Soil Aquifer Treatment Research Articles

Assessment of an arid region soil capacity on natural attenuation of municipal treated wastewater: a column experiment using soil of Varamin area, Iran

Soil aquifer treatment (SAT) is an effective indirect technique for wastewater reuse. The present study aims at assessing the soil capacity in arid region of Varamin on natural attenuation of inorganic constituents of municipal treated wastewater of Tehran City. In order to simulate SAT pond, four columns of 30 cm in height and 4 cm in diameter were filled with sandy loam soil taken from artificial recharge pond in Varamin plain. These columns were recharged by secondary treated wastewater from Shahre-Rey treatment plant under the plan of 12-h wetting and drying cycles. During the experiment, 50 pore volume passed through each column. The pH, EC, TDS, SAL, SAR, major ions, nitrate, phosphate and trace elements were measured in influent and effluent samples. The concentration of Na+, Ca2+, Mg2+, Cl− and SO42− increased in effluent samples due to a washout process and dissolution of minerals. The soil could only attenuate NO3−, K+, Rb and PO43− with the percentage of 18.4, 24.6, 67.7 and 83.6, respectively. The soil of studied area is rich in Cr, Ni, Sr, Pb, Cu, Zn, Ba and Rb. The concentrations of all mentioned trace elements, with the exception of Rb, have increased in the effluent samples with respect to influent. Also, the quality indices of TDS, SAL and SAR have increased 10.6, 25.2 and 8.7%, respectively, in effluent. Soil column samples, at the end of experiment, contain high amounts of major and trace elements. Consequently, there is a potential risk for groundwater contamination in long-term recharge.

Geochemical Processes During Managed Aquifer Recharge With Desalinated Seawater

AbstractWe study geochemical processes along the variably‐saturated zone during managed aquifer recharge (MAR) with reverse‐osmosis desalinated seawater (DSW). The DSW, post‐treated at the desalination plant by calcite dissolution (remineralization) to meet the Israeli water quality standards, is recharged into the Israeli Coastal Aquifer through an infiltration pond. Water quality monitoring during two MAR events using suction cups and wells inside the pond indicates that cation exchange is the dominant subsurface reaction, driven by the high Ca2+ concentration in the post‐treated DSW. Stable isotope analysis shows that the shallow groundwater composition is similar to the recharged DSW, except for enrichment of Mg2+, Na+, Ca2+, and . A calibrated variably‐saturated reactive transport model is used to predict the geochemical evolution during 50 years of MAR for two water quality scenarios: (i) post‐treated DSW (current practice) and (ii) soft DSW (lacking the remineralization post‐treatment process). The latter scenario was aimed to test soil‐aquifer‐treatment (SAT) as an alternative post‐treatment technique. Both scenarios provide an enrichment of ∼2.5 mg L−1 in Mg2+ due to cation exchange, compared to practically zero Mg2+ currently found in the Israeli DSW. Simulations of the alternative SAT scenario provide Ca2+ and remineralization due to calcite dissolution at levels that meet the Israeli standard for DSW. The simulated calcite content reduction in the sediments below the infiltration pond after 50 years of MAR was low (<1%). Our findings suggest that remineralization using SAT for DSW is a potentially sustainable practice at MAR sites overlying calcareous sandy aquifers.

Soil Aquifer Treatment: An initiative for a sustainable drinking water source

Soil Aquifer Treatment: An initiative for a sustainable drinking water source

Optimal Remediation Scheme for a Wastewater Recharge Site: Contaminants Fate and Transport Model.

A 3-dimensional hydrologic groundwater flow and contaminant transport model was developed to address the feasibility and relevant time-scales for remediation of a large soil aquifer treatment (SAT) site for domestic wastewater. The model accounted for a range of organic pollutant retardation factors and biodegradation kinetics. In order to detect the effect of the most retained and the most refracted/recalcitrant pollutants, it was crucial to model fractions of different properties rather than with average set properties. Four aquifer remediation scenarios, including two active washing procedures and two involving natural attenuation, were evaluated. The remediation efficiencies, in terms of residual plume size and mass of pollutant washout, were compared to each other and to the current operation scheme. According to the results, remediation mainly via natural attenuation rather than some form of intense pump and treat technology, is feasible, unlike the situation with hazardous waste sites. Enforced washout becomes less efficient with time due to increasing retardation of the residual pollutants. Therefore, pollution containment with natural biodegradation, which removed 95% of the emerging contaminants within 30 to 40 years was found to be the most valuable remediation scheme.

