Source Of Pb Research Articles

Discrimination of metal contaminant sources in river sediments influenced by mining and smelting activities using stable Pb and Zn isotopes.

To determine the sources and pathways of lead (Pb) and zinc (Zn) in river sediments contaminated with metals from mining and smelting activities, metal concentrations and Pb and Zn isotope ratios were measured in river water and sediment, and potential metal contaminant samples (imported Zn concentrates, smelting wastes, soils around the smelter, mine ores, and riverside tailings). Zn and cadmium (Cd) concentrations in river water and sediment samples were 30- and 11-25-fold higher, respectively, near the smelter than upstream, while a 6-fold increase in sediment Pb concentrations was detected over the same region. Sediment samples near the smelter (207Pb/206Pb = 0.8638 and 208Pb/206Pb = 2.0960) were observed to have a different Pb isotopic composition from upstream of the smelter (207Pb/206Pb = 0.8322 and 208Pb/206Pb = 2.0502), with δ66Zn values increasing from -0.01 to 0.82‰. Analysis of Pb and Zn isotopes and concentrations revealed that dust-contaminated soils were a major Pb source, and baseline sediments were found to be contaminated by regional mining tailings. For Zn in sediments, the main Zn sources were groundwater-derived Zn (δ66Zn = 1.02 ± 0.43‰, n = 4), dust-contaminated soils (δ66Zn = -0.18 ± 0.08‰, n = 3), and tailings-contaminated sediments (δ66Zn = 0.01 ± 0.07‰, n = 10). Endmember mixing model results showed that dust-contaminated soils contributed 78% and 64% of sediment Pb and Zn, respectively, within 2km of the Zn smelter, decreasing to negligible levels after 47.1km downstream. Downstream of the smelter, groundwater-derived Zn contributed 54% of sediment Zn, whereas tailings contaminated sediments contributed 70% and 25% of Pb and Zn, respectively.

ZIF-8@CsPbBr3 Nanocrystals Formed by Conversion of Pb to CsPbBr3 in Bimetallic MOFs for Enhanced Photocatalytic CO2 Reduction.

Perovskite nanocrystals are embedded into metal-organic frameworks (MOFs) to create composites with high light absorption coefficients, tunable electronic properties, high specific surface area, and metal atom tunability for enhanced photocatalytic carban dioxide (CO2) reduction. However, existing perovskite-MOF structures with a large particle size are achieved based on Pb source adsorption into the pores of MOFs, which can significantly break down the porous structure, thereby resulting in a decreased specific surface area and impacting CO2 adsorption. Herein, a novel perovskite-MOF structure based on the synthesis of bimetallic Pb-containing MOFs and post-processing to convert Pb to CsPbBr3 nanocrystals (NCs) is proposed. It is discovered that the additional Pb is not introduced by adsorption, but instead engages in coordination and generates Pb-N. The produced ZIF-8@CsPbBr3 NCs are ≈40nm and have an ultra-high specific surface area of 1325.08 m2g-1, and excellent photovoltaic characteristics, which are beneficial for photocatalytic CO2 reduction. The electronic conversion rate of composites is 450mol g-1h-1, which is more than three times that of pure perovskites. Additionally, the superior reduction capacity is sustained after undergoing four cycles. Density Functional Thoery (DFT) simulations are used to explore the 3D charge density at the ZIF-8@CsPbBr3 NCs interface to better understand the electrical structure.

Synthesis of TiO2–Fe/Fe3O4 photocatalyst using iron rusty waste as Fe source for removal Pb(II) in water media under visible light with good separable property

Synthesis of TiO2–Fe/Fe3O4 photocatalyst using iron rusty waste as Fe source for removal Pb(II) in water media under visible light with good separable property

Higher heavy metal contamination indoors than outdoors during COVID-19 in Mexico City

