Solid-liquid Separation Research Articles

Removal of cesium and strontium ions with enhanced solid-liquid separation by combined ion exchange and BaSO4 co-precipitation

Treatment of cesium and strontium is critical in radioactive liquid waste management, where their ions are difficult to remove in single operations, owing to differences in valence state. Here, the efficacy of composite coagulants synthesised by combining fine clinoptilolite with co-precipitated barite (BaSO4) were investigated for the simultaneous removal of Cs+ and Sr2+ ions, producing aggregates with enhanced dewatering properties. Co-precipitated BaSO4 without clinoptilolite was found to be very effective in the removal of Sr2+ (>99 %) while only giving low-level Cs+ removal (~14 %) for solutions containing 25 ppm of Cs+ and Sr2. Conversely, pure clinoptilolite gave high Cs+ removal (>98 %) with rapid adsorption (<1 h) fitted to a Pseudo-Second Order (PSO) rate model. Composite coagulants were then produced using natural clinoptilolite combined with BaSO4 co-precipitation. Higher Sr2+ removal was obtained in all cases (>99.9 %), whereas Cs+ removal was reduced to <90 %, owing to exchange interactions with free Ba2+ ions. However, NaCl-preactivated clinoptilolite overcame low Cs+ removal efficiency, achieving >95 % removal. Their physical properties, sedimentation rates, and compressional yield stress were also studied to characterise the aggregates solid-liquid separation behaviour. The combined coagulates obtained settling rates almost twice that of pure BaSO4, and produced much greater consolidation, owing to increased aggregate density. Also, the combined systems had a higher gel point and lower specific compressive yield stress, suggesting less resistance to compression under centrifugal forces for dewatering. Overall, this study highlights that the use of composite coagulants can improve the removal efficiency of Cs+ and Sr2+ while also accelerating solid-liquid dewatering.

Adsorption Properties of Magnetic Phosphorous Camellia Oleifera Shells Biochar to Sulfamethoxazole in Water

Magnetic phosphorous biochar （MPBC） was prepared from Camellia oleifera shells using phosphoric acid activation and iron co-deposition. The materials were characterized and analyzed through scanning electron microscopy （SEM）， X-ray diffractometry （XRD）， specific surface area and pore size analysis （BET）， Fourier infrared spectroscopy （FT-IR）， and X-ray photoelectron spectroscopy （XPS）. MPBC had a high surface area （1 139.28 m2·g-1） and abundant surface functional groups， and it could achieve fast solid-liquid separation under the action of an external magnetic field. The adsorption behavior and influencing factors of sulfamethoxazole （SMX） in water were investigated. The adsorbent showed excellent adsorption properties for SMX under acidic and neutral conditions， and alkaline conditions and the presence of CO32- had obvious inhibition on adsorption. The adsorption process conformed to the quasi-second-order kinetics and Langmuir model. The adsorption rate was fast， and the maximum adsorption capacity reached 356.49 mg·g-1. The adsorption process was a spontaneous exothermic reaction， and low temperature was beneficial to the adsorption. The adsorption mechanism was mainly the chemisorption of pyrophosphate surface functional groups （C-O-P bond） between the SMX molecule and MPBC and also included hydrogen bonding， π-π electron donor-acceptor （π-πEDA） interaction， and a pore filling effect. The development of MPBC adsorbent provides an effective way for resource utilization of waste Camellia oleifera shells and treatment of sulfamethoxazole wastewater.

