Southern Spain Research Articles

Influence of cover crops and tillage on organic carbon loss in Mediterranean olive orchards

Olive (Olea europaea L.) is one of the main crops in the Mediterranean area, with Spain leading its production. The majority of the plantations are on rainfed land, poor soils with steep slopes. Regarding to soil, tillage (T) is the main management system used by farmers. Consequently, erosion and the resulting soil organic carbon (SOC) losses associated to it are one of the main environmental problems of olive production. Conservation Agriculture (CA) practices in permanent crops comprise the sowing of groundcovers or cover crops (CC) between the rows of olive trees. CC protect the olive orchard from erosion, preventing soil degradation. However, the relationship between the erosion and SOC losses under CC and T need to be better understood. In a four-year period (2003–2007) water, soil and SOC losses by erosion were measured in micro-plots (1 ×1 m2) that were managed with T and CC in eight study zones in Andalusia (Southern Spain). At the same time, the characteristics of all rainfall events during the study period were registered, and soil cover was estimated from images taken during the field campaigns. SOC output was observed to be statistically positively correlated to runoff and erosion. The loss of water, SOC and sediment were mainly affected by the characteristics of the rainfall events and soil cover. The type of soil or the typology of the olive grove plantation were not so important for the loss of SOC under conservation agriculture management. However, these facts were especially significant for the T conditions. Conversely to T, where only 22.4 % of soil was protected, CC provided a 65.7 % cover throughout the season. This better protection of the soil provided by the CC, resulted in a lower influence of the rainfall events in the loss of water, soil and SOC. This was not the case in the T systems. The conservation management was responsible for a 36.7 % average reduction in runoff and an 85.5 % reduction in erosion compared to T, which decreased SOC loss associated with sediment by 76.4 %.

Holocene summer temperature reconstruction based on a chironomid record from Sierra Nevada, southern Spain

Obtaining accurate temperature reconstructions from the past is crucial in understanding the consequences of changes in external climate forcings, such as orbital-scale insolation or multidecadal to centennial-scale variability on the climate system and the environment. In addition, these reconstructions help in comprehending the amplitude of natural temperature changes in the past, which can assist in evaluating the amplitude and rate of recent anthropogenic global warming. Here we present the first detailed Holocene mean July air temperature reconstruction based on chironomid assemblages from sediments retrieved from Laguna de Río Seco, an alpine lake in Sierra Nevada, southern Spain. Coldest climate conditions are recorded during the last glacial maximum and the last deglaciation. Warming occurred in the Early Holocene and warmest summer temperature conditions and the Holocene thermal maximum (HTM) occurred in the interval roughly between 9000 and 7200 cal yr BP, concurrent with summer insolation maxima. Rapid cooling of ∼1.5 °C occurred after the warmest maximum and between ∼7200 and 6500 cal yr BP, and temperatures stabilized between ∼6500 and 3000 cal yr BP. A further cooling began ∼3000 cal yr BP and culminated with coldest summer conditions during the Dark Ages (DA) and Little Ice Age (LIA) at ∼1550 cal yr BP (∼400 CE) and ∼200 cal yr BP (∼1750 CE), respectively. This cooling temperature trend was interrupted by warmer conditions during the Iberian-Roman Humid Period (IRHP) ∼2000 cal yr BP and during the Medieval Climate Anomaly (MCA) at ∼1000 cal yr BP. Our reconstruction shows a greater than two-degree cooling during the Middle and Late Holocene, agreeing with global mean surface temperature (GMST) reconstructions. Modern climate warming (MCW) during summer exceeds the two-degree Celsius forecasted for the future due to anthropogenic greenhouse gases, suggesting that recent warming is amplified at high elevations. Alpine environments and the biodiversity contained there are thus in danger if the observed temperature trend continues in the next decades.