Massive arrival of desalinated seawater in a regional urban water cycle: A multi-isotope study (B, S, O, H)

“Man-made” or unconventional freshwater, like desalinated seawater or reclaimed effluents, is increasingly introduced into regional water cycles in arid or semi-arid countries. We show that the breakthrough of reverse osmosis-derived freshwater in the largely engineered water cycle of the greater Tel Aviv region (Dan Region) has profoundly changed previous isotope fingerprints. This new component can be traced throughout the system, from the drinking water supply, through sewage, treated effluents, and artificially recharged groundwater at the largest Soil-Aquifer Treatment system in the Middle East (Shafdan) collecting all the Dan region sewage. The arrival of the new water type (desalinated seawater) in 2007 and its predominance since 2010 constitutes an unplanned, large-scale, long-term tracer test and the monitoring of the breakthrough of desalination-specific fingerprints in the aquifer system of Shafdan allowed to get new insights on the water and solute flow and behavior in engineered groundwater systems. Our approach provides an investigation tool for the urban water cycle, allowing estimating the contribution of diverse freshwater sources, and an environmental tracing method for better constraining the long-term behavior and confinement of aquifer systems with managed recharge.

Removal of Nitrogen and COD from Reclaimed Water during Long-Term Simulated Soil Aquifer Treatment System under Different Hydraulic Conditions

Reclaimed water is an important supplementary source for fresh water. Purification is necessary prior to utilization in order to minimize the pollution and human-health risk. A three-year experiment was carried out to study the removal of nitrogen and organics through a simulated soil aquifer treatment (SAT) system under continuous wetting and wetting/drying conditions. The removal performance of nitrogen and chemical oxygen demand (COD) was improved in the wetting/drying column. The average removal efficiencies of the three years were 51% and 78% for the NO3–N, 41% and 51% for the NH4–N, and 40% and 50% for the COD in the continuous wetting and wetting/drying columns. Nitrogen and COD removal mainly took place within the top 20 cm of the columns, which was highly correlated with the distribution of microorganisms. The amount of microorganisms was also positively correlated with the content of organic matter and dissolved oxygen (DO) in both soil columns. NO3–N can be removed effectively via aerobic denitrifying bacteria as the DO concentration was 3–6 mg/L. DO and NO3–N were simultaneously reduced as the electron acceptors for COD degradation, and DO only accounted for 40% of total electron acceptor in COD degradation for the continuous wetting column. Nitrogen and COD can be effectively and steadily removed from reclaimed water during the long-term operation of a SAT system.

Sequential biofiltration – A novel approach for enhanced biological removal of trace organic chemicals from wastewater treatment plant effluent

Recent studies revealed the benefits of oligotrophic and oxic conditions for the biological removal of many trace organic chemicals (TOrCs) during soil-aquifer treatment. These findings indicate an unused tuning potential that might also be applicable in engineered biofiltration systems with drastically reduced hydraulic retention times for an enhanced mitigation of TOrCs during wastewater treatment. This study introduces the novel approach of sequential biofiltration (SBF) for the advanced treatment of secondary effluent using two granular media filters operated in series with an intermediate aeration step aiming for oxic and oligotrophic conditions in the second filter stage. Results from the experiments conducted at pilot-scale confirm a reduced substrate availability and predominantly oxic conditions in the second filter stage of the SBF setup. An increased removal of several TOrCs was observed in an SBF system as compared to a conventional single-stage biofiltration unit operated at the same overall empty bed contact time (EBCT). Short-term tests with varying EBCTs in the first filter stage revealed a high degree of system robustness of TOrC mitigation when confronted with sudden hydraulic load variations. Higher removal of several TOrCs at increased EBCTs in the second filter stage indicates that EBCT might play a crucial role for the degradation of certain compounds.

