Source Of Gold Research Articles

Utilising the 3D mineral system approach to identify the source of alluvial gold deposits in Ibala Town, Southwest Nigeria: an In-depth geological and geophysical exploration

ABSTRACT The Ibala gold field, discovered by artisanal miners in 2018, is located east of Ibala town in Osun State, southwest Nigeria. As older mines are depleted and abandoned, miners are now investigating the source of the deposits, believed to be auriferous quartz veins. This study uses the mineral system approach to trace the origin of the alluvial gold in the Ibala area. The research is conducted in three phases: first, a detailed analysis of the region’s structural patterns and rock distribution is undertaken to understand the area’s tectonic history. Next, a 3D conceptual model is created using an integrated geological and geophysical modeeling techinque to identify exploration targets and map the mineral system components. Finally, on-site verification is performed to validate the findings. The study reveals that the gold originates from auriferous shear zones characterized by high conductivity and chargeability geophysical signatures. These zones were formed by auriferous fluids released during the metamorphic devolatilization of deep volcanic rocks. As the fluids migrated through shear zones, they interacted with host rocks, precipitating gold alongside pyrite. When weathered, the gold-bearing material is transported via drainage channels, which miners now exploit. By using a mineral system approach, this research pinpoints the primary gold sources, supporting more efficient resource management and sustainable mining practices in the region.

Pyrite in-situ S–Fe isotope constraints on the ore-forming sources and mineralization processes of gold and polymetallic deposits in the Liaodong Peninsula, North China Craton

Plenty of gold and polymetallic deposits are widespread in the eastern part of the North China Craton. They are associated with mafic to felsic dikes and hosted by Precambrian basement or Mesozoic granitoids. However, the sources of gold and other metals in the ore-forming fluids remain controversial. Here we present in-situ S and Fe isotopes and trace element contents of pyrites from various gold and Pb–Zn–(Ag) deposits in the Liaodong Peninsula, China. Pyrites from quartz vein-type gold deposit hosted by Mesozoic granites in the Wulong deposit have relatively homogeneous magmatic-like S isotopes (δ34S values of 0.9 ‰ to 2.5 ‰) and Co/Ni ratios, indicating derivation of sulfur and, by inference, of ore fluids/materials most likely from Mesozoic magmas. In contrast, pyrites from gold and Pb–Zn–(Ag) deposits in the Qingchengzi orefield hosted by Precambrian basement have high and variable δ34S values (9.7 ‰ to 12.7 ‰ for the Wandigou altered rock-type gold deposit and 4.7 ‰ to 8.5 ‰ for the Xiquegou Pb–Zn deposit and the Zhenzigou Pb–Zn–Ag deposit), identical to those of host rocks, indicating the important contributions of gold and other metals from wall rocks to the ore deposits. Pyrites from the various deposits have variable δ56Fe values of 0.08 ‰ to 0.63 ‰ for the Pb–Zn–Ag deposit, –0.58 ‰ to 1.23 ‰ for the altered rock-type gold deposit, and –0.68 ‰ to 0.77 ‰ for the quartz vein-type gold deposit, indicating distinct mineralization processes. Rapid precipitation of pyrites (with negative δ56Fe values) in the alteration rock and subsequent deposition of pyrites (with positive δ56Fe values) from the residual fluids in an Fe-open hydrothermal system during intensive ore-forming fluid-wall rock interaction account for the Pb–Zn–Ag mineralization, while weak fluid-rock interaction and pyrites precipitation from a Fe-closed hydrothermal system contribute to gold mineralization. Our observations provide a robust S–Fe isotope evidence for the contribution of various sources and metallogenic processes for distinct gold and polymetallic deposits.

Age and Sources of Low-Sulfide Gold–Quartz Mineralization of the Karalon Ore Field, North Transbaikalia, Russia: Results of Isotopic–Geochemical (Rb–Sr and Pb–Pb) Studies

Age and Sources of Low-Sulfide Gold–Quartz Mineralization of the Karalon Ore Field, North Transbaikalia, Russia: Results of Isotopic–Geochemical (Rb–Sr and Pb–Pb) Studies

Mineralogy and Primary Sources of Gold in the Davenda-Klyuchevskiy Ore-Placer Cluster (Eastern Transbaikalia)