Dynamic performance of the Mosque-Cathedral of Córdoba under different earthquake scenarios: The Abd al-Rahman I sector

The Mosque-Cathedral of Córdoba is one of the most important monuments in Spain. Owing to its authenticity, its integrity and its influence on later architecture, it was declared as a World Heritage Site by the UNESCO in 1984. The monument is located in Andalusia, in southern Spain. This region presents a moderate seismic hazard, and it is affected by two kinds of seismic sources: a) far away earthquakes of large/very large magnitude; b) close earthquakes of moderate magnitude. Particularly, the Mosque-Cathedral had to endure the well-known 1755 Lisbon's earthquake (Mw = 8.5, at 488 km) and the 1504 Carmona earthquake (Mw = 6.8, at 82 km). This research has analysed its dynamic behaviour under several earthquake scenarios: code-base response spectrum, previous historic earthquakes and fault maximum magnitude earthquakes. However, after the seismic hazard analysis and due to the lack of faults registered surrounding the building, no worst-case scenario considering the maximum expected magnitude has been found. Owing to the complexity of the building, this work has focused on the Abd al-Rahman I sector, which is the most aged part, dating from the VIII century. A refined 3D numerical model has been developed and calibrated through free ambient vibration tests. The distribution of the maximum amplitudes (internal displacements and absolute accelerations) under the different scenarios has been comparatively presented. Also, the seismic performance has been assessed considering the drifts and the damage expected. The results showed that the damage would be concentrated in the contact between the arcades and the courtyard wall. Also, the lower part of the North-South closing wall would be damaged. According to the seismic performance, the building is expected to present moderate damage. In contrast, the analysis of the drifts, according to the codes, suggest that the building would resist each damage limit. Also, it was shown that the far fault earthquake scenario is more demanding than the close fault earthquake scenario. Next, it should be noted that the behaviour of the building for a seismic action of 475-year return period is expected to be similar to the far-fault earthquake scenario. The most demanding earthquake scenario has been the 975-year return period one.

Short-term rentals’ supply-side structure and the struggle for rent appropriation: Insights from Andalusia, Spain

Platform capitalism is a growing reality with a widening social and economic impact. The rapid expansion of Short-Term Rental (STR) platforms has led to new challenges for policy regulation. The main objective of this paper is to shed some light on current conflicts surrounding the regulation of STR. The body of literature on this topic mainly focuses on the increasing substitution of sharing economy by commercial hosts. By contrast, we explain that the ideological notion of host hinders the understanding of the supply-side structure. A critical approach (as critique of ideology and ideological categories) should entail a class perspective based on rent theory and engage with critical works on platform capitalism. In this article, we propose an innovative analytical approach to STR supply-side supported by rent theory, which focuses on the relationship of agents with land and technology ownership and specialised management services, as these are forms of rent appropriation. From this point of view, these supply-side agents are not hosts, but class factions with common and competing economic interests in rent appropriation. Therefore, they can employ a variety of strategies to influence the political regulation of STRs. Based on in-depth interviews with landlords, individual managers, and corporate agencies in Andalusia (Southern Spain), we show the conflicting internal structure behind the ideological notion of host and even professionalisation.

Monitoring the dynamics of consumption of ungulate game by-products in vulture feeding stations in Iberian Mediterranean ecosystems

Vulture feeding stations (VFS) are strategic sites for the management of ungulate game by-products, with major implications for the conservation of obligate avian scavengers. These feeding points are designed to prevent access by facultative mammalian scavengers and to reduce the risk of trophically transmitted pathogen infection through scavenging behaviour. The aim of this study, using camera trap video recordings, was to evaluate the feeding dynamics around 32 lots of ungulate game by-products deposited in VFS in southern Spain. During the study period (2017–2022), 11 different avian and mammal scavenger species was detected. Also, many feeding events involving all scavenger species (51.1%; 362/709) and mammal scavenger species (23.4%; 166/709) was recorded. A significantly earlier presence of major obligate scavengers (Gyps fulvus and Aegypius monachus) (P = 0.023) and a lower persistence of by-products deposited (P < 0.001) were detected during October–December compared to January–March. Our results confirm that VFS play an important role in vulture conservation in Iberian Mediterranean ecosystems. However, we also point out the potential risk of VFS as hotspots of foodborne pathogens for mammal scavengers, particularly when the hunting offal persists longer. Consequently, we urge the competent authorities to update the regulations affecting VFS management, and hunting estate managers to make every effort to correctly apply those preventing scavenging mammals from gaining access to VFS. Further studies tackling access of non-target species to VFS are also warranted to properly assess the sanitary implications and geographical extent of these problems for mammal species inhabiting areas where VFS are installed.