People spend most of their time indoors, especially during the coronavirus disease. Prolonged exposure to heavy metal-contaminated dust can be harmful to human health. The objectives of this study were to identify the contamination level in outdoor and indoor dust, compare contamination in both environments, and assess the human health risk. Two-hundred thirty-nine samples of dust were taken by Mexico City citizens in 38 homes on the weekends of May 2020. Heavy metal concentrations were measured through XRF. The contamination level was set using the contamination factor with a local and global background value, mixed linear models were used to identify indoor and outdoor differences, and USEPA human health risk methodology was used. Pb, Zn, and Cu had the highest contamination levels, followed by Sr and Mn, using both the local and global background values. The Pb, Zn, and Cu contamination was greater indoors, while higher Mn, Sr, and Fe were detected outdoors. According to the outdoor/indoor ratios, the main sources of Ca, Pb, Zn, and Cu must be indoors, while the main sources of Fe, Mn, Sr, Y, and Ti are outdoors. A human health risk was not detected, as the hazard index was lower than one. However, ailments can be developed due to exposure to Pb, Mn, and Fe in children (hazard index > 0.1). A higher risk due to Pb exposition was found indoors. Indoor environments in Mexico City were more contaminated by heavy metals and represented a higher risk to human health than outdoors during the pandemic isolation.

Concentration, seasonality, and sources of trace elements in atmospheric aerosols from Godavari in the southern Himalayas

Atmospheric pollution has detrimental effects on human health and ecosystems. The southern region of the Himalayas, undergoing rapid urbanization and intense human activities, faces poor air quality marked by high aerosol loadings. In this study, we conducted a two-year PM10 sampling in the suburban area (Godavari) of Kathmandu, a representative metropolis situated in the southern part of the central Himalayas. The trace elements were measured to depict aerosol-bound element loadings, seasonality, and potential sources. The mean concentrations of trace elements varied considerably, ranging from 0.27 ± 0.19 ng m−3 for Tl to 1252.78 ng m−3 for Zn. The average concentration of Co and Ni was 1.2 and 22.4 times higher, respectively, than those in Lhasa city in Tibet in the northern Himalayas. The concentration of Pb was 38 times lower than that in Lahore, Pakistan, and 9 times lower than urban sites in India. For the seasonality, the trace element concentrations displayed remarkable variation, with higher concentrations during the non-monsoon seasons and lower concentrations during the monsoon season. This trend was primarily influenced by anthropogenic activities such as low-grade fuel combustion in vehicles, coal combustion in brick kilns, and biomass burning, along with seasonal rainfall that induced aerosol washout. The enrichment factors (EFs) analysis revealed that Cd, Zn, Sb, Ni, Cu, Cr, and Pb had higher EFs, indicating their significant contributions from anthropogenic sources. In contrast, elements like Tl, Co, V, Cs, U, Ba, Th, and Sr, characterized by lower EFs, were mainly associated with natural sources. The Pb isotopic ratio profiles exhibited the Pb in PM10 are derived major contribution from legacy lead. Biomass burning contributed to the Pb source in winter. These findings provide policymakers with valuable insights to develop guidelines and strategies aimed at improving air quality and mitigating the impact of aerosol pollution on human health in the Himalayan region.

Accelerated export and transportation of heavy metals in watersheds under high geological backgrounds

The geological background level of metals plays a major role in mineral distribution and watershed diffuse heavy metal (HM) pollution. In this study, field research and a distributed hydrological model were used to analyze the distribution, sources, and pollution risk of watershed HMs in sediments with high geological HM backgrounds. Study showed that the mineral distribution and landcover promoted the transport differences of watershed HMs from upstream to the estuary. And the main sources of Co, Ni, and V in the estuarine sediments were natural sources. Sources of Pb and Zn were dominated by anthropogenic sources, accounting for 76% and 64% of their respective totals. The overall ecological risk of anthropogenically sourced HMs was dominated by Pb (46.6%), while the contributions of Co and Ni were also relatively high, accounting for 35.70% and 33.40%. Moreover, redundancy analysis showed that HM variations in the sediments were most sensitive to soil erosion and mineralizing rock distribution. The spatial patterns of watershed HMs from natural sources were significantly influenced by P loading, precipitation, and forest distribution. This combination of experiments and model improves the understanding of watershed HM variation and provides a new perspective for formulating effective watershed HM management strategies.

Effect of Community Water Service on Lead in Drinking Water in an Environmental Justice Community.

