Soil Evolution Research Articles

Evolution of mechanical behavior in granular soil during fine particle loss simulated by salt dissolution: Insights from ring shear tests

Fine particle loss in soil is one of the main causes of slope instability and geotechnical structure failure. Loss of fines can cause instability in granular assembles by changing the fabric and microstructure of the sample. However, real-time monitoring of the evolution of mechanical behavior in granular soils during the particle loss process is still poorly explored. This study presents a novel approach by simulating fine particle loss through salt dissolution in ring-shear tests, offering real-time insights into the mechanical evolution of granular soils under realistic stress conditions. Meanwhile, the shear resistance, shear displacement, vertical displacement, salt content, and acoustic emissions were simultaneously recorded. The test results showed that the instability of the sample was triggered by the loss of fine particles. With a gradual loss of fine particles, both the vertical and shear deformations and the void ratio increased. The evolution of shear resistance in the sample can be divided into three stages: stress weakening, then strengthening, and finally recovery to the initial value. We infer that the evolution of shear resistance originated from the collapse and rearrangement of its granular fabric and microstructure. Additional evidence for this hypothesis was provided by high-frequency acoustic emissions (approximately 150 kHz), suggesting buckling of the force chains accompanying the particle loss process. Furthermore, the sample experienced greater shear deformations and stress weakening that developed under a larger initial fine content or a higher normal stress. This finding may provide valuable insights into the mechanical behavior of granular soil during the fine particle loss process.

Numerical modeling and parametric analysis of temperature distribution in soil based on water content variation under radio frequency heating for in-situ thermal remediation

Radio frequency heating (RFH) is recognized as an efficient and economical method for volatilizing organic pollutants from contaminated soils. Although some numerical simulations have been conducted to predict temperature changes during RFH, models that account for effects of water content (WC) variation on dielectric properties and temperature evolution in soil were rarely reported. To address this, a three-dimensional numerical model integrating electromagnetic-thermal conversion, heat transfer, and mass transfer was developed with coupling dynamic changes in WC and corresponding impacts on soil properties. The effects of soil types and RFH engineering parameters on temperature evolution and energy utilization were evaluated. The model's temperature prediction was validated using experimental data, indicating that temperature decreases outward from hot electrode, with high-temperature regions forming at the top and bottom regions near electrode. Water evaporation in soil causes a temperature plateau with >76.25 % of energy utilized for heating and evaporating water during 60-d RFH. Moreover, higher soil WC could increase electromagnetic-thermal conversion capability, counteracting the negative impact of increased specific heat capacity on temperature rise. Thermophysical properties of soil are crucial in RFH: sand, with lower specific heat capacity and higher thermal conductivity, results in faster heating rates. While, clay, with higher density and specific heat capacity, results in lower heating rates but greater energy utilization efficiency. Low-power RHF and wider well spacing improve the uniformity of temperature distribution but require more time to reach target temperatures. Moreover, input power influences the magnitude and timing of optimal energy utilization efficiency, while well spacing primarily affects timing. The models developed in this study provide essential guidance for RFH-based soil remediation projects.

Exploring soil pedogenesis through frequency-dependent magnetic susceptibility in varied lithological environments