Primary parasitoids of Aulacaspis tubercularis Newstead (Hemiptera: Diaspididae) occurring in Spanish mango orchards

The white mango scale (WMS), Aulacaspis tubercularis, is the main pest of mango crops in Southern Spain. Field surveys were carried out from July 2019 to May 2022 to investigate the identity, seasonal abundance and active parasitism rates of A. tubercularis primary parasitoid species, using yellow sticky traps and periodic leaf sampling. The combination of morphological characters and DNA sequences of the mitochondrial cytochrome c oxidase subunit 1 (mtCOI) and 28S ribosomal (28S rDNA) genes allowed the identification of only two parasitoid species belonging to the genus Encarsia Förster (Hymenoptera: Aphelinidae). The most prevalent, E. citrina (Crawford), is a widespread species and proved to be the dominant species in the sampled mango orchards. Next, Encarsia sp., is an unidentified species genetically close to E. lounsburyi Berlese but significantly differs in the sequences of the mtCOI and 28S rDNA regions. Population abundance and active parasitism rates of Encarsia parasitoids depended on the presence of susceptible WMS stages for parasitism and on the abiotic conditions. The seasonal abundance of these parasitoid species fluctuated around the year, being lower during the winter but it increased in late spring, reaching the highest values at the end of summer. The average percentage of active parasitism was 12.48% for female scales and 13.97% for male scales but reached maximum values of 38.56 and 43.52%, respectively at specific seasons in the year. The highest rates of parasitism for female scales were observed in summer, while for male scales were observed in winter. The natural occurrence of parasitoids was unable to control the WMS populations and, consequently, complementary measures should be implemented to reduce its density levels.

As above, so below: Deposition, modification, and reutilization of human remains at Marmoles cave (Cueva de los Marmoles: Southern Spain, 4000-1000 cal. BCE).

The deposition and manipulation of human remains in natural caves are well known for the Neolithic of Southern Iberia. The cultural meaning of these practices is however still largely unclear. Cueva de los Marmoles (CM, Priego-Córdoba) is one of the most important cave contexts from Southern Spain, which returned a large number of commingled skeletal remains suggesting its funerary use from the Neolithic to the Late Bronze Age. Here we discuss CM from a chronological and cultural perspective based on new radiocarbon, anthropological, and taphonomic analyses. These include the estimation of the minimum number of individuals, the exploration of fragmentation patterns characterizing different skeletal regions, and the macroscopic and microscopic analysis of modifications to the remains of possible anthropic origin. Radiocarbon data point to a funerary use of CM between the 5th -2nd millennium cal. BCE. MNI estimates reveal the presence of at least 12 individuals (seven adults and five nonadults). The low representation of elements from hands and feet suggests that individuals were placed in the cave while partially decomposed. Anthropic traces on the remains (e.g. fresh fractures, marrow canal modifications, and scraping marks) hint at their intentional fragmentation, cleaning from residual soft tissues, and in some cases reutilization. These practices are well-exemplified by the recovery of one "skull cup" and of two long bones used as tools. These data align with those from other cave contexts from the same geographic region, suggesting the presence, especially during the Neolithic period, of shared ideologies centered on the human body.

Hydrological modelling and evolution of lakes and playa-lakes in southern Spain constrained by geology, human management and climate change

The hydrological functioning of wetlands in S Spain is poorly understood. We perform a 22-years hydrological modelling of seven playa-lakes located in a semi-arid region of southern Spain, including dry and wet periods. To do that, we applied a hydrological balance model to reconstruct past lake water levels. In addition, we investigated the hydrochemistry of the water, the basin bathymetry, and the geological setting of the watersheds, acquiring new lithology and active structures data. Once the models were constrained, scenarios considering increases on temperature and human management were implemented, and discussed. The water balance is simplified to precipitation (water input) and basin discharge (evapotranspiration), as the lakes are disconnected from groundwater because of the low-permeability substrate. In addition, unlike in previous studies, we add overflows to the modelling. The results of the model agree with actual lake water monitoring data (R2 > 0.8). We observed that the hydroperiods of some of these lakes vary from permanent lakes to ephemeral, depending strongly on the basin bathymetry. Lakes with steeply margins show longer hydroperiods, whilst it is shorter for low-lying floor playa-lakes. In addition, we observed that steeply lake margins respond to active faults and/or lithological changes. To forecast the effects of climate change on the lake hydroperiods, we applied a 1 °C increase in average temperature in our hydrological modelling. The hydroperiod is significantly reduced for ephemeral playa-lakes, whilst is barely affected in permanent lakes. Moreover, we detected the high sensitivity of ephemeral playa-lakes to the anthropogenic management, including siltation, plant colonization and changes watershed surface.

