South China Block Research Articles

Seismic Reflection Imaging Reveals Relict Subduction Zone of the Paleo-Pacific Plate in the Northeastern South China Sea

The South China Sea (SCS) is widely accepted as an active margin that is associated with the subduction of the Paleo-Pacific plate during the Mesozoic. However, the exact location of the subduction or suture zone remains unclear. Understanding the location of the subduction zone is crucial for comprehending the Mesozoic tectonic evolution of the South China Block and the Cenozoic rifting process of the SCS. To clarify the position of the subduction zone and the influences of preexisting structures, we used a multichannel seismic reflection profile to investigate the crustal architecture. The seismic profile reveals a crustal “crocodile” structure that is interpreted as relict subduction in the Chaoshan Depression and a set of south-dipping crust-mantle reflectors related to the initial rifting in the continent–ocean transition (COT) zone. The results indicate that a Mesozoic subduction zone is located at the northeastern margin of the SCS and that preexisting structures (subduction-related structures) facilitated the rifting process. Combined with previous studies on the oceanic plateau collision-accretionary zone of the northern SCS and the Mesozoic accretionary zone in Palawan of the southern SCS, we infer that a section of the suture zone of the Paleo-Pacific plate subduction is preserved at the northeastern SCS margin and that the rifting of the SCS may have initiated at the suture zone.

Lithospheric resistivity structure of the Xuefeng Orogenic Belt and its implications for intracontinental deformation in South China

The Xuefeng Orogenic Belt (XFOB), located in the central part of the South China Block, is a typical Mesozoic intracontinental orogen in the central Jiangnan Orogenic Belt. By collecting magnetotelluric (MT) data across the XFOB, we obtained the resistivity structure of the lithosphere, which sheds light on the Mesozoic intracontinental orogenic processes in the XFOB. The resistivity structure reveals a low-resistivity body (<10 Ω∙m), beneath the XFOB, dipping southeast wards from a depth of 10 km to the bottom of the crust. This conductor is interpreted as a relic of the lower detachment zone, which coincides with low-density areas obtained from joint inversion of seismic models. It is believed to result from mineral fluids migrating along the thrust fault and squeezing sulfides into folds. Four low-resistivity bodies were identified at three extensional locations along the Jiangshan-Shaoxing Fault and at the Cili-Baojing Fault. The low-resistivity body (<10 Ω∙m) at the junction of the Shaoyang and the Hengyang Basin is located at the point where the Moho depth thins. The variation trend of the terrestrial heat flow values, with this low-resistivity body as the plate boundary, is consistent with the average variation of the terrestrial heat flow values within the block. We propose that the low-resistivity body under the Qidong-Yongzhou-Guilin fault conforms to the characteristics of the suture zone in the resistivity structure. Its existence indicates that the missing location of the Jiangshan-Shaoxing suture zone of the Yangtze and Cathaysia Block in the middle-southwest section of the South China Block is the Qidong-Yongzhou-Guilin fault. The Yangtze Block and the Hengyang Basin show high resistivity, the depth of which reaches 100 km and 40 km, respectively. Based on the resistivity model and geological data, the XFOB experienced Triassic compression, leading to basement decollement, thrusting, and nappe structures due to low-angle Paleo-Pacific Plate subduction. This compression also led to the uplift of the orogenic belt. Moreover, under the tension caused by the high-angle retreat of the Paleo-Pacific Plate, the Cretaceous extensional tectonics led to detachment along the thrust faults, forming half-graben and basin structures along the margins.

Lithospheric Folding Controls the Intracontinental Orogen of South China: Insight from Numerical Simulation