Mineralogy and Primary Sources of Gold in the Davenda-Klyuchevskiy Ore-Placer Cluster (Eastern Transbaikalia)

The Carboniferous Wuzunbulake orogenic gold deposit in South Tianshan Orogen (NW China): Sericite Rb[sbnd]Sr geochronology, pyrite geochemistry, and metallogeny

The Kumishi area is located in the eastern part of the South Tianshan Orogen, which hosts several gold deposits and has substantial gold discovery potential. The timing of gold mineralization at Kumishi, however, has been poorly constrained owing to the absence of suitable dating minerals. Hydrothermal activity at Wuzunbulake is divided into the pre-ore stage 1 pyrite-quartz, syn-ore stage 2 quartz(-sulfide) and post-ore stage 3 quartz-calcite alteration/mineralization. Three types of pyrite have been recognized, i.e., Py1 (stage 1), Py2 (stage 2), and PyWR (from wallrock). Our in-situ RbSr dating on stage 2 sericite yielded an isochron age of 351.0 ± 17.4 Ma, indicating Early Carboniferous gold mineralization. Py1 and Py2 have δ34SΣS = 8.28–15.97 ‰ (avg. 12.88 ‰) and 6.92–8.70 ‰ (avg. 7.67 ‰), respectively, indicating that the sulfur in Py1 was metamorphic fluid sourced, while that of Py2 may have a mixed metamorphic fluid and wallrock source (0.84–3.27 ‰; avg. 2.31 ‰). For Py1, its contents of Au, As, Ag, Bi, Co, Cu, Mn, Ni, Pb, Sb, Tl are the lowest. Py2 has significantly higher Au-As-Ag, slightly higher Co-Cu-Ni-Sb-Tl, but lower Bi-Mn-Pb contents than those in PyWR. Considering also the sulfur isotope features, we considered that Py1 was primarily originated from the initial ore-forming fluid, and Py2 was derived from both the ore fluid and PyWR, with the former being more important and represents the source of gold. Based on that Py2 was formed by metasomatism on the PyWR margin and the element spatial coupling characteristics shown in EPMA geochemical maps, we inferred that the Au enrichment and precipitation are associated with fluid-rock reactions. The initial ore fluid is likely featured by the enrichments in Au, As, Ag, Co, Cu, Ni, Sb, Tl, and depletions in Bi, Mn, and Pb. The Wuzunbulake is best classified as an orogenic gold deposit based on its tectonic background, wallrock alteration style, and the ore-fluid source and characteristics.

LA-ICP-MS Analyses of Sulfides from Gold-Bearing Zones at the Perron Deposit, Abitibi Belt, Canada: Implications for Gold Remobilization through Metamorphism from Volcanogenic Mineralizations to Orogenic Quartz–Carbonate Veins

The Perron deposit, located in the northern part of the Archean Abitibi belt, bears some of the highest gold-grade mineralization for orogenic-vein-type deposits worldwide (High-Grade Zone: HGZ). More than 13 gold-bearing zones with different sulfide assemblages, hydrothermal alterations, and gold grades have been recently outlined, and they range from volcanogenic to orogenic in origin. In addition, seven zones are hosted in a restricted volume of ~1 km3, which is called the Eastern Gold Zone. Pyrite, sphalerite, pyrrhotite, and chalcopyrite—each from a different gold-bearing zone—were analyzed with LA-ICP-MS to decipher their genetic links, mineralizing processes, and temperature of formation. The temperatures calculated with the sphalerite GGIMFis thermometer range from 348 to 398 °C. All gold-bearing zones recorded volcanogenic hydrothermal inputs at different intensities, manifested by pyrrhotite. Pyrite was late-metamorphic and related to the orogenic gold system induced by the contact metamorphism of amphibolite facies. The pyrrhotite grains had very homogeneous trace element signatures in all zones, which is a characteristic of metamorphic recrystallization, exhibiting a loss of mobile elements (Au, Te, Bi, Tl, Sn, W, In) but high concentrations of Ni, Co, and As. Conversely, the pyrite was systematically enriched with all elements depleted from pyrrhotite, bearing five specific signatures of element enrichments: W, Tl, Sn, In-Cd-Zn, and Bi-Te-Au. For gold-rich zones (e.g., the HGZ), gold was linked to the Bi-Te-Au signature of pyrite, with Bi enrichment occurring at up to 72,000 times the background level in Archean shale pyrite. It was concluded that gold was transported, at least in part, as Bi-Te melts in the previously documented non-aqueous orogenic fluids, hence accounting for the very-high-grade gold content of the HGZ. Genetically, the metamorphism of primary gold-bearing volcanogenic mineralizations was the main source of gold during the overprinting of amphibolite (600 °C) in a metamorphically induced orogenic mineralizing event. A strong volcanogenic pre-enrichment is considered the main factor accounting for the gold endowment of the Eastern Gold Zone.

