Solar Thermoelectric Generator Research Articles

Tailoring of Polypyrrole Wrapped Cotton Fiber Sponge for Simultaneous Solar Steam and Solar Thermoelectric Generation

AbstractSolar steam generation (SSG) using floatable evaporators to absorb solar energy and generate heat at the water–air interface has attracted increasing interest in achieving water purification and desalination. Using biodegradable and porous biomass materials as evaporators to fabricate high‐performance SSG devices is a promising route, but the poor efficiency and fussy and energy‐intensive manufacturing process for biomass material‐based evaporators will restrict their practical application. Here, an old commercial cotton quilt is used to prepare porous cotton fiber sponges (CFS) via a simple and scalable mechanical foaming strategy. After being decorated by the polypyrrole (PPy), the CFS@PPy sponge with a hierarchical porous structure shows broadband light absorption capacity, good hydrophilicity, and excellent photothermal capacity. The obtained sponge can be directly used as an evaporator floating on the seawater and shows a high steam‐generation efficiency of 85.07% under 1 sun irradiation. Additionally, it can be used as a photothermal material to construct a solar thermoelectric generation (STG) device and achieve an enhanced open‐circuit voltage (Vout) of 0.4 V and output current (Iout) of ≈59.6 mA under 5 sun irradiations. With the help of a boost converter, the power generation from the STG device can continuously charge the electric bulb and wristband.

Concentrated solar thermoelectric power generator equipped with a novel ultrathin wet porous membrane cooling technique; experimental study

One side of any thermoelectric power generator (TEG) is hot while the other side should always stay cold. The higher the temperature difference, the greater the power generation. This paper offers a particular ultrathin wet porous membrane (UWPM) as a new cooling method for a solar thermoelectric power generator. According to the graphical abstract, the membrane has a capillary-wicking feature on one side, making it possible to be soaked spontaneously and create a steady thin water film on the ceramic layer of the thermoelectric, thereby serving as an energy-free, enthalpy of vaporization-based cooling method (surface vaporization). Interestingly, water is replenished spontaneously as long as the water exists in the tank. The suggested mechanism is tested under two weather conditions: one hot, dry day (ambient air around 40 °C) and one moderate day (ambient air around 30 °C), with different air speeds between 1.5 and 4.5 m/s to simulate different wind speeds in real applications. Power, cold side surface temperature, maximum conversion efficiency, etc., are measured, evaluated, discussed, and compared with the common fin-pin heatsink/fan thermal management tool. Notably, the implementation of the UWPM demonstrates a substantial enhancement in thermoelectric generator performance. It is noted that the lowest temperature that can be obtained through vaporization can be colder than ambient air temperature, approaching the wet-bulb temperature. The UWPM keeps the cold side temperature up to 10 degrees colder than that achieved in the heatsink method. This is why the generated power by the TEG is around 2.5 times higher when utilizing the UWPM. Furthermore, unlike the fin-pin heatsink (FPH) thermal management tool, warmer weather conditions do not diminish the cooling quality of the UWPM method. Indeed, the cold side temperature on a hot, dry day is almost the same as that on a moderate day using the UWPM technique. This is because hot ambient temperature induces greater and easier vaporization, leading to a higher cooling effect.

Development of Steg with Concentrating System

Solar cells, also known as photovoltaic cells, convert light energy into electrical energy through the photovoltaic effect. Integrating a thermoelectric generator into a photovoltaic system enhances power output and efficiency by utilizing waste heat. Concentrators are employed to further improve solar panel efficiency. This study aims to develop a solar thermoelectric generator (STEG) with a concentrating system that includes a heat sink cooling system, thermoelectric generator, and concentrator. Three conditions will be tested to observe the power output of each solar module: PV standalone, STEG with a heat sink, and STEG with a heat sink and concentrator. The efficiency appears to improve from 9.21% for PV standalone to 10.11% for STEG with a heat sink and 10.23% for STEG with a concentrating system. The results of these studies aim to establish a benchmark for enhancing the efficiency of future STEG systems.

