Specific Resistance Values Research Articles

Specific resistance and adsorption performance of acid-modified fly ash for escaped ammonia in flue gas

Escaped ammonia emission following Selective Catalytic Reduction denitrification significantly influences subsequent flue gas treatment processes. This study investigates the adsorption capabilities of acid-modified fly ash concerning escaped ammonia (NH3) and its consequential impact on specific resistance. Furthermore, the adsorption mechanism of acid-modified fly ash on NH3 was explained. Acid activation facilitated the dissolution of a portion of Fe and Al constituents within the fly ash, the contents of Fe and Al in SFA decrease by 4.91% and 5.64%, respectively. In addition, the specific surface area and porosity of fly ash are obviously improved. The specific surface areas of HFA and SFA increased from 1.83 (OFA) to 4.69 and 7.71 m2/g, respectively. Adsorption kinetics adhered to the pseudo-first-order model. SFA showed the best adsorption performance, with NH3 adsorption up to 10.65 mg/g, which was 4.27 times higher than OFA. The creation of a surface liquid film during NH3 adsorption led to decreased specific resistance values across all fly ash samples after-adsorption. The highest specific resistance values recorded for original fly ash (OFA), hydrochloric acid-modified fly ash (HFA) and sulfuric acid-modified fly ash (SFA) were 6.21 × 1012, 3.37 × 1011 and 5.02 × 1010 Ω·cm, respectively. Sulfuric acid activation makes fly ash have stronger adsorption capacity for escaping ammonia, and SFA maintains good specific resistance characteristics, which has good application prospects in electrostatic precipitation and air pollution control.

Assessment of denitrification efficiency and membrane fouling potential in a sulfur-driven membrane bioreactor treating effluent from biological treatment

In this study, any remaining nitrate not eliminated during a biological treatment process with a low C/N ratio was effectively removed using sulfur powder in an autotrophic denitrification membrane bioreactor. Moreover, particular attention was given to investigating the potential for membrane fouling in a sulfur-based denitrification reactor, with a comparative analysis to conventional activated sludge in an aerobic membrane bioreactor. At an influent nitrate concentration of 320 mg/L, the removal efficiency reached 94–98 % within a 4-hour hydraulic retention time and at a reactor temperature of 30 °C. The sulfur-based denitrification reactor exhibited soluble microbial products concentration and specific cake resistance values of 38.3 mg/L and 1.4 × 1013 m/kg, respectively, which were 5.47 and 2.26 times higher than those of conventional activated sludge. Furthermore, it was observed that the supernatant from the sulfur-based denitrification reactor resulted in more significant fouling within the membrane surface.

Pathway to high performance, low temperature thin-film solid oxide cells grown on porous anodised aluminium oxide

Reversible solid oxide cells (rSOCs) present a promising solution to future energy challenges through the efficient conversion between electrical and chemical energy. To date, the benefits of rSOC technology have been off-limits to portable power and electrolysis applications due to the excessive polarisation resistance of the oxygen electrode at low temperatures, characterised by high area specific resistance (ASR) values below 500 °C. In this work we demonstrate growth of symmetric and complete rSOC structures based on state-of-the-art vertically aligned nanocomposite (VAN) films grown by pulsed laser deposition (PLD) on porous Pt-coated anodised aluminium oxide (AAO) substrates. The symmetric rSOC structures give the first demonstration of an rSOC oxygen electrode with ASR below 0.1 Ωcm2 at temperatures less than 450 °C. This is achieved through oxygen vacancy tuning by annealing, as confirmed by Time-of-Flight Elastic Recoil Detection Analysis (ToF-ERDA) and Rutherford Backscattering Spectrometry (RBS) measurements. Thus, the present work describes a promising route towards future high-performance rSOC devices for portable power applications.