Microbial diversity in dairy manure environment under liquid-solid separation systems

ABSTRACT In dairy manure, a wide array of microorganisms, including many pathogens, survive and grow under suitable conditions. This microbial community offers a tremendous opportunity for studying animal health, the transport of microbes into the soil, air, and water, and consequential impacts on public health. The aim of this study was to assess the impacts of manure management practices on the microbial community of manure. The key novelty of this work is to identify the impacts of various stages of manure management on microbes living in dairy manure. In general, the majority of dairy farms in California use a flush system to manage dairy manure, which involves liquid-solid separations. To separate liquid and solid in manure, Multi-stage Alternate Dairy Effluent Management Systems (ADEMS) that use mechanical separation systems (MSS) or weeping wall separation systems (WWSS) are used. Thus, this study was conducted to understand how these manure management systems affect the microbial community. We studied the microbial communities in the WWSS and MSS separation systems, as well as in the four stages of the ADEMS. The 16S rRNA gene from the extracted genomic DNA of dairy manure was amplified using the NovoSeq Illumina next-generation sequencing platform. The sequencing data were used to perform the analysis of similarity (ANOSIM) and multi-response permutation procedure (MRRP) statistical tests, and the results showed that microbial communities among WWSS and MSS were significantly different (p < 0.05). These findings have significant practical implications for the design and implementation of manure management practices in dairy farms.

The Oil:Water Ratio in the Vertical Centrifuge Separator and Its Influence in Phenolic Compounds in the Virgin Olive Oil and the Olive Mill Wastewater (Alpechín)

The use of the vertical centrifuge in the olive oil production process is generally assumed to be habitual and necessary for the elimination of both the vegetation water and the small olive pulp particles that are not eliminated during solid–liquid separation (horizontal centrifugation). Trials were carried out with different oil:water ratios to study the influence of this variable on both the quality parameters of the olive oils obtained and the loss of oil with the olive wastewater. The trials were carried out at the industrial mill level with oil:water ratios between 0.6 and 5.5. While no differences were observed in the quality parameters of the oils obtained, correct adjustment of the oil:water flow rates reduced the loss of phenols present in the oils by around 30%. In addition, the results show a direct relationship between the soluble effluent and the conductivity of the olive mill wastewater (alpechín) with the loss of oil in the effluent. This work proves that both oil quality and the competitiveness of the olive oil value chain can be increased with energy savings, water consumption reduction, and environmental sustainability.

Estimating methane emissions from swine waste treatment lagoons and the reduction through solid-liquid separation: A multiscale case evaluation

With an estimated global warming potential of 27 to 30 over 100 years, methane (CH4) is a significant greenhouse gas emitted by livestock operations across the United States. In particular, the swine production industry of North Carolina where agglomeration of the production and the use of open-air lagoon systems for waste treatment, cause substantial emissions of CH4 and alter the environmental quality. Yet the possibility of reducing CH4 emissions from these lagoons represents an avenue to sustain environmental quality. However, quantitative estimates of methane emissions potentials at county, and regional levels are needed to envision effective emissions reduction initiatives. In this study, updated guidelines of the Intergovernmental Panel on Climate Change (IPCC) and fifteen-month full-scale data of two scenarios of waste treatment systems were used for a multiscale estimation of CH4 emissions from swine farms in North Carolina. Scenario 1 (baseline) was the conventional lagoon-based swine waste treatment system. Scenario 2 (project activity) was the conventional lagoon-based system retrofitted with a solid-liquid separation module that diverted organic compounds from reaching the anaerobic lagoon and processed with aerobic in-vessel composting. Both scenarios are feeder-to-finish swine operations and the related in-situ data utilized are monthly animal population and weight, liquid waste temperature, and 5-day biological oxygen demand (BOD5). The farm-scale estimates showed an annual emission of 332.2 kg CH4 per 1000 kg swine mass for scenario 1 and 114.7 kg CH4 per 1000 kg swine mass for scenario 2 sustaining an overall 65.5% CH4 abatement ascribable to the solid-liquid separation system. Methane emissions potentials were upscaled at the county, and state levels. The multiscale estimates highlighted hotspots of swine lagoons CH4 emissions in the North Carolina region. Two counties, Duplin and Sampson, contributed 49% of the state-level swine lagoon emissions estimated as 117,227 Mg CH4/year. However, the solid-liquid separation, as a mitigation practice, could reduce the total emissions at the state-level by 76,723 Mg CH4/year. Hence, the spatial disparities highlighted through the multiscale scenarios analyses could help to plan strategies for CH4 emission avoidance and abatement through technology improvement such as solid-liquid separation modules.

