Inelastic deformation of solids is almost always, if not always, associated with the evolution of discrete defects such as dislocations, vacancies, twins and shear transformation zones. The focus here is on discrete defects that can be modeled appropriately by continuum mechanics, but where the discreteness of the carriers of plastic deformation plays a significant role. The formulations are restricted to small deformation kinematics and the defects considered, dislocations and discrete shear transformation zones (STZs), are described by their linear elastic fields. In discrete defect plasticity both the stress–strain response and the partitioning between defect energy storage and defect dissipation are outcomes of an initial/boundary value problem solution. For such defects an explicit expression for the dissipation rate is presented and, because there is a length scale associated with the discrete defects, the stress–strain response and the evolution of the dissipation rate can be size dependent. Discrete dislocation plasticity modeling results are reviewed that illustrate the implications of defect dissipation evolution for friction, fracture, fatigue crack growth and thermal softening. Examples are also given of the consequences in constrained shear of three modes of the evolution of discrete defects for the size dependence of the stress–strain response and the associated dissipation. For a purely mechanical formulation the Clausius–Duhem inequality specializes to the requirement that the dissipation rate is non-negative. Requiring a non-negative dissipation rate for all points of a body and for all time imposes restrictions on kinetic relations for the evolution of discrete defects. In statistical mechanics, the Clausius–Duhem inequality can be violated for sufficiently small regions for a sufficiently short time. Explicit kinetic relations for discrete dislocation plasticity dissipation and for discrete STZ plasticity dissipation identify conditions that can lead to a negative dissipation rate. In continuum mechanics, at least in some circumstances, satisfaction of the Clausius–Duhem inequality can be regarded as a stability requirement. Nevertheless, simple one-dimensional continuum calculations illustrate that there can be a negative dissipation rate over a small region and for a short time period with overall stability maintained. Implications for discrete defect plasticity modeling are briefly discussed.
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