Reinforced concrete (RC) solid piers are unavoidably affected by air temperature changes and solar radiation during service life. Nevertheless, the deterioration of pier concrete with increased exposure age remains unclear. A novel thermal-mechanical numerical algorithm (finite element model) for characterizing the deterioration characteristics of RC structures under cyclic environmental loads has been suggested. The deterioration of RC pier concrete after 100 years of air temperature and solar radiation cycles is simulated. The numerical results demonstrate that tensile damage of pier concrete during air temperature and solar radiation cycles increases continuously with exposure age. After one year of exposure, the tensile damage value of pier surface concrete increased to 0.201 and further increased to 0.286 and 0.357 as the exposure age grew to 10 and 100 years. Pier concrete tensile damage can be mitigated by using surface short-wave absorption-reducing methods, controlling the thermal properties of concrete, and raising the concrete peak tensile strain. The proposed finite element framework and numerical solutions enable a viable simulation-based method for the analysis of bridge structural long-term deterioration behavior and design of the bridge engineering.