AbstractDespite produced exclusively on the dayside, photoelectrons, as an important population of the Martian ionosphere, have also been observed on the nightside. Here we present a statistical survey of nightside photoelectrons using the suprathermal electron measurements, made by the Solar Wind Electron Analyzer onboard the Mars Atmosphere and Volatile Evolution. We find that nearly 30% of the available nightside suprathermal electron spectra show clear photoelectron signatures. Nightside photoelectrons have an occurrence rate that decreases with increasing solar zenith angle and they are characterized by a preferentially field‐aligned pitch angle distribution. Our analysis also suggests that nightside photoelectrons are less likely observed under the high solar wind condition. These observations are favorably interpreted by the scenario of photoelectron transport along cross‐terminator magnetic field lines, as supported by a simplified test particle model. Our study highlights a complex plasma environment near Mars modulated by both internal and external conditions.