Emerging organic pollutants in the vadose zone of a soil aquifer treatment system: Pore water extraction using positive displacement

Trace organic compounds in effluents, water streams and aquifers are amply reported. However, the mobile pool of Emerging Organic Contaminants (EOCs) in the deep parts of the vadose zone is hard to estimate, due to difficulties in extraction of sufficient quantity of pore water. Here, we present a new methodology for depth profiling of EOCs in pore water by Positive Displacement Extraction (PDE): Pore water extraction from unsaturated soil samples is carried out by withdrawal of soil cores by direct-push drilling and infiltrating the core by organics free water. We show that EOC concentrations in the water eluted in the plateau region of the inverse breakthrough curve is equal to their pore water concentrations. The method was previously validated for DOC extraction, and here the scope of the methodology is extended to pore water extraction for organic pollutants analysis. Method characteristics and validation were carried out with atrazine, simazine, carbamazepine, venlafaxine, O-desmethylvenlafaxine and caffeine in the concentration range of several ng to several μg/liter. Validation was carried out by laboratory experiments on three different soils (sandy, sandy-clayey and clayey).Field studies in the vadose zone of a SAT system provided 27 m deep EOC profiles with less than 1.5 m spatial resolution. During the percolation treatment, carbamazepine remained persistent, while the other studied EOCs were attenuated to the extent of 50–99%.The highest degradation rate of all studied EOCs was in the aerobic zone. EOC levels based on PDE and extraction by centrifugation were compared, showing a positive bias for centrifugation.

Impact of inoculum sources on biotransformation of pharmaceuticals and personal care products

Limited knowledge of optimal microbial community composition for PPCP biotreatment, and of the microbial phylotypes that drive biotransformation within mixed microbial communities, has hindered the rational design and operation of effective and reliable biological PPCP treatment technologies. Herein, bacterial community composition was investigated as an isolated variable within batch biofilm reactors via comparison of PPCP removals for three distinct inocula. Inocula pre-acclimated to model PPCPs were derived from activated sludge (AS), ditch sediment historically-impacted by wastewater treatment plant effluent (Sd), and material from laboratory-scale soil aquifer treatment (SAT) columns. PPCP removals were found to be substantially higher for AS- and Sd-derived inocula compared to the SAT-derived inocula despite comparable biomass. Removal patterns differed among the 6 model compounds examined (diclofenac, 5-fluorouracil, gabapentin, gemfibrozil, ibuprofen, and triclosan) indicating differences in biotransformation mechanisms. Sphingomonas, Beijerinckia, Methylophilus, and unknown Cytophagaceae were linked with successful PPCP biodegradation via next-generation sequencing of 16S rRNA genes over time. Results indicate the criticality of applying engineering approaches to control bacterial community compositions in biotreatment systems.

Evaluation of PFCA removal by SAT using a pilot-scale reactor

Wastewater reuse using soil aquifer treatment (SAT) is a rational and realistic solution in countries and regions with limited freshwater resources. The behaviour and removal of perfluoroalkyl carboxylic acids (PFCAs) under long hydraulic retention times (HRTs) in SAT may warrant further investigation. In this study, actual treated effluent from a wastewater treatment plant (WWTP) was continuously treated using a pilot-scale SAT reactor with a designed HRT of 30 days, located in the WWTP; PFCA removal characteristics were investigated based on a 14-month monitoring period. Continuous SAT reactor operations were accomplished for 30 months under the designed HRT (28 days, as calculated by a tracer test); stable treatments were achieved during the period, represented by dissolved organic matter removal from 3.94 mgC/L to 0.701 mgC/L. Removal of PFCAs by SAT under an HRT of 28 days was found to be difficult, as indicated by perfluorooctanoic acid level from 18.4 to 19.0 ng/L. In addition, PFCA concentrations may be increased after SAT, probably due to the influences of PFCA precursors; this is indicated by the increase in perfluorononanoic acid from 11.6 to 14.1 ng/L. Based on the guideline values, further removal of PFCAs in SAT-treated effluent may be required.