A three-stage process of Mn(VII)-Fe(III)/PDS system for enhancing sludge dewaterability: Effective driving of Fe(II)/Fe(III) cycle and adequate assurance of ROS

Sludge dewatering helps to reduce the cost of sewage treatment plants and environmental impact. Hence, we used a type of permanganate (Mn(IV)) activated ferric chloride (Fe(III))/ peroxydisulfate (PDS) system to enhance sludge dewaterability. At optimal dose, the simultaneous addition of Mn(IV), Fe(III) and PDS (MFP treatment) reduced the value of specific resistance to filtration (SRF) from 6.76 × 108 s2/g to 2.01 × 108 s2/g. There is a three-stage process during MFP conditioning: oxidation/flocculation, adsorption/oxidation, and reflocculation. X-ray photoelectron spectroscopy (XPS) and Electron spin resonance (ESR) analyses were employed to investigate the oxidation mechanism. Meanwhile, the analysis of Mn valence was improved by considering metal leaching rates. The cycles of Mn(II)/Mn(III)/Mn(IV) were initiated under the reaction between Mn(VII) and extracellular polymeric substances (EPS)/PDS. This process sustained the cycle of Fe(II)/Fe(III) to promote activation of PDS, which continuously promoted to generate OH•, SO4-•, •O2–, 1O2 and Fe(IV). Additionally, sludge EPS was proven to be the primary electron donor of Fe(II)/Fe(III) cycle, resulting in the increasing of Fe(II) proportion. Notably, the hydrophilicity and water-holding capacity of EPS declined significantly following excellent oxidation, which promoted the conversion of bound water. The effective destruction of hydrogen bonds and protein secondary structures explained the outstanding effects. Meanwhile, XDLVO calculation revealed that sludge coagulation performance enhanced through Fe(III) flocculation, MnO2 adsorption and hydrophobic flocculation. Raw and converted free water would be effectively removed through the more hydrophobic surface of large and tough drain pores formed after the reflocculation process. The efficient drainage of sludge water created strong sludge dewaterability. This study verified the practicality of MFP treatment by exploring the oxidation and coagulation mechanisms to clarify the dewatering mechanism.

Experimental evaluation of the nonselective and selective TMEM16 family calcium-activated chloride channel blockers in the airways

Abstract Background The family of calcium-activated chloride channels, TMEM16, plays a significant role in contributing to the pathogenesis of airway inflammatory diseases. Targeting these ion channels and aiming to modulate them may provide an interesting new approach to the therapy of these potentially fatal diseases. Methods We tested this hypothesis in both healthy and ovalbumin (OVA)-sensitized male Dunkin-Hartley guinea pigs. The ion channel activity was modulated by TMEM16A-nonselective (benzbromarone) and TMEM16A-selective blockers (CaCCinh-A01). In vivo airway reactivity, induced by histamine and methacholine, was expressed as specific airway resistance (sRaw) values. The number of citric acid-induced coughs was counted using a double-chambered body plethysmograph, and the frequency of ciliary beating (CBF) was assessed in vitro by brushing method. For comparison, salbutamol and codeine were tested under the same conditions. Results The results showed significant differences in the responses of unsensitized and sensitized airways to both TMEM16 blockers administered. CaCCinh-A01 and benzbromarone significantly reduced the number of cough efforts in the group of OVA-sensitized guinea pigs. Significant improvement in sRaw values could be observed in OVA-sensitized TMEM16 blocker–treated animals compared to salbutamol when challenged with inhalational histamine, and the outcome was similar to salbutamol when challenged with methacholine. CBF was significantly inhibited in animals sensitized to OVA treated with selective inhibition of TMEM16A. Conclusions The results demonstrated that treatment with blockers of TMEM16 can reduce both cough effort and sRaw, and the difference between TMEM16A-selective and TMEM16A-nonselective blocking is only negligibly in favor of CaCCinh-A01. It is also worthwhile to note the impairment of CBF in OVA-sensitized animals treated with CaCCinh-A01.

