ABSTRACT Quantitatively evaluating the debris cloud-induced pitting damage in the AL-Whipple structure of spacecraft, is still a challenge, let alone microstructural plastic deformation usually accompanied by geometric cratering defects, which may decrease material stress-carrying capacity and structural life. With this motivation, a dedicated modelling technique is proposed to gain an insight into various modalities (i.e., geometric and plastic defects) of pitting damage-induced thermal modulation for infrared inspection. Then, a sequence of infrared images is obtained and analysed using the gap smoothing algorithm and naive Bayes classification methods. On this basis, a quantitative characterization framework is proposed to characterize the damage modalities and their morphologies. This method is validated using a 3D numerical model which contains pitting damage acquired from the real-world structure. Modality classification and morphology evaluation results are well consistent with the artificial defects, in terms of the modality, diameter, and depth. Then they‘re experimentally corroborated, in which the severity and distribution of pitting damage are precisely characterized, in terms of the crater number and morphologies, as well as the size of plastic regions around these craters, which are consistent with the actual observations. This work proposes a non-destructive strategy for pitting damage evaluation, which is engineering-friendly.