The stereospecific 1,2âmigration of boronate complexes is one of the most representative reactions in boron chemistry. This process has been used extensively to develop powerful methods for asymmetric synthesis, with applications spanning from pharmaceuticals to natural products. Typically, 1,2âmigration of boronate complexes is driven by displacement of an Îąâleaving group, oxidation of an Îąâboryl radical, or electrophilic activation of an alkenyl boronate complex. The aim of this article is to summarize the recent advances in the rapidly expanding field of electrophileâinduced stereospecific 1,2âmigration of groups from boron to sp2 and sp3 carbon centers. It will be shown that three different conceptual approaches can be utilized to enable the 1,2âmigration of boronate complexes: stereospecific Zweifelâtype reactions, catalytic conjunctive coupling reactions, and transition metalâfree sp2âsp3 couplings. A discussion of the reaction scope, mechanistic insights, and synthetic applications of the work described is also presented.