Abstract Orogenic processes worldwide have been attributed to various deformation mechanisms. However, the significance of lithospheric folding in these processes has often been overlooked and underestimated. Within the South China Block (SCB), a region marked by notable temporal and spatial variability in intracontinental deformation, the emergence of fold-and-thrust belts during the Paleozoic and Mesozoic periods has captured a scientific interest. The mechanisms governing the genesis of these belts remain a subject of debate, with no discernible subduction interface accounting for the extensive-scale fold-thrust deformation. Moreover, the SCB presents a substantial variation in lithospheric thickness, exceeding 100 km, offering a plausible mechanism for lithospheric folding. To interrogate this mechanism, we conducted lithospheric compression simulations via two-dimensional finite element methods, incorporating variable viscosity both laterally and vertically within the SCB. Our models elucidate that disparities in lithospheric strength beget distinctive deformational manifestation within the SCB. We observe that a weaker lithosphere tends to uplift, whereas a stronger lithosphere tends to subside during compression. Lithospheric strength also influences the Xuefengshan uplift and the spatial distribution of deformational features. In addition, lithospheric folding can account for crustal shortening and the presence of deep anomaly structures. A compelling correlation emerges between lithospheric folding and fluctuations in Moho depth and lithospheric thickness, suggesting its potential influence over the prolonged topographical evolution and shifts in depositional environments within the SCB. This study sheds new light on the role of lithospheric folding in the complex geodynamic history of the SCB and highlights its importance in understanding the broader context of orogenic processes worldwide.

Constraints on the Growth and Evolution of Continental Crust in the Northeast Cathaysia Block: Insights from Detrital Zircon U-Pb Age and Hf-O Isotope Analysis in Tingjiang Sediments

Fluvial detrital zircons provide crucial insights into the early Precambrian crustal evolution. In this study, we utilize U-Pb geochronology and Hf-O isotopic compositions of detrital zircons from the Tingjiang River to comprehend the provenance and continental crustal evolution of the northeast Cathaysia Block. Zircon U-Pb ages display seven major populations at 105-177 Ma, 200-262 Ma, 376-520 Ma with a striking peak at ca. 422 Ma, 606-775 Ma, 836-1457 Ma, 1710-2042Ma, and 2300-2661Ma, corresponding to the documented tectonic-thermal events in the South China Block. Episodic magmatism was the response to the formation and breakup of the Columbia and Rodinia supercontinent. The episode of 422 Ma matches with the ages of widely spread early Paleozoic intraplate orogenic events in the South China Block. The isotopic signatures of Hf and O in the detrital zircons indicate that the majority of Precambrian zircons likely originated from the re-melted ancient continental crust, with contributions from juvenile mantle-derived magmas. Phanerozoic zircons, on the other hand, were formed through partial melting of recycled crustal material. Analysis of crustal growth rates, based on the two-stage Hf model ages, suggests a significant presence of juvenile crustal growth during the Paleoproterozoic era. Specifically, it is estimated that approximately 40% and 90% of the present crust within the northeastern Cathaysia Block were formed around 2.3 Ga and 1.6 Ga, respectively.

Involvement of the Northeastern Margin of South China Block in Rodinia Supercontinent Evolution: A Case Study of Neoproterozoic Granitic Gneiss in Rizhao Area, Shandong Province

Involvement of the Northeastern Margin of South China Block in Rodinia Supercontinent Evolution: A Case Study of Neoproterozoic Granitic Gneiss in Rizhao Area, Shandong Province

Structural and chronological constraints for Longquan‐Badu ductile shear zone: Implication for Triassic intraplate orogeny in South China Block

The ductile shear deformation of Precambrian basement rocks in Wuyishan provides a crucial perspective on intraplate orogeny in the South China Block (SCB). This study focuses on the Longquan‐Badu ductile shear zone in southeastern Zhejiang, employing field observations, thin section analysis, quartz electron backscatter diffraction (EBSD), zircon U–Pb dating and 40Ar/39Ar geochronology. Two distinct phases of deformation, referred to as D1 and D2, have been identified. D1 is primarily characterized by a WNW–ESE striking foliation within a NE‐plunging lineation, indicating top‐to‐SSW shearing. The paragneiss within the Badu complex that experienced D1 deformation has been dated to 247–239 Ma through zircon U–Pb analysis, corresponding to the prevalent high‐pressure metamorphic age in the region. This correlation suggests that the D1 deformation event coincided with crustal thickening during the Early Triassic. D2 deformation exhibits folds, foliation, S‐C fabrics and mylonitic microstructures and is mainly characterized by striking NNE–SSW with steeply dip, demonstrating a dominant dextral strike–slip component. Quartz c‐axis orientations in mylonitic rocks indicate deformation temperatures between 350°C and 550°C with asymmetric girdle patterns suggesting simultaneous basal and prism slip. The plateau ages of muscovite from mylonitic rocks obtained through 40Ar/39Ar dating are approximately ~228 Ma implying that the D2 deformation occurred under retrograde amphibolite to greenschist facies metamorphic conditions during Middle Triassic. Collectively these data along with regional geological evidence signify two distinct intracontinental orogenic processes occurring in eastern SCB. Considering Early Mesozoic tectonothermal events in Cathaysia Block, it can be inferred that intraplate orogeny in Wuyishan resulted from plate‐margin collisions between SCB and peripheral plates following scissors closure of Palaeo‐Tethys from east to west.