Multiple recent studies have found elevated lead (Pb) concentrations in tap water in U.S. homes relying on unregulated private wells. The main Pb source is dissolution from household plumbing, fixtures, and well components. Here, we leverage a natural experiment and citizen science approach to evaluate how extending community water service to an environmental justice community relying on private wells affects Pb in household water. We analyzed Pb in 260 first-draw kitchen tap water samples collected by individual homeowners over a 5-month period in residences that did and did not connect to the community system. Before the community water system was extended, 25% of homes had Pb > 15 μg/L (the U.S. regulatory action level for community water systems) in first-draw water samples. Pb was significantly correlated with nickel (ρ = 0.61), zinc (ρ = 0.50), and copper (ρ = 0.40), suggesting that corrosion of brass fittings and fixtures is the main Pb source. Among homes that connected to the community system, Pb decreased rapidly and was sustained at levels well below 15 μg/L over the study period. Overall, connecting to the municipal water supply was associated with a 92.5% decrease in first-draw tap water Pb.

Identification of anthropogenic source of Pb and Cd within two tropical seagrass species in South China: Insight from Pb and Cd isotopes

Seagrass beds are susceptible to deterioration and heavy metals represent a crucial impact factor. The accumulation of heavy metal in two tropical seagrass species were studied in South China in this study and multiple methods were used to identify the heavy metal sources. E. acoroides (Enhalus acoroides) and T. hemperichii (Thalassia hemperichii) belong to the genus of Enhalus and Thalassia in the Hydrocharitaceae family, respectively. Heavy metal concentrations in the two seagrasses followed the order of Cr > Zn > Cu > Ni > As > Pb > Co > Cd based on the whole plant, and their bioconcentration factors were 31.8 ± 29.3 (Cr), 5.7 ± 1.3 (Zn), 7.0 ± 3.8 (Cu), 3.0 ± 1.9 (Ni), 1.2 ± 0.3 (As), 1.7 ± 0.9 (Pb), 9.1 ± 11.1 (Co) and 2.8 ± 0.6 (Cd), indicating the intense enrichment in Co and Cr within the two seagrasses. The two seagrasses were prone to accumulate all the listed heavy metals (except for As in E. acoroides), especially Co (BCFs of 1124) and Cr (BCFs of 2689) in the aboveground parts, and the belowground parts of both seagrasses also accumulated most metals (BCFs of 27) excluding Co and Pb. The Pb isotopic ratios (mean 208Pb/204Pb, 207Pb/204Pb and 206Pb/204Pb values of 38.2054, 15.5000 and 18.3240, respectively) and Cd isotopic compositions (δ114/110Cd values ranging from –0.09‰ to 0.58‰) within seagrasses indicated the anthropogenic sources of Pb and Cd including coal combustion, traffic emissions and agricultural activities. This study described the absorption characteristics of E. acoroides and T. hemperichii to some heavy metals, and further demonstrated the successful utilization of Pb and Cd isotopes as discerning markers to trace anthropogenic origins of heavy metals (mainly Pb and Cd) in seagrasses. Pb and Cd isotopes can mutually verify and be helpful to understand more information in pollution sources and improve the reliability of conclusion deduced from concentrations or a single isotope.

Ecological and health risk assessment of heavy metals in agricultural soils from northern China.

Soil pollution by heavy metals can cause continuing damage to ecosystems and the human body. In this study, we collected nine fresh topsoil samples and 18 maize samples (including nine leaf samples and nine corn samples) from agricultural soils in the Baiyin mining areas. The results showed that the order of heavy metal concentrations (mg/kg) in agricultural soils was as follows: Zn (377.40) > Pb (125.06) > Cu (75.06) > Ni (28.29) > Cd (5.46) > Hg (0.37). Cd, Cu, Zn, and Pb exceeded the Chinese risk limit for agricultural soil pollution. The average the pollution load index (4.39) was greater than 3, indicating a heavy contamination level. The element that contributed the most to contamination and high ecological risk in soil was Cd. Principal component analysis (PCA) and Pearson's correlation analysis indicated that the sources of Ni, Cd, Cu, and Zn in the soil were primarily mixed, involving both industrial and agricultural activities, whereas the sources of Hg and Pb included both industrial and transportation activities. Adults and children are not likely to experience non-carcinogenic impacts from the soil in this region. Nonetheless, it was important to be aware of the elevated cancer risk presented by Cd, Pb, and especially Ni. The exceedance rates of Cd and Pb in corn were 66.67% and 33.3%, respectively. The results of this research provide data to improve soil protection, human health monitoring, and crop management in the Baiyin district.

