Ratio Of SO2 Research Articles

Experimental Study on Softening High-Calcium Sulfate Reverse Osmosis Concentrate Using Induced Crystallization Method

Reverse osmosis (RO) concentrate often contains high levels of sulfate and calcium ions due to the use of antiscalants, leading to significant calcium sulfate supersaturation and creating favorable conditions for induced crystallization. This study utilized a combination of static and dynamic experiments to investigate the key factors influencing the removal of calcium sulfate from RO concentrate via induced crystallization. The static experiments examined the effects of seed crystal concentration, stirring speed, reaction temperature, and the molar ratio of SO42− to Ca2+ on removal efficiency, with response surface methodology (RSM) employed to analyze the interactions among these factors. In the dynamic experiments, gypsum particles were used as seed crystals in a fluidized bed reactor to study the impact of initial seed crystal dosage and influent flow rate on the removal performance. Optimization strategies for stable operation were also explored. The static experiments revealed that seed crystal concentration was the most critical factor affecting removal efficiency. Under optimal conditions, the calcium ion concentration in the treated water could be reduced to 453 mg/L, achieving a removal rate of 63.8%. In the dynamic experiments, the effluent calcium ion concentration was reduced to 724 mg/L, with a removal rate of 52.5%. However, prolonged continuous operation led to a gradual increase in effluent calcium ion levels, which could be mitigated by recycling seed crystals from the settling zone back to the reaction zone. Characterization of the induced seed crystals and simulation calculations demonstrated that Ca2+ and SO42− reacted to form calcium sulfate crystals, primarily as CaSO4·2H2O, which adhered to the seed crystal surfaces. The growth of the seed crystals, indicated by an increase in particle size, correlated with the volume of water treated. This study provides valuable insights and data for the application of calcium sulfate-induced crystallization as a method to reduce sulfate and calcium ion concentrations in RO concentrate, offering a viable approach to water softening and resource recovery.

SO2 and OCS toward high-mass protostars

Context. OCS and SO2 are both major carriers of gaseous sulfur and are the only sulfurated molecules detected in interstellar ices to date. They are thus the ideal candidates for exploring the evolution of the volatile sulfur content throughout the different stages of star formation. Aims. We aim to investigate the chemical history of interstellar OCS and SO2 by deriving a statistically significant sample of gas-phase column densities toward massive protostars and comparing them to observations of gas and ices toward other sources, from dark clouds to comets. Methods. We analyzed a subset of 26 line-rich massive protostars observed by ALMA in Band 6 as part of the High Mass Protocluster Formation in the Galaxy (ALMAGAL) survey. Column densities were derived for OCS and SO2 from their rare isotopologs O13CS and 34SO2 toward the compact gas around the hot cores. We compared the abundance ratios of gaseous OCS, SO2, and CH3OH with ice detections toward both high- and low-mass sources as well as dark clouds and comets. Results. We find that gas-phase column density ratios of OCS and SO2 with respect to methanol remain fairly constant as a function of luminosity between low- and high-mass sources, despite their very different physical conditions. In our dataset, OCS and SO2 are weakly correlated. The derived gaseous OCS and SO2 abundances relative to CH3OH are overall similar to protostellar ice values, with a significantly larger scatter for SO2 than for OCS. Cometary and dark-cloud ice values agree well with protostellar gas-phase ratios for OCS, whereas higher abundances of SO2 are generally seen in comets compared to the other sources. Gaseous SO2/OCS ratios are consistent with ices toward dark clouds, protostars, and comets, albeit with some scatter. Conclusions. The constant gas-phase column density ratios throughout low- and high-mass sources indicate an early-stage formation before intense environmental differentiation begins. Icy protostellar values are similar to the gas-phase medians and are compatible with an icy origin for these species followed by thermal sublimation. The larger spread in SO2 compared to OCS ratios with respect to CH3OH is likely due to a more water-rich chemical environment associated with the former, as opposed to a CO-rich origin for the latter. Post-sublimation gas-phase processing of SO2 can also contribute to the large spread. Comparisons to ices in dark clouds and comets point to a significant inheritance of OCS from earlier to later evolutionary stages.