Cambrian Furongian–Middle Ordovician conodonts in the northeastern margin of the South China Block (Chuzhou, Anhui province) and their paleogeographic implications

Cambrian Furongian–Middle Ordovician conodonts in the northeastern margin of the South China Block (Chuzhou, Anhui province) and their paleogeographic implications

Relationship between electrical conductivity, metallogeny, and lithospheric structure in south China

The South China Block (SCB) is located at the junction of the Pacific, Eurasian, and Indo-Australian plates. Their interaction led to large-scale multi-stage mineralization in the SCB during the Mesozoic. Several regional ore-concentration areas, such as the Middle-Lower Yangtze Metallogenic Belt (MLYMB), the Qinzhou-Hangzhou Metallogenic Belt (QHMB), the Wuyishan Metallogenic Belt (WYMB), and the Nanling Metallogenic Belt (NLMB) were formed during this process. However, the dominant mineral types of these metallogenic belts are different. To study the deep mechanisms of the different metallogenic types developed in the same tectonic background at almost the same period, the magnetotelluric sounding (MT) data from 691 sites located mainly within the eastern SCB are employed to obtain a regional lithospheric 3-D resistivity model.It could be concluded from the resistivity model that deep low-resistivity anomalies and mantle upwelling channels mainly controlled almost all the Mesozoic deposits. Large-scale low-resistivity bodies extend from the crust to the upper mantle beneath the MLYMB and the QHMB, interpreted as channels of mantle-derived magma and melts/fluids containing metallogenic elements upwelling. However, the MLYMB and the QHMB have different upper crustal ore-conducting and ore-controlling structures, thus forming porphyry copper and copper-bearing tungsten deposits. Small-scale low-resistivity anomalies are invading the high-resistivity crust in the NLMB. And remelting the upper crust, mixing, and intrusion of crust-source magma, enriching tungsten-tin elements near the NLMB. Larger-scale low-resistivity anomalies exist deep in the WYMB, remelting the lower crust and resulting in the formation of porphyry copper in it. Significantly, the upper-mantle low-resistivity anomalies beneath the eastern SCB show a spatial distribution that is gradually shallowing from south to north, probably indicating that the asthenospheric materials are upwelling from south to north, corresponding with the changing progressively of magma and metallogenic activities. We propose that the lithospheric delamination and asthenospheric upwelling caused by the far-field effects of the Paleo-Pacific Plate subduction are the sources of solid magmatic activities and related metallogeny.

Deep recycling of volatile elements in the mantle: Evidence from the heterogeneous B isotope in intra-plate basalts

Volatiles in the mantle are crucial for Earth’s geodynamic and geochemical evolution. Understanding the deep recycling of volatiles is key for grasping mantle chemical heterogeneity, plate tectonics, and long-term planetary evolution. While subduction transfers abundant volatile elements from the Earth’s surface into the mantle, the fate of hydrous portions within subducted slabs during intensive dehydration processes remains uncertain. Boron isotopes, only efficiently fractionating near the Earth’s surface, are valuable for tracing volatile recycling signals. In this study, we document a notably large variation in δ11B values (−14.3‰ to +8.2‰) in Cenozoic basalts from the South China Block. These basalts, associated with a high-velocity zone beneath East China, are suggested to originate from the mantle transition zone. While the majority exhibit δ11B values (−10‰ to −5‰) resembling the normal mantle, their enriched Sr-Nd-Pb isotope compositions and fluid-mobile elements imply hydrous components in their source, including altered oceanic crust and sediments. The normal δ11B values are attributed to the dehydration processes. Remarkably high δ11B values in the basalts indicate the presence of subducted serpentinites in their mantle source. A small subset of samples with low δ11B values and radiogenic isotope enrichments suggests a contribution from recycled detrital sediments, though retaining minimal volatile elements after extensive dehydration. These findings provide compelling evidence that serpentinites within subducted slabs predominantly maintain their hydrous nature during dehydration processes in subduction zones. They may transport a considerable amount of water into deep mantle reservoirs, such as the mantle transition zone.