Predictions of heavy metal concentrations by physiochemical water quality parameters in coastal areas of Yangtze river estuary

Due to the degradation-resistant and strong toxicity, heavy metals pose a serious threat to the safety of water environment and aquatic ecology. Rapid acquisition and prediction of heavy metal concentrations are of paramount importance for water resource management and environmental preservation. In this study, heavy metal concentrations (Cr, Ni, Cu, Pb, Zn, Cd) and physicochemical parameters of water quality including Temperature (Temp), pH, Oxygen redox potential (ORP), Dissolved oxygen (DO), Electrical conductivity (EC), Electrical resistivity (RES), Total dissolved solids (TDS), Salinity (SAL), Cyanobacteria (BGA-PE), and turbidity (NTU) were measured at seven stations in the Yangtze river estuary. Principal Component Analysis (PCA) and Spearman correlation analysis were employed to analyze the main factors and sources of heavy metals. Results of PCA revealed that the main sources of Cr, Ni, Zn, and Cd were steel industry wastewater, domestic and industrial sewage, whereas shipping and vessel emissions were typically considered sources of Pb and Cu. Spearman correlation analysis identified Temp, pH, ORP, EC, RES, TDS, and SAL as the key physicochemical parameters of water quality, exhibiting the strongest correlation with heavy metal concentrations in sediment and water samples. Based on these results, multiple linear regression as well as non-linear models (SVM and RF) were constructed for predicting heavy metal concentrations. The results showed that the results of the nonlinear model were more suitable for predicting the concentrations of most heavy metals than the linear model, with average R values of the SVM test set and RF test set being 0.83 and 0.90. The RF model showed better applicability for simulating the concentration of heavy metals along the Yangtze river estuary. It was demonstrated that non-linear research methods provided efficient and accurate predictions of heavy metal concentrations in a simple and rapid manner, thereby offering decision-making support for watershed managers.

Bioaccumulation and Potential Risk Assessment of Heavy Metals in Tropical Bamboo Plantations of Dendrocalamus brandisii under Two Cultivation Patterns in Yunnan, China

Heavy metal (HM) pollution nowadays is a hot issue concerning global ecological and food safety. As one of the most important woody bamboos for edible shoots in Southeast Asia and southwest China, Dendrocalamus brandisii usually occurs in red soil with a high HM geological background. However, the bioaccumulation process and possible risks of HMs in their cultivation area remain unclear. In this study, a comprehensive risk assessment of HM pollution was conducted in the main cultivation area of D. brandisii under two cultivation patterns in Yunnan, China. The results revealed that moderate to heavy HM pollution existed in the soil of the study area, while bamboo shoots displayed either no pollution or weak contamination. The “large-area intensive afforestation” cultivation pattern can better control HM pollution in soil and shoots than the “small-scale farmer management” pattern. Strong and complex correlations among HMs were unveiled in both soil and shoot samples. The Cr content of 39% of the shoot samples exceeded China’s national standards. Cu and Zn were the two most easily accumulated HMs in shoots, with BCF of 0.1235 and 0.1101, respectively. Bioaccumulations of As and Cd were positively correlated with their concentrations in soil. Furthermore, the positive matrix factorization model (PMF) identified three main sources of soil HMs, i.e., Pb and Zn from traffic emissions accounting for 30%; Ni, Mn, and Cr from pedogenic parent material making up 35.4%; and As from mining and metallurgical activities accounting for 34.6%. Monte Carlo simulations suggested the probability of total noncarcinogenic risk for children from bamboo shoots was 24.82% and that As in the soil was the primary element of health risk to children (HQc = 13.94%). These findings emphasize the urgent need to control and mitigate HM pollution from the identified sources and may contribute to the sustainable cultivation of D. brandisii and food safety in Yunnan and similar tropical areas with high HM contents.

