Specific Pore Structure Research Articles

Designing activated carbon and porous carbon nanofibers for insight into their differences in adsorption affinity mechanisms of VOCs

The adsorption technology has been considered as an effective and economical strategy to control volatile organic compounds (VOCs) through various types of porous materials. As two potential porous materials, activated carbon and carbon nanofibers were synthesized as VOCs adsorbents. In order to investigate the difference in the adsorption of VOCs between activated carbon and carbon nanofibers, the specific surface area, pore structure and chemical functional groups of VOCs adsorbent were analyzed. In particular, the carbon nanofibers (CNF) activated at 800 ℃ showed an excellent specific surface area (2524 m2·g−1), abundant pores (1.66 mL·g−1), and rich functional groups (N: 8.29 at%). Meanwhile, the carbon nanofibers had a better adsorption performance for acetone (1069.82 mg·g−1) and toluene (427.72 mg·g−1) than activated carbon materials. Furthermore, the theoretical calculations were conducted to reveal the mechanism of favorable adsorption on the CNFs. The theoretical adsorption energies of CNF are −31.9 kJ·mol−1 (acetone) and −67.5 kJ·mol−1 (toluene), respectively, which have more favorable adsorption sites and stronger charge redistribution than activated carbon. This research guided the approach to obtain the porous carbon nanofibers and provided the evidence for CNFs (curved carbon) exhibiting a better adsorption ability to VOCs.

Characterization of dust emission during ore unloading and analysis of its influencing factors

Dry bulk terminals at ports generate dust in the process of ore loading / unloading and transfer, and these particulate matters disperse to the atmospheric environment causing pollution and endangering human health. This study focuses on the funnel unloading point of a portal crane at a port terminal, and the variation characteristics of dust emission under different mass flow rates, ambient wind speeds, and moisture contents are investigated. The microscopic features of ore powders, i.e., wetting time, contact angle, particle size, specific surface area and pore structure, as well as microscopic morphology, are also determined to explore the intrinsic mechanism between wettability, moisture content, and dust emission. The impact of mass flow rate, ambient wind speed, and moisture content on dust emission is evaluated by employing the orthogonal test range method and response surface method. The experimental data reveals that the dust at the unloading point is dominated by coarse particles of total suspended particulate (TSP), and increasing the moisture content effectively reduced the dust emissions, with a suppression efficiency of TSP > PM10 > PM2.5. The experimental results on the microscopic features of the ore powders indicate that the above difference is attributed to wettability, which weakens with diminishing particle diameter. It is also concluded that the wettability of Australian ore 1 is determined to be superior to bauxite 394. Therefore, Australian ore 1 exhibits an excellent dust suppression effect at a moisture content of 4% ∼ 5%, whereas bauxite 394 requires a moisture content of approximately 5% ∼ 7% to achieve the same dust suppression. By conducting the orthogonal test range method, the three factors on the dust emission, in descending order, are moisture content > ambient wind speed > mass flow rate. According to the response surface method, the optimal parameter combination is determined and the dust emission is minimized as 4.149 μg/s, which corresponds to 0.386 mg TSP/ton, with the conditions of mass flow rate 10.356 kg/s, ambient wind speed 4.289 m/s, moisture content 6.983%.

Enhanced Performance of Electrical Double-Layer Capacitor by Controlling the Specific Surface Area and Pore Structure of ZIF-67

Enhanced Performance of Electrical Double-Layer Capacitor by Controlling the Specific Surface Area and Pore Structure of ZIF-67

ZIF-67-derived Co@NC as an efficient catalyst for magnesium sulfite oxidation in the flue gas desulfurization process

Magnesium desulfurization is a wet flue gas desulfurization (WFGD) technology widely used in China, however, the low oxidation rate of magnesium sulfite (MgSO3), a byproduct of WFGD, causes the subsequent oxidation and crystallization process to require amount energy. Here, we prepared a cobalt-based nitrogen-doped porous carbon catalyst (Co@NC) using ZIF-67 as a precursor for the efficient catalytic oxidation of MgSO3 generated during magnesium desulfurization. The performance of Co@NC catalysts obtained at an optimal calcination temperature of 650 °C showed that the catalysts with oxidation rates up to 0.1332 mmol·L−1·s−1 of MgSO3 were considerably better than those previously studied, which outperformed the catalysts described in earlier research by a considerable margin. Further studies revealed that the Co@NC’s exceptional catalytic activity was attributed to both its special porous structure and the exposed active Co sites in the organic skeleton. The uniformly dispersed Co species act as the active sites of the Co@NC that can be fully contacted with the reactant. The presence of 0.5 g·L−1 Co@NC increases the MgSO3 oxidation rate by about 14 times compared to the noncatalytic benchmark. A practical tactic is furnished by this research for energy saving and emission reduction in the WFGD process, especially for the efficient oxidation and resource conversion of the by-product MgSO3.