Nickel-doped NdBa0.5Sr0.5Co1.5Fe0.5O5+δ oxygen electrode material for high performance reversible protonic ceramic cells

To enhance the electrocatalytic activity in the oxygen reduction and the evolution reactions of air electrode materials, we fabricate a double perovskite structured NdBa0.5Sr0.5Co1.5Fe0.5-xNixO5+δ with triple-conducting properties for reversible protonic ceramic cells (RPCCs). In particular, Ni doping into B-site (of ABO3 perovskite structure) is used to tailor the surface properties and bulk diffusion of NdBa0.5Sr0.5Co1.5Fe0.5O5+δ perovskites. Among the various amounts of dopants, doping with 5 mol% Ni significantly increases the activity of oxygen electrodes in moist air, including the conductivity of protons and oxygen-ions. The area specific resistance (ASR) values of the NdBa0.5Sr0.5Co1.5Fe0.45Ni0.05O5+δ (NBSCFN5) electrode in the BaZr0.1Ce0.7Y0.1Yb0.1O3-δ electrolyte are 0.70 Ω·cm2 at 650 ℃. The electrical conductivity of NBSCFN5 is 423–714 S·cm−1 at the RPCCs operating temperature (500–700 ℃), which is significantly higher than that of the conventional perovskite air electrode materials. Furthermore, the ASR of the NBSCFN5 symmetrical cell decreases considerably from 9.02 to 6.86 Ω·cm2 in dry air to pH2O = 0.6 atm at 550 ℃, implying its excellent proton conduction. This suggests that NBSCFN5 is a promising air electrode material for next-generation high-performance RPCCs at lower temperatures.

(Digital Presentation) (La0.7-xNdx )Sr0.3Co1-YFeyO3- δ (x = 0.35, y = 0.2) a Novel Perovskite Type Air Electrode Material for Protonic Conducting Solid Oxide Cell (H-SOC)

Proton conducting solid oxide cell (H-SOC) is a highly efficient energy conversion device converting electrical energy into hydrogen by splitting water using solid oxide proton conductor at intermediate temperature range (500-700 0C) [1]. To enhance electrochemical performances in terms of efficient hydrogen generation, robust and durable air electrode materials are required to facilitate faster water oxidation and oxygen reduction reaction, which are the key steps for both electrolyser and fuel cell at a lower temperature [2-3]. In the present study, we have developed ‘La’ and ‘Nd’ A-site co-doped strontium cobaltite and cobalt ferrite: La0.35Nd0.35Sr0.3Co0.8Fe0.2O3-δ(LNSCF) a perovskite type cathode material exhibiting higher electrical and electrochemical performances. The electrical and O2- ion conductivity of the material shows metallic nature, and the highest conductivity values are 973 S cm-1 and 0.318 S cm-1 respectively at 400 oC. The higher value of electrical and ionic conductivity is attributed to highly efficient Co2+ to Co3+ and Fe3+ to Fe4+ transition. Electrochemical impedance spectroscopy analysis of the symmetrical cell (LNSCF/Zirconium and Yttrium doped Barium Cerate (BZCY)/LNSCF) revealed the value of Area Specific Resistance (ASR) to be 0.14, 0.47 and 3.06 Ω cm2 at 800,700 and 600 oC respectively. When operated in H-SOFC mode with humidified hydrogen as fuel and Air (3%H2O) as oxidant, the LNSCF based single cell: Ni-BZCY/BZCY (385m)/ LNSCF+BZCY achieves a maximum current density of 522, 383, and 231mA/cm2 at 800, 700, and 600 oC, respectively at 0.002 V. Whereas, in H-SOEC mode a maximum current density of -1380, -862 and -517 mA/cm2 are obtained at 800, 700, and 600 oC, respectively at 2.5 V. The contribution of different ions (O2- and H2+) and electrons (e-) in the electrochemical performances are evaluated using ion-blocking cells. The figure (1) below represents the Current Density versus Voltage (i-V) characteristic attributes for both H-SOFC and H-SOEC.