Material characteristic of Vetvisty creek placer gold and prospects for atypical-source deposits in the middle course of the Selennyakh river (Momsky and Abyisky district, Yakutia)

Background. The lower-middle course of the Selennyakh River in the Momsky and Abyisky districts of the Republic of Sakha, Yakutia, is characterized by a wide distribution of alluvial gold placers. The absence of obvious potential primary sources of these placers raises the question of their identification. Aim. To identify sources of gold placers found in interfluve area of the Selennyakh and Indigirka rivers, as well as to assess the gold-bearing potential of this area.Materials and methods. The data on the studied area obtained in previous works was analyzed. Microprobe analysis (CSRF IGEM RAS) was used to study the composition of alluvial gold grains sampled during field works in the Vetvisty Creek, the right tributary of the Selennyakh River, conducted in 2020–2021. The mineral composition of heavy concentrate was also studied.Results. The source of the gold placer under study was established to be an intermediate reservoir, i.e., Neogene coarse sand and gravel. Possible paths of gold transit within the placer were revealed. Theoretically, this allows enriched layers in the sediments feeding the placer to be localized.Conclusion. In order to replenish the gold mineral base of the country, including in such hard-toreach regions as the Arctic zone of the Russian Federation, regional research projects should be resumed. In addition, new models should be developed for forecasting and prospecting of atypical placer deposits, with gold sources from Tertiary sediments filling large Cenozoic depressions in the western rim of the Yano-Indigirskaya lowland).

Iron isotope constraints on the genesis of giant Beiya Au-base metal deposits, Yunnan, Southwest China

The Beiya Au-base metal deposit in southwest China is characterised by a huge amount of iron associated with gold mineralization. The formation of the Beiya deposit is generally thought to be related to Tertiary potassic intrusion, as porphyry- and skarn-type mineralization are the two most important types of mineralization in the region. However, the lack of direct evidence to constrain the source of iron and gold as well as other metals makes it difficult to accurately conceptualise the ore genesis model. In this study, we report high-precision (0.03 ‰; 2sd) Fe isotope data on Fe-bearing minerals including magnetite, pyrite and chalcopyrite, and major igneous rocks exposed in the area, including monzogranite porphyry (MGP), mafic microgranular enclave (MME), lamprophyre and basalt. Magnetites have a wide range of δ Fe from 0.15 to 0.64 ‰, reflecting substantial isotopic fractionation at different mineralization stages. MMEs have heaviest Fe isotopic composition (0.35 ‰ to 0.88 ‰) compared to MGPs (0.19 ‰ to 0.48 ‰), lamprophyre (∼0.2 ‰) and basalt (∼0.0 ‰). A negative correlation between δ56Fe and TFe2O3 is found for both MPGs and MMEs, which indicates the leaching of iron by hydrothermal fluids mobilizes light Fe and leaves behind isotopically heavy Fe in the remaining source rock. Fe isotopic compositions of MPG and MME overlap with those of magnetite, both of which are proposed to be the source of Fe in magnetite. The basalt has δ56Fe value of 0 ± 0.03 ‰, similar to those of global basalts, suggesting a negligible contribution to the formation of iron ores. Therefore, we propose that magmas parental to the MGP and MME may be the main source of iron to form the Beiya deposit; post-magmatism hydrothermal activities play a key role in leaching the metals out and transporting them to the mineralization area.