Thermally enhanced solid-liquid separation process in food waste biorefinery: modelling the anaerobic digestion of solid residues.

The biochemical valorization potential of food waste (FW) could be exploited by extracting decreasing added-value bio-based products and converting the final residues into energy. In this context, multi-purpose and versatile schemes integrating thermal and biochemical conversion processes will play a key role. An upstream thermal pretreatment + solid-liquid separation unit was here proposed to optimize the conversion of the liquid fraction of FW into valuable chemicals through semi-continuous fermentation process, and the conversion of the residual solid fraction into biomethane through anaerobic digestion. The solid residues obtained after thermal pretreatment presented a higher soluble COD fraction, which resulted in higher methane production with respect to the raw residues (0.33 vs. 0.29 Nm3CH4 kg-1VSfed) and higher risk of acidification and failure of methanogenesis when operating at lower HRT (20d). On the contrary, at HRT = 40 d, the pretreatment did not affect the methane conversion rates and both tests evidenced similar methane productions of 0.33 Nm3CH4 kg-1VSfed. In the reactor fed with pretreated residue, the association of hydrogenotrophic methanogens with syntrophic bacteria prevented the acidification of the system. Modelling proved the eligibility of the FW solid residues as substrates for anaerobic digestion, given their small inert fractions that ranged between 0% and 30% of the total COD content.

Soluble carbon source recovery using preconditioning coagulants for applicable short-term fermentation of waste activated sludge in WWTPs

A huge production of waste activated sludge (WAS) has been a burden for wastewater treatment plants (WWTPs) with high disposal cost and little benefit back to wastewater purification. The short-chain fatty acids (SCFAs) produced by a short-term acidogenic fermentation of WAS before methane production have been proven to be a high-quality carbon source available for microbial denitrification process. The dual purpose of full recovery of fermentation liquid products and facilitating disposal of residual solid waste necessitate an efficient solid-liquid separation process of short-term fermentation liquid. The transformation and loss of various soluble carbon sources between solid and liquid are very important issues for carbon recovery efficiency when combining short-term fermentation and sludge dewatering in WWTPs. Here we testified the three conventional preconditioning coagulants, Polyferric Sulfate (PFS), Poly Aluminum Chloride (PAC) and Polyacrylamide (PAM), to improve the efficiency of subsequent solid-liquid separation. The results show that conversion yield of SCFAs in the liquid phase of sludge after short-term fermentation was 195 mg COD/g VSS, when using the coagulants PFS, PAC, and PAM for recovery, the recovery ratio was 79.5%, 82.0%, and 85.9%, respectively, while the dewaterability could be improved after preconditioning short-term fermentation sludge. The complexation of Al3+/Fe3+ in metal coagulants with carboxyl groups of SCFA demonstrated by Density Functional Theory calculation led to small part of soluble carbons co-migration to the solid phase, mainly a loss of high molecular weight organic compounds (carbohydrate, proteins, humic acids), while the application of PAM had little impact on carbon recovery. Economic calculations further showed PAM preconditioning short-term fermentation liquid of WAS could achieve higher recovery benefits.