Evaluating The Impact of Increased Heavy Oil Consumption on Urban Pollution Levels through Isotope (δ13C, δ34S, 14C) Composition

The impact of heavy fuel oil (HFO) on the chemical and isotopic composition of submicron particulate matter (PM1) was investigated. For this purpose, we conducted an analysis of water-soluble inorganic ions (WSIIs) and multiple isotopes (δ34S, δ13C, 14C) of PM1 and SO2 collected during two heating periods: before (2021–2022) and during the use of HFO (2022–2023) in Vilnius, Lithuania. The results showed that the combustion of HFO increased the concentrations of SO₂ (by 94%) and PM1-related sulfate (by 30%). It also altered the chemical composition of PM1, with sulfate becoming the predominant component (~40%) of WSIIs. The stable sulfur isotope ratios of SO2 (δ34SSO2) and sulfate (δ34SPM1) shifted significantly to more negative values (δ34SSO2 = 0.4‰, δ34SPM1 = −0.3‰) compared to the previous heating period. Anticorrelation between δ¹³C and δ³⁴S values indicated increased contributions of ¹³C-enriched fossil fuel sources (coal and HFO) in EC, although the share of fossil fuels in elemental carbon (EC) slightly decreased during the HFO period. The combustion of HFO affected the concentrations of PM1 chemical components and substantially impacted the isotopic composition and source contributions of sulfate and EC.

Seasonal oxidative dynamics and isotopic fractionation of NOx and SO2 in Ostrava, Czech Republic: Insights from stable isotope analysis

The city of Ostrava, NE Czech Republic, is known for its industrial pollution. It has well-characterized emission sources and stable air movement patterns. These features are conveniently used to generalize on atmospheric NOx and SO2 oxidation processes. In 2021, we conducted a series of sampling campaigns to assess the isotopic fractionation conducive to NO3− and SO42− aerosols in PM10. These sampling campaigns were timed to capture varying atmospheric conditions, including climatic inversion periods, providing also insights into urban emission dynamics over the course of the year. Gaseous NOx and SO2 were collected on passive filters, while their oxidized forms, NO3− and SO42, were captured on PM10 particle filters, enabling us to analyze the transformation dynamics of these pollutants. Isotopic analyses distinguished the sources of NOx emissions—coal combustion (δ15N = −3‰) and vehicular emissions (δ15N = −7 ‰)—and allowed quantifying isotope fractionation during their conversion to NO3− (εNOx-NO3- = 11.5 ± 1.15 ‰). This fractionation, however, was influenced by seasonal variations, and appears to be notably affected by NH4NO3 decomposition during warmer months. The correlation of the NO3− to NOx ratio with PM10 and atmospheric moisture highlighted the interplay between particulate matter and humidity in relevant atmospheric transformations. Similarly, for SO2, primarily emitted from coal combustion (δ34S = −2‰), we identified distinct fractionation patterns during oxidation to SO42− encompassing both kinetic (εSO2-H2O = −1.3 ± 0.5‰) and equilibrium (εSO2- SO42- = 2.24 ± 0.67‰) effects. The SO42−/SO2 ratio was correlated with PM10 but showed no dependence on humidity. Significantly, atmospheric inversion conditions accelerated oxidation, modifying the fractionation patterns for both NOx (εNOx-NO3- = 7‰) and SO2 (εSO2- SO42-= −0.9 ± 0.3‰). Our methodology elucidates pivotal mechanisms in atmospheric pollution transformation, underlined by the tracing of NOx and SO2 to aerosol conversions via δ15N and δ34S isotopic analyses. The isotope fractionation underscores equilibrium processes in oxidation reactions, while the effect of PM10 and humidity reveals the complexity of these atmospheric oxidative transformations. The role of wet deposition in removing SO2 highlights an essential pathway in the atmospheric sulfur cycle.

Highly selective separation of sulfur dioxide in a triphenylamine-based nanoporous organic polymer

The urgent need for effective SO2 capture materials has driven research into the development of novel nanoporous organic polymers (NOPs). Herein, we developed a triphenylamine-based nanoporous organic polymer, designated as ANOP-5, through the self-condensation of an AB2 triphenylamine monomer. The adsorption/separation properties of SO2 and CO2 are comparatively evaluated through the investigation of static gas adsorption isotherms. At 273 K and 100 kPa, ANOP-5 displays a high SO2 adsorption capacity of 399 cm3 g−1 and a high selectivity of 388 for SO2/CO2, with a molar ratio of SO2 to CO2 at 10/90. The exceptional performance of desulfurization is attributed to the strong interaction between ANOP-5 and SO2, in addition to the ultramicroporous structure. These findings are further supported by the dispersion-corrected density functional theory calculations. This study contributes valuable insights into the design and preparation of NOPs with high gas adsorption properties, particularly for addressing environmental pollution challenges related to SO2 emissions.