A lingering legacy of leaded gasoline in Southeast Asia

Recent reports of 1 in 3 children globally having blood lead levels ≥ 5microgram decilitre−1 demands thorough understanding of lead (Pb) sources of the present century and the fate of legacy Pb from the past use of leaded gasoline. The present hotspot of pollution is South and Southeast Asia. To investigate this issue, here we compile Pb isotopic compositions of aerosols (n = 341) along with established and previously excluded sources for Singapore, Thailand, Vietnam, and India. The data was subjected to Bayesian 3D isotope mixing model simulation. Model estimates reveal consistent contributions from natural background. Leaded gasoline is the largest contributor in Southeast Asia (39%). Tertiary coal/fuelwood combustion and ore processing dominate in India, while ship emission contribute up to 15%. Thus, along with Pb from present sources, the historic use of leaded gasoline left a legacy of Pb in soil which is remobilised to the atmosphere after more than two decades of its phase-out.

Determining multiple fluid pulse and evolution using zoned garnet in Mengya’a skarn Pb-Zn-polymetallic deposit, Tibet

Skarn deposits, which serve as a significant source of Pb, Zn, Fe, W, Cu, and Au, are typically formed through interactions between fluids and carbonate rocks. However, the discovery of skarn deposits faces obstacles due to a limited understanding of the factors influencing their size. Many studies increasingly assume that the presence of large skarn deposits may be closely associated with multi-stage fluid pulses. Nonetheless, this assumption has not undergone explicit testing. In this study, zoned garnet grains from the large Mengya’a Pb-Zn-polymetallic deposits were used to unravel the multi-stage fluid pulse and evolution within a magmatic-hydrothermal system. In-situ major and trace elemental analysis reveals that the garnets exhibit two distinct zones, namely Ti-Al-enriched (G1) and Ti-Al-poor (G2) zones. The G1 domains are characterized by high HFSEs, slight enrichment in heavy rare earth elements (HREE), and minor variable Eu anomalies, as well as a linear relationship between REE and Y concentrations. These observations suggest that their formation reflects the fluid flux in a nearly closed system. The G2 domains exhibit oscillatory zoning in Al, Fe, Sn, HFSE, and various other elements, reflecting the intermittent flow of fluids originating from a degassing magma reservoir. The Al-, Zn-, and HFSE-rich characteristics of G2, along with their low δEu anomalies in comparison to G1, are associated with fluids that have undergone multiple recharge events from a magma chamber containing a significant amount of meteoric water in an open system. The presence of Sn-rich and In-rich zones within G2, accompanied by high δEu anomalies, indicates a gradual cooling and evolution of the pulsed fluids, resulting in the enrichment of Sn and volatile elements in the remaining fluid. Consequently, it can be concluded that the contribution of multiple fluid flows from a recharged magma chamber, undergoing extended cooling and evolution, plays a pivotal role in the formation of large skarn deposits. An additional implication of this study is that the zoning of Sn in garnet serves as a crucial indicator of Sn mineralization within skarn deposits.

Origin of Archean Pb isotope variability through open-system Paleoarchean crustal anatexis

Abstract Lead isotopic data imply that thorium and uranium were fractionated from one another in Earth’s early history; however, the origin of this fractionation is poorly understood. We report new in situ Pb isotope data from orthoclase in 144 granites sampled across the Archean Yilgarn craton (Western Australia) to characterize its Pb isotope variability and evolution. Granite Pb isotope compositions reveal three Pb sources, a mantle-derived Pb reservoir and two crustal Pb reservoirs, distinguished by their implied source 232Th/238U (κPb). High-κPb granites reflect sources with high 232Th/238U (~4.7) and are largely co-located with Eoarchean–Paleoarchean crust. The Pb isotope compositions of most granites, and those of volcanic-hosted massive sulfide (VHMS) and gold ores, define a mixing array between a mantle Pb source and a Th-rich Eoarchean–Paleoarchean source. Pb isotope modeling indicates that the high-κPb source rocks experienced Th/U fractionation at ca. 3.3 Ga. As Th/U fractionation in the Yilgarn craton must have occurred before Earth’s atmosphere was oxygenated, subaerial weathering cannot explain the apparent differences in their geochemical behavior. Instead, the high Th/U source reflects Eoarchean–Paleoarchean rocks that experienced prior high-temperature metamorphism, partial melting, and melt loss in the presence of a Th-sequestering mineral like monazite. Archean Pb isotope variability thus has its origins in open-system high-temperature metamorphic processes responsible for the differentiation and stabilization of Earth’s continental crust.