Developing a novel technology for slurry management by project-based learning

Farming is responsible for 30% of global anthropogenic emissions. A novel technology, aligning with current regulations of covering slurry stores, has been developed for processing anaerobic digestate liquor, which is obtained from the screw press stage. Instead of using hazardous chemicals, such as sulfuric acid, to capture ammonia and greenhouse gases, the artifact contains calcium chloride as deliquescent salt. Preliminary simulations in Aspen Plus® v12 showed that the absorption of NH3 and carbon dioxide during the solid–liquid separation was feasible and the resulting clean brine could be used as chemical amendment of untreated slurry. The characterization of the performance of the artifact was organized following a project-based learning active teaching method, for a group of 3 students (17-year-olds) of secondary education, as part of the In2ScienceUK program. The collection of empirical data allowed the contents of the curriculum to be contextualized, enhancing environmental awareness of participants. A titrimetric method was employed to determine the content of NH3 and CO2 in the brine, and the granulation of the dewatered liquor with the fibers of anaerobic digestate was investigated by determining the compression strength required to break the pellets. The operation capacity of the prototype was found to be 250 m3 of liquor per year, at a cost of £1/m3. The use of the filtered brine as chemical amendment also represented an additional 5.60 grams of ammoniacal nitrogen and 0.96 grams of inorganic carbon per cubic meter of unprocessed slurry. The concentrated liquor was a good binding agent that provided the pellets with a compressive strength of 207.00 ± 26.36 N, which was above the threshold value for commercialization purposes (50 N). The advances in the development of the prototype enhanced the suitability of the technology for industrial scale applications but hindered the adoption of subsequent editions of this pedagogic tool.

Unveiling the role of pore characteristics in sludge dewatering: Visualization by Nano-CT and micromodel study

The solid-liquid separation is an indispensable and primary link in the process of sludge treatment and disposal. The past research was focused primarily on the technique explorations of sludge dewatering and always disregarded the internal pore structure and water migration behavior in sludge. In this work, the real three-dimensional pore structure of sludge was obtained by Nano-CT. Based on this, a pore-scale heterogeneous sludge micromodel was firstly presented, and the water flooding experiment was carried out to visualize the water migration behavior. The results showed that the sludge structure transformed from sheet-like floc to microsphere particles, and then agglomerated into large globular granules during anaerobic ammonia oxidation. And the equivalent pore size increases from 342 μm to 617 μm, improving the sludge dewaterability characterized by capillary suction time (CST). The most significant implication of this work was revealing the critical role of invalid connected pore in sludge dewatering. Such pore was not contributed to fluid flow but the circulating vortex in it even induced energy dissipation, thus deteriorated the sludge dewaterability. This work may be helpful to understand the critical role of pore characteristic in water migration and shed light on the new dewatering techniques from the perspective of regulating sludge structure.

Controlling Crystal Growth of a Rare Earth Element Scandium Salt in Antisolvent Crystallization

Recovering scandium from hydrometallurgical residue bears the potential of a better supply of an industry depending on imports from countries with more mineral resources than Europe. To recover scandium from unused metal production residue, strip liquors from a solvent extraction process are treated with an antisolvent to crystallize the ammonium scandium fluoride salt (NH4)3ScF6 with high product yields. However, high local supersaturation leads to strong nucleation, resulting in small crystals, which are difficult to handle in the subsequent solid-liquid separation. Reducing local supersaturation makes it possible to reduce nucleation and control crystal growth. Key operation parameters are the concentration of ethanol in the feed and its addition rate. The concentration of the antisolvent in the feed causes a shorter mixing time in the proximity of the antisolvent inlet, which leads to a smaller local supersaturation and therefore less nucleation and more crystal growth. Lowering the antisolvent addition rate enhances this effect. The crystal size distribution during and at the end of the fed-batch process is analyzed by SEM imagery of sampled and dried crystals. To produce reproducible crystal size distribution from SEM images the neural network Mask R-CNN has been trained for the automated crystal detection and size analysis.

Full quantitative resource utilization of raw mustard waste through integrating a comprehensive approach for producing hydrogen and soil amendments