AbstractThe use of percent frequency-dependent magnetic susceptibility (χfd%) is well-established for detecting superparamagnetic (SP) components in fine-grained soils and sediments. This study employs χfd% as a direct indicator of pedogenetic processes in soils from the Moroccan Rif region. Three soil transects (T1, T2, and T3), each comprising four soil cores with depths reaching 100 to 120 cm, were sampled from distinct lithological formations within an area subject to moderate to intense erosion. A total of 272 soil samples were collected and analyzed using MS2 Bartington Instruments, providing values to calculate χfd% and identify ultrafine ferrimagnetic minerals (SP, < 0.03 μm). In Quaternary fluvial terraces (T1) soils, approximately 60% of the samples indicate a mixture of SP, multidomain (MD), and Single Stable Domain (SSD) magnetic grains, while 30% contained coarser MD grains. Only 10% of the samples exhibit predominantly superparamagnetic (SP) grains. Soils on marly substrates (T2) showed 90% of samples with a combination of SP, MD, and SSD, and just 10% had SP grains. In contrast, soils from Villafranchian sandy deposits displayed χfd% values exceeding 10% in over 50% of samples, indicating that almost all iron components consist of SP grains. Physico-chemical analyses of the soils in profiles T1, T2, and T3 reveal distinct characteristics, including variations in clay content, organic matter, nutrient levels, and proportions of free and total iron. These results are important for understanding soil evolution and pedogenesis, with profiles T1 and T3 showing advanced development marked by high mineral iron, clay, and organic matter content. In contrast, profile T2 reflects a weak stage, influencing nutrient availability and contributing to overall soil dynamics in the respective profiles. The results of this study suggest that magnetic susceptibilities in these samples primarily originate from pedogenetic sources, revealing significantly advanced pedogenesis compared to T1 and T2 soils. The findings of this study align with previous research on soil erosion and degradation in the region, demonstrating that soils developed on terraces and marly substrates are more degraded and less stable than those on sandy substrates. This study underscores the utility of magnetic susceptibility as a rapid and effective indicator for initial soil assessment and gauging the degree of pedogenesis.

Soil Phosphorus Transport in Response to Climate Change at Mid‐High Latitudes Under Intensive Agriculture

ABSTRACTPhosphorus (P) is an important soil element for sustaining plant growth and the integrity of terrestrial ecosystems, and the soil P cycle is strongly influenced by climate change and agricultural activities. However, little is known about how soil P has evolved with climate change and intensive agriculture at mid‐high latitudes, where the soil P cycle is sensitive to climate change. To answer this question, an ecohydrological model (EcoHAT‐P) driven by remote sensing data was used in this study to calculate soil P concentration and loss and was calibrated and validated using 272 soil samples collected in the Sanjiang Plain, a typical mid‐high latitude region with a long history of strong agricultural activity. Soil P concentration and loss, and plant uptake of soil P, were analyzed for the years 2000–2019 and 2020–2040. The results showed that soil total P, soil P loss, and plant P uptake all increased under intensive agriculture. The soil P cycle at mid‐high latitudes was more sensitive to temperature than to precipitation. Increased temperature would increase soil P loss and plant P uptake by 93.94% and 8.16%, respectively, and soil legacy P from intensive agriculture would become the main source even if external P inputs were eliminated. The results highlight the evolution of soil P transport at mid‐high latitudes and clarify the response of soil P cycle to climate change under intensive agriculture.

Sedimentary phosphorus sequential extraction method offers new insight into soil development

Fractionation of soil phosphorus (P) by sequential extraction is one of tools to study the soil development in Earth’s critical zone for characterization of weathering pattern and soil evolution. A sequential extraction method originally developed for sediment with advantage of separating CaCO3-bound P from igneous fluorapatite has been used to quantify different forms of P in New England native forest soils. Total soil phosphorus is fractionated into exchangeable, iron-bound, CaCO3-bound, igneous fluorapatite and refractory organic P pools. Seven surface soil samples were collected from coastal, terrestrial, and lacustrine environments. Total P (TP) ranges from 11.4 to 21.5 μmol P g-1. Averaging over all sampling locations, the largest fraction is igneous fluorapatite with an average concentration of 4.9 ± 1.6 μmol P g-1, accounting for 29.2 ± 9.5 % of TP. Refractory organic P is the second largest fraction with an average concentration of 4.4 ± 1.6 μmol P g-1, accounting for 27.0 ± 9.6 % of TP. Iron-bound P is the third largest fraction with an average concentration of 3.3 ± 1.7 μmol P g-1, accounting for 20.3 ± 10.0 % of TP. CaCO3 -bound P is the second smallest fraction with an average concentration of 2.8 ± 1.4 μmol P g-1, accounting for 16.3 ± 7.5 % of TP. As usual, the smallest fraction is exchangeable P with an average concentration of 1.2 ± 0.8 μmol P g-1, accounting for 7.2 ± 4.3 % of TP. Data from this study are well fitted to a linear model based on the previous sequential extraction data compiled from global soils and sediments samples. The sequential extraction method used here offers an improved procedure that quantify the abundance of igneous fluorapatite as primary P mineral, which provides an estimate of the state and degree of weathering and soil development in the region.