Geochronological and sulfide geochemical evidence for gold mineralization related to post-collisional magmatism in the Wulonggou goldfield of the East Kunlun Orogen, northern Tibet

The relationships among magmatism, orogeny, and gold mineralization in lode gold deposits have been controversial for a long time. The East Kunlun Orogen in northern Tibet has experienced a complex Paleo-Tethyan tectono-magmatic evolution and hosts the largest Wulonggou lode gold deposits (>120 t). The Shuizhadonggou-Huanglonggou (SZDG-HLG) gold deposit is the largest in the Wulonggou goldfield and is an excellent candidate for solving the controversy through detailed field observations, magmatic and hydrothermal mineral in-situ U-Pb dating, and gold-bearing sulfide in-situ trace elements and sulfur-lead isotopes. Gold mineralization in the SZDG-HLG deposit includes sulfide disseminations and minor amounts of small quartz-sulfide veins in hydrothermal alteration assemblages along a ductile shear zone. Gold mineralization can be divided into four stages based on crosscutting relationships and associated alteration assemblages. U-Pb ages from magmatic zircon, hydrothermal rutile, and hydrothermal monazite support field relationships that gold mineralization was later than the ductile deformation but synchronous with the post-collisional porphyries. Gold mineralization evolved from high to low temperatures (560℃ to less than 300℃), accompanied by markedly decreased sulfur fugacities (–6.3 to –12.5) and oxygen fugacities (–20.7 to –40.5). The gradual increase of sulfur isotopes (δ34S) from stage 1 (–0.9 to 1.8 ‰ in Py1a) to stage 3 (up to 8 ‰) is ascribed to sulfide precipitation from a finite fluid reservoir, while the sharp decrease of δ34S values in stage 4 (down to –24 ‰) is caused by the fluid oxidation. The negative covariations of δ34S and Se/S values, positive correlations between Au and chalcophile elements (As, Sb, Te, and Bi) in most sulfides, and overlapping lead isotopes of sulfides and Late Triassic granodiorite-diorite confirm a post-collisional magmatic gold and sulfur source. This study demonstrates that lode gold deposits in Phanerozoic orogens having similar characteristics to their counterparts in Archean metamorphic terranes can be genetically related to post-collisional magmatism.

The sources and physical–chemical conditions of gold mineralization in the Qi189 porphyry deposit, Qiyugou gold orefield, Eastern Qinling

The Qiyugou gold orefield is situated in the Eastern Qinling. It is a magmatic hydrothermal system, which includes cryptoexplosive breccia-type, vein-type, and porphyry gold deposits. However, the gold sources and physical–chemical conditions of precipitation of the newly discovered porphyry gold deposit, the Qi189, have not yet been well studied. It also hinders the comprehensive understanding of magmatic–hydrothermal gold systems in the Qiyugou gold orefield. Thus, detailed field and microscopic observations, C–O–He–Ar isotopic analysis, in situ major/trace element analysis, and thermodynamic studies on the Qi189 porphyry gold deposit have been carried out in this study. This deposit has three hydrothermal stages: the (I) early quartz–K-feldspar–molybdenite–magnetite stage, (II) middle quartz–sericite–pyrite–Te–Bi-mineral stage, as well as (III) late calcite–quartz stage. The carbon and He–Ar isotopic compositions suggest deep-seated sources of ore-forming fluids with mantle component proportions of up to 37 %. Oxygen isotopic compositions indicate the gradual involvement of more meteoric water in ore-forming fluids during stages I–III. The meteoric water input and reduction in temperature and pressure in the early stage II increased oxygen fugacity and decreased the pH values of ore-forming fluids. Then, in hematite and sulfides formation during late stage II, the oxygen and sulfur fugacities of ore-forming fluids gradually decreased. Precipitation of native gold and Au-bearing telluride grains with quartz-sericite alteration in stage II is significant for Au enrichment, which occurred under acidic (pH = 3.64–5.71), low-logfO2 (<-34.86), low-logfS2 (−13.07 to −11.13) and low-logfTe2 (−15.55 to −10.32) conditions. Therefore, abundant mantle components and changes in the pH, logfO2, logfS2, and logfTe2 of the ore-forming fluids play important roles in gold enrichment. Combined with previous studies, this work also provides some new evidence for identifying a magmatic-hydrothermal gold system in this district, including similar sulfide trace elements, δ13CV-PDB compositions, and changes in logfO2 and logfS2 of various types of gold deposits in a gold orefield.