Construction of SU-102 for adsorption and photocatalytic synergistic removal of tetracycline.

Tetracycline (TC) is a significant group of broad-spectrum antibiotics that are frequently employed in medical health and animal husbandry. However, the problem of TC residues has been increasing globally with the large-scale production and widespread use, posing a serious threat to the human health and ecological environment. In this paper, a green plant-based MOF SU-102 was prepared, and the adsorption characteristics of SU-102 on TC were investigated. SU-102 was columnar crystal with considerable specific surface area and pore structure, and it could adsorb TC quickly and effectively. And compared to SU-102-a, the adsorption rate of TC by SU-102-b has increased by nearly four times. The adsorption reaction was a spontaneous, entropy-gaining, heat-absorbing process. The adsorption mechanisms between SU-102 and TC were π-π interaction and hydrogen bonding. In addition, SU-102 also had considerable photocatalytic properties, and its application in adsorbent desorption treatment effectively solved the problem of secondary pollution.

Porous poly(bismaleimide-co-divinylbenzene) microspheres as dispersive solid-phase extraction adsorbent coupled to high-performance liquid chromatography for the determination of triazine herbicide residues in vegetable samples.

In this work, monodisperse and nano-porous poly(bismaleimide-co-divinylbenzene) microspheres with large specific surface area (427.6 m2 /g) and rich pore structure were prepared by one-pot self-stable precipitation polymerization of 2,2'-bis[4-(4-maleimidophenoxy) phenyl] propane and divinylbenzene. The prepared poly(bismaleimide-co-divinylbenzene) microspheres were employed as dispersive solid-phase extraction (DSPE) adsorbent for the extraction of triazine herbicides. Under optimized conditions, good linearities were obtained between the peak area and the concentration of triazine herbicides in the range of 1-400µg/L (R2 ≥ 0.9987) with the limits of detection of 0.12-0.31µg/L. Triazine herbicides were detected using the described approach in vegetable samples (i.e., cucumber, tomato, and maize) with recoveries of 93.6%-117.3% and relative standard deviations of 0.4%-3.5%. In addition, the recoveries of triazine herbicides remained above 80.7% after being used for nine DSPE cycles, showing excellent reusability of poly(bismaleimide-co-divinylbenzene) microspheres. The adsorption of poly(bismaleimide-co-divinylbenzene) microspheres toward triazine herbicides was a monolayer and chemical adsorption. The adsorption mechanism between triazine herbicides and adsorbents might be a combination of hydrogen bonding, electrostatic interaction, and π-π conjugation. The results confirmed the potential use of the poly(bismaleimide-co-divinylbenzene) microspheres-based DSPE coupled to the high-performance liquid chromatography method for the detection of triazine herbicide residues in vegetable samples.

Regulated synthesis of 3D nano-flower-like MnCo2O4.5 catalytic materials to enhance thermal decomposition of ammonium perchlorate

Morphological control enables precise modulation of the specific surface area, pore structure, and crystal structure of catalytic materials, thereby enhancing catalytic efficiency. In this study, morphology controlled synthesis of MnCo2O4.5 samples was achieved by solvent-hydrothermal method by varying the ethylene glycol to deionized water volume ratio. The 3D nano-flake-like MnCo2O4.5 material with a larger specific surface area was successfully prepared at a volume ethylene glycol to deionized water (6:40). The ammonium perchlorate (AP) is high temperature decomposition (HTD) peak temperature decreases from 473.48 °C of pure AP to 304.39 °C and the heat release increases from 888.26 J g−1 to 2094.50 J g−1 after the addition of 2.0 % 3D nano-flower-like MnCo2O4.5. The activation energy (Ea) goes down to 89.2 kJ mol−1 relative to pure AP (296.8 kJ mol−1). When applied to Hydroxy-terminated polybutadiene composite solid propellant (HTPB-CSP), the combustion process of HTPB-CSP containing 3D nano-flower-like MnCo2O4.5 is more intense compared with only containing pure AP. The time to achieve the maximal combustion effect is accelerated from 390 ms to 268 ms, and the ignition delay time is lowered from 35 ms to 23 ms. Based on its microstructural design and optimization, MnCo2O4.5 has a remarkable catalytic performance for AP thermal decomposition, according to the experimental results.