Combined effects of occupational physical activity and ambient heat on kidney function in female harvest workers in Southern Spain

Combined effects of occupational physical activity and ambient heat on kidney function in female harvest workers in Southern Spain

Assessing Terrestrial Water Storage Variations in Southern Spain Using Rainfall Estimates and GRACE Data

This paper investigates the relationship between rainfall, groundwater and Gravity Recovery and Climate Experiment (GRACE) data to generate regional-scale estimates of terrestrial water storage variations in the Andalucía region of southern Spain. These estimates can provide information on groundwater depletion (caused by periods of low rainfall or droughts) and groundwater recovery. The spatial distribution of groundwater bodies in southern Spain is complex and current in situ groundwater monitoring methods are deficient, particularly in terms of obtaining representative samples and in implementing and maintaining groundwater monitoring networks. The alternative approach proposed here is to investigate the relationship between precipitation time series and changes in the terrestrial water storage estimated from GRACE observations. The results were validated against the estimated fluctuation in regional groundwater. The maximum correlation between the mean groundwater level and the GRACE observations is 0.69 and this occurs at a lag of one month because the variation in gravity is immediate, but rainfall water requires around one month to travel across the vadose zone before it reaches the groundwater table. Using graphical methods of accumulated deviations from the mean, we show that, in general, groundwater storage follows the smooth, multi-year trends of terrestrial water storage but with less short-term trends; the same is true of rainfall, for which the local trends are more pronounced. There is hysteresis-like behaviour in the variations in terrestrial water storage and in the variations of groundwater. In practical terms, this study shows that, despite the abnormal dryness of the Iberian Peninsula during the 2004–2010 drought, the depleted groundwater storage in Andalucía recovered almost to its pre-drought level by 2016. In addition, groundwater storage and terrestrial water storage show very similar trends but with a delay in the groundwater trend.

Feasibility of utilization of recycled HDPE in manhole covers for urban traffic areas and industrial zones

The consumption of plastic raw materials has been exponentially growing throughout the world in the last decade and so has, in the same proportion, their associated waste. Recycling through the mechanical treatment of the heavy fraction of these plastics is the most economic and the safest alternative to use this waste and to recirculate it for reuse within the same industry or for other related industries located near the place where the waste is generated. In this paper, a study of characterization and post-processing of recycled high density polyethylene received by a hazardous waste manager in southern Spain is presented, an area in which containers, Intermediate Bulk Containers, and drums, originally used for oil products from refineries and petrochemical industries nearby, are employed. These high density polyethylene materials are validated to meet the requirements of the harmonized standards to be used as self-supply in the production of manhole covers. EN 124–6:2015 standard allows the use of plastic materials such as PE or PP, even using material externally reprocessed, such as material derived from thermoplastic products that have not been previously used as lids or manhole covers. Class A-15 and B-125 of the standard are oriented for the construction of these types of elements to cover or close in certain urban spaces such as pedestrian areas, parking areas or multi-story car parks for vehicles. The study shows that the recycled material fully complies with the density; it keeps unalterable during fire test after application of the coating, there are no adverse effects on artificial ageing; the decrease of the average value of the tensile impact strength by 21.84%; and achieves 6 mm of maximum deflection against the test load Fp (45.3 MPa). Therefore, it can be considered a valid scenario for the effective use of solid plastic waste in products that make up part of the urban or industrial areas, as an example of complete circularity material and offers a valid alternative to the end-of-waste condition.

