

Titanium alloys, with the high specific strength and low elastic modulus, are currently the research focus of many applications. Various surface treatments have been applied with the intention of improving their wear and corrosion resistance. Micro-arc oxidation (MAO) technology originated from anodic oxidation (AO) technology, which has the advantages of simple process, high efficiency and environmentally friendly electrolyte. However, due to the micro-arc discharge effect, MAO coatings inevitably show the characteristic of high porosity. In this study, post-treatment of MAO coatings using AO was proposed to obtain a composite coating with both high hardness and low roughness and porosity thereby compensating for the defects of MAO coatings. After preparation, each sample was analyzed and characterized. The results indicated that AO was main conducted in the discharge channel of MAO coating and an amorphous phase coating with the matrix oxide as main component was grown in situ. The composite coating showed a slight increase in thickness and significant reduction in roughness than MAO coating and with superior wear and corrosion resistance. In conclusion, this study provides new idea and data support for improving the performance of MAO coatings, which is expected to be widely used in the field of surface treatment.

Identifying effective parameters on capillary tube performance with HCFCs, HFCs blends, and hydrocarbon refrigerants: Numerical assessment

This work offers a comprehensive numerical evaluation of the performance of capillary tube utilizing different refrigerants, including HCFCs, HFCs blends (Zeotropic, Azeotropic), and hydrocarbon, such as such as R22, R404A, R407C, R410A, R507A, and R290 refrigerants to predict the critical length of the adiabatic capillary tube. Utilizing a comprehensive thermodynamic model is applied to simulate the behavior of different refrigerants. Moreover, the effective design parameters based on the internal diameter for the adiabatic capillary tube (ACT), inside surface tube roughness, degree of subcooled, metastable region, condenser diameter, design of evaporator pressure (at critical length), condenser operating pressure, and refrigeration capacity are considered. The numerical model is developed based on the governing equations for mass, momentum, and energy, while a specified empirical equations are employed to represent each of the friction factor for single-and-two phase flow and metastable region. The results showed that the longest length of the ACT of 10.5 m revealed with R410A at mass flow rate of 8 g/s compared with 0.25 m at mass flow rate of 16 g/s for R290. Also, the results showed that the minimum value of friction factor of 0.0189 for R410A compared with maximum value of 0.0208 for R407C. The developed model is validated with available experimental results and models under different operation conditions and is found expectable with a good agreement. Where the standard error for different refrigerant with range value between (2.774% to 3.677%). However, the model represents accurate prediction the flow behavior and the thermal performance of the ACT.

AC breakdown and decomposition products detection characteristics of eco-friendly insulating medium in gas insulated switchgear

Gas Insulated Switchgear (GIS) was a crucial electrical equipment that provides the safety and security of power systems, and finding the eco-friendly alternatives of sulphur hexafluoride (SF6) as insulating medium in GIS has been an urgent demand in past decades. However, few studies reported the specific dielectric strength under various electrodes and partial discharge (PD) decomposition products detection of applying the eco-friendly gas in GIS. In this paper, the insulation properties among C4F7N/CO2 mixtures, dry air and CO2 were explored under the reduced-scale gas-insulated experimental device. The relationship between AC breakdown voltage and gas pressure was gained under the different electrodes and gap distances, and 0.6 MPa 7% C4F7N/93% CO2, 0.9 MPa dry air, 0.9 MPa CO2 all possess the capacity to be the insulating medium in eco-friendly gas insulated switchgear. Furthermore, the partial discharge experimental was also carried out to realize the decomposition products detection of dry air, which designs three common defect types including metal protrusion defects, air gap defects, and metal contamination defects. The decomposition products detection result shows that the contains of CO2, CO, and NO2 linearly increase with the increasing applied voltages and times, and the partial discharge defects are distinguished according to the ratios of c(CO2 + CO)/c(NO2) and c(CO2)/c(CO). The results can provide the basis for the further development of eco-friendly gas insulated switchgear.