Lithium-Rich Deposits in the Liangshan Formation during the Permian in the Upper Yangtze Plate, China

With the increasing demand for lithium (Li) resources in industry, there has been new attention on clay-type lithium-rich deposits recently. In this study, a Li-rich clay deposit with a Li2O content up to 0.3% in the Liangshan Formation in the upper Yangtze, South China Block was demonstrated. We analysed the mineralogy and element geochemistry of the samples from the Liangshan Formation and its underlying and overlying layers. Kaolinite (average 53%, up to 93%) was the major mineral in the samples from the Liangshan Formation. The Li concentrations increased with increasing kaolinite compositions and Al2O3 concentrations. Furthermore, based on the geochemical indicators, it was suggested that the clay formation and Li enrichment were related to the weathering processes of the bottom impure limestone under the hot and wet climate, and the sedimentary processes in the anoxic, still, and flat land–sea interaction area in the Upper Yangtze. The Li was probably sourced from the bottom impure limestone during the weathering stage. The samples from the Liangshan Formation also showed REE enrichment from 117 to 729 μg/g.

Dual-mineralization in the intracontinental Jiangnan Orogen, South China: Evidence from textures and in-situ trace elements and oxygen analysis of quartz from the Woxi Au-Sb-W deposit

The Jiangnan Orogenic Belt (JOB), situated in the interior of the South China Block (SCB), harbors numerous gold-polymetallic deposits, but the ore genesis has been a long-standing controversy. This study examines the Woxi super-large gold deposit in the middle JOB, which is characterized by simultaneous large-scale antimony-tungsten mineralization. The investigation shows that the Woxi ore deposit have developed multiple-stage quartz, i.e., Qz1 (early quartz-carbonate, stage I), Qz2 (quartz-wolframite-scheelite, stage II), Qz3a (quartz-gold-pyrite, early stage III), Qz3b (quartz-stibnite-scheelite, late stage III) and Qz4 (late quartz-carbonate, stage IV). We conducted SEM-CL texture imaging, LA-ICP-MS trace element, and SIMS oxygen isotope analysis on the quartz samples from the main mineralization stages (mainly Qz2 and Qz3). The results reveal a dual mineralization process of the Woxi gold-antimony-tungsten deposit. In the initial stage, the quartz (Qz2) exhibits intense brightness in CL imaging and spiderweb-like texture, shows high concentrations of trace elements, especially Ge, Al and Ti, and has δ18Ofluid values ranging from 10.84 ‰ to 11.64 ‰. These characters are consistent with a magmatic fluid that is acidic (pH<3), reducing, and of relatively high-temperature. In the second stage, the quartz (including Qz3a, Qz3b and Qz4) shows relatively darker CL image and band texture or cobweb mosaic coexistence texture, low concentrations of trace elements, especially Al and Ti, and a low δ18Ofluid values (8.01 ‰ to 9.19 ‰ for Qz3a and 5.83 ‰ to 6.51 ‰ for Qz3b) consistent with characteristics of mantle-derived fluids. The results of this study supports an “intracontinental reactivation metallogenic model”, in which the gold-polymetallic deposits in the JOB formed from a dual-stage mineralization related to tectono-magmatic activities in a back-arc setting. The dual ore-forming processes revealed in this study provide important insights for a comprehensive understanding of the gold-polymetallic deposits in the JOB, and it may be a significant mechanism in the formation of large to super-large gold-polymetallic deposits in this region, which is indicative perspective for exploration of the gold-polymetal deposits. Our work also demonstrates that quartz is an effective tool for identifying the mineralization in the JOB.