How well are aerosol–cloud interactions represented in climate models? – Part 1: Understanding the sulfate aerosol production from the 2014–15 Holuhraun eruption

Abstract. For over 6 months, the 2014–2015 effusive eruption at Holuhraun, Iceland, injected considerable amounts of sulfur dioxide (SO2) into the lower troposphere with a daily rate of up to one-third of the global emission rate, causing extensive air pollution across Europe. The large injection of SO2, which oxidises to form sulfate aerosol (SO42-), provides a natural experiment offering an ideal opportunity to scrutinise state-of-the-art general circulation models' (GCMs) representation of aerosol–cloud interactions (ACIs). Here we present Part 1 of a two-part model inter-comparison using the Holuhraun eruption as a framework to analyse ACIs. We use SO2 retrievals from the Infrared Atmospheric Sounding Interferometer (IASI) instrument and ground-based measurements of SO2 and SO42- mass concentrations across Europe, in conjunction with a trajectory analysis using the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model, to assess the spatial and chemical evolution of the volcanic plume as simulated by five GCMs and a chemical transport model (CTM). IASI retrievals of plume altitude and SO2 column load reveal that the volcanic perturbation is largely contained within the lower troposphere. Compared to the satellite observations, the models capture the spatial evolution and vertical variability of the plume reasonably well, although the models often overestimate the plume altitude. HYSPLIT trajectories are used to attribute to Holuhraun emissions 111 instances of elevated sulfurous surface mass concentrations recorded at European Monitoring and Evaluation Programme (EMEP) stations during September and October 2014. Comparisons with the simulated concentrations show that the modelled ratio of SO2 to SO42- during these pollution episodes is often underestimated and overestimated for the young and mature plume, respectively. Models with finer vertical resolutions near the surface are found to better capture these elevated sulfurous ground-level concentrations. Using an exponential function to describe the decay of observed surface mass concentration ratios of SO2 to SO42- with plume age, the in-plume oxidation rate constant is estimated as 0.032 ± 0.002 h−1 (1.30 ± 0.08 d e-folding time), with a near-vent ratio of 25 ± 5 (µg m−3 of SO2 / µg m−3 of SO42-). The majority of the corresponding derived modelled oxidation rate constants are lower than the observed estimate. This suggests that the representation of the oxidation pathway/s in the simulated plumes is too slow. Overall, despite their coarse spatial resolutions, the six models show reasonable skill in capturing the spatial and chemical evolution of the Holuhraun plume. This capable representation of the underlying aerosol perturbation is essential to enable the investigation of the eruption's impact on ACIs in the second part of this study.

A new accurate retrieval algorithm of bromine monoxide columns inside minor volcanic plumes from Sentinel-5P TROPOMI observations

Abstract. Bromine monoxide (BrO) is a key radical in the atmosphere, influencing the chemical state of the atmosphere, most notably the abundance of ozone (O3). O3 depletion caused by the release of bromine has been observed and modeled in polar regions, salt pans, and in particular inside volcanic plumes. Furthermore, the molar ratio of BrO and SO2 – which can be detected simultaneously via spectroscopic measurements using the differential optical absorption spectroscopy (DOAS) method – is a proxy for the magmatic composition of a volcano and potentially an eruption forecast parameter. The detection of BrO in volcanic plumes from satellite spectroscopic observations is limited by the precision and sensitivity of the retrieval, which so far only allowed for the detection of BrO during major eruptions. The unprecedented spatial resolution of up to 3.5 km×5.5 km and the high signal-to-noise ratio of the TROPOspheric Monitoring Instrument (TROPOMI) on board Sentinel-5 Precursor (S-5P) enable observing and monitoring volcanic bromine release globally even for minor eruptions or even quiescent degassing. In this study, we investigate how far the BrO retrieval can be improved using TROPOMI data and how well BrO can be detected, even in small eruptions and during quiescent volcanic degassing. There are two steps for which improvements in accuracy are investigated and applied: the improvement and quantitative determination of (1) the detection limit of the DOAS BrO column retrieval and (2) the correction of the non-volcanic background BrO signal. First, the DOAS retrieval settings are varied, and their influence on accuracy and precision is investigated with respect to the detection limit and potential systematic influences. Based on these results, we propose a dedicated DOAS evaluation scheme optimized for the detection of BrO in volcanic plumes. For the DOAS retrieval, we propose the use of a large fit window from 323–360 nm, yielding a statistical uncertainty lower by a factor of 1.8 compared to previous BrO DOAS algorithms while not enhancing systematic influences. Second, the effect of the background BrO is reduced by a latitude-dependent empirical correction scheme correlated to cloud information as well as information on the O3 column. Via these improvements, the combined statistical and systematic uncertainties in the resulting BrO vertical column density is on the order of 7×1012moleculescm-2. We present a new and accurate retrieval algorithm of BrO columns from TROPOMI observations which allows for the detection of even slightly enhanced BrO amounts inside minor eruptive plumes of bromine-rich volcanoes. While designed specifically for TROPOMI observations, the retrieval algorithm is in general also applicable to other hyperspectral satellite observations. However, some parts might require adaptation.