Spatial-temporal variation, source apportionment and risk assessment of lead in surface river sediments over ∼20 years of rapid industrialisation in the Pearl River Basin, China

Lead (Pb) is a highly toxic element and is not essential to the human body. Lead pollution caused by human activities and a high geological background is considered a global environmental issue. According to the China Geochemical Baseline (CGB) project, the Pearl River Basin had the highest Pb content in alluvial sediments of 30 first-level basins in China. For this reason, it is of great significance to determine the temporal and spatial variations in Pb and their influencing factors in the Pearl River Basin. In this study, 956 stream sediment samples collected in the 1980 s (early stage) and 129 river sediment samples collected from 2008 to 2010 (late stage) were used to study the background value and spatial-temporal variation characteristics of Pb in river sediments in the Pearl River Basin. The Pb source apportionment and an ecological risk assessment were also carried out. The background value of Pb (36.2 mg·kg–1) in the river sediments of the Pearl River Basin was significantly higher than that in China (22.1 mg·kg–1). The parent rocks determine the Pb background in sediments and the high Pb background areas mainly comprised carbonate rocks and acid volcanic rocks. Over 20 years of rapid industrialisation, the average Pb increased from 43.3 to 68.3 mg·kg–1 in the Pearl River Basin. The BCR analysis revealed that Pb mainly existed in the reducible phase (48 % on average) and residue phase (42 % on average). The enrichment factor and geo-accumulation index indicated that the late-stage sediments experienced more Pb pollution than the early-stage sediments. However, the risk assessment code (RAC) showed that there was a low ecological risk of Pb in the late-stage sediments. The factor analysis results for the two rounds of data were significantly different. The Pb content in early-stage sediments was closely related to Al2O3 and Zr, while Pb in the late-stage sediments was mainly related to Zn, As, Sb, Au and Hg, indicating that the increase in Pb in the later samples was mainly influenced by human activities. The Pb isotope composition of the late-stage sediments confirmed that low Pb content was mainly controlled by natural sources, while high Pb content was significantly affected by anthropogenic sources. Combining the results of spatial-temporal variation, chemical speciation and source apportionment indicated that the rapid rise of Pb in late-stage sediments in certain areas could be attributed to mining and smelting activities during the process of industrialisation over 20 years. The anthropogenic exogenous Pb could be immobilised by Fe-Mn (hydro)oxides when it entered the soil, so although there was a high background the ecological risk of Pb in river sediments was low. In the future, Pb pollution control and remediation needs to be strengthened in the Pearl River Basin to avoid the outbreak of potential ecological risks linked to Pb.

Status, Source, and Risk Assessment of Heavy Metal(Loid)s and Polycyclic Aromatic Hydrocarbons (PAHs) in the Street Dust of Ilam, Iran