Spatial−temporal variations in Mesozoic crustal thickness along the northeast Asian continental margin: Response to the subduction history of the Paleo-Pacific Plate

The initial timing and history of subduction of the Paleo-Pacific Plate beneath Eurasia are controversial. The crustal thickness variations at a convergent margin typically reflect the convergent process between the two plates. This study used a recently proposed machine-learning model to estimate the crustal thickness variations along the northeast Asian continental margin during the Mesozoic. The northeast Asian continental margin, particularly the eastern North China Craton, had its thickest crust during the Early Triassic and underwent crustal thinning during the Middle−Late Triassic. The former reflects the subduction and collision between the South China Block and North China Craton, and the latter occurred in a post-orogenic extensional setting. From the Early to Middle Jurassic, sustained crustal thickening occurred along the northeast Asian continental margin, which coincided with initial subduction of the Paleo-Pacific Plate beneath Eurasia. From the Early to Late Cretaceous, the northeast Asian continental margin generally underwent crustal thinning, but crustal thickening events occurred at 130 Ma, 110 Ma, and 90 Ma, which is consistent with rollback of the subducted Paleo-Pacific Plate beneath Eurasia. The relationship between crustal thickness and mineralization suggests that thicker crust favored the formation of porphyry-type Cu-Mo deposits, whereas thinner crust in an extensional setting favored the formation of epithermal Au deposits related to magmatism.

Integrating soil geochemistry and machine learning for enhanced mineral exploration at the dayu gold deposit, south China block

Combining traditional geochemical methods with advanced analytical techniques is a hallmark of contemporary exploration efforts. This study explores the intricate geological dynamics of the Dayu gold deposit, located in the Dayao Uplift of the South China Block. Using a multidisciplinary approach that includes soil geochemistry, conventional geochemical methods and advanced computational techniques such as machine learning and Discriminant Projection Analysis (DPA), we aim to uncover the deposit formation information. Our results reveal a complex pattern of element anomalies, which serve as a geochemical fingerprint of the Au mineralization processes that shaped the deposit over geological time. Principal Component Analysis (PCA) and cluster analysis on soil samples highlight significant correlation among Au and its pathfinder elements. By leveraging the predictive capabilities of machine learning algorithms, particularly Convolutional Neural Networks (CNN), we improve exploration strategies, enhance the precision of target delineation and guide sampling efforts. DPA further identifies distinct discriminant functions, aiding in group differentiation and providing insights into prospective mineralization zones. This study exemplifies the integration of traditional and innovative methodologies, offering a pathway to a deeper understanding of mineralization processes and improving the effectiveness of exploration in complex geological terrains. The findings advance our knowledge of the Dayu gold deposit and demonstrate the potential of these integrated approaches in similar geological settings.

Tracing provenance of phosphorite in the Shifang phosphorite deposit: Insights from the genesis of detrital zircon

Phosphorites (P2O5 content > 18 wt%) are widespread in the world; however, high-quality phosphorite (P2O5 content > 30 wt%) is exceptionally rare. In South China, the Devonian Shifang phosphorite deposit represents not only a high-quality phosphorus ore resource but also hosts abundant rare earth elements (up to 3677.6 ppm). Despite its significance, the provenance of this unique phosphorite deposit has remained unclear. In this study, we conducted U-Pb dating, Hf isotope, and trace element concentrations analysis of detrital zircon from the phosphorite in the Shifang phosphorite deposit to well constrain the specific provenance and potential material source of the phosphorite. Cathodoluminescence (CL) images and trace elements analysis of zircons suggested that the majority of zircons have a magmatic origin. The U-Pb dating age of these zircons revealed three main age peaks at ∼ 560–520 Ma, ∼850–750 Ma and ∼ 1050–950 Ma. A comparison of the εHf values of zircons for the same age group worldwide revealed the following: (1) The 1050 ∼ 950 Ma detrital zircon in the Shifang phosphorite deposit could be derived from North India; (2) The 850–750 Ma zircons originated from Tonian granites in the western South China Block; (3) The 560–520 Ma zircons had two sources, one could be the Kuungan orogeny in the east-Gondwana, and another could be the Arabian-Nubian Shield in the northern-west-Gondwana. In addition, our new age histograms of detrital zircon U-Pb ages are well consistent with underlying strata, such as Silurian and early-middle Devonian. Combining these findings with the geological activities in the study area, we conclude that zircons in the Shifang phosphorite deposit may directly originate from the underlying strata in the study area and the Cambrian Qingping phosphorite deposit may have served as an essential phosphorus source for the Shifang phosphorite deposit.