The flower-like Ni-MOF modified BiOBr nanosheets with enhancing photocatalytic degradation performance

A novel BiOBr/Ni-MOF composite was fabricated by in-situ growth of BiOBr nanosheets on Ni-MOF through a convenient precipitation process. The optimal photocatalytic performance was achieved with a Ni-MOF mass content of 45 wt% in the BiOBr/Ni-MOF composite. This composite exhibited remarkable efficiency, degrading 98.33 % of Rhodamine B in 90 min, surpassing the degradation rate constants of pristine BiOBr and Ni-MOF by 4.2 and 160 times, respectively. The superior performance was primarily ascribed to the efficient separation of photogenerated carriers facilitated by the formation of heterojunctions. Additionally, the increased specific surface area and pore structure provided numerous adsorption and active sites. Radical scavenger experiments and electron spin resonance experiments further revealed that O2− and h+ played crucial roles in the degradation process. Furthermore, the structural properties of the prepared photocatalysts and the effects of different photocatalytic conditions on the degradation of RhB were investigated. This work offers an alternative perspective on the design and fabrication of BiOBr-based composite photocatalysts.

A novel ethylene linkage-based covalent organic framework for turn-on fluorescence sensing for Al3+ with excellent selectivity and sensitivity

Covalent organic Framework (COFs) has become a new platform for functional research and material design. A novel covalent organic framework (CN-COF) was first synthesized with p-xylylene dicyanide and 2-hydroxy-1,3,5-benzenetrialdehyde through the Knoevenagel condensation reaction. CN-COF is a porous crystal material with strong thermal and chemical stability. CN-COF exhibits a selective “turn-on” fluorescence response to Al3+ in ethanol with blue-shifted emission spectra over the other tested metal ions. The color changes from pink to earth yellow, and the fluorescence effect is clearly visible. The fluorescence intensity of CN-COF was linearly related to the concentration of Al3+, and the detection limit was 1.815 μM. Importantly, CN-COF exhibits a satisfactory recovery for detecting Al3+ in drinking water and fish samples. CN-COF also showed the intuitive semi-quantitative detection ability for Al3+ via the color change with the naked eyes. The special pore structure is conducive to allow Al3+ enter to coordinate with O and N atoms on the wall of CN-COF scaffold. The revisable fluorescence change upon the selective addition of Al3+ and XRD, EDTA, XPS and DFT results demonstrated the complex process. The inhibition of the photoinduced electron transition from O atoms to Al3+ induced the fluorescence enhancement. This study not only presents a synthesis idea for a new structural organic framework, but also offers a highly selective and sensitive fluorescence chemical sensor for the identification and detection of Al3+.

Influence of Porosity on Fatigue Behaviour of 18Ni300 Steel SLM CT Specimens at Various Angles.

In order to improve understanding of the fatigue behaviour in additive manufactured samples, this research delves into the challenging interplay between building parameters, particularly fabrication angles, and the presence of pores. The primary objective is to explore the characterisation of these pores and unravel their relationship with the fatigue properties of the material under investigation. Through a systematic analysis of porosity distribution in various fabrication orientations, supplemented by a detailed examination of the elemental dispersion around specific porous structures using energy-dispersive X-ray spectroscopy, a consistent behavioural pattern emerges across the samples. In assessing fatigue behaviour, an examination of the variables reveals that only area and aspect ratio significantly influence the behaviour of the samples. Such studies can contribute substantially to academic research in the field of material science and engineering.

Inorganic Hydrogel Based on Low-Dimensional Nanomaterials.