A total of 25 Ilam street dust specimens were sampled to investigate the possible ecological and health risks of heavy metal(loid)s and polycyclic aromatic hydrocarbons (PAHs). We found that the average concentrations of heavy metal(loid)s, namely Pb, Zn, Cu, Cr, Cd, Ni, V, and As, were 52, 213, 63, 46, 0.4, 44, 31, and 5 mg/kg, respectively. The average concentration of all heavy metal(loid)s except for Cr and V was several times higher than the baseline values. We evaluated Zn and Pb in the region using the average enrichment factor (EF) and pollution index (PI); the Nemerow integrated pollution index (NIPI) indicated that 76% of the samples had high degrees of pollution. According to principal component analysis (PCA), three principle components are involved in the heavy metal(loid) pollution of Ilam street dust. For example, the pollution sources of Cu, Cr, Cd, and Ni likely originated from anthropogenetic origins, including traffic, tire depreciation, and gasoline use. The sources of Pb and Zn were other anthropogenic activities, such as metal corroding and the combustion of garbage and gases from industries, while V and As were probably from natural sources. The range of sum over 11 PAHs was 167–11,497 μg/kg with a mean of 2242 μg/kg. The concentration of low molecular weight (LMW) PAHs averaged 1471 μg/kg, accounting for 66% of the total PAHs; their sources were mainly associated with combustion and pyrogenic emissions. The PCA also revealed that PAHs mainly originated from burning fossil fuels. The values of RQ∑PAHs (MPCs) and RQ∑PAHs (NCs) were respectively >1 and ≥800, indicating a high ecosystem risk for PAHs. Mean values for RQ∑PAHs (MPCs) and RQ∑PAHs (NCs) were 4 and 1021, respectively, implying that Ilam street dust poses a relatively high ecosystem risk of PAHs. Street dust PAHs’ toxic equivalency quotient (TEQ) varied from 26 to 199 μg/kg. The total cancer risk was 3.92 × 10−4 and 4.06 × 10−4 for adults and children, respectively, indicating that the potential for cancer risk is very high through dust dermal contact and ingestion.

Will different land uses affect heavy metal pollution in soils of roadside trees? An empirical study from Shanghai.

Heavy metal pollution in roadside soil may harm humans, animals, plants, and local ecosystems. This study aimed to explore the sources and potential ecological risks of heavy metals in soils of roadside trees under different land uses, using soil samples collected from 136 roads across 16 administrative districts in Shanghai. The contents, pollution characteristics, potential ecological risks, and sources of seven heavy metals were analyzed, including Cr, Ni, Cd, Pb, As, Cu, and Zn. Results showed that (1) land use patterns affected the heavy metal contents, with industrial and construction areas showing higher contents while agricultural and forestry areas lower; (2) the ranking of heavy metal pollution levels was Cd > As > Pb > Cu > Ni > Cr > Zn. Cd exhibited the highest potential ecological risk, falling within the moderate to considerable potential ecological risk interval; (3) the sources of Cu, Zn, Cr, Ni, Cd, and Pb were associated with traffic emissions, whereas As had independent other sources and Pb in industrial and construction areas was also influenced by industrial emissions. These results provide valuable references on the control of heavy metal pollutants and the management of land uses in megacities.

Soil contamination, pollution indices, and ecological risk in agricultural areas of important mining region of Türkiye

ABSTRACT Heavy metals accumulate mostly in soil in nature, and heavy metal pollution is becoming a serious concern. This study aimed to determine the pollution level and possible sources of heavy metals in the agricultural areas in the Emet district of Kütahya, where a significant boron mine is located worldwide. 64 soil samples were taken from Emet district of Kütahya, Türkiye in 2016, and Cr, Co, Fe, Ni, Cu, Zn and Pb analysed. Heavy metal pollution was determined using the Enrichment Factor (Ef), Geoaccumulation Index (Igeo), Contamination Factor (Cf), and Ecological Risk Factor (Er), Pollution Load Index (PLI), and Potential Ecological Risk Index (RI). According to the pollution index Ef, the study area is moderately enriched in terms of Pb (4.18) and Zn (2.17), while in terms of Cf, the study area is moderately polluted in terms of Pb (2.13) and Zn (1.02). Moreover, the PLI (2.67) index shows that soils are under multiple heavy metal pollution. According to Pearson correlation analysis and principal component analysis, the source of Pb and Zn in the study area is anthropogenic. However, no heavy metal pollution caused by boron mine was found in the study area.