BackgroundPickled mustard, the largest cultivated vegetable in China, generates substantial waste annually, leading to significant environmental pollution due to challenges in timely disposal, leading to decomposition and sewage issues. Consequently, the imperative to address this concern centers on the reduction and comprehensive resource utilization of raw mustard waste (RMW). To achieve complete and quantitative resource utilization of RMW, this study employs novel technology integration for optimizing its higher-value applications.ResultsInitially, subcritical hydrothermal technology was applied for rapid decomposition, with subsequent ammonia nitrogen removal via zeolite. Thereafter, photosynthetic bacteria, Rhodopseudomonas palustris, were employed to maximize hydrogen and methane gas production using various fermentation enhancement agents. Subsequent solid-liquid separation yielded liquid fertilizer from the fermented liquid and soil amendment from solid fermentation remnants. Results indicate that the highest glucose yield (29.6 ± 0.14) was achieved at 165–173℃, with a total sugar content of 50.2 g/L and 64% glucose proportion. Optimal ammonia nitrogen removal occurred with 8 g/L zeolite and strain stable growth at 32℃, with the highest OD600 reaching 2.7. Several fermentation promoters, including FeSO4, Neutral red, Na2S, flavin mononucleotide, Nickel titanate, Nickel oxide, and Mixture C, were evaluated for hydrogen production. Notably, Mixture C resulted in the maximum hydrogen production (756 mL), a production rate of 14 mL/h, and a 5-day stable hydrogen production period. Composting experiments enhanced humic acid content and organic matter (OM) by 17% and 15%, respectively.ConclusionsThis innovative technology not only expedites RMW treatment and hydrogen yield but also substantially enriches soil fertility. Consequently, it offers a novel approach for low-carbon, zero-pollution RMW management. The study’s double outcomes extend to large-scale RMW treatment based on the aim of full quantitative resource utilization of RMW. Our method provides a valuable reference for waste management in similar perishable vegetable plantations.

Impacts of Liquid Fractions from Two Solid–Liquid Separation Technologies on the Soil Porosity, Ammonia, and Greenhouse Gas Emissions

Application of organic manure on farmland is one of the most important tasks in agricultural recycling. However, few studies have investigated the potential impact of different solid–liquid separation (SLS) technologies on soil porosity and greenhouse gas (GHG) emissions as a result of the application of liquid fractions (LFs). A microcosm experiment was conducted to track the emissions of ammonia (NH3), nitrous oxide (N2O), carbon dioxide (CO2), and methane (CH4) from soils (1) without liquid manure application (CK), (2) with a raw dairy slurry (RM), (3) with the liquid fractions of mechanical solid–liquid separation (MS) technologies, and (4) with the LF of an enhanced solid–liquid separation technology including a flocculant (tannic acid, Ta) (MS + Ta). Soil porosities of different treatments were measured using computed tomography (CT). The saturated water conductivities of the RM and MS treatments were 53.38% and 78.63%, respectively, lower than that of the CK. The application of raw slurry and LFs reduced the gas diffusion due to the strong decrease in pore sizes &gt;500 μm and increased gas emissions compared to the CK. Compared with RM, MS had greater N2O and lower CH4 emissions, whereas MS + Ta had lower NH3 and N2O emissions. MS had the greatest CO2-e emissions, mainly owing to high N2O emissions, followed by RM and MS + Ta. The implementation of a simple SLS led to an increase in nitrogen (N) loss and GHG emissions when the resultant LFs were applied to farmlands, whereas high emissions were reduced when a simple SLS was combined with a flocculant, such as Ta. Further research is required to elucidate the reduction mechanism and its effectiveness under field conditions.

Cytogenotoxicity of raw and treated dairy manure slurry by two-stage chemical and electrocoagulation: An application of the Allium cepa bioassay