Spark plasma sintering of cenosphere-derived Cs/Sr-aluminosilicates for 137Cs and 90Sr immobilization in mineral-like ceramics

In this study, a promising method of spark plasma sintering (SPS) was investigated for the fabrication of ceramic matrices designed for the reliable immobilization of highly radioactive radionuclides 137Cs and 90Sr. The ceramic matrices were derived from a mixed composition of two aluminosilicate mineral-like phases – pollucite (Cs,Na)AlSi2O6 and gehlenite Sr2Al2SiO7. The originality of the developed approach lies in the utilization of hydrothermal synthesis for obtaining granulated precursor material. Hollow aluminosilicate microspheres (cenospheres) from coal fly ash served as the initial raw material, which were treated with alkaline solutions containing Cs+ and Sr2+ ions as simulants for the corresponding radionuclides. This method facilitated the achievement of high efficiency in cation removal from solutions exceeding 98 %. For a comprehensive examination of the composition and morphology of cenosphere-derived precursor particles, and the influence of sintering temperature on phase and structure formation of ceramic matrices under non-equilibrium conditions of spark plasma heating, various analytical techniques were employed. These included thermogravimetry/differential thermal analysis (TG/DTA), powdered X-ray diffraction analysis (PXRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), as well as the method of low-temperature nitrogen adsorption for determining the specific surface area. The obtained ceramic samples exhibited high values of specific density (2.688–2.915 g/cm³), compressive strength (666–808 MPa), and Vickers microhardness (1.8–2.5 GPa), attesting to their high quality and stability. The results of the hydrolytic stability assessment revealed that the leaching rates of Cs+ and Sr2+ ions from the ceramics are extremely low, within the range of 10−5–10−6 g/cm²·day. These values fully satisfy the requirements of GOST R 50926–96 and the international standard ISO 6961:1982 for solidified forms of high-level waste.

Insight into the less β-phase induction by calcium pimelate in polypropylene random copolymer

Although calcium pimelate (CaPim) is recognized as an efficient β-nucleating agent for polypropylene with nucleating ability solely for the β-phase, it was found to induce less β-phase in polypropylene random copolymer (PPR) compared to polypropylene homopolymer (PPH). Generally, this reduction is attributed to unfavorable β-growth. Besides growth, here, nucleation behavior was also investigated in detail. With nucleation barrier determined through fractionated crystallization, the relative β-nuclei proportion induced by CaPim was calculated to be 96.6 % for PPH and 79.1 % for PPR with 7.3 mol% ethylene inserted. This fewer β-nuclei induction may be linked to a decreased proportion of isometric sequences exceeding the critical length required for β-nucleation. As expected, the relative growth rate of the β- to α-phase (Gβ/Gα) is lower in PPR indicating unfavorable β-growth. These results indicate that diminished β-nuclei induction and subsequent unfavorable β-growth jointly result in less β-phase induction in PPR.

Failure Behavior of Titanium/CFRP Hybrid Composites Under Tensile Loading

Carbon fiber reinforced polymer (CFRP) composites have found widespread use in various lightweight engineering applications, owing to their high stiffness and strength at low density. Nevertheless, they exhibit certain weaknesses, such as low bearing strength, leading to reduced impact resistance in CFRP components. In addressing this challenge, metal/CFRP composites have emerged as an alternative, leveraging the ductility of metals along with the high specific strength of the CFRP composites. In this study, tensile tests were conducted on the CFRP composite plates with 0°, 90°, and ±45° stacking sequences, and the corresponding load-displacement curves were obtained. The numerical simulation of tensile tests was conducted by the LS-DYNA software, and the numerical model was verified with the experimental results. Furthermore, numerical simulations were conducted to examine the influence of various metal types on the failure behavior of metal alloy/CFRP hybrid composite plates with different thicknesses under tensile loading. The results indicate that both the thickness of the hybrid CFRP composites and the type of metal have a substantial impact on the performance of metal-hybrid components. Additionally, a comparison between the tensile test results and numerical simulation results reveals a good agreement.