Metallogenic Model for Pb-Zn Deposits in Clastic Rocks of the Dahai Mining Area, Northeast Yunnan: Evidence from H-O-S-Sr-Pb Isotopes

The Dahai Pb-Zn mining area is located in the northwestern Pb-Zn district in northeastern Yunnan Province in the Sichuan-Yunnan-Guizhou Pb-Zn metallogenic triangle (SYGT), east of the Xiaojiang fault. Numerous Pb-Zn deposits (spots) occur in clastic rocks in this area. In this study, the Maliping, Laoyingqing, and Jinniuchang Pb-Zn deposits, representative clastic rocks in the Dahai mining area, were selected as research objects. The results of H-O-S-Sr-Pb isotope analyses show that the three deposits mainly formed through the mixing of a basinal brine with a hydrothermal fluid derived from deep within the underlying (deformed) basement, and brines leached organic matter from wall rocks. The δ34S values range from −2.62–30.30‰. The S isotope results show two different sources of reduced S: one in the Laoyingqing deposit derived from the S reduction generated by the pyrolysis of sulfur-bearing organic matter in the carbonaceous slate of the Kunyang Group, and the second in the Maliping and Jinniuchang deposits derived from the S reduction generated by the thermochemical sulfur reduction (TSR) of seawater sulfate in the Lower Cambrian Yuhucun Formation and Sinian Dengying Formation. The Pb isotope results show that the Pb sources of the three deposits are derived from basement rocks (Kunyang Group) with a small portion derived from Devonian–Permian carbonate rocks and Dengying Formation dolomite, both of which have undergone homogenization during mineralization. The Sr content varied from 0.09629 to 0.2523 × 10−6, and the study shows that the main source of Sr is a mixture of ore-forming fluid flowing through basement rocks (Kunyang Group) and through sedimentary cover. However, most of the Sr in the Maliping deposit is derived from marine carbonate, and in the Laoyingqing deposit, it is provided by basement rocks (Kunyang Group). Based on a comparative study of the deposits, the Pb-Zn deposits in the clastic rocks of the Dahai mining area and the SYGT belong to the same metallogenic system and were formed under the same metallogenic geological background. Finally, a unified metallogenic model of the two types of fluid migration and mixed mineralization of the Pb-Zn deposit in clastic rocks of the Dahai mining area is proposed. The metallogenic model provides a basis for the study of the Pb-Zn metallogenic system and guidance for deep and peripheral prospecting in this area.

Characterization of the Sedimentary Environment of the Shanxi Formation in the Southeastern Ordos Basin Revealed by Detrital Zircon and Geochemical Analyses

The interpretation of the sedimentary paleogeographic environment of the Lower Permian Shanxi Formation (P1s) coal strata in the southeastern Ordos Basin remains a subject of significant debate. In this paper, based on detrital zircon U–Pb source analysis, paleosalinity assessment, the sandstone modal composition, and other methods, we analyzed the P1s source system and constructed a model of the sedimentary evolution. The findings reveal that the primary source of the clastic materials in the study area stems from a mixed-source within the recycling orogenic belt. During the deposition period, the Shanxi Formation developed two predominant material source systems: one in the north, primarily linked to the Paleo-Yinshan Fold Orogenic Belt (YFOB), and the other in the south, originating from the North Qinling Orogenic Belt (NQinOB). These two major source systems converged in the Yichuan–Fuxian area. From the early stages of the Shanxi Formation period (Shan1), there was a regional retreat of the sea in the area. The seawater receded in a southeastward direction, leading to a gradual reduction in the paleosalinity and Sr/Ba-ratio variability during the Shan1 period. The influence of the seawater diminished, transitioning into a deltaic depositional system. This shift towards a terrestrial lakeshore basin reached its full development during the Lower Xiashihezi period. This study concludes that the Shanxi Formation in this area represents the evolution of a deltaic depositional system originating from a shallow sea shelf. This evolution can be divided into three major stages: remnants of the shallow sea shelf, barrier island–lagoon–littoral, and deltaic deposition. Within this framework, the shoreline underwent frequent lateral migration, influencing a broad range of characteristics. In the vertical direction, numerous alternating sets of sandstone bodies and mudstone, shale, and coal beds formed, creating a significant relationship between coal hydrocarbon sources and reservoirs. This study also establishes the stratigraphic-sequence framework of the basin for this period. These results hold great importance for the expansion of natural gas exploration and development efforts.