Livestock farming is an essential agricultural practice. However, the improper management of livestock wastes and discharge of untreated or partially treated livestock manure slurry poses significant environmental problems. In this study, we aimed to compare the cytogenotoxic potential of untreated and treated dairy manure slurry treated with a two-stage chemical and electrocoagulation (EC) using the Allium cepa bioassay. The A. cepa bioassay is a well-established standard tool for assessing the cytogenotoxic effects of environmental contaminants, especially those that are occurred as complex contaminant mixtures. The dairy manure slurry was subjected to chemical treatment utilizing polyaluminum chloride (PAC) and cationic polyacrylamide (CPAM) at optimized conditions, followed by EC utilizing either aluminum (Al) or steel anodes. The treated and untreated samples were then evaluated for their potential cytogenotoxicty using the A. cepa bioassay, by measuring the nuclear abnormalities (NAs) and chromosomal aberrations (CAs), along with the mitotic indices (MIs). Our findings revealed a significant reduction in cytogenotoxic indicators in the treated liquid fraction compared to the untreated dairy manure slurry. Specifically, the frequency of total NAs showed a significant reduction from 154 ‰ to 37 ‰ when the dairy manure slurry was treated with chemical coagulation followed by EC utilizing an Al anode. Moreover, the MI exhibited a significant improvement from 7 ‰ to 123 ‰, suggesting the mitigation of toxic effects. These results collectively demonstrate the effectiveness of the two-stage chemical and EC treatment under optimal conditions in treating diary manure slurry while reducing its cytogenotoxicity for living systems. The A. cepa bioassay proved to be a sensitive and reliable method for assessing the toxicity of the treated samples. The efficient solid–liquid separation and the reduction of toxicity in the liquid fraction for biological systems achieved through this treatment process highlight its potential for sustainable management of livestock waste and the preservation of water quality. Nevertheless, further studies are required to assess the toxicity of solid fraction.

Upcycling waste tempura flake-derived starch powder as an environment-friendly polymer matrix filler for thermoplastic starch compounds

Waste tempura flakes collected from local restaurants were upcycled to be utilized as a polymer filler material. The oil fraction in collected waste tempura flakes were extracted two times via centrifugal solid-liquid separation and organic solvent extraction. Then, oil-extracted residual starch was freeze-milled to produce fine powders. Waste tempura flake-derived starch powder was substituted with 1%, 3%, and 5% (wt%) of virgin starch powder to produce thermoplastic starch. Composition, X-ray diffraction, and Fourier transform infrared analyses showed that the mixture was successfully thermally plasticized. Substitution of waste tempura flake-derived starch decreased tensile strength while increasing elongation at break of some samples. Produced thermoplastic starch samples again were compounded with polylactic acid (PLA) and poly-butylene adipate-co-terephthalate (PBAT) following a mixing ratio of 3:5:2. The analyses indicated that thermoplastic starch, PLA, and PBAT were successfully compounded. The compound containing 1 wt% substituted thermoplastic starch showed the minimal mechanical strength decrease. This study revealed the possibility of upcycling waste fried food into a valuable bioplastic material. Waste tempura flakes can be utilized as both bio-jet fuel and bioplastic filler material.

Enhancing the nitrogen and phosphorus content of faecal-derived biochar via adsorption and precipitation from human urine

Urine diversion in toilets is a promising strategy to maximise nutrient recovery and produce low-cost urine-derived fertilisers. There are various methods for nutrient recovery from urine, including precipitation and adsorption onto porous media, such as biochars. This study uses faecal-derived biochars to produce and, for the first time, comprehensively characterise enriched biochar fertilisers with the addition of fully hydrolysed undiluted human urine. The evolution of urea hydrolysis and nutrient content during urine storage was initially investigated over a 6-month storage period and NH4+ adsorption mechanisms studied under varying biochar doses and NH4–N concentrations. The process was further optimised by adding MgO to induce precipitation reactions, enabling the combined recovery of NH4+ and P. For NH4+ adsorption, experimental data exhibited a good fit to both the Freundlich (R2 = 0.989) and Langmuir (R2 = 0.974) isotherm models and the rate of the reaction was well described by a pseudo 2nd order kinetics model (R2 = 0.988). The NH4+ uptake was rapid during the initial 2 h of the reaction and the adsorption process reached completion after 24 h. The NH4–N adsorption capacity of the faecal-derived biochar was 19.8 mg/g and the main adsorption mechanism identified was ion exchange (K+ ↔ NH4+), as confirmed by XRD and ICP-OES. The effect of different biochar doses (0, 25, 50, 100 g/L) and MgO addition scenarios (Mg:P = 0, 1.5, 4) on N and P recovery showed that the combination of MgO (Mg:P = 1.5) with the lower biochar dose (25 g/L) produced the most NP-rich fertiliser product which was easily separated from the urine. Faecal-derived biochar had a limited adsorption capacity for P, with precipitation being the main mechanism for P recovery. When MgO was added to urine, >98% of total P was recovered via precipitation of struvite/struvite-K and substituted hydroxyapatite, as identified via SEM-EDX. Faecal-derived biochar was a successful carrier to recover the P-containing precipitates and facilitate liquid-solid separation after treatment. The findings of this study provide proof-of concept for the systemic management of source separated human excreta and pave the way for the production of marketable waste-derived fertilisers from on-site sanitation systems.