Assessing the compression properties of Gravel-bearing forest soil in northeast China’s seasonally frozen regions under Freeze-thaw cycles and varying gravel content

Due to climate change, human activities and natural disturbances in high-latitude permafrost and seasonally frozen areas are gradually increasing, attracting more attention from scholars. However, research primarily focuses on soil biology and chemistry in these regions, with limited exploration of their mechanical properties, especially compression properties. This study aims to evaluate the effects of gravel content and freeze–thaw (F-T) cycles on the compression properties of coarse-grained layered forest soil from northeast China’s seasonally frozen regions, with the goal of predicting the soil’s compressive changes under heavy mechanical loads. Specifically, using uniaxial confined compression tests (UCCT) on 252 disturbed soil samples (including two soil layers: AB and Bhs; six gravel contents; and seven F-T cycles), three characteristic compression coefficients—precompression stress (σpc), compression index (Cc), and swelling index (Cs)—were measured. Additionally, scanning electron microscopy (SEM) was used to analyze the mesostructure evolution of coarse-grained gravel-bearing soil. Volume changes of samples were measured after 15F-T cycles with varying gravel contents. Results indicate non-linear effects of gravel content and F-T cycles on σpc. Gravel content below 50% positively influences σpc, while content above 50% increases soil pore content, decreasing σpc. Cc and Cs exhibit an approximately negative correlation with gravel content and initially increase followed by a decrease with more F-T cycles. Moreover, the σpc and Cc of the AB layer are higher than those in the Bhs layer, likely due to differences in clay and organic carbon contents. Notably, the observed trends differ from previous studies on other soil types such as farmland and paddy fields. This study fills a gap in understanding the compression characteristics of layered gravel-bearing forest soil in seasonally frozen regions, providing valuable insights for evaluating soil compression in both seasonally frozen and permafrost regions, and understanding mechanical vehicle-soil interactions. It also lays the theoretical groundwork and provides data support for constructing compression models of layered gravel-bearing forest soil.

Климатические и палеоклиматические факторы почвообразования на территории Крымского полуострова

The article provides data on the peculiarities of climate dynamics on the territory of the Crimean Peninsula during the Holocene. Taking into account paleoclimatic data is necessary to predict the direction of evolution of soils and soil cover of the peninsula. It is especially important to take into account the presence of relict properties of soils, taking into account the progressive anthropogenic interference in the processes of modern soil formation. Attention is focused on the need to take into account features unusual for zonal soils when developing Soil management strategies. After all, most often, for objective reasons, a changed or inherited trait disappears forever from the current natural environment and cannot be restored.

Опыт изучения трансформации подзолистых почв в условиях городской среды Севера

The results of soil studies of one of the medium-sized cities of the Russian European Northeast – Syktyvkar (Russia, Komi Republic, middle taiga subzone) are presented in the article. The series from a podzolic soil with a microprofile of podzol (Albic Retisol (Loamic, Protospodic)) typical for the region to various variants of its human transformation in urban conditions – cultivated agrodernovo-podzolic soil (Eutric Albic Retisol (Loamic, Aric, Humic)), represented on the site of the Botanical Garden, to urbodernovo-podzolic soil (Eutric Albic Retisol (Loamic, Humic, Transporti-Novic, Thaptoaric)) and urbostratozem (Urbic Technosol (Loamic, Eutric, Humic Transport)) described in the central part of the city, included in the urban development in the first half of the XX century is considered. In urbo-soil and urbanostratozem the thickness of urbogenic horizons is approximately 40 and 70 cm. It is shown the first stages of the development of the territory of Syktyvkar city are associated with the agricultural impact. Subsequently, the arable horizons overlap with the horizons of the urban cultural layer. In the considered series of soils, weak alkalinization, an increase in the absorbed bases and the total mineralization of the soil solution were found. A noticeable increase in the concentration of organic carbon in modern arable and urban horizons, as well as the thickness of horizons with the organic carbon content of more than 0.6% was revealed. An indirect evidences of changes in the composition of iron and manganese minerals (due to an increase in the pH) with partial preservation of zonal soil formation trends has been found. The revealed direction of soil evolution is consistent with the one previously described in the cities of the European part of Russia.