Structural, compositional, morphological and electrical characteristics of thermally evaporated Au Ohmic Contact on p-type HgCdTe substrate for possible infrared detectors

Gold (Au) thin films were deposited over the HgCdTe (mercury cadmium telluride) surface by a thermal-evaporation deposition technique. The thermally grown Au films were investigated using different characterization techniques, X-ray diffraction (XRD), energy dispersive X-ray (EDX) analysis, atomic force microscopy (AFM), scanning electron microscopy (SEM), and current-voltage (I–V)/resistance measurement. The maximum film growth occurs along with the preferred orientation (111). The grown Au film possesses a cubic fcc structure, desired elemental compositions, and purity. The AFM confirms that the films were uniform, dense, and had very low roughness. The films attained the desired grain size of film-forming particles. The optimized Au films were established and further employed to fabricate the transfer length method (TLM) structure with configuration (Au/p-HgCdTe). The I–V and resistance measurements of the as-deposited TLM structure produced the Ohmic Au-contact with low specific contact resistance (ρc) of 2.73 × 10−3 Ω cm2. Annealing treatment (contacts annealed for 2 h at 80 °C in the air) was applied to the as-deposited TLM structure and the measured value of specific contact resistance (ρc) for the annealed Au contact (Ohmic behaviour) is 7.11 × 10−4 Ω cm2 that is relatively low than the as-deposited contacts. Thermal annealing has reduced the magnitude of ρc by about one order. TLM structures (as-deposited and annealed) exposed the efficiency of Au thin films as an effective Ohmic contact. Thus, Au thin films could be used to create a compelling and appropriate Ohmic p-contact to fabricate HgCdTe infrared detectors.

The properties of machine-tractor unit (MTU) regarding soil preparation with bed ridging

BACKGROUND:One of the main criteria for assessment of work performance is productivity. It depends on a number of indicators: towing resistance, optimal use of energy, used technical equipment, the adaptability of the equipment to the operation conditions, etc. Experimental studies are required in order to establish the patterns of influence of these indicators on work efficiency.
 AIMS:Carrying out theoretical calculations and practical observations on the process of bed ridging for potatoes, assessment of the unit assembly for the technological process performing and the using of the unit.
 METHODS:Field tests of a machine-tractor unit with subsequent result processing using the Microsoft Office applications.
 RESULTS:Recommendations are given for practical use in the unit formation depending on velocity and operation width of the unit for various values of specific resistance.
 CONCLUSIONS:The practical value of the study lies in the opportunity of using the proposed patterns for optimization the machine-tractor unit assembly according to operation conditions, selection of power unit, development of combined machines and units.

Ohmic contact structures on β-Ga2O3 with n+ β-Ga2O3 pulsed laser deposition layers

Thin (40–150 nm), highly doped n+ (1019–1020 cm−3) Ga2O3 layers deposited using pulsed laser deposition (PLD) were incorporated into Ti/Au ohmic contacts on (001) and (010) β-Ga2O3 substrates with carrier concentrations between 2.5 and 5.1 × 1018 cm−3. Specific contact resistivity values were calculated for contact structures both without and with a PLD layer having different thicknesses up to 150 nm. With the exception of a 40 nm PLD layer on the (001) substrate, the specific contact resistivity values decreased with increasing PLD layer thickness: up to 8× on (001) Ga2O3 and up to 16× on (010) Ga2O3 compared with samples without a PLD layer. The lowest average specific contact resistivities were achieved with 150 nm PLD layers: 3.48 × 10−5 Ω cm2 on (001) Ga2O3 and 4.79 × 10−5 Ω cm2 on (010) Ga2O3. Cross-sectional transmission electron microscopy images revealed differences in the microstructure and morphology of the PLD layers on the different substrate orientations. This study describes a low-temperature process that could be used to reduce the contact resistance in Ga2O3 devices.