Efficient and recycled magnetic self-stirring hollow fiber-solid/liquid phase system: An extraction and removal technique for personal care pollutants

The removal of personal care products (PCPs) in aqueous environments is a huge challenge. Traditional powder and magnetic materials are not conducive to complete solid–liquid separation, which hinders their practical application. In this study, the convenient recyclable magnetic self-stirring system combining with n-octanol hollow fiber-liquid phase micro-extraction (HF-LPME), wormhole-like mesoporous carbon (WMC) solid phase and magnetic stirring was constructed to improve the extraction and removal efficiency of the trace PCPs (triclosan, triclocarban, 2, 2′-Dihydroxy-4-methoxybenzophenone, and 2, 4-dihydroxydiphenylketone) in wastewater. The adsorption process of triclosan and 2,2′-dihydroxy-4-methoxybenzophenone on the WMC surface followed the pseudo-first-order kinetics as well as Freundlich isotherm model. Because WMC had oxygen-containing groups and the multiple mesoporous distribution forming the n-octanol microextraction unit and the shearing strength generated by the stir bar in the water sample accelerated the mass transfer efficiency of PCPs, this system had the advantage of simultaneous removal and extraction of four PCPs from wastewater samples. The extraction mechanism involved the hydrophobic force and size effect between the WMC and PCPs. In addition, the factors affecting extraction efficiencies (EEs) were discussed, such as the concentrate of WMC (1 mg/L), rotation rate (400 rpm), extraction time (15 min), and salt concentration (30%). The results indicated that the method possessed a wide linear range (0.05–200 μg L-1), and lower limits of detection (LODs) (S/N = 3, 0.005–0.05 μg L−1), at the optimal conditions. This method also showed excellent reusability and stability, with higher recovery (88–98%) and fewer relative standard deviations (2.4–6.3%). This work not only minimized secondary pollution from powder adsorbents, but provided an economic and green magnetic self-stirring system and absorbent for the extraction, removal, and determination of typical PCPs pollutants from actual wastewater samples.

Liquid-solid phase separation and recycling of permalloys in liquid Mg

Liquid-solid phase separation of permalloy in liquid Mg results in selectively dissolved Ni, which provides a unique opportunity for the design of immiscible heterogeneous composite materials and the comprehensive metal recycling of permalloy scraps. A guideline of the alloy design for the liquid-solid phase separation system was proposed. The effects of immersion temperature and time on the Ni extraction were studied by an experimental method. The diffusion behavior of Ni from the permalloy to liquid Mg and the microstructure evolution in the permalloy during the liquid-solid phase separation were discussed. The results show that the Ni in the permalloy was quickly extracted into the liquid Mg and formed an Mg-Ni alloy, while the other components such as Fe, Co, and Mn were held back in the phase-separated permalloy. The phase-separated permalloy with the solidified Mg exhibits a three-dimensional (3D) Fe/Mg bicontinuous composite structure. Furthermore, simple treatments were carried out for the reaction products such as the Fe/Mg bicontinuous composite and the Mg-Ni alloy, and the recycling strategies for functionalization of these treated reaction products were provided. A 3D porous Fe-based alloy with electromagnetic interference (EMI) shielding efficiency of 52 dB can be obtained if Mg is removed from the Fe/Mg bicontinuous composite. Instead of the complete separation of pure Ni from the recycled Mg-Ni alloy by vacuum distilling, the Mg-Ni alloy can be enriched into Mg2Ni as an initial hydrogen storage material.

