Abstract

Photovoltaic (PV) cells, widely adopted in solar energy applications, achieve a maximum efficiency of only 30 % and remain inactive during nighttime. In contrast, solar-thermal power generation has surpassed 50 % efficiency. To address these limitations, we introduce the Solar- Radiative cooling -Thermoelectric system (Solar-RC-TE), integrating solar energy, radiative cooling (RC), and thermoelectric power generation. This system enhances energy density, reduces consumption, lowers costs, and minimizes environmental impact while enabling nighttime power generation. For the optimization of the Solar-RC-TE model to further improve power generation efficiency, we employ the comprehensive three-dimensional methodology of COMSOL, considering material properties, structural configurations, and environmental factors. Research findings reveal that a 710 mm × 710 mm radiative cooling film can generate 386.12 mV of voltage on the thermoelectric generator (TEG). Environmental factors, such as increased solar irradiance, lead to temperature elevation, affecting efficiency. Overheating and higher wind speeds also contribute to decreased TEG efficiency. Regarding materials, improving the thermoelectric figure of merit (ZT) and film emissivity positively impact power generation efficiency. Elevating the film emissivity from 0.7 to 0.89 significantly enhances performance by 1.2 %. These outcomes provide a tangible and practical solution for addressing energy crises and environmental concerns.

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