Composed of three-dimensional (3D) nanoscale inorganic bones and up to 99% water, inorganic hydrogels have attracted much attention and undergone significant growth in recent years. The basic units of inorganic hydrogels could be metal nanoparticles, metal nanowires, SiO2 nanowires, graphene nanosheets, and MXene nanosheets, which are then assembled into the special porous structures by the sol-gel process or gelation via either covalent or noncovalent interactions. The high electrical and thermal conductivity, resistance to corrosion, stability across various temperatures, and high surface area make them promising candidates for diverse applications, such as energy storage, catalysis, adsorption, sensing, and solar steam generation. Besides, some interesting derivatives, such as inorganic aerogels and xerogels, can be produced through further processing, diversifying their functionalities and application domains greatly. In this context, we primarily provide a comprehensive overview of the current status of inorganic hydrogels and their derivatives, including the structures of inorganic hydrogels with various compositions, their gelation mechanisms, and their exceptional practical performance in fields related to energy and environmental applications.

Superhydrophilic floral foam-based solar evaporator with excellent salt-resistance and cost advantages for high efficient desalination

Effective management of heat, outstanding water transport paths, and hydrophilicity are essential for porous solar-driven interfacial evaporators, but their development still faces many difficulties. Here, by cross-linking a carbon black (CB)/polyvinyl alcohol (PVA) slurry with three-dimensional super hydrophilic floral foam (FF) to form a CB/PVA functional film on the surface of FF, a CB/PVA-decorated floral foam based (FFCP) solar-driven water evaporator with low-cost was finally obtained. Owing to the super hydrophilicity, sufficient water supply, self-holding water capacity and the special porous structure of the FF, as well as efficient light absorption and photothermal conversion efficiency of the dispersed CB. The gas-liquid interface temperature of the optimized FFCP-1.0 evaporator reaches 41.2 °C under single solar irradiation, obtaining an evaporation rate of up to 1.69 kg m−2 h−1. In addition, the FFCP-1.0 evaporator had a great evaporation rate in highly concentrated salt solutions. Moreover, the FFCP-1.0 evaporator has remarkable purification effects on seawater, organic dye effluents and heavy metal ion solutions. The evaporator has low cost, excessive evaporation rate and excellent durability. Therefore, this work is of considerable scientific significance for promoting the practical application of porous-based solar evaporators and clean water production.

High-energy-density, ultralong-life manganese oxide composite carbon aqueous zinc-ion asymmetric supercapacitors

Transition metal oxide composites integrate the characteristics of metal oxides and carbon materials, thereby combine the advantages of both battery-type and capacitive electrodes. Using bimetallic aluminum‑manganese metal-organic frameworks (MOFs) as precursors, the MOFs are calcined under a nitrogen atmosphere, followed by etching in a sodium hydroxide solution to obtain the MnO/C (MO/C) composite material. The resulting high specific surface area composite material (583.76 m2 g−1) exhibits outstanding electrochemical performance, achieving a high energy density of 146 Wh kg−1 and a power density of approximately 1000 W kg−1 at a current density of 1 A g−1, along with excellent stability. Even under a high current density of 10 A g−1 and after 5000 cycles, the material maintains a capacitance retention rate of 96.7 %. The high specific surface area and abundant pore structures provide more electrochemical active sites, facilitating ion diffusion. The carbon framework enhances conductivity, effectively mitigating structural collapse caused by volume expansion during repetitive charge and discharge processes, thereby improving material stability. This study provides robust support for the development of high-performance electrochemical energy storage materials.

Adsorption Performance and Mechanism of Oxytetracycline in Water by KOH Modified Biochar Derived from Corn Straw

The pollution control of tetracycline antibiotics in the environment has become a hot topic, and biochar adsorption has become an important technology to remove organic pollutants. Pyrolytic biochars (BC400, BC500, and BC600) were prepared from corn straw and then were modified by KOH to obtain KBC400, KBC500, and KBC600. Among them, KBC400 was selected for secondary pyrolysis activation at 400-600℃ to obtain AKBC400, AKBC500, and AKBC600. The structure characteristics and surface properties of AKBC were also characterized. The adsorption kinetics and thermodynamic characteristics of oxytetracycline hydrochloride (OTC) in the solution by AKBC were investigated using batch experiments. Compared to that of BC400, the specific surface area and pore structure of AKBC were significantly improved, and the aromaticity was also enhanced, resulting in the notable enhancement of the adsorption capacities for OTC. The pseudo-second-order kinetics model could better fit the adsorption process, and AKBC500 had the largest adsorption rate constant and capacity. Both the intraparticle diffusion and film diffusion were the rate-limiting steps. The Langmuir, Freundlich, and Temkin models could fit the adsorption isotherms perfectly. The adsorption of OTC on AKBC was a spontaneous, endothermic, and entropy-increasing process by both physisorption and chemisorption. The pH values in the range of 3.0-7.0 were favorable for the adsorption of OTC by AKBC. The adsorption capacity decreased with the humic acid concentration over 10 mg·L-1. The adsorption mechanism of OTC by AKBC involved pore filling, hydrogen bonding, π-π conjugation, cation-π bond, and strong electrostatic effect. AKBC still had good reusability for OTC removal after five times of regeneration. The obtained AKBC is a potential adsorbent for OTC removal from water due to the good pore structure, high adsorption capacity, and stable adsorption effect.