The Role of Soil Aquifer Treatment (SAT) for Effective Removal of Organic Matter, Trace Organic Compounds and Microorganisms from Secondary Effluents Pre-Treated by Ozone

ABSTRACTSoil aquifer treatment (SAT) is an effective natural and economically feasible tertiary treatment for wastewater reuse. An innovative hybrid process based on biofiltration, ozonation and short SAT (sSAT, with ~22 days retention time) was demonstrated in a 6 m3/hr pilot system to remove emerging trace organic compounds (TrOCs), organic matter and control Mn2+ dissolution in reclaimed water. The biofiltration stage was proposed for nitrification of ammonia as well as removal of dissolved and particulate organic matter (DOM and POM), to enable efficient ozonation of secondary effluents. The pilot system was operated in two modes, where samples were periodically taken from all pilot stages to observe changes in product water quality. At first (Mode 1), biofiltered effluents were infiltrated through sSAT (i.e., no ozonation prior infiltration). During this operation, ammonia, nitrite and phosphate were completely removed, and pathogens were highly reduced. In addition, all measured TrOCs were effectively removed after sSAT, besides the persistent TrOCs Carbamazepine (CBZ) and Iodine-organic contrast media Iopamidol (IPDL). In Mode 2, biofiltered and ozonated (1.0–1.2 mg ozone/mg DOC) effluents were infiltrated through sSAT. In the final reclaimed product, values of DOC, UVA and Mn2+ were reduced to 0.8 mg/L, 2.2 L/m, and 29–35 µg/L, respectively. Furthermore, ammonia and nitrite were not detected in the product, and good bacterial quality was obtained. Following 56–75 days of operation at Mode 2, all TrOCs were reduced down to <100 ng/L. The delay in the effect of the pretreatment stages on TrOCs removal by sSAT (>56 days instead of ~22 days) could be explained by their displacement retardation in the upper soil layers of the pilot SAT (0–25 cm). In-depth sampling in the observation well after 111 days at Mode 2 showed homogeneity along the overall perforated section of the well (from −14 to −26 m) with 0.7–0.9 mg/L DOC, 2.1–2.2 1/m UVA and <10 ng/L CBZ. This result proved that the ozonated water completely covered the area around the observation well and positively affected the quality of the reclaimed water.

Multi-criteria Decision Support System (DSS) for optimal locations of Soil Aquifer Treatment (SAT) facilities

Managed Aquifer Recharge is a wide-spread well-established groundwater engineering method which is largely seen as sound and sustainable solution to water scarcity hydrologically sensitive areas, such as the Circum Mediterranean. The process of site selection for the installation of a MAR facility is of paramount importance for the feasibility and effectiveness of the project itself, especially when the facility will include the use of waters of impaired quality as a recharge source, as in the case of Soil-Aquifer-Treatment systems.The main objective of this study is to present the developed framework of a multi-criteria Decision Support System (DSS) that integrates within a dynamic platform the main groundwater engineering parameters associated with MAR applications together with the general geographical features which determine the effectiveness of such a project. The proposed system will provide an advanced coupled DSS-GIS tool capable of handling local MAR-related issues -such as hydrogeology, topography, soil, climate etc., and spatially distributed variables -such as societal, economic, administrative, legislative etc., with special reference to Soil-Aquifer-Treatment technologies.

Quantification of dissolved organic matter in pore water of the vadose zone using a new ex-situ positive displacement extraction

Quantification of dissolved organic carbon (DOC) in pore water is vital for understanding the transport of solutes and the fate of contaminants. However, the extraction of pore water from saturated soils, and even more so, from unsaturated soils without an artificial increase in the DOC content is challenging. To this end, we have established a methodology for pore water extraction from unsaturated and saturated soils based on the displacement of the pore water from cores withdrawn from the ground by direct-push drilling machines. The displacement extraction is performed by introducing distilled water at the top of a liner filled with soil core and collecting the displaced eluent from the bottom. This positive displacement extraction (PDE) method was compared to pore water extraction by centrifugation for the analysis of DOC. Method validation was carried out with various DOC levels using different flow rates and three different soil types: sandy, sandy-clayey and clayey. The limit of detection for the suggested method was <0.22mgL−1 for all soil types, and for all studied saturation levels (>15%) under flow rates lower than 1mLmin−1. Extraction by centrifugation gave biased, unacceptable results throughout the studied DOC range (0–25mgL−1).Detailed parametric dependence by mobile – immobile modeling showed that for most soils and saturation levels collection of the first 10% of the pore water initially present in the core will introduce a bias of less 8% in DOC. For clayey soils with an exceedingly high immobile water fraction, a pedotransfer parameter estimation or comprehensive column tests should be carried out in order to estimate accurately the collectible water fraction and assure accurate prediction of the DOC level.Field studies that were carried out in a Soil Aquifer Treatment system provided 30m deep DOC profiles with <1.5m spatial resolution, a resolution that is unattainable by alternative techniques.