Enhancing solar thermoelectric power generation with supercritical CO2 cooling: Hydraulic, thermal, and exergy analysis

This research investigates the dynamic behavior and impact of various factors on the hydraulic, thermal, and exergetic characteristics of a solar-based thermoelectric device using a pin–fin heatsink cooled by supercritical CO2. A comprehensive numerical model analyzes the heat dissipation and performance of the power generator, integrating a thermoelectric generator and a pin–fin heatsink with various pin shapes. Key geometric and operational parameters, such as the height of PN (P-type and N-type semiconductor) legs of the TEG, the number of thermocouples, operating pressure, Reynolds number, and CO2 temperature, are examined for a comprehensive performance assessment. The study highlights the superior performance of CO2 coolant over traditional water-cooling system. Near the critical temperature of CO2, enhanced heat transfer significantly boosts power output, conversion efficiency, and exergetic efficiency. For example, at 8 MPa, the TEG’s (thermoelectric generator) power output increases from 1.31 mW at 295 K to 2.35 mW at 310 K. Comparisons reveal that while water coolant lowers the cold side temperature more effectively, it results in reduced power output due to decreased temperature differentials and increased pressure loss. Conversely, CO2 coolant maintains higher cold side temperatures while having advantages in power output. At 315 K, the cold side temperature with water is 315.7 K compared to 346.7 K with CO2. Increasing the number of thermocouples from 18 to 32 for a leg height of 1 mm leads to an approximate 102.3 % increase in voltage. Raising the PN leg height from 1 mm to 2 mm for an NTC of 50 results in a nearly 99.8 % increase in voltage. Lozenge-shaped fin produces a peak power output of 2.73 mW, while square fin generates 2.62 mW. This research underscores CO2’s potential as a high-performance coolant in solar thermoelectric applications, offering insights into optimizing system design for maximum efficiency.

Experimental study on a solar thermoelectric power generation system under non-uniform irradiation

Non-uniform irradiation caused by high light concentration significantly affects the performance of the solar thermoelectric power generation system, but the research remains at the theoretical stage. This paper establishes an experimental setup for the solar thermoelectric system and conducts a comprehensive experimental study of the system operating under non-uniform irradiation. The temperature, power and efficiency of the systems are tested for different input powers, cooling methods and structures, and irradiation uniformity. The results indicate that the output power of the solar thermoelectric system slightly increases and then decreases as the irradiation uniformity increases. The system’s output power is minimized when the irradiation uniformity approaches 100%. The optimum irradiation uniformity of the solar thermoelectric system is 47.4% and the maximum efficiency is 1.495%, which is an improvement of 7.6% compared to the efficiency of 98.4% irradiation uniformity. The performance of the solar thermoelectric system can be further improved by using a double-layer TE structure. At a concentration ratio of only 12.4, the double-layer system connected in series achieved a maximum efficiency of 2.06%, which is 0.55% higher than the single-layer system. The importance of optimizing irradiation uniformity to improve system performance is experimentally revealed. These results are important for clarifying the operating principle of the solar thermoelectric system under non-uniform irradiation and can guide the subsequent design of high-efficiency solar thermoelectric systems.

Revealing the Structural, Electronic, Optical, and Thermoelectric Aspects of the Gold‐Based Double Perovskites X2Au+Au3+Br6 (X = Cs, Rb) Using a First‐Principles Approach

Lead‐free double perovskites are now assumed to be suitable candidates for green energy harvesting in particular as active materials for solar cells and thermoelectric generators, which can meet future generation energy needs. Therefore, we explore the Au‐based halide double perovskites X2Au+Au3+Br6 (X = Cs, Rb) from the first principles approach. Density functional theory (DFT) is utilized to explore the electronic structure with DFT code Quantum ESPRESSO. The mechanical, thermodynamic, and structural stability is ensured from Burn‐Haun criterion, formation energies, and Goldschmidt factors, respectively. The examined materials have stable structures with direct band gaps i.e. 1.54 and 1.72 eV. The existence of band gaps in the visible region motivates us to explore the optical properties, which give fascinating outcomes. The absorption coefficients and optical conductivity peaks are found to be significant in the visible region i.e., ≈104 cm−1 and ≈1015 s−1, respectively. Additionally, the thermoelectric properties are also investigated using Boltzmann transport theory. There are several good gestures for the usage in the thermoelectric generators since the values of Seebeck coefficients (446.5, and 225.2 μV K−1), power factors (1.75 × 1011 W mk−2 s, and 1.24 × 1011 W mk−2 s), and figure of merits (0.92 and 0.73) are noteworthy for Cs2AuAuBr6 and Rb2AuAuBr6, respectively, at room temperature T = 300 K.