Enhanced Water Resistance of TiO2-GO-SMS-Modified Soil Composite for Use as a Repair Material in Earthen Sites.

Most earthen sites are located in open environments eroded by wind and rain, resulting in spalling and cracking caused by shrinkage due to constant water absorption and loss. Together, these issues seriously affect the stability of such sites. Gypsum-lime-modified soil offers relatively strong mechanical properties but poor water resistance. If such soil becomes damp or immersed in water, its strength is significantly reduced, making it unviable for use as a material in the preparation of earthen sites. In this study, we achieved the composite addition of a certain amount of sodium methyl silicate (SMS), titanium dioxide (TiO2), and graphene oxide (GO) into gypsum-lime-modified soil and analyzed the microstructural evolution of the composite-modified soil using characterization methods such as XRD, SEM, and EDS. A comparative study was conducted on changes in the mechanical properties of the composite-modified soil and original soil before and after immersion using water erosion, unconfined compression (UCS), and unconsolidated undrained (UU) triaxial compression tests. These analyses revealed the micro-mechanisms for improving the waterproof performance of the composite-modified soil. The results showed that the addition of SMS, TiO2, and GO did not change the crystal structure or composition of the original soil. In addition, TiO2 and GO were evenly distributed between the modified soil particles, playing a positive role in filling and stabilizing the structure of the modified soil. After being immersed in water for one hour, the original soil experienced structural instability leading to collapse. While the water absorption rate of the composite-modified soil was only 0.84%, its unconfined compressive strength was 4.88 MPa (the strength retention rate before and after immersion was as high as 93.1%), and the shear strength was 614 kPa (the strength retention rate before and after immersion was as high as 96.7%).

Characteristics of Bacterial Community Structure and Function in Artificial Soil Prepared Using Red Mud and Phosphogypsum.

The preparation of artificial soil is a potential cooperative resource utilization scheme for red mud and phosphogypsum on a large scale, with a low cost and simple operation. The characteristics of the bacterial community structure and function in three artificial soils were systematically studied for the first time. Relatively rich bacterial communities were formed in the artificial soils, with relatively high abundances of bacterial phyla (e.g., Cyanobacteria, Proteobacteria, Actinobacteriota, and Chloroflexi) and bacterial genera (e.g., Microcoleus_PCC-7113, Rheinheimera, and Egicoccus), which can play key roles in various nutrient transformations, resistance to saline-alkali stress and pollutant toxicity, the enhancement of various soil enzyme activities, and the ecosystem construction of artificial soil. There were diverse bacterial functions (e.g., photoautotrophy, chemoheterotrophy, aromatic compound degradation, fermentation, nitrate reduction, cellulolysis, nitrogen fixation, etc.), indicating the possibility of various bacteria-dominated biochemical reactions in the artificial soil, which can significantly enrich the nutrient cycling and energy flow and enhance the fertility of the artificial soil and the activity of the soil life. The bacterial communities in the different artificial soils were generally correlated with major physicochemical factors (e.g., pH, OM, TN, AN, and AP), as well as enzyme activity factors (e.g., S-UE, S-SC, S-AKP, S-CAT, and S-AP), which comprehensively illustrates the complexity of the interaction between bacterial communities and environmental factors in artificial soils, and which may affect the succession direction of bacterial communities, the quality of the artificial soil environment, and the speed and direction of the development and maturity of the artificial soil. This study provides an important scientific basis for the synergistic soilization of two typical industrial solid wastes, red mud and phosphogypsum, specifically for the microbial mechanism, for the further evolution and development of artificial soil prepared using red mud and phosphogypsum.