Porous carbon derived from a by-product of traditional Chinese medicine for high-performance aqueous zinc-ion hybrid supercapacitors

The rational utilization of biomass waste for the production of usable energy holds immense significance. The present study proposes the effective utilization of a byproduct derived from traditional Chinese medicine, specifically momordica grosvenori shell, as a precursor for fabricating high-performance porous carbon electrodes in rechargeable aqueous zinc ion supercapacitors. The MGCx-T electrodes are prepared by KOH activation and carbonization with MG (momordica grosvenori shell). The influence of KOH addition amount and carbonization temperature on the properties of the prepared materials were studied. Resulting that MGC3–800 has good electrical conductivity, high specific surface area (1141 m2 g−1) and abundant pore structure. The maximum specific capacity reaches 228.7 mAh g−1 at 0.2 A g−1 in 2 M ZnSO4 electrolyte. In the gelatin/ZnSO4 electrolyte, the specific capacity reaches a maximum of 186.1 mAh g−1. Additionally, it exhibits an energy density of 167.5 Wh kg−1 and a power density of 6300 W kg−1. Furthermore, exceptional cycling stability is observed with a capacity retention rate of 92.6 % after 10,000 cycles. Hence, the realization of an industry-effective strategy that not only utilizes biomass waste, but also produces high-performance zinc-ion hybrid supercapacitor electrodes has been achieved.

Metal-free β zeolite used as an efficient NH3-SCR catalyst can achieve complete immunity to SO2: Unique design strategy of sulfur-resistant catalyst

Sulfur oxides present in flue gas can deactivate metal oxide catalysts or metal cation exchange zeolite catalysts used in NH3-SCR, as the deposition of (NH4)2SO4/NH4HSO4 and metal sulfate can obstruct and damage active sites, respectively. The physical poisoning of the (NH4)2SO4/NH4HSO4 deposition can be prevented by selecting an appropriate reaction temperature range (reversible), while chemical poisoning caused by the sulfation of active sites is challenging to avoid and can permanently deactivate the catalyst (irreversible). This research addresses the issue of irreversible catalyst deactivation resulting from sulfur poisoning by employing metal-free β zeolite without redox sites, which effectively prevents redox site sulfation at its source and shields the catalyst from physical poisoning by operating at moderate to high temperatures. This metal-free β zeolite with an appropriate pore structure exhibited exceptional deNOx activity, N2 selectivity, stability, and sulfur resistance at 300 °C. The NO oxidation experiment and DFT analysis demonstrated that the specific pore structure of β zeolite functioned as a sub-nano reactor, facilitating the oxidation of NO to NO2, thereby triggering the subsequent series catalytic reaction of “fast” SCR. Even in an atmosphere with a high concentration of 300 ppm SO2, the β zeolite catalyst maintained over 80 % NOx conversion after 130 h. The slight reduction in activity was attributable to the inhibitory influence of SO2 on the collision reaction between NO and O2; however, SO2 did not have any poisonous impact on the catalyst. The unique design strategy found in present work provides valuable insights for the sulfur resistance of metal-free zeolites used in NH3-SCR process, and provides a new idea for the design of completely sulfur-resistant catalysts.

Artificial spinal dura mater made of gelatin microfibers and bioadhesive for preventing cerebrospinal fluid leakage.

Artificial spinal dura mater was designed by combining solution blow-spun gelatin microfibers and dopamine-capped polyurethane bioadhesive. Notably, the gelatin microfibers had a special pore structure, good water adsorption capability, and excellent burst pressure resistance. The bioadhesive layer contributed to the excellent sealing performance in the wet state. This material provides a promising alternative as an artificial spinal dura mater to prevent cerebrospinal fluid leakage.