Theoretical investigations of double perovskites Rb2YCuX6 (X =Cl, F) for green energy applications: DFT study

Double perovskites, which have remarkable performance, great stability, environmental friendliness, and are Pb-free, are emerging materials for solar cells and thermoelectric generators. Herein, we present density functional theory (DFT) calculations on novel metal Pb-free double halide perovskites, Rb2YCuX6 (X = Cl, F), aiming to explore their potential for renewable energy applications. The compounds' negative formation energy confirms their thermodynamic stability, the Goldsmith tolerance factor (tG) provides evidence for their structural stability in the cubic crystalline form and the stable phonon dispersion spectrum confirm its dynamic stability. We found that the lattice constant increases noticeably as the halogen anions change (i.e replacing F by Cl). The mechanical stability of the compounds is validated by the relationships between elastic constants (ECs), namely C11–C12 > 0, C11 > 0, C11 + 2C12 > 0, and B > 0. Utilizing the TB-mBJ potential, it has been determined that the compound Rb2YCuCl6 exhibits an indirect bandgap semiconducting nature with a band gap of 2.31 eV. On the other hand, the compound Rb2YCuF6 demonstrates properties of a direct bandgap semiconductor with a band gap of 2.47 eV. In order to evaluate their suitability for applications in solar cells and optoelectronic devices, we analyze the dielectric function (ε(ω)), optical conductivity (σ(ω)), and reflectivity (R(ω)) of the compounds. Moreover, the thermoelectric performance has been elucidated through the analysis of the power factor (PF) and figure of merit (ZT). The presence of ultralow lattice thermal conductivity and a significant Seebeck coefficient (S) further enhance ZT, making these compounds suitable for thermoelectric applications. Our findings provide comprehensive insight in exploring the properties of Pb-free Rb2YCuX6 (X = Cl, F) double perovskites. It confirms their stability, suitable bandgaps, and impressive thermoelectric properties, highlighting their potential for solar cells and thermoelectric generators as environmentally friendly and sustainable energy solutions.

Harnessing solar power: Innovations in nanofluid-cooled segmented thermoelectric generators for exergy, economic, environmental, and thermo-mechanical excellence

Addressing the imperative need for advancements in thermoelectric generation, this study pioneers an analysis of nanofluid-cooled solar segmented thermoelectric generators with non-uniform cross-sections. Insights into thermal management, structural integrity, and economic efficiency in thermoelectric systems are provided, employing a numerical model that accurately represents thermoelectric effects by accounting for temperature dependencies of semiconductor materials. Through research, exploration of diverse coolant strategies, including TiO2, Fe3O4, Al2O3, and graphene, offers key insights into their impact on cooling dynamics. Findings demonstrate that graphene nanofluid, operating at a flow velocity of 2 m/s, outperforms others, achieving optimal power generation of 221.77 mW and an exergy efficiency of 8.99 %. Additionally, at a concentrated irradiance of 595 kWm−2, graphene leads in environmental benefits, with the highest CO2 savings of 0.38 kgyr−1, and demonstrates economic advantages with a cost-effective dollar per mW value of 3.79×10−6 $mW−1. Furthermore, the study verifies the structural integrity of these systems, with graphene achieving an optimal von Mises stress of 1.35 GPa at a semiconductor height of 0.2 mm. These advancements contribute to environmentally friendly and high-performance generators for sustainable energy solutions, paving the way for future innovations in thermoelectric technology.

Investigating the power and efficiency of the 3D model of the concentrated photovoltaic thermoelectric hybrid system and estimating the power consumption of the water pump for cooling

Solar energy is one of the most useful types of renewable energy. Solar cells are being used to convert solar energy into electricity. By focusing the radiation on the cells, more energy is radiated in a smaller area of the cell which is called concentrated photovoltaic (CPV). Due to the concentration of radiation, the temperature of the cell rises which can be converted into electricity through thermoelectric generators (TEG). The present study is a hybrid system of solar cell, thermoelectric generator, and heat exchanger (CPV-TEG). By this survey being created, it was revealed that the combined power produced by the CPV-TEG reaches its maximum value at concentration ratio of 40. This increase continues with the increase in fluid flow rate. however, according to the power consumption of the pump, it was observed that in all types of heat exchangers, an increase in flow rate of more than 8 liters per hour reduces the output power of the system. The replacement of the secondary heat exchanger with the primary one illustrated that the increase of the channels in the exchanger, despite the increase in the power consumption of the pump, causes a very small increase in the output power and efficiency of the system. Moreover, replacing the tertiary heat exchanger instead of the secondary exchanger showed that changing the direction of fluid output increases the power consumption of the pump in high flow rates.

