Solution Preparation Process Research Articles

The Effects of Polymer Solution Preparation and Injection on Drag Reduction

The understanding of drag reduction by injection of polymer solutions requires an adequate and accurate polymer solution preparation process as well as a thorough understanding of the effects that the delivery system might have on the polymer flow. Mass production of polymer solutions for engineering applications could be more cost effective if large batches of highly concentrated polymer solutions are prepared and then diluted to the final concentrations of interest. However, as shown in this study, depending on the type of polymer used this procedure might be more or less adequate. This study also corroborates that the presence of macro-molecular polymer structures induced by injecting highly concentrated polymer solutions into a shear flow translates into a drag increase and substantial degradation endurance especially at high Reynolds numbers in comparison to homogeneous polymer solutions.

Proton and carbon-13 NMR investigations of lead zirconate titanate (Pb(Zr,Ti)O3) thin-film precursor solutions

Solvent reactions, ligand substitutions, and the oligomer/polymer backbone structure are important factors in the solution preparation of ceramic films. In this study the authors have used H and C NMR spectroscopy to characterize solvent and ligand effects in precursor solutions used for the deposition of ferroelectric PZT (lead zirconate titanate) thin films. Solutions were prepared by a sequential precursor addition method from carboxylate and alkoxide precursors of the three cations, and the solvent, acetic acid, methanol, and water. The results indicate that acetic acid was a key component in the solution preparation process. As observed previously for single metallic component systems, its presence resulted in esterification reactions, leading in the present case to the formation of methyl, isopropyl, and n-butyl acetates. Second, acetic acid functioned as a chemical modifier, or chelating agent, replacing essentially all of the alkoxy ligands of the original precursors. Since alkoxy replacement appeared to be complete, we may describe the PZT species formed in solution as oxo acetate in nature. Finally, the solvent and ligand behavior of a solution prepared by an inverted mixing order was compared to the behavior of the solution prepared by a sequential precursor addition. The spectra for the two solutions weremore » similar, and only differences in the relative intensities of the ester and alcoholic resonances were observed. 29 refs., 5 figs., 3 tabs.« less

Optimization of the spinning solution preparation process in the manufacture of polyvinyl chloride fibre

The effect of spinning solution preparation parameters on the fibre preparation process and on the properties of polyvinyl chloride fibre have been studied using the experiment planning method.