Geophysical research of underground hydraulic structures, old Glubochinsky water tunnel case study

Research objective is to study the features of geophysical fields and parameters in the area of the artificial underground water tunnel and estimate the capabilities of geophysical methods of identifying hidden underground industrial facilities. Methods of research. Measurements of self-potential signals (SP) were carried out using nonpolarizing electrodes and an electrical exploration receiver. The magnetic exploration was carried out by a proton magnetometer. Electrotomography was carried out using multielectrode electrical survey equipment with a Schlumberger symmetrical scheme of surveys. The microseismic background was recorded using an autonomous seismic station. The georadar survey was carried out using the SIR-3000 ground penetrating radar and antennas with the frequencies of 100 MHz and 270 MHz. Results. Based on the survey results, graphs of magnetic and self-potential fields, electrotomographic and microseismic sections, and radarogram were built on the research profile. The research has shown different levels of the magnetic field and the SP in the area of volcanic rocks and dikes of gabbro-dolerites occurrence. A significant increase in microseismic noise was observed with an increase in the weathering crust thickness. A local decrease in the SP potential, abnormally high values of specific electrical resistivity and intensive reflections of radio waves from the tunnel top were recorded above the underground water tunnel. Conclusions. Qualitative and quantitative geophysical characteristics were obtained in the area of the old underground water tunnel. The research showed different levels of the magnetic field and spontaneous polarization potentials in the occurrence area of rocks of different composition. A significant increase in microseismic noise was recorded with an increase in the weathering crust thickness. Geophysical signs of the boundaries between geological structures and artificial underground objects are revealed. The exact position and depth of the old underground tunnel of Glubochinsky hydraulic structures was determined.

Study of Single and Multipass f-rGO Inkjet-Printed Structures with Various Concentrations: Electrical and Thermal Evaluation.

Reduced graphene oxide (rGO) is a derivative of graphene, which has been widely used as the conductive pigment of many water-based inks and is recognized as one of the most promising graphene-based materials for large-scale and low-cost production processes. In this work, we evaluate a custom functionalised reduced graphene oxide ink (f-rGO) via inkjet-printing technology. Test line structures were designed and fabricated by the inkjet printing process using the f-rGO ink on a pretreated polyimide substrate. For the electrical characterisation of these devices, two-point (2P) and four-point (4P) probe measurements were implemented. The results showed a major effect of the number of printed passes on the resulting resistance for all ink concentrations in both 2P and 4P cases. Interesting results can be extracted by comparing the obtained multipass resistance values that results to similar effective concentration with less passes. These measurements can provide the ground to grasp the variation in resistance values due to the different ink concentrations, and printing passes and can provide a useful guide in achieving specific resistance values with adequate precision. Accompanying topography measurements have been conducted with white-light interferometry. Furthermore, thermal characterisation was carried out to evaluate the operation of the devices as temperature sensors and heaters. It has been found that ink concentration and printing passes directly influence the performance of both the temperature sensors and heaters.

ЧУТЛИВІ ЕЛЕМЕНТИ ПЕРЕТВОРЮВАЧІВ ТЕМПЕРАТУРИ НА ОСНОВІ ТЕРМОМЕТРИЧНОГО МАТЕРІАЛУ HfNi1-xCuxSn

ЧУТЛИВІ ЕЛЕМЕНТИ ПЕРЕТВОРЮВАЧІВ ТЕМПЕРАТУРИ НА ОСНОВІ ТЕРМОМЕТРИЧНОГО МАТЕРІАЛУ HfNi1-xCuxSn

Влияние режимов формирования контактной системы Pd/Ge/Au к n-GaAs на ее электрические характеристики

The investigations of Pd/Ge/Au contact system forming regimes influence on the specific contact resistivity to n-type conductivity GaAs layer were carried out. The method of samples surface treatment before the layers evaporation and thermal annealing regimes in H2, N2 and Ar atmosphere influence on contact system parameters was investigated. The specific contact resistivity value 2-3•10-6 Ohm•cm2 at the reduced annealing temperature 190 C was archived.

