Urban heat islands (UHI) have become an increasingly pressing issue owing to the global warming trend and a steady growth of urban areas. Revegetation, shading, or the reduction of sealed surfaces is not always possible in cities. Therefore, one way to fight UHIs is through adapting currently used pavements. This study assesses the thermal behavior of 12 different pavement materials in a custom-made test stand. The materials include mastic asphalt ( MA 8, MA 8 white), porous asphalt ( PA 4, PA 4 abraded, PA 4 white, PA 8, PA 8 abraded, PA 8 white), asphalt concrete ( AC 11 transparent, AC 8 yellow), and semi-flexible pavements ( SFP 8, SFP 8 zeolite). The albedo was assessed using pyranometer. Sensors and thermal imaging were used to measure temperatures during two simulated heat cycles. Both the temperatures underneath the test specimens and at the surface were considered, as well as the cooling times of the materials. The results showed high maximum temperatures for PA and MA, as well as low maxima for the white painted materials, with differences in maxima of up to 15°C. Porous asphalt, like PA 8, cools faster than MA 8 from roughly 47°C to 28°C, taking 3.7 h compared with MA 8’s 5.1 h. This highlights the importance of considering cooling times and regional solar phases in experimental setups. Through the wide range of tested materials, a significant linear correlation between the measured albedo and surface temperature was proven. Ultimately, a foundation for thermal comparability between these materials was established.