Deciphering sources of lode gold deposits in the South Tianshan, NW China: Insights from Pb isotope systematics

The Tianshan hosts numerous giant and world-class lode gold deposits, forming one of the world’s largest gold provinces. However, the sources of gold remain equivocal. Herein, we present a comprehensive Pb isotopic investigation of the Precambrian basement, Neoproterozoic mafic dykes, and the Lower Paleozoic sequences of the South Tianshan in NW China. These data were compared with existing Pb isotope datasets from major lode gold deposits and coeval granitoid and mantle-related rocks, to trace the sources of gold and constrain the relative contributions from potential reservoirs. Gold-bearing sulfides from major lode gold deposits have relatively uniform Pb isotopic ratios, which are significantly different from regional coeval granitoid and mantle-related rocks. Conversely, the Pb isotopic characteristics from gold-bearing sulfides are comparable to those from the Paleoproterozoic metasedimentary rocks, showing well-defined linear relations. Binary mixing modeling shows that the Paleoproterozoic metasedimentary rocks might have contributed 70% to 90% for the source of Pb and, by inference other metals. Integrating geochemical and isotopic features from major lode gold deposits in the region, we propose that it invokes fertilization of ancient Au archives during metamorphic volatilization in the deep crust during subduction of the South Tianshan Ocean. Following the final closure of the South Tianshan Ocean, the regional tectonic uplift and thermal effect during widespread granitoids emplacement associated with the amalgamation of the Tarim with Kazakhstan-Yili terranes, mobilizing the deep roots of the fertilized ancient Au reservoirs, leading to the formation of the gold deposit hosted in fault systems of the South Tianshan.

Timing and Evolution of Gold Mineralization in the Maljavr Occurrence (NW Russia), NE Part of the Fennoscandian Shield

Gold occurrence Maljavr is the first Archean conglomerate-hosted gold mineralization found in the Fennoscandian Shield. Gold-mineralized metasomatic rocks form a set of lenses within a 10 m thick linear zone, conformable to the bedding of host conglomerates. The lenses are up to 10 m long and up to 1 m thick and they clearly exhibit three alteration envelopes: the rock in the central part consists of garnet and quartz or garnet-only; biotite, garnet, and quartz make the intermediate biotite–garnet envelope; hornblende, hedenbergite, and quartz are the principal rock-forming minerals in the outer zone of the lenses. All metasomatic rocks contain sulfide mineralization up to 15–20 vol.% and up to 0.6 g/t Au. The main ore mineral is pyrrhotite, and the minor minerals are arsenopyrite, chalcopyrite, pentlandite, löllingite, and troilite. The age of zircon from biotite gneiss in the zone of alteration is 2664 ± 18 Ma, this is considered as the time of formation of lenses of metasomatic rocks. Biotite gneiss-conglomerate and metasomatic rocks were later intruded by tourmaline granite pegmatite 2508 ± 7 Ma. The injection of pegmatite caused re-crystallization of sulfides (mainly arsenopyrite and löllingite) and redistribution of gold. Visible gold in association with Bi minerals native bismuth, ehrigite, maldonite, bismuthinite, joseite-B, and hedleyite was found in inclusions in recrystallized arsenopyrite and löllingite. Au content in the rocks with recrystallized arsenopyrite and löllingite is &gt;1 g/t, up to 30 g/t in hand samples. The 2508 Ma pegmatite is interpreted as synchronous with formation of gold mineralization in its present form. The linkage of gold mineralization with pegmatite and geochemical association Au-As-Se-Te-Bi in the mineralized rocks agree with characteristics of intrusion-related gold deposits worldwide. Biotite gneiss–metaconglomerate, hosting the mineralized altered rocks, was the probable primary source of arsenic and gold for mineralization.

Morphostructural, Chemical and Genetic Features of Native Gold in Brown Coals from the Yerkovetsky Deposit, Far East Russia