Spatio-temporal joint modelling on moderate and extreme air pollution in Spain

Very unhealthy air quality is consistently connected with numerous diseases. Appropriate extreme analysis and accurate predictions are in rising demand for exploring potential linked causes and for providing suggestions for the environmental agency in public policy strategy. This paper aims to model the spatial and temporal pattern of both moderate and extremely poor PM10\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_{10}$$\\end{document} concentrations (of daily mean) collected from 342 representative monitors distributed throughout mainland Spain from 2017 to 2021. We first propose and compare a series of Bayesian hierarchical generalized extreme models of annual maxima PM10\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_{10}$$\\end{document} concentrations, including both the fixed effect of altitude, temperature, precipitation, vapour pressure and population density, as well as the spatio-temporal random effect with the Stochastic Partial Differential Equation (SPDE) approach and a lag-one dynamic auto-regressive component (AR(1)). Under WAIC, DIC and other criteria, the best model is selected with good predictive ability based on the first four-year data (2017–2020) for training and the last-year data (2021) for testing. We bring the structure of the best model to establish the joint Bayesian model of annual mean and annual maxima PM10\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_{10}$$\\end{document} concentrations and provide evidence that certain predictors (precipitation, vapour pressure and population density) influence comparably while the other predictors (altitude and temperature) impact reversely in the different scaled PM10\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_{10}$$\\end{document} concentrations. The findings are applied to identify the hot-spot regions with poor air quality using excursion functions specified at the grid level. It suggests that the community of Madrid and some sites in northwestern and southern Spain are likely to be exposed to severe air pollution, simultaneously exceeding the warning risk threshold.

Effects of a Sport Education Season of an Alternative Sport on School Climate, Emotional Intelligence, and Perceived Competence of Elementary School Students in a Culturally Diverse Context

Purpose: The aim of this study was to explore the influence of a Sport Education Model (SEM) season about colpbol on primary education students’ school climate, emotional intelligence, and perceived competence. Method: 77 (42 boys, 35 girls; 64% immigrant) fourth-to-sixth grade students (Mage = 10.87; SD = 1.09) from a southern Spain school took part in this study. Sixth-grade students were taught through co-teaching, while other grades followed traditional teaching. Over a five-week period, students participated in a season of 10 sessions of colpbol. Dependent variables were measured through questionnaires. Results: Results showed significant improvements in sixth-grade students (all analyzed variables) and fifth-grade students (perceived competence and emotional control and regulation). No significant changes were found in fourth-grade students. Discussion: It is shown the positive influence of co-teaching in culturally diverse classrooms on both psychological and socio-affective learning dimensions. Likewise, alternative sports could enhance the inclusive principles of the SEM inspired by the ‘sport for all’ policy. Keywords: alternative sport, physical education, pedagogical model, culturally diverse classrooms, co-teaching.

Study of the presence and environmental risk of organic contaminants policed by the European Union and other organic compounds in the water resources of a region overlapping protected areas: The Guadiaro River basin (southern Spain)

The study presented here is a first qualitative assessment of the occurrence of organic contaminants contemplated and not yet contemplated in European Union environmental legislation in water resources in the little anthropized Guadiaro River basin (70% of its area is covered by natural vegetation), in southern Spain. Water samples were collected from four carbonate aquifers, two detrital aquifers and four surface water courses and were analyzed for (i) 171 organic contaminants, (ii) major ions and (iii) stable isotopes (δ18OH2O, δ2HH2O, δ13CDIC). An environmental risk assessment was conducted through calculation of risk quotients comparing measured concentrations with ecotoxicological data found in the literature. Twenty-five organic contaminants were detected, at least once, including pesticides, pharmaceuticals, drugs of abuse and polycyclic aromatic hydrocarbons (PAHs). Cocaine and its main metabolite were detected in 85% and 95% of water samples, respectively (0.001–0.18 μg/L and 0.004–0.6 μg/L, respectively). Pyrene (PAH) was found in all water samples (0.001–0.015 μg/L) and forest fires were pointed out as a potential diffuse source. Relationship between rivers and aquifers is reflected by the distribution of organic contaminants, essentially the drugs of abuse. Concentration of contaminants were generally higher in groundwater samples, especially from detrital aquifers, potentially due to an accumulation process promoted by irrigation-return flows and by its slow dynamic compared to that of karstic systems. Pyrene concentration was also higher in some springs from karstic aquifers. Hence, calculated risk quotients were in general higher in groundwater, meaning that the threat to surface aquatic systems can grow as aquifers increase their influence on the water courses as the dry season progresses. The relationship between δ13CDIC and most organic contaminants (especially pyrene) reveal the role of the soil as storage media.