Transpression in the Eastern Jiangnan Orogen and its implications for ductile deformation process and regional Tectonics of the South China block

The transpressive deformation in the eastern Jiangnan Orogen during the Early Paleozoic is the structural response to the oblique convergence of the Yangtze-Cathaysia blocks, and this relationship is critical for understanding the tectonics of South China. The Jiangwan–Huangshan shear zone (JHSZ) and Baiji–Sanyang shear zone (BSSZ) exhibit NEE–SSW-trending oblique dextral and sinistral shearing, respectively, and their evolution resulted in local E–W dextral strike-slip shearing. Most kinematic vorticity values range from 0.4 to 0.81, which implies that the JHSZ and BSSZ deformed under the contribution of both pure-shear and simple-shear components, suggesting complicated deformation histories for those orogenic shear zones. The quartz and feldspar deformation mechanisms, opening angles and lattice preferred orientation (LPO) patterns of the quartz c-axis fabrics suggest shear deformation temperatures between 400 and 550 °C in the eastern Jiangnan Orogen. Locally deformation occurred under high-temperature (>600 °C) conditions. Combined with previous data and regional geology, these findings indicate that the shearing deformation in the eastern Jiangnan Orogen accommodated the oblique convergence between the Yangtze and Cathaysia blocks during the Early Paleozoic, which was possibly caused by the final assembly of Gondwana.

Late Cretaceous cooling and pulsed cenozoic uplift in the Fenghuang Shan: Insights into the tectonic evolution of the Qinling Orogen, central China

Reactivation of the Qinling Orogen since the Late Jurassic has been controlled by the combined effects of the convergence between the South and North China blocks, the subduction of the Pacific Plate, and the northeastward expansion of the Tibetan Plateau. In this study, we present new apatite (U–Th)/He ages from a vertical transect in the Fenghuang Shan located in the North Daba Mountains, where rapid cooling at ∼95-90 Ma is identified. Inverse thermal history modeling results reveal another pulse of accelerated exhumation at ∼50 Ma. In addition, we analyzed longitudinal profiles of rivers draining the northern flank of the Fenghuang Shan and identified knickpoints that break channels into gentle upstream and steep downstream segments. We deduce that these knickpoints were initiated by an increase in the mountain-bounding fault throw, based on nearly constant chi values (an integral to the upstream drainage area distribution) and a reliance of knickpoints’ retreat distances on catchment areas. Assuming a linear slope exponent and erodibility of 10−6 m0.1/a, we estimated knickpoint ages to be ∼5.7 ± 1.7 Ma. We interpret the Late Cretaceous cooling as a result of lithospheric extensional collapse following the Late Jurassic intra-continental compression between the North and South China blocks. The early Cenozoic exhumation might relate to the active normal faulting, as a far-field response to the west Pacific back-arc extension. The expansion of the NE Tibetan Plateau may have triggered the late Miocene uplift of the mountain range. The multiple episodes of tectonic events in the Fenghuang Shan might correspond to various geodynamic regimes on the tectonic evolution in the Qinling Orogen.

Late Jurassic granitoids in Mufushan complex and their significance for the Mesozoic tectonic evolution of eastern South China