We studied the morphostructural features and chemical composition of micron and submicron particles of native gold from brown coals and overcoal sediments of the Yerkovetsky deposit (Zeya-Bureya sedimentary basin, Far East Russia). The samples of coal and host rocks in the form of thin sections, as well as coal particles and grains of native gold obtained during the process of dispersion and the fractionation of loose and crushed samples divided according to size and density, were analyzed using scanning electron microscopy in combination with X-ray microanalysis, involving various visualization modes. It was revealed that native gold is syngenetic with the mineralization of brown coals, and microphases dispersed in the minerals of overcoal loose and sandy-clay sediments were the source of native gold. In coal, gold is accumulated at the stages of formation (alluvial and eolian, including terrigenous and ionogenic subtypes) and the diagenesis of coal deposits (ground-infiltration subtype). A significant part of the mineralization process of coals and the formation of microparticles of native gold was contributed to by the descending water infiltration of polycomponent colloid solutions. During the dehydration of hydroxysiliconized iron-based hydrogels, mineral phases have an unstable composition and floccular structure and contain submicron gold particles. The coatings of all gold microparticles have identical origin and composition. Coal beds that border host rocks are an open system with a constant inflow of the substance, which leads to the gradual formation of polycomponent aggregated particles in micro cavities. Part of the gold in coals occurs as sulfur-bearing complexes dissolved in pore water. The key factor in the migration and deposition of gold in coals is the inorganic substances involved in the processes of coal mineralization. Organic substances play a more passive role and have medium-forming, fractionating (colloid, molecular, and ionic sieves), and accumulation functions.

A Gold Needle Tip Array Ultrafast Electron Source with High Beam Quality.

Electron sources are crucial elements in diverse applications such as electron microscopes, synchrotrons, and free-electron lasers. Nanometer-sharp needle tips are electron emitters with the highest beam quality, yet for a single needle the current is limited. Combining the emission of multiple needles promises large current yields while preserving the individual emitters' favorable properties. We present an ultrafast electron source consisting of a lithographically fabricated array of sharp gold tips illuminated with 25 fs laser pulses. The source provides up to 2000 electrons per pulse for moderate laser peak intensities of 1011 W/cm2 and a narrow energy width of 0.5 ± 0.05 eV at low current. The electron beam has a well-behaved Gaussian profile and is highly collimated, yielding a small normalized emittance on the order of nm·rad. These properties are well suited for applications requiring both high current and spatial resolution, such as free-electron light sources and chip-based particle accelerators.

NOVEL APPROACH FOR ONE-POT SELF-ASSEMBLED MONOLAYER PREPARATION OF GOLD TIPPED CdSe/CdS NANORODS

In this study, CdSe/CdS nanorods (NRs) were synthesized via hot injection method to perform simultaneous self-assembly studies with gold tip formation on the nanorods. In this new approach, we propose and demonstrate reductant chemical and gold organosol-free synthesis of gold-tipped nanocrystals on the subphase. Instead of gold organosol usage, gold precursor was prepared by addition of gold source into subphase, and photocatalytic reduction of gold on the tip of nanorods was achieved by exciting the samples under UV-light excitation. Reduction of gold nanoparticles on the tip of NRs was also tried by heating effect, which results in nanopillar formation. The optical properties of these nanorods were determined by spectrophotometric measurements, and gold-tipped nanorods were imaged by TEM analysis. This method enables self-assembly of nanorods and following gold tip formation on the subphase, and it can pave the way to prepare well-defined metal-tipped oriented surfaces that can be used for optical and photocatalysis applications.

Gold source and deposition in the Sanakham gold deposit, SW Laos: Constrains from textures, trace element geochemistry and in-situ sulfur isotopes of pyrite

The Luang Prabang (Laos) – Loei (Thailand) metallogenetic belt is endowed with major porphyry-skarn, and epithermal gold deposits. The Sanakham gold deposit is a newly discovered hydrothermal vein-type orogenic gold deposits (10.6 t Au @ 3.05 g/t) in the belt, and consist of a series of quartz-sulfide veins that are controlled by secondary structures of the regional NNE-trending brittle-ductile shear zone. Its mineralization can be divided into four stages: (I) quartz–pyrite–arsenopyrite, (II) quartz–pyrite–pyrrhotite–chalcopyrite, (III) quartz–pyrite–base-metal sulfide, and (IV) quartz–carbonate. Three pyrite generations were identified: py1 (stage I) as disseminated euhedral to subhedral coarse grains; py2 (stage II) as subhedral to anhedral fine grains occur around the cataclastic and corrosion textures in py1; py3 (stage III) as subhedral to anhedral fine grains occurred in sulfide veins or veinlets that overprint the existing quartz-sulfides. All three generations of pyrite have low trace-element contents including very low lattice-bound gold (py1: 0.040 ppm; py2: 0.098 ppm; py3: 0.028 ppm) and arsenic (py1: 227 ppm; py2: 133 ppm; py3: 13.3 ppm) contents. Visible gold grains are sited in textures of pyrite grains that relate to brittle cataclastic deformation. Considering the relatively low contents of pyrite in the ores of Sanakham, it is impossible to derive the high-gold grade orebodies through local remobilization of originally lattice-bound gold in pyrite. The py2 might be formed during hydrothermal overprinting and dissolution of py1 led by continuous supply of ore fluids with relatively higher contents of Au, Ag, Cu, Sb, Te, Pb, and Bi. A reduction reaction related to reduced carbon species in wallrock is an assignable cause for gold deposition, even though the fluid-rock interaction and fluid immiscibility processes might be important. The Au- and As-poor pyrites have similar δ34S values (py1: –2.58 to –0.83 ‰; py2: –2.17 ‰ to + 0.25 ‰; py3: –1.24 to –0.60 ‰ ppm) that close to 0 ‰, indicating the sulfur may have been originated from magmatic or mantle sources. Therefore, we propose that the Sankham gold deposit is a member of the orogenic deposit class, but notably characterized by the low concentrations of invisible gold in the relatively As-poor pyrite lattice.