Variability of heat stress using the UrbClim climate model in the city of Seville (Spain): mitigation proposal

Climate change is creating an increase in temperatures, which is harming the quality of life of people all over the world, particularly those with minimal financial resources. While 30% of the world’s population is now vulnerable to extreme heat, estimates show that ratio will rise to 74% in the next 20 years, according to forecasts. Using the UrbClim climate model, this study examines the space-time variability of the heat stress index (HI) in different local climate zones (LCZs), as well as how heat wave conditions might affect this index based on land use and land cover. To that end, Seville, in Southern Spain, was investigated during the summer of 2017, when it had four heat waves. The following indices were considered for each urban sub-area: Normalized Difference Vegetation, Proportion Vegetation, Normalized Difference Built, and Urban Index. The goal is to conduct a statistical analysis of the link between the aforementioned elements and the heat stress index in order to recommend mitigation and resilience techniques. Our findings showed that compact and industrial LCZs (2, 3, and 10) are less resistant to HI than open and rural regions (5, 6, B, D, and G), which are more resistant to HI due to higher vegetation rates. The heat wave condition exacerbates the HI in all LCZs. As a result, initiatives such as enhancing open space, increasing green space, or using green roofs and façades might alleviate heat stress and improve people’s quality of life.

Tracing acid mine drainage and estuarine Zn attenuation using Cd and Zn isotopes

It has been estimated that the acid mine drainage (AMD) impacted Odiel river basin in southern Spain supplies 0.37% and 15% of the global riverine fluxes of Cd and Zn to the oceans, respectively (Sarmiento et al., 2009). However, the behaviour of Cd and Zn in the Ria of Huelva estuary, which connects the Odiel and Tinto watersheds with the Gulf of Cadiz, has yet to be fully investigated. Furthermore, very few studies have investigated Cd and Zn isotope behaviour in estuaries worldwide. This study presents Cd and Zn concentrations and isotopic compositions for the Ria of Huelva estuary and surrounding watersheds, sampled in 2017 and 2019. Sulfide-rich rock samples extracted from three mines yield Cd and Zn isotope compositions that range from –0.14‰ to +0.07‰ (n = 4) for δ114Cd and –0.01‰ to +0.29‰ (n = 4) for δ66Zn. However, a uniform riverine signal of about +0.02‰ for Cd and +0.17‰ for Zn indicates that tracing of individual mining regions using Cd and Zn isotopes is challenging. Limited variability was observed in dissolved δ114Cd values throughout the watershed, including AMD, the estuary, and the Gulf of Cadiz, with a mean value of ±0.00 ± 0.13‰ (n = 25, 2 SD; excludes one AMD outlier, at +0.48‰), including both 2017 and 2019 data. By contrast, δ66Zn values ranged from –0.12‰ to +0.35‰ (n = 28) for the same geographical and temporal scope. In May 2017, a large spill from an abandoned mine, La Zarza, resulted in a drastic increase in the concentrations of trace metals reaching the estuary compared to 2019, but no impact of this mine spill on Cd or Zn isotope compositions is observed. In 2019, an increase in δ66Zn values in the estuary coincided with high pH values (up to pH = 8.8) and chloride concentrations (2.73%), which may reflect an alkaline anthropogenic input from the active neighbouring industrial complex. Overall, Cd concentrations and isotope compositions in the estuary are largely consistent with conservative mixing behaviour. By contrast, Zn behaviour is non-conservative, with removal of 49–97% of dissolved riverine Zn in the estuary during the period 2017–2019, associated with a relatively small isotopic shift to lighter Zn isotope compositions. Removal of Zn to the particulate phase in the Ria of Huelva estuary therefore largely attenuates high riverine Zn fluxes from AMD, indicating that previously estimated Odiel river basin Zn fluxes were overestimated. Nevertheless, the variable but generally light AMD Cd and Zn isotope compositions, coupled with high dissolved metal concentrations, suggest that Cd and Zn isotopes may be useful tracers of regionally averaged AMD inputs to the Gulf of Cadiz and beyond.

A deep-marine ichnofossil assemblage from the Tertiary-age Algeciras Formation and related units, Campo de Gibraltar Complex, Southern Spain

A deep-marine ichnofossil assemblage from the Tertiary-age Algeciras Formation and related units, Campo de Gibraltar Complex, Southern Spain

‘All our eggs in one basket’: touristification and displacement amidst the pandemic in Seville, Spain

