In this work, we formalize the effect of mechanical shaking by using various forms of an externally exerted force, which may be constant or may be position-dependent, and we examine the changes in the potential energy surfaces that quantify the chemical reaction. We use a simple toy model to model the potential energy surfaces of a chemical reaction, and we study the effect of a constant or position-dependent externally exerted force for various forms of the force. As we demonstrate, the effect of the force can be quite dramatic on the potential energy surfaces, which acquire new stationary points and new Newton trajectories that are distinct from the original ones that were obtained in the absence of mechanochemical effects. We also introduce a new approach to mechanochemical interactions, using a dynamical systems approach for the Newton trajectories. As we show, the dynamical system attractor properties of the trajectories in the phase space are identical to the stationary points of the potential energy surfaces, but the phase space contains much more information regarding the possible evolution of the chemical reaction—information that is quantified by the existence of unstable or saddle fixed points in the phase space. We also discuss how an experimental method for a suitable symmetric liquid solution substance might formalize the effect of shaking via various forms of external force, even in the form of an extended coordinate-dependent force matrix. This approach may experimentally quantify the Epstein effect of shaking in chemical solutions via mechanochemistry methods.
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