Stable Radicals in Dihydrophenazine Derivatives-Doped Epoxy Resin for High Photothermal Conversion.

Organic radicals exhibit great potential in photothermal applications, however, their innate high reactivity with oxygen renders the preparation of stable organic radicals highly challenging. In this work, a series of co-doped radical polymers ares prepared by doping dihydrophenazine derivatives (DPPs) into the epoxy resin matrix. DPPs can form radical species through the electron transfer process, which are further stabilized by the complex 3D network structure of epoxy resin. Experimental results show that the photothermal conversion efficiency is as high as 79.9%, and the temperature can quickly rise to ≈130°C within 60 s. Due to the excellent visible light transmittance and mechanical properties of co-doped systems, this study further demonstrates their practical applications in energy-saving solar windows and thermoelectric power generation.

Cost-efficient sunlight-driven thermoelectric electrolysis over Mo-doped Ni5P4 nanosheets for highly efficient alkaline water/seawater splitting

Thermoelectric water spitting to hydrogen systems has great potential in the production of environment-friendly fuel using renewable solar energy in the future. In this work, we prepared porous nanosheet Mo doping Ni5P4 catalysts on nickel foam with efficient hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) performance in alkaline media. Density Functional Theory (DFT) calculations and experimental studies have shown that Mo doping deadeneds the interaction between H and O atomic orbitals of transition state water molecules, effectively weakening the activation energy of H2O dissociation. Therefore, Mo doping is favorable for enhancing HER activity with overpotential at 10 mA cm–2 of 93 mV and Tafel slope of 40.1 mV dec–1 in 1 M KOH. Besides, it exhibits high alkaline OER activity with an ultra-low overpotential of 200 mV at 10 mA cm–2. Moreover, this catalyst only needs 1.537 V in a dual-electrode configuration of the electrolytic cell, which is much lower than the commercial Pt/C-RuO2 couple (1.614 V). In addition, we have developed and constructed a solar thermoelectric generator (TEG) that is capable of floating on water. This TEG has a continuous power output and an exceptionally long lifespan, providing a stable power supply to the synthesized catalyst electrolyzer. It can produce a maximum power output of over 90 mW, meeting the requirement of converting solar radiation heat into usable electricity. As a result, the system achieves productivity of 0.11 mL min–1 H2. This solar thermal energy conversion technology shows the possibility of large-scale industrial production of H2 and provides a new idea for exploring heat source utilization.

Effects of temperature uniformity and nonuniformity on thermoelectric generator performance across hot and cold sides

Solar Thermoelectric Generators (STEG) are gaining attention for clean energy but face nonuniform temperature distribution due to optical concentrators and heat sinks. While prior studies used central circles or identical squares to represent temperature variations, this paper examines six circular and rectangular patterns. Using COMSOL, the TEG module was simulated under four boundary conditions: (1) uniform temperatures on both sides, (2) six patterns on the hot side, (3) six patterns on the cold side, and (4) six patterns on both sides for the first time. Experimentally, the I–V and P–V characteristics of STEG were measured using the capacitor technique for four concentration ratios (20, 40, 60, and 80 suns) obtained using the KIRAN-42 simulator. Simulations aligned well with all experiments under condition (1). The 3rd circular and rectangular pattern matched 11 times, while the 1st pattern matched once under conditions (2) − (4). The Root Mean Square Error (RMSE) between the measured and simulated Pmax, based on average measured temperatures, was 0.505. For condition (1), the RMSE was 0.017, while for conditions (2) − (4), it was 0.027 (0.033), 0.031 (0.031), and 0.044 (0.047) for the 3rd circular (rectangular) pattern, respectively. These findings indicate improved alignment between experiments and simulations.

Photothermal conversion-enhanced thermoelectric generators combined with supercapacitors: An efficacious approach to integrated power generation and storage