Touristification refers to the multi-dimensional transformation of an area due to severe and rapid tourism intensification, which can harm that place's inhabitants in different ways. The activity’s boom in the 2010s brought about an exponential increase in short-term tourist rentals (STRs) in traditionally non-tourist areas across cities worldwide, triggering or expanding displacement dynamics. The study delves into the connections between touristification and displacement and how the latter has conditioned neighbors’ lives. As the health crisis abruptly stopped tourist hypermobility, we also question how displacement has been affected and the ways in which it might evolve in the post-pandemic city. We focus on Seville, the capital of Andalusia in southern Spain, a region highly dependent on the tourism and real estate sectors that has annually broken its visitors’ records until the Covid-19 pandemic broke out. We reflect upon how local populations in central and increasingly tourist neighborhoods have experienced expulsion before and amidst the pandemic through thirty interviews with residents and displacees from different socio-economic backgrounds in Seville's historic district. We conclude that the reconversion of STRs into long-term leases during and after the pandemic has resolved little compared with the damage already done.

Reducing nutrient loss in drainage from tomato grown in free-draining substrate in greenhouses using dynamic nutrient management

Substrate-grown crops represent approximately 10% of the cropping area of intensive greenhouse horticulture in southern Spain. The vast majority are free draining, in that they do not collect and recirculate drainage. The substantial nutrient loss in drainage contributes to contamination of water bodies. This study examined the effectiveness of dynamic management approaches to appreciably reduce the large nutrient loss associated with free-draining substrate-grown crops. For three tomato crops, grown in substrate, this study (i) compared management of N, P and K based on the ratio of the concentration in drainage to that in the nutrient solution, to conventional management, (ii) derived uptake concentration values for N, P and K throughout the crop cycle, and (iii) evaluated uptake concentration as a nutrition management tool. Ratio-based management reduced the amounts of N, P and K in drainage, in relation to conventional management by 58–61%, 65–80% and 55–77% respectively. The amounts of applied N, P and K were reduced by 22–28%, 37–43%, and 28–34% compared to conventional management. N, P and K concentrations in the applied nutrient solution slightly below the uptake concentration were associated with much lower concentrations in the drainage solution. In contrast, when the applied nutrient concentration exceeded the uptake concentration this was associated with much higher drainage nutrient concentrations. In conclusion, the two nutritional management strategies examined, ratio-based management, and use of uptake concentrations were both associated with reduced nutrient application and a considerable reduction of nutrient loss in drainage. Fruit production was maintained with the improved nutrient management practices. These strategies offer approaches that can considerably reduce the substantial nutrient loss in drainage associated with free-draining substrate cropping in greenhouse production in southern Europe.

Xerophytic Lichens from Gypsiferous Outcrops of Arid Areas of Andalusia as a Source of Anti-Phytopathogenic Depsides.

In a survey to evaluate the potential of lichens associated with gypsum areas as sources of new antifungal metabolites, six species of lichens were collected in the gypsum outcrops of the Sorbas Desert (Diploschistes ocellatus and Seirophora lacunosa) and the Tabernas Desert (Cladonia foliacea, Acarospora placodiformis, Squamarina lentigera and Xanthoparmelia pokornyi) in southern Spain. Raw lichen acetone extracts were tested against a panel of seven phytopathogenic fungi, including Botrytis cinerea, Colletotrichum acutatum, Fusarium oxysporum f.sp cubense TR4, Fusarium ploriferaum, Magnaporthe grisea, Verticillium dahliae and Zymoseptoria tritici. Active extracts of Cladonia foliacea, Xanthoparmelia pokornyi and Squamarina lentigera were analyzed by HPLC-MS/MS and Molecular Networking to identify possible metabolites responsible for the antifungal activity. A total of ten depside-like metabolites were identified by MS/MS dereplication and NMR experiments, of which one was a new derivative of fumaroprotocetraric acid. The compounds without previously described biological activity were purified and tested against the panel of fungal phytopathogens. Herein, the antifungal activity against fungal phytopathogens of 4'-O-methylpaludosic acid, divaricatic acid and stenosporic acid is reported for the first time. Stenosporic and divaricatic acids displayed a broad antifungal spectrum against seven relevant fungal phytopathogens in a micromolar range, including the extremely resistant fungus F. oxysporum f. sp. cubense Tropical Race 4 (TR4). 4'-O-methylpaludosic acid exhibited specific antifungal activity against the wheat pathogen Z. tritici, with an IC50 of 38.87 µg/mL (87.1 µM) in the absorbance-based assay and 24.88 µg/mL (55.52 µM) in the fluorescence-based assay.