Novel selective adsorption cooling materials for heating cigarettes

Heated cigarettes are becoming trendy due to their advantage of not burning the tobacco material and thus reducing the amount of harmful ingredients released, while being able to leave the nicotine and tar content of the smoke untouched. However, the high temperature of the smoke as it enters the human mouth can affect the user experience. Therefore, the development of adsorption cooling materials for use in heated cigarettes is gradually becoming a hot topic. In this work, an adsorption cooling material based on embossed rod powder was prepared. It was found that compared with the commercial Yoga cooling material, the embossed rod powder based adsorption cooling material was able to reduce the maximum smoke temperature to 45.16 °C. In addition, it reduced the adsorption of nicotine by the cooling material, and increased the glycerol and nicotine content in the cooled smoke, which effectively promoted the taste of the smoke. Furthermore, the molecular simulation results found that the higher specific surface area and rich microscopic pore structure could increase the heat conduction area of the high-temperature flue gas, which enhanced the heat transfer effect of the flue gas. Finally, the periodic characteristic velocity pulsation destroyed the boundary layer formed by the fluid in the wall region, which increased the convective heat transfer effect between the fluid and the particles. The optimum sample 03 had the largest specific surface area and the lowest crystallinity, and thus had the best cooling effect. This work could provide some reference significance for the development of cooling materials for heating cigarettes.

Dehydrogenation of Diethylene Glycol to Para-Dioxanone over Cu/SiO2 Catalyst: Effect of Structural and Surface Properties

Para-dioxanone, a typical monomer for high-performance biomedical polymers, is generally obtained from the catalytic dehydrogenation of diethylene glycol. In this work, Cu/SiO2 catalysts were prepared by two different methods and applied in diethylene glycol dehydrogenation. The effects of catalyst properties on the performance of para-dioxanone production were systematically explored by combined techniques. The results showed that the high specific surface area and regular pore structure of the catalyst promoted and stabilized the high dispersion of the copper species with an abundant Cu-Si interface, thereby providing numerous reactive sites. The appropriate Cu0/Cu+ ratio in the active components produced efficient synergy, which was responsible for the excellent dehydrogenation performance. In addition, the low surface acid density (0.532 μmol/m2) of the catalyst greatly reduced the occurrence of diethylene glycol dehydration, thus improving para-dioxanone selectivity over 90% with promising stability.

A convenient functionalization strategy of polyimide covalent organic frameworks for uranium-containing wastewater treatment and uranium recovery

The purpose of this research was to design and synthesize an adsorbent based on polyimide covalent organic frameworks (PICOFs) for uranium-containing wastewater treatment and uranium recovery. A modified solvothermal method was innovatively proposed to synthesize PICOFs with high specific surface area (1998.5 m2 g−1) and regular pore structure. Additionally, a convenient functionalization strategy of PICOFs was designed through polydopamine (PDA) and a well-dispersed polymer (MPC-co-AO) containing multiple functional groups, forming stable composite (PMCA-TPPICOFs) in which the hydrogen bonding and cation-π interactions between PDA and MPC-co-AO played a key role. The obtained PMCA-TPPICOFs as an adsorbent exhibited strong selectivity for uranyl ions (maximum adsorption capacity was 538 mg g−1). In simulated wastewater with low uranium concentrations, the removal rate reached 98.3%, and the concentration of treated simulated wastewater met discharge standards. Moreover, PMCA-TPPICOFs was suitable for fixed-bed column adsorption because of its favorable structure. According to the research about adsorption mechanism, the adsorption primarily relied on electrostatic interaction and complexation. In summary, PMCA-TPPICOFs exhibited good potential for uranium-containing wastewater treatment, expanding the application of PICOFs. And the proposed functionalization strategy and modified solvothermal method may promote research in the fields of material functionalization and COFs synthesis. Environmental ImplicationUranium is a raw material for nuclear energy applications, which is toxic and radioactive. If uranium is discharged with wastewater, it would not only pose a threat to the environmental protection and life safety, but also cause the loss of precious nuclear raw materials. Although adsorption was considered to be an effective way to remove uranium, many of the developed adsorbents were difficult to apply due to the harsh wastewater environment and complex preparation processes. This study reported a novel adsorbent and a new functionalization strategy, which was expected to solve the problem of uranium recovery in wastewater.