The Mesozoic tectono-thermal evolution of eastern South China plays an important role in forming the abundant magmatic rocks and associated giant polymetallic deposits. The middle-late Mesozoic granitoids in Mufushan and adjacent regions (e.g., Lianyunshan, Wangxiang, Taohuahsan, etc.) represent the western front of the southeast China magmatic province. However, the tectonic regimes and petrogenesis of the magmatic rocks are still elusive. Here, we report zircon UPb ages, geochemistry, and Sr-Nd-Hf-Pb isotopic data for the granitic rocks in the Mufushan region, in combination with data available from the literatures, to discriminate the middle-late Mesozoic tectono–magmatic history of the Mufushan complex in north-central South China Block. New zircon UPb dating suggests that the Mufushan two-mica monzogranites were emplaced at 149–144 Ma, a short time after the 153–151 Ma granodiorites. These late Jurassic felsic magmas share broad similarities in geochemical-isotopic characteristics, with significant enrichment in LREEs and LILEs (e.g., Ba, Rb, Th, and K), depletion in some HFSEs (e.g., Nb, Ta, Ti, and P) and positive Pb anomalies, similar to those of arc-type rocks. The common existence of Neoproterozoic zircons within the magmatic rocks indicates a certain amount of ancient material involved in the genesis of the magma. The two-mica monzogranites have εHf(t) values ranging from −13.4 to +3.5, overlapping with those of the granodiorites (−11.3 to +6.6), but both are lower than contemporaneous diorites (−2.4 to +0.59), suggesting a greater incorporation of enriched materials into the source for the granitoids. The two-mica monzogranites and granodiorites have εNd(t) values ranging from −7.9 to −8.8 and − 10 to −7.9, with corresponding two-stage Nd model ages of 1.7–1.6 Ga and 1.6 Ga, respectively, falling within their two-stage Hf model ages of 2.0–1.4 Ga and 1.8–1.4 Ga, respectively. Compared with the geochemical and isotopic compositions of the coeval magmatic rocks in eastern South China, we favor that the late Jurassic Mufushan granodiorites evolved from variable mixing and differentiation of the diorites and granitoids, accompanied by a continuous magma assimilation. The presence of late Jurassic highly fractionated granites suggests an extensive magma differentiation in eastern South China and the well-developed early Cretaceous A-type granites in eastern South China reflect a dominant extensional tectonic regime induced by slab roll-back of the Izanagi plate. The involvement of subduction-related melts facilitated the underplating of mantle-derived magma and crustal heating, triggering intensive partial melting of the lithosphere and magma enrichment, as well as the polymetallic deposits in eastern South China.

Reassessing early to mid-Neoproterozoic (∼885–720 Ma) tectonic evolution of the southwestern Jiangnan Orogen: A detrital zircon perspective

The Neoproterozoic Jiangnan Orogen (JNO) marks the consolidation of the South China Block, sparking ongoing debates on its early to mid-Neoproterozoic tectonic evolution. In this study, we have gathered detrital zircon data from the southwestern JNO, presenting new detrital zircon U-Pb ages alongside trace element data from the mid-Neoproterozoic Banxi Group and Sinian System within this region. Our objective is to illuminate the early to mid-Neoproterozoic tectonic evolution within the southwestern JNO through a comprehensive detrital zircon analysis. The obtained dating results derived from detrital zircons reveal maximum depositional ages of ∼733 Ma and ∼713 Ma for Mobin Formation (Banxi Group) and Jiangkou Formation (Sinian System) sedimentary rocks, suggesting a proximal source, possibly originating from magmatic rocks within the southwestern JNO. Within the paleo-geographic context, it is plausible that these samples were deposited within the deep-water expanse of the Nanhua Rift Basin. Trace element analysis of detrital zircons within the southwestern JNO highlights distinctive fluctuations, delineating three crucial time points (∼885 Ma, ∼835 Ma, and ∼810 Ma): the beginning of early Neoproterozoic subduction of the South China Ocean towards the Yangtze Block beneath the southwestern JNO, the subduction slab rollback, and the Nanhua rifting initiation. The discernible shifts in detrital zircon age distributions within these sedimentary rocks serve as robust validation for the proposed model and crustal reworking. We then propose that the southwestern JNO was in a lull of magmatism before ∼885 Ma, then transitioned to a convergent setting around 885–835 Ma, subsequently subduction slab rollback after ∼835 Ma. The time of final assembly of the Yangtze and Cathaysia blocks in the southwestern JNO is no later than ∼810 Ma. This transformative period (∼810–720 Ma) witnessed the development of a rift basin concurrently with the accumulation of deep-water deposits within the southwestern JNO.