Mass transfer research on solid-liquid separation of extracted coal tar residue based on diffusion model

A large amount of coal tar residue (CTR) produced in the process of coal coking and tar processing is recognized as hazardous industrial waste with a high carbon content and strong carcinogenic polycyclic aromatic hydrocarbons. Through solvent extraction, CTR can be separated into economically valuable tar and fixed carbon, and waste recycling can be realized. In this paper, a mathematical model of CTR solid-liquid extraction is established based on a diffusion model and experiments, and the mass transfer law, mass transfer equation, and influence of different conditions of solid-liquid separation of CTR from toluene extraction are studied. First, the empirical formula is used to derive the change in the mass transfer coefficient kf outside the particles during extraction, and the kf gradually decreases as the extraction progresses. The particle swarm optimization is used to obtain the best effective diffusion coefficient Deff, inside the particles, which is 9.65 × 10−14 m2/s. The effective diffusion coefficient, Deff, was determined and corrected based on experimental data. A second-order function was fitted to describe the variation of Deff with temperature. MATLAB software was used to solve the model the concentration change law and extraction law during extraction were obtained. According to the model simulation, the influence of different conditions such as agent residue ratio, stirring speed, particle radius, and temperature on the extraction process is calculated.

Phosphonate functionalized magnetic mesoporous silica for rare earth element recovery from citrate assisted solid waste extracts

The growing high demand of rare earth elements (REEs) has prompted extensive research on REE recovery from waste streams. This study reports the synthesis and evaluation of phosphonate-functionalized magnetic mesoporous silica (MMS-PP) for REE recovery from the acidic extracts of solid wastes. MMS-PP was synthesized using surfactant template and post-synthesis methods, and tested using simulated and real extraction solutions from citrate-assisted REE extracts from municipal solid waste incineration (MSWI) ash. The organic-inorganic hybrid MMS-PP was evaluated for La recovery from 50 mM simulated citrate extract, with the adsorption capacity of 13.5 mg/g compared to ∼2.5 mg/g for non-functionalized MMS. The MMS-PP material exhibited fast adsorption within 10 min, good La selectivity against competing Na+ and Ca2+, moderate selectivity against Al3+ and Fe3+, high recyclability over multiple adsorption-desorption cycles, and equivalent efficiency for La, Ce, Nd, and Y recovery. The MMS-PP material also demonstrated 70–95% REE recovery from real citrate extracts of MSWI ash, and the spent MMS-PP material can be regenerated and reused for multiple cycles. Functionalized mesoporous materials in combination with organic-ligand assisted extraction can potentially provide a green, effective, and tunable solid-liquid separation platform for REE recovery from complex solid waste streams.

Analysis of microbial communities in solid and liquid pig manure during the fertilization process

Utilizing livestock manure as organic fertilizer in sustainable agriculture is crucial and should be developed through an appropriate manufacturing process. Solid–liquid separation contributes to reducing odor, managing nutrients in livestock excretions, and lowering the cost of transporting manure to arable soil. To investigate the impact of fermentation after solid–liquid separation, we examined the specific correlation between chemical properties and bacterial communities in solid–liquid manures before and after the fermentation process. In terms of chemical properties before fermentation, the levels of electrical conductivity, nitrogen, ammonium nitrogen (NH4+-N), potassium, sodium, and chloride were higher in the liquid sample than in the solid sample. However, the chemical components of the liquid sample decreased during fermentation, which could be attributed to the low organic matter content. Many chemical components increased in the solid samples during fermentation. Fifty-six bacterial species were significantly correlated with NH4+-N and phosphorus. Following fermentation, their abundance increased in the solid samples and decreased in the liquid samples, indicating the potential for NH4+-N release or phosphorus mineralization from organic matter. These results provide information regarding changes in nutrient and bacterial formation when applying the fermentation process after solid–liquid separation.