Investigating soils of barrows in the Rozumice Forest (SW Poland) – Dynamics of soil and landscape evolution in a Central European loess plateau

Soil properties reflect a host of environmental conditions and land-use patterns. Formation of cultural landscapes may well be studied at barrow cemeteries, which give the opportunity of comparing the properties of buried soils, the material building the mounds and the present-day soil cover. Current archaeo-pedological research on Late Neolithic long-barrows indicates a widespread Early Holocene presence of fertile chernozemic soils in the loess zone in Silesia (SW Poland) and their subsequent transformation (en masse) into Luvisols during the Subboreal and Subatlantic. Since the timing of the transformation remains a question – to elaborate the regional chronosequence of soil evolution – we examined the barrow cemetery in the Rozumice Forest, presumably of early medieval age. We assessed the chronology of the burial mounds and properties of the soil record by analysis of ALS data and magnetometer survey, as well as pedological and archaeobotanical analyses and 14C dating of samples from cores extracted from four of the barrows. The results show that the barrows in the Rozumice Forest were most likely built in the Early Middle Ages (7-9th c. AD) using local Luvisol (clay-illuvial soil) material, after vegetation clearance by fire. The buried Luvisols found beneath the mounds bear traces of human land-use – settlement and/or agriculture during the Late Neolithic, and may be polygenetic, being the result of transformation of Early Holocene chernozemic soils.

Roxarsone reduces earthworm-mediated nutrient cycling by suppressing aggregate formation and enzymic activity in soil with manure application

The application of manure and earthworms are frequently used in fertilization practices to improve C, N, and P cycling in soil, which may be adversely affected by roxarsone (ROX), as an organoarsenical pollutant. To effectively address this issue, in this work, the interactive impacts of ROX and earthworm Eisenia foetida on the aggregate formation, input of organic carbon (OC), and changes in the available N and P following 56-day cultivation were systematically investigated. Compared to the control, earthworms increased the mean weight diameter (MWD) of the soil aggregates from 0.6 to 1.1 mm. Thereby, they activated soil enzymes including catalase (CAT), sucrase (SC), urease (UE), and neutral phosphatase (NP), with the soil's pH decreased to 7.1. Consequently, the values of OC, soluble nitrite (NO3-N), and Olsen-P content were respectively increased by 0.78-, 1.69-, and 0.87- folds in the E treatment (14.3 vs. 25.5 g/kg, 12.8 vs. 33.3 mg/kg, and 7.8 vs. 14.6 mg/kg). Although the changes in the R treatment were slight, ROX reduced the earthworm-mediated improvements of soil fertility during the application of the RE treatment compared to the E treatment, i.e., the values of MWD, OC, NO3-N, and Olsen-P were reduced to 0.9 mm, 20.4 g/kg, 25.4 mg/kg, and 11.6 mg/kg, respectively. From the well-fitted structural equation models, it was demonstrated that earthworms enhanced the aggregate formation and nutrient cycling of OC, NO3-N, and Olsen-P, which were inhibited by ROX. Overall, these adverse effects can be offset by earthworm addition, which can play the dual role of monitor and driver for the soil properties. Our work provides insightful strategies for ROX-bearing manure management.

Effects of water stress on apoplastic barrier formation in soil grown roots differ from hydroponically grown roots: Histochemical, biochemical and molecular evidence.

In root research, hydroponic plant cultivation is commonly used and soil experiments are rare. We investigated the response of 12-day-old barley roots, cultivated in soil-filled rhizotrons, to different soil water potentials (SWP) comparing a modern cultivar (cv. Scarlett) with a wild accession ICB181243 from Pakistan. Water potentials were quantified in soils with different relative water contents. Root anatomy was studied using histochemistry and microscopy. Suberin and lignin amounts were quantified by analytical chemistry. Transcriptomic changes were observed by RNA-sequencing. Compared with control with decreasing SWP, total root length decreased, the onset of endodermal suberization occurred much closer towards the root tips, amounts of suberin and lignin increased, and corresponding biosynthesis genes were upregulated in response to decreasing SWP. We conclude that decreasing water potentials enhanced root suberization and lignification, like osmotic stress experiments in hydroponic cultivation. However, in soil endodermal cell suberization was initiated very close towards the root tip, and root length as well as suberin amounts were about twofold higher compared with hydroponic cultivation.