Implications of Late Triassic–Middle Jurassic detrital zircons from the southeastern margin of the South China Block for the Paleo-Pacific Plate subduction

There existed an early Mesozoic tectonic regime transformation in the South China Block (SCB). Although it was believed that this transformation was closely related to the subduction of Paleo-Pacific Plate, the process and initial time of the subduction of the Paleo-Pacific Plate have been controversial for a long time. Based on the published Upper Triassic and Middle Jurassic succession detrital zircons geochronology from the southeastern margin of the SCB, the newly obtained Late Triassic to Middle Jurassic detrital zircons Hf isotope data, and the available magmatic age data and Hf isotope data, this study discussed the subduction of the Paleo-Pacific Plate. The Hf isotope composition of zircon grains selected from the Early Mesozoic strata of the SCB, spanning from the Late Triassic to the Middle Jurassic, exhibits a consistent temporal trend with that of the Triassic–Middle Jurassic magmatic rocks. Both display a transition from negative to positive εHf(t) values, indicative of a gradually increasing contribution of mantle-derived materials from the Triassic to the Middle Jurassic. Zircon trace elements indicate that a magmatic arc appeared outside the southeastern margin of the SCB at 200–190 Ma and continued to develop into the Middle Jurassic, which may have been generated by the Paleo-Pacific Plate subduction. This study proposed that the Paleo-Pacific Plate subduction was confined to the southeastern coast of the SCB in the Late Triassic, and the subduction of the flat slab was halted by obstruction at the end of the Late Triassic. In the Early Jurassic, the Paleo-Pacific Plate began to subduction again, and arc-related magmatic rocks were formed along the coast of SCB. At the same time, due to the remote effect of the subduction of the Paleo-Pacific Plate, the weak tectonic belt existing in the Nanling area was reactivated, resulting in the Nanling area in the intraplate extensional setting. Subsequently, the continuous subduction of the Paleo-Pacific Plate led to the thickening of the crust along the SCB in the Middle Jurassic, and the Nanling area was still under in the extensional setting.

Two stages of gold mineralization in the Hebaoshan deposit: Evidence from the U-Pb dating and trace element geochemistry of rutile, monazite and apatite

The Hebaoshan gold deposit (41.5 t Au @ 3.5 g/t) is located in the southeastern region of the South China Block, central part of the Wuyishan metallogenic belt. The ore-hosting rocks in this area are predominantly Precambrian metasedimentary rocks and Caledonian granitic rocks. Two hydrothermal mineralization stages can be distinguished: a quartz-sericite-pyrite-native gold (stage I) and a chlorite-quartz-sericite-chalcopyrite-electrum (stage II), with hydrothermal monazite and rutile are firstly identified in separate stages. The complex geological history of the region has resulted in ongoing debates regarding the age of gold mineralization and the genesis of the major gold deposits in this area. In order to precisely constrain the mineralization age of the deposit and further establish a genetic model for the ore deposit, LA-ICP-MS U-Pb dating and trace element analysis on accessory minerals were conducted. Based on the textures mineral assemblages, and geochemical features of the accessory minerals, magmatic apatite, hydrothermal rutile, and both magmatic and hydrothermal monazite were identified. The U-Pb ages of magmatic apatite and monazite are determined to be 445.3 ± 15.80, 441.3 ± 15.10 Ma and 446.57 ± 1.03 Ma, respectively, suggesting that these ages represent the emplacement ages of the Caledonian intrusive rocks. The ages of hydrothermal monazite and hydrothermal rutile are determined to be 238.46 ± 2.01 Ma (single-mineral analysis), 238.46 ± 2.01 Ma (in-suit analysis) and 179.54 ± 7.28 Ma, respectively, suggesting that represent two mineralization events during the Late Triassic to early Jurassic in the Hebaoshan area. These data provide new constraints on the mineralization process in the Hebaoshan deposit and excludes the link between gold mineralization and the intrusion of the Caledonian granites. Regionally, It is speculated that the two mineralization events at Hebaoshan are respectively associated with intracontinental orogenic movements between the Yangtze Block and Cathaysia Block, the flat-slab subduction of the Paleo-Pacific Plate (stage I), and the subsequent extensional tectonics related to the collision between the Yangtze Block and Cathaysia Block (stage II).Our study indicates that the timing of multiple episodic mineralization can be constrained by analysis of accessory minerals, which provides a geological basis for better genetic model for the deposit and provide geological evidence for unraveling the relationships between magmatic activities and mineralization events in the region.