Thermoelectric generators (TEGs), which harness and convert solar-thermal energy into electrical energy, possess immense potential within the field of photothermal conversion (PTC). However, the widespread adoption of conventional TEGs in PTC domain has encountered some obstacles, which represent that TEGs have poor inherent PTC performance, resulting in low solar-thermoelectric conversion efficiency, and this solar-thermal-electric conversion method lacks the capability of electrical energy storage. Hence, an urgent imperative exists to develop integrated and synergistic energy technologies that can respond to these underlying challenges. Herein, we reported a novel strategy for employing spinel-type Cu1.5Mn1.5O4 PTC coating to adorn conventional TEG to construct the solar-thermoelectric generator (STEG) which exhibited excellent solar-thermoelectric conversion capability, and then integrating the STEG in series with a supercapacitor composed of synthetic ionic liquid electrolytes and carbon electrodes to fulfill the conversion and storage of solar-thermal energy into electrical energy. The results indicated that, when compared to a conventional TEG, the STEG attained a drastically elevated internal temperature difference due to the excellent PTC capability of spinel-type coating. As a result, remarkable enhancements were observed in both the steady-state voltages (Voc) and maximum output power density (Pmax) of the STEG, exceeding a 6-fold and 40-fold increase, respectively. Furthermore, we conducted experimental validation to ascertain the viability of the solar-driven STEG to charge a supercapacitor, thereby achieving the conversion and storage of solar-thermal energy into electrical energy, and the working mechanism of this integrated system has been revealed. This study offers invaluable insights into the development of highly efficient solar-thermal energy conversion and storage methods.

Model development and preliminary study of the concentrated-radiative cooling based thermoelectric generator

Photovoltaic (PV) cells, widely adopted in solar energy applications, achieve a maximum efficiency of only 30 % and remain inactive during nighttime. In contrast, solar-thermal power generation has surpassed 50 % efficiency. To address these limitations, we introduce the Solar- Radiative cooling -Thermoelectric system (Solar-RC-TE), integrating solar energy, radiative cooling (RC), and thermoelectric power generation. This system enhances energy density, reduces consumption, lowers costs, and minimizes environmental impact while enabling nighttime power generation. For the optimization of the Solar-RC-TE model to further improve power generation efficiency, we employ the comprehensive three-dimensional methodology of COMSOL, considering material properties, structural configurations, and environmental factors. Research findings reveal that a 710 mm × 710 mm radiative cooling film can generate 386.12 mV of voltage on the thermoelectric generator (TEG). Environmental factors, such as increased solar irradiance, lead to temperature elevation, affecting efficiency. Overheating and higher wind speeds also contribute to decreased TEG efficiency. Regarding materials, improving the thermoelectric figure of merit (ZT) and film emissivity positively impact power generation efficiency. Elevating the film emissivity from 0.7 to 0.89 significantly enhances performance by 1.2 %. These outcomes provide a tangible and practical solution for addressing energy crises and environmental concerns.

A synergistic approach to optimizing the performance of a concentrating solar segmented variable area leg thermoelectric generator using numerical methods and neural networks

This study presents an optimized design for segmented variable area leg thermoelectric modules using finite element methods and Bayesian regularized neural networks. We explored the impact of geometry and thermal parameters on module performance using ANSYS software, identifying optimal parameters for power output and efficiency. Key findings revealed the higher influence of geometric parameters and confirmed the advantages of segmented thermoelectric generators for high-temperature applications like concentrated solar systems. With this optimization, power output and efficiency of the module increased by 875% and 165%, respectively, under 25 Suns. To refine the optimization process, a Bayesian regularized neural network was utilized, proving effective in predicting module performance with a low mean squared error and high coefficient of determination. This research provides important insights into high-performance thermoelectric modules for sustainable energy applications, demonstrating the significant role of advanced computational methods in energy solutions.

Band gap engineering of vacancy-ordered halide perovskite Cs2SnCl6 from substitutional doping of Pt (Cs2Sn(1-x)PtxCl6 where x = 0, 0.25, 0.50, 0.75 and 1.00) and its effects on thermoelectric properties using the first-principles approach

Researchers have shown substantial interest in vacancy-ordered halide perovskites for non-traditional energy harvesting applications including solar cells and thermoelectric generators. In this study we performed band gap engineering of vacancy-ordered halide perovskite Cs2SnCl6 from substitutional doping of Pt (Cs2Sn(1-x)PtxCl6 where x = 0, 0.25, 0.50, 0.75 and 1.00) and studied its effects on thermoelectric properties using first-principles approach. Thermodynamic stability has been proven by computing the formation energies and the tolerance factors. The band gaps were efficiently reduced to 2.50 eV from 3.61 eV by the band gap engineering approach of Pt doping. Consequently, the materials exhibited improved thermoelectric properties, including low thermal conductivities, high Seebeck coefficients, and high values of ZT. The maximum value of ZT = 2.27 was estimated for x = 1.00. The Pt doping technique can be deemed effective based on the enhanced structural and thermoelectric performance parameters.