Forming regimes of Pd/Ge/Au contact system to n-GaAs influence on its electric parameters

The investigations of Pd/Ge/Au contact system forming regimes influence on the specific contact resistivity to n-type conductivity GaAs layer were carried out. The method of samples surface treatment before the layers evaporation and thermal annealing regimes in H2, N2 and Ar atmosphere influence on contact system parameters was investigated. The specific contact resistivity value (2-3)· 10-6 Ohm· cm2 at the reduced annealing temperature 190oC was archived.. Keywords: Pd/Ge/Au, n-GaAs, surface treatment, thermal annealing

Electrical properties of the base film heterosystem Al/ITO/polyimide/Al2O3 for capacitive converter

On the basis of the conducted structural studies of thin films, a structural and technological solution was developed and a thin film capacitive transducer was created for acoustic monitoring of metal products by a capacitive method. It was determined that along with the crystalline structure of the layers, it is also necessary to control the surface electrical resistance of the conductive ITO layer, the values of which determine the possibility of using such a structure as a coating of a capacitive converter without significant losses of the useful signal, and the dielectric permeability of the Al2O3 layer, which significantly affects the value of the useful signal With the help of the four-probe method, it was established that the surface electrical resistance (R□) of ITO layers under optimal deposition conditions is equal to 8–15 Ohm/□. The study of electric power Hall results indicate that the obtained value of specific electrical resistance is determined by the concentration of the main charge carriers from about 8.3·1020 cm–3 and the mobility of the main charge carriers at the level of 44 cm2/(V·s). The results of studies of dielectric properties indicate an increase in the value of the dielectric constant of the polyimide/Al2O3 structure, which is 8.5–11.5 relative to units, relative to the polyimide film (3–3.9 relative units) by approximately 3 times at frequencies of the exciting signal in the range of 10 Hz–10 MHz. This fact confirms the assumption about the possibility of increasing the dielectric constant of the interlayer due to the application of a thin layer of Al2O3 on the polyimide film. To confirm the possibility of increasing the sensitivity of the method due to the use of a capacitive transducer based on the Al/ITO/polyimide/Al2O3 structure, in comparison with classical transducers, a series of aluminium samples was studied at an oscillation frequency of 2.5 MHz. The value of the received signal when using a thin-film converter increases by 7.6 times compared to a classic converter, which correlates well with the measurements of dielectric permeability of dielectric layers and taking into account the decrease in the thickness of the dielectric layer. Thus, the increase in the sensitivity of the capacitive method in the case of using thin-film capacitive converters based on the Al/ITO/polyimide/Al2O3 structure is experimentally confirmed. The maximum amplitude of the acoustic displacement occurs at the edge of the plate, so studies were conducted on electrodes with cutouts, which made it possible to increase the acoustic signal twice for a large internal cutout.

The Reaction of Airways of Employees Working in the Environments Polluted with Heavy Metals in Mine Kosovo

This paper is studied the respiratory function as a result of the impact of air pollution in the environment of the sector of exploitation of heavy minerals such Pb, Zn, Au, Ag, Bi, Cd, PM in the mines of Trepça, Kosovo. Lung function parameters are determined by Body plethysmography. Airway resistance (Raw) was recorded and Intra-Thoracic Gas Volume (ITGV) was measured and specific resistance (SRaw) and airway specific conductance (SGaw) were calculated. The research was done in two groups, the control group and the experimental one. The control group consisted of 24 healthy people, while the experimental one is made up of 52 mining workers for the exploitation of minerals in the Trepçamine, Kosovo. The results obtained from this research indicate that the mean value of specific resistance (SRaw) is significantly higher in the experimental group (p<0.01), compared to the control group (p>0.1). Also, in this study it was confirmed that smoking favors the negative effects of air contamination in the mineral exploitation sector, the changes are significant (p<0.01). Respiratory system parameters of the control group and the experimental group were measured before and after bronchoprovocation with histamine-aerosol (1 mg/ml). The differences between these two groups after provocation were statistically significant (p<0.01). Respiratory changes from air pollution with noxae in mines where metals are mined, it takes a long time for changes in respiratory function to appear. Therefore, exposure of workers to these conditions poses a risk to their health, causing bronchial reactivity, bronchial asthma or, obstructive pulmonary syndrome.

