Hybrid hydrothermal systems, in which both water-rock reactions and magmatic fluids contribute to sulfide mineralization, have recently been reported in some submarine arcs and mature back-arc basins. Owing to their high mineralization efficiency, hybrid hydrothermal systems have attracted significant attention from geologists. This study provides first clues for the identification of a novel hybrid hydrothermal system (synproportionation-controlled instead of the more common disproportionation-controlled) in the Tangyin field, Southern Okinawa Trough. The studied samples are native sulfur-type precipitates, primarily composed of elemental sulfur with minor sulfide disseminations. The distinct crystallization conditions and S isotope compositions of elemental sulfur and sulfide disseminations indicate their different genesis. The S in sulfide disseminations (δ34S = −2.7 to 1.6 ‰) is derived from water-rock reaction and subsequently influenced by fluid phase separation, which is further demonstrated by the trace element contents of pyrite (low Tl/Pb, Sb/Pb, Te/As, Te/Sb ratios). In contrast, the elemental sulfur (δ34S = 3.9 to 4.3 ‰) is formed by the synproportionation of magmatic SO2 and hydrothermal H2S from the boiled liquid. A simple two-component mixing calculation indicated that the contributions of the water-rock reactions and magmatic fluids to the Tangyin hydrothermal system were approximately equal. The higher temperature (> 350 °C) and oxygen fugacity conditions may be the key factors for the development of a synproportionation-controlled hybrid hydrothermal system in the Tangyin field. Hydrothermal systems in back-arc basins exhibit higher sulfide accumulation rates than those in mid-ocean ridges; this may be attributed to the prevalence of hybrid hydrothermal vents in back-arc settings.
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