Wet deposition of sulfur and nitrogen in the Jiuzhaigou World Heritage Site, China: Spatial variations, 2010–2022 trends, and implications for karst ecosystem conservation

Excessive sulfur and nitrogen deposition is a threat to natural ecosystems. This study investigated the spatio-temporal changes of wet sulfur and nitrogen deposition in Jiuzhaigou to understand the responses of wet deposition chemistry to local and national air pollutant emission changes and to assess relevant ecological risks. The results show that local emission sources (e.g., tourism, post-earthquake reconstruction, and vegetation damages) largely elevated the concentrations of SO42−, NO3−, NH4+, and Ca2+ at the non-background sites during 2021–2022; However, the gaps of annual sulfur and nitrogen wet deposition fluxes among the background, semi-background, and non-background sites were reduced by annual precipitation. The pH was also higher at the non-background sites due to stronger acid neutralization capacities from crustal dust there, and acid precipitation (pH < 5.6) was not detected at all the sites. During the 2010 to 2022 period, the wet deposition of SO42− and TIN (i.e. total inorganic nitrogen) and the equivalent ratio of SO42−: NO3− generally presented a declining trend at the background and semi-background sites, as a result of regional and national emission reductions. The TIN reduction from 2015 to 2016 to 2021–2022 at the background site was more from wet NH4+ deposition and the site's NO3− concentrations and fluxes were relatively stable. Compared to the critical loads (CLs) of sulfur and nitrogen for acidification and eutrophication, the annual wet and wet+dry deposition fluxes of sulfur and nitrogen were lower in almost the entire watershed, except for the CLmin of nitrogen for acidification in considerable areas. However, all the wet deposition samples were calcite-unsaturated and had annual TIN concentrations higher than the national environmental standard of total nitrogen for surface water. More field investigations are needed to better assess the ecological risks.

Ascorbic acid addition to rosé: Impact on the oxidative and reductive development of bottled wine.

The impact of ascorbic acid on the oxidative and reductive development of rosé wine during bottle ageing has not been previously established. A rosé wine that contained 0.25mg/L of Cu was bottled with levels of 0, 50 or 500mg/L of ascorbic acid and different total packaged oxygen concentrations (3 and 17mg/L), and was stored for 15months at 14°C in darkness. Ascorbic acid increased the first-order oxygen consumption rate from 0.030±0.001 to 0.040±0.001days-1, and decreased the mole ratio of total SO2 consumed to oxygen consumed from 1.0:1 to 0.7:1. Although ascorbic acid did accelerate the loss of a Cu form that can suppress reductive aromas, it did not induce reductive aromas. These results indicate that ascorbic acid can accelerate the removal of oxygen from bottled rosé wine while maintaining higher concentrations of sulfur dioxide, however, it did not promote reductive development.

Effect of gaseous pollutant and greenness exposure on mortality during treatment of newly treated tuberculosis patients: a provincial population-based cohort study.

