Architecture principles affect a software system holistically. Given their alignment with a business strategy, they should be incorporated within the validation process covering aspects of sustainability. However, current research discusses the influence of architecture principles on sustainability in a limited context. Our objective was to introduce a reusable process for monitoring and evaluating the impact of architecture principles on sustainability from a software architecture perspective. We sought to demonstrate the application of such a process in professional practice. A qualitative case study was conducted in the context of a Dutch airport management company. Data collection involved a case analysis and the execution of two rounds of expert interviews. We (i) identified a set of case-related key performance indicators, (ii) utilized commonly accepted measurement tools, and (iii) employed graphical representations in the form of spider charts to monitor the sustainability impacts. The real-world observations were evaluated through a concluding focus group. Our findings indicated that architecture principles were a feasible mechanism with which to address sustainability across all different architecture layers within the enterprise. The experts considered the sustainability analysis valuable in guiding the software architecture process towards sustainability. With the emphasis on principles, we facilitate industry adoption by embedding sustainability in existing mechanisms.