Numerical Simulation Study of Cavity Formation in Soil under Blast Load

The main applications of civil explosives in soils are soil compaction, mass excavation, and in situ pile creation. The suitability of explosives for each of these applications strongly depends upon the explosive properties and the soil properties. For those reasons, a reliable estimation or process simulation regarding cost efficiency and explosive work ability in the soil with known soil parameters is relevant. This paper presents a numerical simulation study of different types of soil (different amounts of gravel, sand, silt, and clay) under a blast load modeled using Ansys 2020 R1 Autodyn 2D hydrocode, with different types of explosives. The calculated results from the Ansys 2020 R1 Autodyn 2D and the experimental results obtained from the in situ cavity formation caused by blasting are presented. The Jones–Wilkins–Lee (JWL) equation of state parameters was calculated using EXPLO5 V7.01.01 supported by experimental data, while the soil and explosive properties were measured in laboratory and in situ.

DEM Investigation of the Effect of Gradation on the Strength, Dilatancy, and Fabric Evolution of Coarse-Grained Soils

DEM Investigation of the Effect of Gradation on the Strength, Dilatancy, and Fabric Evolution of Coarse-Grained Soils

Accelerated Iron Evolution in Quaternary Red Soils through Anthropogenic Land Use Activities

Iron in soil exists in various valence states and is prone to changes with alterations in soil environmental conditions. Its migration and transformation are crucial for soil formation and understanding soil evolution. This study focuses on Quaternary red soils found in woodland, sparse forest grassland, grassland, and cultivated land located in the semi-humid region of the middle temperate zone. For comparison, buried Quaternary red soil was also examined. A soil reconstruction model was used to quantitatively calculate the variation of different forms of iron in order to analyze various forms of iron composition, migration, and transformation within the soil profile, as well as the evolutionary traits of Quaternary red soils influenced by diverse land use activities. This study found that after exposure and use, iron from the topsoil of buried Quaternary red soil migrated to the subsoil, altering the iron distribution. Free iron and crystalline oxides decreased in the topsoil but increased in specific subsoil layers, with woodland and grassland showing the most significant changes. Silicate-bound iron pooled in the soil weathered to form free iron under different land uses, and poorly crystalline iron oxides transformed into crystalline oxides, with grassland exhibiting the highest transformation intensity. Conversion processes predominated over iron migration in the Quaternary red soils. The evolution of Quaternary red soils can be divided into three stages, marked by changes in iron composition and crystallization due to anthropogenic land use activities. Initially, during 140−94 ka BP, iron composition was stable. Then, between 94–24 ka BP, plant decomposition formed iron–metal complexes, releasing and crystallizing poorly crystalline iron oxides. Finally, from 24 ka BP to the present, anthropogenic activities intensified, increasing the formation and conversion rates of these oxides. This study quantifies iron migration and transformation in Quaternary red soils, providing insights for sustainable soil management, especially in regions where human activities have accelerated iron evolution. Based on these findings, the following policy recommendations are proposed: implement sustainable land use practices, encourage land management strategies that preserve natural vegetation, promote research on soil management techniques, develop and implement regulatory policies, and support educational programs to maintain the health and stability of Quaternary red soils, particularly in regions prone to accelerated iron evolution due to anthropogenic activities.

Quantifying mine waste rock physical weathering rate and processes for improved geomorphic post-mining landforms

Erodibility of landform surfaces depends on several factors and numerical methods are needed to predict erosion and landform evolution particularly for post-mining landscapes. Surface armouring caused by immobile coarse particles tends to reduce the erosion potential of landform surfaces significantly. However, the breakdown of such material through weathering could destabilise this armour and lead to high erosion rates. Hence, the surface erodibility of newly constructed landforms (here we focus on post-mining landforms) can rapidly change over a few years to decades. At present, it is difficult to predict with certainty the rate, or in some cases the dominant processes and pathways, of soil erodibility and soil production over post-mining landscape design lifetimes (typically 100–1000 years). To improve our understandings of soil evolution and its relationship to soil erosion, data is needed to determine the rate at which fine transportable material is produced from the weathering of larger, non-transportable particles, the resultant fragment size distribution together, and how that distribution evolves over time.Here, laboratory weathering experiments were conducted for four different materials from a single coal mine in the Bowen Basin, Queensland, Australia. Wetting and drying cycles were found to rapidly weather all materials. After 32 wet and dry cycles, all materials had a less coarse particle size distribution than at the start. Heating and cooling had no measurable influence on weathering. Due to the rapid reduction of particle sizes caused by high weathering rates, the materials examined would not provide surface armour capability. A new mathematical methodology was developed to determine the weathering parameters for an existing numerical model based on the weathering mechanism and particle size-dependent weathering rate. Although the materials were collected from the same geographical location, they undergo weathering through different mechanisms and rates. Size dependent weathering rate analysis showed that most samples have high weathering rates for large particles and lower weathering rates for smaller particles. The methods used here are simple and inexpensive and can be easily employed to assess mine rehabilitation materials' weathering and armour potential.

