An electrical resistivity survey was conducted at different locations within Ayede Ekiti, Ekiti State, Southwestern Nigeria. This is aimed at evaluating groundwater potential zones and aquifer properties within the study area. Data were acquired at four (4) different locations using the vertical electrical sounding method by employing the Schlumberger array configuration. This study utilizes resistivity data processed with IPI2win software to analyze the subsurface geology of a basement complex region. The result of the study showed that qualitatively, three major curve types (A, HA, and H) were observed. Varying curve types, predominantly A curves, were observed across the research area, with notable groundwater potential indicated by H and HA curve types at select points. Through curve matching techniques, three to four distinct geo-electric layers were identified, while the quantitative interpretation resulted in deducing layers with different resistivity and thickness values for each VES(s) of the study area. It was deduced that the VES 2 and 3 zones are connected to a high output of groundwater. However, VES 1 and 4 are characterized by low groundwater potential. This research contributes valuable insights for geological mapping and groundwater resource assessment in complex basement terrains of the study area.