Plasmonic Nanoparticles Boost Solar-to-Electricity Generation at Ambient Conditions.

Sunlight-to-electricity conversion using solar thermoelectric generators (STEGs) is a proven technology to meet our ever-growing energy demand. However, STEGs are often operated under a vacuum with customized thermoelectric materials to achieve high performance. In this work, the incorporation of plasmonic gold nanoparticle (AuNP) based solar absorbers enabled the efficient operation of STEGs under ambient conditions with commercially available thermoelectric devices. AuNPs enhanced the performance of STEG by ∼9 times, yielding an overall solar-to-electricity conversion efficiency of ∼9.6% under 7.5 W cm-2 solar irradiance at ambient conditions. Plasmonic heat dissipated by AuNPs upon solar irradiation was used as the thermal energy source for STEGs. High light absorptivity, photothermal conversion efficiency (∼95%), and thermal conductivity of AuNPs enabled the efficient generation and transfer of heat to STEGs, with minimal radiative and convective heat losses. The power generated from plasmon-powered STEGs is used to run electrical devices as well as produce green hydrogen via the electrolysis of water.

ADVANCED HYBRID SOLAR THERMOELECTRIC GENERATOR THEORETICAL ANALYSES

Due to the fact that much of the world’s best solar resources are inversely correlated with population centers, significant motivation exists for developing the technology, which can deliver reliable and autonomous conversion of sunlight into electricity. Thermoelectric generators (TEG) are gaining incremental ground in this area due to its extensive use in solar thermal application as power generators, known as solar thermoelectric generators (STEG). STEG systems are gaining significant interest in both, concentrated and non-concentrated systems and have been employed in hybrid configurations with the solar thermal and photovoltaic systems. In this dissertation, mainly studies of Hybrid Solar Thermoelectric Generators (HSTEG) configuration are presented. HSTEG systems are much less studied both experimentally and theoretically, despite their clear technoeconomic advantages. There is a scope for significant improvement in the performance (efficiency) and a need for detailed performance analysis to understand the fundamentals of the energy transfer process. HSTEG systems (conventional) reported till date, initially the solar energy is utilized by the TEG for generating electricity and then transferred to other low temperature thermal cycles (heating or cooling). As an alternative one can design an advanced HSTEG system, in such way to first utilize the solar energy in the heat transfer fluid (HTF), which can run high temperature thermal cycle for heating or cooling or power generation) and then generate electricity by using TEG. Further, there is no advanced HSTEG system is available in the literature, which could deliver high temperature heat output from the hot side of the HSTEG system. Key Words: optics, photonics, light, lasers, stencils, journals

A Superhydrophobic Self-Cleaning Flexible Hydrogel for Solar Thermoelectric Power Generation

A Superhydrophobic Self-Cleaning Flexible Hydrogel for Solar Thermoelectric Power Generation

Mussel-Inspired Self-Adhesive and Tough Hydrogels for Effectively Cooling Solar Cells and Thermoelectric Generators.

Adhesive hydrogel-based evaporative cooling, which necessitates no electricity input, holds promise for reducing energy consumption in thermal management. Herein, inspired by the surface attachment of mussel adhesive proteins via abundant dynamic covalent bonds and noncovalent interactions, we propose a facile strategy to fabricate a self-adhesive cooling hydrogel (Li-AA-TA-PAM) using a copolymer of acrylamide (AM) and acrylic acid (AA) as the primary framework. The monomers formed hydrogen bonds between their carboxyl and amide groups, while tannic acid (TA), rich in catechol groups, enhances the adhesion of the hydrogel through hydrogen bonding. The hydrogel demonstrated strong adhesion to various material surfaces, including plastic, ceramic, glass, and metal. Even under high-speed rotation, it still maintains robust adhesion. The adhesion strength of the Li-AA-TA-PAM hydrogel to aluminum foil reached an impressive value of 296.875 kPa. Interestingly, the excellent contact caused by robust adhesion accelerates heat transfer, resulting in a rapid cooling performance, which mimics the perspiration of mammals. Lithium bromide (LiBr) with hydroactively sorptive sites is introduced to enhance sorption kinetics, thereby extending the effective cooling period. Consequently, the operation temperature of commercial polycrystalline silicon solar cells was reduced by 16 °C under an illumination of 1 kW m-2, and the corresponding efficiency of energy conversion was increased by 1.14%, thereby enhancing the output properties and life span of solar cells. The strategy demonstrates the potential for refrigeration applications using viscous gels.