Experimental study on the strength characteristics and micro-mechanism of fluid solidified soil under carbonation

The carbonation of cementitious materials with CO2 was utilised to prepare fluid solidified soil, and the characteristics of fluid solidified soil were investigated. Experimental tools such as flow extensibility, unconfined compressive strength, thermogravimetric analysis, and scanning electron microscopy were employed to explore the influence laws of different carbon dioxide pressures, cement dosages, and initial water contents on the strength properties and microstructural evolution of fluid consolidated soils. The results showed that with the increase of CO2 pressure, the flow characteristics of carbonated fluid solidified soil decreased and the unconfined compressive strength increased. This is due to the fact that after the carbonation process, the formation of carbonation products such as calcium carbonate and hydration products in the fluid solidified soil significantly improves the microstructure of the soil, which is the main reason for the increase in its strength. In addition, the carbonation test revealed that the ratio of the amount of CO₂ generated to the mass of cement was as high as 18.36 % under the condition of CO₂ pressure up to 0.20 MPa, which fully proved the high efficiency of the carbonation technology. Therefore, the carbonation technology has great potential and broad application prospects in optimising the performance of fluid solidified soil as well as achieving effective carbon sequestration.

Unravelling the thermodynamic properties of soil ecosystems in mature beech forests

Thermodynamics is a vast area of knowledge with a debatable role in explaining the evolution of ecosystems. In the case of soil ecosystems, this role is still unclear due to difficulties in determining the thermodynamic functions that are involved in the survival and evolution of soils as living systems. The existing knowledge is largely based on theoretical approaches and has never been applied to soils using thermodynamic functions that have been experimentally determined. In this study, we present a method for the complete experimental thermodynamic characterization of soil organic matter. This method quantifies all the thermodynamic functions for combustion and formation reactions which are involved in the thermodynamic principles governing the evolution of the universe. We applied them to track the progress of soil organic matter with soil depth in mature beech forests. Our results show that soil organic matter evolves to a higher degree of reduction as it is mineralized, yielding products with lower carbon but higher energy content than the original organic matter used as reference. These products have higher entropy than the original one, demonstrating how the soil ecosystem evolves with depth, in accordance with the second law of thermodynamics. The results were sensitive to soil organic matter transformation in forests under different management, indicating potential applicability in elucidating the energy strategies for evolution and survival of soil systems as well as in settling their evolutionary states.

Long-term Application of Agricultural Amendments Regulate Hydroxyl Radicals Production during Oxygenation of Paddy Soils.

Hydroxyl radicals (•OH) play a significant role in contaminant transformation and element cycling during redox fluctuations in paddy soil. However, these important processes might be affected by widely used agricultural amendments, such as urea, pig manure, and biochar, which have rarely been explored, especially regarding their impact on soil aggregates and associated biogeochemical processes. Herein, based on five years of fertilization experiments in the field, we found that agricultural amendments, especially coapplication of fertilizers and biochar, significantly increased soil organic carbon contents and the abundances of iron (Fe)-reducing bacteria. They also substantially altered the fraction of soil aggregates, which consequently enhanced the electron-donating capacity and the formation of active Fe(II) species (i.e., 0.5 M HCl-Fe(II)) in soil aggregates (0-2 mm), especially in small aggregates (0-3 μm). The highest contents of active Fe(II) species in small aggregates were mainly responsible for the highest •OH production (increased by 1.7-2.4-fold) and naphthalene attenuation in paddy soil with coapplication of fertilizers and biochar. Overall, this study offers new insights into the effects of agricultural amendments on regulating •OH formation in paddy soil and proposes feasible strategies for soil remediation in agricultural fields, especially in soils with frequent occurrences of redox fluctuations.