A Suitable Tool for Sustainable Groundwater Management

Artificial recharge is used to increase the availability of groundwater storage and reduce saltwater intrusion in coastal aquifers, where pumping and droughts have severely impaired groundwater quality. The implementation of optimal recharge methods requires knowledge of physical, chemical, and biological phenomena involving water and wastewater filtration in the subsoil, together with engineering aspects related to plant design and maintenance operations. This study uses a novel Decision Support System (DSS), which includes soil aquifer treatment (SAT) evaluation, to design an artificial recharge plant. The DSS helps users make strategic decisions on selecting the most appropriate recharge methods and water treatment technologies at specific sites. This will enable the recovery of safe water using managed aquifer recharge (MAR) practices, and result in reduced recharge costs. The DSS was built using an artificial intelligence technique and knowledge-based technology, related to both quantitative and qualitative aspects of water supply for artificial recharge. The DSS software was implemented using rules based on the cumulative experience of wastewater treatment plant engineers and groundwater modeling. Appropriate model flow simulations were performed in porous and fractured coastal aquifers to evaluate the suitability of this technique for enhancing the integrated water resources management approach. Results obtained from the AQUASTRESS integrated project and DRINKADRIA IPA CBC suggest the most effective strategies for wastewater treatments prior to recharge at specific sites.

Impacts of Accumulated Particulate Organic Matter on Oxygen Consumption and Organic Micro-Pollutant Elimination in Bank Filtration and Soil Aquifer Treatment

Bank filtration (BF) and soil aquifer treatment (SAT) are efficient natural technologies in potable water reuse systems. The removal of many organic micro-pollutants (OMPs) depends on redox-conditions in the subsoil, especially on the availability of molecular oxygen. Due to microbial transformation of particulate and dissolved organic constituents, oxygen can be consumed within short flow distances and induce anoxic and anaerobic conditions. The effect of accumulated particulate organic carbon (POC) on the fate of OMPs in BF and SAT systems is not fully understood. Long-term column experiments with natural sediment cores from the bank of Lake Tegel and from a SAT basin were conducted to investigate the impact of accumulated POC on dissolved organic carbon (DOC) release, on oxygen consumption, on mobilization of iron and manganese, and on the elimination of the organic indicator OMPs. The cores were fed with aerated tap water spiked with OMPs to exclude external POC inputs. Complete oxygen consumption within the first infiltration decimeter in lake sediments caused mobilization of iron, manganese, and DOC. Redox-sensitive OMPs like diclofenac, sulfamethoxazole, formylaminoantipyrine, and gabapentin were eliminated by more than 50% in all sediment cores, but slightly higher residual concentrations were measured in effluents from lake sediments, indicating a negative impact of a high oxygen consumption on OMP removal.

Multi-criteria analysis of site selection for groundwater recharge with treated municipal wastewater.

Geographic information systems (GIS) and remote sensing techniques are used as a decision support system to identify potential soil aquifer treatment (SAT) sites for groundwater recharge of Kerman aquifer, which is located in the southeast of Iran. These sites are identified using a single-objective multi-criteria analysis. To ensure technical feasibility, environmental sustainability, social acceptability and economical viability a number of criteria are considered for the site selection. The criteria selected for the different variables and acceptable ranges are based on standards published in national and international guidelines and technical documents. Multi-criteria evaluation was performed combining all produced thematic maps by means of the weighted index overlay method in order to select sites meeting all the criteria. The resulting map of this analysis shows potential sites are located in the north, southwest and southeast of the study area. Considering field observations, a potential site, which is located in the southwest of the study area, is proposed as the most suitable site for SAT. The result indicates that the study area has sufficient required suitable space for groundwater recharge with treated wastewater.