Features of the Tanalyk gold placer and its primary sources (the Baymak ore-placer cluster, Southern Urals)

The article presents the results of a study of the Tanalyk placer, which is part of the Baymak ore-placer cluster. It is shown that gold is predominantly bright yellow in color and has lump-shaped, wedge-shaped, plate-shaped and wire-rod-shaped forms. In terms of granulometric composition, it belongs to the large and medium class and is characterized mainly by medium roundness. The uniformity of morphological varieties of gold in different lithological and stratigraphic horizons indicates the inheritance of gold from ancient deposits to young ones.&#x0D; Placer gold is of high quality and has a fairly consistent composition; the main impurity here is silver, the content of which varies from 0.2 to 9%. The average fineness of gold in the placer in the following areas: Baymak pond – 938, Shurinsky log – 935, Aktash log – 943, Tanalyk (lines 1502-1559) – 917. Hypergene new formations on the surfaces of gold grains are represented by high-fineness rims. A common feature for gold of all size classes is the presence in the depressions and on their surface of films of iron and manganese hydroxides, crusts of fine-grained quartz, chlorite, and less commonly biotite, in which a large number of microparticles of very high-fine gold measuring 0.1–0.5 μm were found.&#x0D; The typomorphism of schlich gold, its composition and features of the internal structure indicate that the main source of gold was gold-quartz mineralization in the zones of wall-metasomatites of the Kul-Yurt-Tau gold-pyrite deposit, gold-polymetallic and gold-barite deposits Grafskoye, Troitsk and Novo-Troitsk. The junction points of diagonal neotectonically active lineaments with meridional magma- and ore-supplying faults form polychronic and polygenic through ore-concentrating structures. Dispersed gold occurrences in these structures are placer-forming and serve as the main source of the formation of large placers.

The ugly side of the Africa-UAE (United Arab Emirates) gold trade: Gold export misreporting and smuggling

United Arab Emirates (UAE) has become one of the major world's gold hubs and sources most of its gold from Africa. This paper examines the magnitude and patterns of gold export misreporting in the Africa-UAE gold trade. Africa-UAE gold trade is found to be characterized by overwhelming misreporting and smuggling. The most common practice is found to be gold export underreporting. To examine the drivers of gold export misreporting in the Africa-UAE gold trade, a dynamic panel data model was estimated. The estimation results indicate that export tax, the gold price, and institutional factors are the main drivers of gold export misreporting in the Africa-UAE gold trade. The drivers of pure gold smuggling are found to be the gold price and real exchange rate. The results indicate also that both gold export misreporting and smuggling exhibit some persistence behavior. The findings of this study point to improving African countries' institutions to reduce the extent of gold export misreporting in the Africa-UAE trade. Export tax rate can also be reduced to lower the incentives of gold export underreporting. African countries can also work towards harmonizing the regulatory frameworks concerning gold trade, to curb gold smuggling across African countries. UAE has a major role to play in deterring gold smuggling from Africa; export documents and proof of payment of export taxes from the exporting countries, should be required from those hand-carrying gold as they declare their gold to customs officers in Dubai.