Low ohmic contact resistivity realized by in situ SiNx insertion for high Al-composition-AlGaN/GaN heterostructure

A low ohmic contact resistance (Rc) is a challenge for an AlGaN/GaN heterostructure with a high Al-composition barrier, which is highly desired to further push the performance of GaN transistors. In this Letter, an effective ohmic contact technique with an in situ SiNx layer inserted between the conventional Ti/Al/Ni/Au metal stack and the III-nitride was proposed and the inside physical mechanisms were investigated for an Al0.65Ga0.35N/GaN heterostructure. The fabricated ohmic contact has a low Rc of 0.17 Ω·mm and a specific contact resistivity value (ρc) of 8.45 × 10−7 Ω·cm2, which is obviously improved compared with the Rc of 0.32 Ω·mm and ρc of 2.84 × 10−6 Ω·cm2 without in situ SiNx inserted. The strong temperature dependency of ρc with in situ SiNx insertion shows that the dominant current transport mechanism is the thermionic field emission. Transmission electron microscopy and energy dispersive x-ray spectroscopy analyses suggest that the enhanced ohmic contact is due to the possible formation of low-work function silicides and more TiN alloys during annealing.

Effect of Extremely Short-Sized MWCNT as Additive Material in High Surface Area Activated Carbon and Its Enhanced Electrical LIC Performance.

Extremely short-sized multi-wall carbon nanotube (CNT) and high surface area activated carbon were used to increase the electrical performance of lithium-ion capacitors (LIC). After electrodes were synthesized using extremely short-sized CNTs and high specific surface area activated carbon, their electrochemical characteristics were evaluated by XRD, SEM, TEM, cyclic voltammetry, EIS, BET, adoption isotherm, t-plot, and pore size distribution. In the process of electrode preparation using extremely short-sized CNTs and high specific surface area activated carbon, CNTs certainly caused a space-filling effect between these two materials, which had a significant effect on the evaluation of electrical characteristics. These relationships were demonstrated by the results of adsorption–desorption isotherm, pore size distribution, t-plot, and BJH plot. Particularly, in the electrochemical cyclic test, as the content of CNT increased, the current density significantly increased with the formation of a near-perfect rectangular shape. This tendency also exhibited excellent characteristics in a t-I plot, Tafel plot, and LSV plot, which clearly affected the electrochemical oxidation–reduction reaction due to the densification of filling density and space structure by adding extremely short-sized CNTs to the active material. In addition, YP80_CNT3 formed a specific resistance value in the range of 7.2 to 6.2 Ω/cm2, showing significantly reduced values compared to other samples. This research presented herein offers a promising route for the rational design of MWCNT and stable electrochemical reaction with LIC working mechanism.

Novel SrO-Containing Glass-Ceramic Sealants for Solid Oxide Electrolysis Cells (SOEC): Their Design and Characterization under Relevant Conditions.

This study presents results on the development of strontium oxide (SrO) containing glass sealants used to join Crofer22APU to yttria-stabilized zirconia (3YSZ), in which the main glass components, that is, silicon oxide (SiO2), strontium oxide (SrO), calcium oxide (CaO) and aluminum oxide (Al2O3), have been varied appropriately. Certain properties, such as the crystallization behavior, the coefficient of thermal expansion, adhesion, and reactivity of the sealants in contact with Crofer22APU, have been reviewed and discussed. The optimized glass composition (with CTE in the 9.8–10.3 × 10−6 K−1 range) results in a good joining behavior by hindering the formation of undesirable strontium chromate (SrCrO4) on contact with the Crofer22APU steel after 1000 h. at 850 °C. High specific resistivity values of about 106 Ohm.cm have been obtained, thus demonstrating good insulating properties at 850 °C under an applied voltage of 1.6 V. A negligible degradation in the electrical resistivity trend was measured during the test up to 1000 h, thus excluding the presence of detrimental reactions of the glass-ceramic sealant in contact with Crofer22APU under a dual atmosphere, as confirmed using SEM-EDS post-mortem analyses.