Soil aquifer treatment of secondary effluents and combined sewer overflows in highly permeable soils typical of southwestern Ontario

Wastewater reclamation is becoming an important alternative for sustainable water resources management and building climate change resiliency in many regions around the world. This research investigated the polishing of secondary effluents and combined sewer overflows (CSOs) by a laboratory-scale soil aquifer treatment considering local soils and wastewater characteristics of southwestern Ontario. Results show that high permeability soils of southwestern Ontario, have the ability to polish secondary effluents in terms of dissolved organic carbon, Escherichia coli, and total coliforms. Regarding the simulated CSOs, low to moderate improvements of wastewater quality were observed. Denitrification of secondary effluents improved significantly by the addition of readily available organic matter, which supports the importance of protecting recharge wetlands for groundwater quality protection. Soil aquifer treatment in southwestern Ontario is a feasible alternative for the recharge of non-potable and potable aquifers with secondary effluents. However, for potable aquifers further treatment of wastewater effluents may be required.

Assessing the Impact of Recycled Water Quality and Clogging on Infiltration Rates at A Pioneering Soil Aquifer Treatment (SAT) Site in Alice Springs, Northern Territory (NT), Australia

Infiltration techniques for managed aquifer recharge (MAR), such as soil aquifer treatment (SAT) can facilitate low-cost water recycling and supplement groundwater resources. However there are still challenges in sustaining adequate infiltration rates in the presence of lower permeability sediments, especially when wastewater containing suspended solids and nutrients is used to recharge the aquifer. To gain a better insight into reductions in infiltration rates during MAR, a field investigation was carried out via soil aquifer treatment (SAT) using recharge basins located within a mixture of fine and coarse grained riverine deposits in Alice Springs, Northern Territory, Australia. A total of 2.6 Mm3 was delivered via five SAT basins over six years; this evaluation focused on three years of operation (2011–2014), recharging 1.5 Mm3 treated wastewater via an expanded recharge area of approximately 38,400 m2. Average infiltration rates per basin varied from 0.1 to 1 m/day due to heterogeneous soil characteristics and variability in recharge water quality. A treatment upgrade to include sand filtration and UV disinfection (in 2013) prior to recharge improved the average infiltration rate per basin by 40% to 100%.

The Use of Stable Water Isotopes as Tracers in Soil Aquifer Treatment (SAT) and in Regional Water Systems

This study examines the feasibility of tracing and quantifying the progress of different water sources along the water–effluent–SAT (Soil Aquifer Treatment) chain using 2H and 18O isotopes. The research was conducted at the Dan Region Reclamation Plant (Shafdan), which reclaims ~135 MCM/year of effluent for irrigation. Water samples representing different stages along the chain were taken in two surveys during 2010–2011 and 2014. δ18O and δ2H values were used for mixing ratios (MR) calculations, and compared with calculated MRs using chloride and carbamazepine concentrations. The results showed a relative enrichment of 18O and 2H in the Israeli water system compared to the regional groundwater, due to the addition of massive quantities of desalinated water. A linear correlation for δ2H vs. δ18O with a slope of 4.5 was found for the different freshwater sources and their mixing products, suggesting evaporation-mixing effects. MR values indicate on the spreading of new type of effluent originating from desalinated water in the aquifer. A dilution model explains the isotopic compositions in the water system and of the Shafdan effluents. Water isotopes have an advantage over other tracers, due to the ability to predict their ratio in the supply system and in the effluent, based on mass balance calculations and on knowledge of water supply volumes.

Development of multi-criteria decision support system (DSS) coupled with GIS for identifying optimal locations for soil aquifer treatment (SAT) facilities

Managed Aquifer Recharge is a wide-spread well-established groundwater engineering method which is largely seen as an alternative potential major source for water and this conclusion becomes even more pronounced in semi-arid and/or arid areas, such as the Mediterranean Basin. The process of site selection for the installation of a MAR facility is of paramount importance for the feasibility and effectiveness of the project itself, especially when the facility will include the use of waters of impaired quality as a recharge source. The main objective of this study is to present the developed framework of a multicriteria Decision Support System (DSS) that integrates within a dynamic platform: the main groundwater engineering parameters associated with MAR applications together with the general geographical features which determine the effectiveness of such a project. The proposed system will provide an advanced coupled DSS-GIS tool capable of handling local MAR-related issues -such as hydrogeology, topography, soil, climate etc., and spatially distributed variables -such as societal, economic, administrative, legislative etc., with special reference to Soil-Aquifer- Treatment technologies. The new SAT-selection tool in question is integrated in ArcGIS software -within a user friendly environment- where data can be processed and displayed using Arc tools for spatial analysis.