Ti3AlC2 MAX Phase: A surprising candidate material for highly selective and efficient gold recovery from strong acid solutions

Given the scarcity of natural gold sources and associated mining challenges, the recovery of gold from secondary sources, such as electronic equipment waste (e-waste), becomes imperative. E-waste is typically treated with aqua regia to obtain highly acidic gold-containing solutions, which are subsequently processed by various methods to recover gold. Gold recovery materials offer numerous benefits but often exhibit insufficient selectivity, efficiency, and cost-effectiveness. To address this problem, we herein used a nonmodified pristine Ti-Al-C MAX phase (Ti3AlC2) to realize the one-pot room-temperature recovery of gold from highly acidic solutions (pH < 1) in the form of easily collectable bulky ball-shaped Au0 aggregates. High gold selectivity (Kd = 2.03 × 106 mL/g) and extraction efficiency (∼99 %) were observed even in the presence of interfering metal ions (Pd2+, Pt4+, Co2+, Ni2+, Cu2+, Zn2+), and the maximum gold extraction capacity (>6000 mg/g) surpassed that of previously reported gold recovery materials. The recovered gold was highly pure (>90 mass%) and contained minimal amounts of the original MAX phase, which obviated the need for intensive postpurification. The results of instrumental analyses suggested that gold recovery relied on electron transfer, similar to cementation, and primarily involved the reduction of solution-phase Au3+ to Au0via electron transfer from the Ti and Al of Ti3AlC2. Thus, our work demonstrates the significant potential of pristine Ti3AlC2 for the energy-efficient recovery of gold from highly acidic solutions and paves the way for the efficient valorization of e-waste.

Mineralogy, fluid regime and potential ore content of the post-accretion Ivdel gabbrodolerite-monzonite-granodiorite complex (Northern Urals)

Research subject. Hypabyssal intrusive bodies of a gabbro-dolerite-monzonite-granodiorite composition, common among the Devonian island-arc sequences of the East Tagil structural-formational zone in the Northern Urals. These bodies are dated as the Late Devonian-Early Carboniferous and attributed to the post-accretionary continuously differentiated Ivdel complex. Material and methods. The composition of rock-forming and accessory minerals of these intrusive bodies was studied using an SX-100 microanalyzer. This made it possible to obtain new data on the conditions of their formation, features of the fluid regime, and potential ore content. In addition, the geodynamic setting of this period was clarified, along with the composition, possible position of the primary mantle source, and the features of its fluid regime. Results. It was established that the mafic rocks (dolerites) in the Ivdel complex correspond to derivatives of the depleted mantle, with a primary source close to N-MORB basalts. The connection between the source and the separation of the slab and the “mantle window” located under the frontal zone of the former East Tagil island arc was substantiated. Such a position of the melting chamber determines the primary weak water saturation of dolerite magmas and their redox regime. According to mineralogical data, this feature is further manifested in the formation of the entire series of rocks of the Ivdel complex (with an increase in the iron index of clinopyroxenes and amphiboles, an increase in titanium contents in titanomagnetite, and other data). Further evolution of magmas (from dolerites to monzonites, quartz diorites, and granodiorites) occurred as they moved upward to the Earth’s surface and reflected the increasing contamination of differentiated melts by suprasubduction island-arc matter. Another important petrological feature of this complex is its formation with the participation of a chlorine-rich magmatogenic fluid. Depending on the composition of intruding melts, their contents of water, chlorine and oxygen activity, a number of autonomous degassing fluid-magmatic systems are formed. These systems are characterized by noticeable features in the processes of post-magmatic autometasomatosis, with the participation of an iron-chloride fluid. According to the regime of volatiles (halogens, water, and oxygen), the common affiliation of such autonomous fluid-magmatic systems to titanomagnetite ferrofacies (according to G.B. Fershtater), determines both their general metallogenic specialization and potential ore content. The removal of volatiles from such fluid-magmatic systems could be accompanied by extraction and transfer of chlorophyll ore elements from crystallizing melts to exocontacts of intrusive bodies. This, in the presence of migration zones favorable for fluids (faults, crushing zones, etc.) and geochemical barriers (especially in the presence of favorable enclosing sulfide-bearing island-arc strata), could have contributed to the formation of hydrothermal-metasomatic ore mineralization (Cu, Zn, Au, Mo and etc.). Such ore-bearing zones during erosion could be the primary source of gold for the known placers of this region. Large bodies of gabbrodolerites of the Ivdel complex may be promising for high-Ti magnetite-ilmenite mineralization.