Previous studies addressing the impact of environmental factors on TB prognosis are scarce, with only some studies examining the effect of particulate pollutants on TB mortality. Moreover, few studies have evaluated the effects of multiple gaseous pollutants and greenness exposures on newly treated TB patients on a large population scale. Through the Centers for Disease Control and Prevention, data were collected from January 1, 2015 to December 31, 2020 for newly treated TB patients in Anhui Province, China. Data on gaseous pollutants sulfur dioxide, nitrogen dioxide, carbon monoxide, and ozone were collected through the National Earth System Science Data Center of China. Normalized vegetation index data were obtained through NASA. The Cox proportional risk model was also applied to calculate the hazard ratios of SO2, NO2, CO, O3, and NDVI with 95% confidence intervals for mortality among newly treated TB patients. Multifactorial Cox regression analysis showed that for every 0.10μg/m3 increase in SO2, the risk of death among newly treated TB patients increased by 13.2% (HR = 1.132, 95% CI: 1.045-1.1.225), for every 10μg/m3 increase in NO2, the risk of death among newly treated TB patients increased by 11.4%, and for each 0.1 mg/m3 increase in CO, the risk of death among newly treated TB patients increased by 5.8%. For each 0.1 increase in NDVI 250m-buffer and 500m-buffer, the risk of death among newly treated TB patients decreased by 8.5% and 6.4%, respectively. The effect of gaseous pollutants on mortality decreased progressively with elevated greenness exposure when greenness exposure was grouped from low to high. Gaseous pollutants are a risk factor during the treatment of newly treated TB patients and greenness exposure is a protective factor. Higher greenness exposure reduces the risk of death due to exposure to gaseous pollutants.

A mineralogical reason why all exoplanets cannot be equally oxidizing

ABSTRACT From core to atmosphere, the oxidation states of elements in a planet shape its character. Oxygen fugacity ($f_{\rm O_2}$) is one parameter indicating these likely oxidation states. The ongoing search for atmospheres on rocky exoplanets benefits from understanding the plausible variety of their compositions, which depends strongly on their oxidation states – and if derived from interior outgassing, on the $f_{\rm O_2}$ at the top of their silicate mantles. This $f_{\rm O_2}$ must vary across compositionally diverse exoplanets, but for a given planet, its value is unconstrained insofar as it depends on how iron (the dominant multivalent element) is partitioned between its 2+ and 3+ oxidation states. Here, we focus on another factor influencing how oxidizing a mantle is – a factor modulating $f_{\rm O_2}$ even at fixed Fe3+/Fe2+ – the planet’s mineralogy. Only certain minerals (e.g. pyroxenes) incorporate Fe3+. Having such minerals in smaller mantle proportions concentrates Fe3+, increasing $f_{\rm O_2}$. Mineral proportions change within planets according to pressure, and between planets according to bulk composition. Constrained by observed host star refractory abundances, we calculate a minimum $f_{\rm O_2}$ variability across exoplanet mantles, of at least two orders of magnitude, due to mineralogy alone. This variability is enough to alter by a hundredfold the mixing ratio of SO2 directly outgassed from these mantles. We further predict that planets orbiting high-Mg/Si stars are more likely to outgas detectable amounts of SO2 and H2O; and for low-Mg/Si stars, detectable CH4, all else equal. Even absent predictions of Fe3+ budgets, general insights can be obtained into how oxidizing an exoplanet’s mantle is.

Groundwater quality assessment in the alluvial region of upper yamuna basin, India

The study is undertaken to assess the groundwater quality in the alluvial region of the Yamuna basin, mainly comprising unconsolidated sand, silt and clays. A total of 14 and 13 water samples were collected in pre- and post-monsoon seasons, respectively, from handpumps, tubewells, ponds and irrigated fields to assess the water quality for human consumption and identify possible sources of contaminants in water. According to the Gibbs diagram, the ionic composition of water is mainly dominated by the rock weathering processes. The major hydrochemical facies is Ca–Mg–HCO3 type. The scatter plots between Ca+Mg:SO4+HCO3 and Na:Cl indicate the occurrence of silicate weathering which is supported by HCO3/HCO3+SO4 ratio <1. Manganese (Mn) concentration in 57% and 54% water samples in pre- and post-monsoon season exceeds the permissible limit i.e. 0.3 mg/L. Further, high iron (Fe) concentration (up to 33.5 mg/L) is also detected mainly in the shallow groundwater. The presence of higher Mn and Fe concentrations in the water samples is generally associated with the regions having low or negative redox values. Additionally, their positive correlation with sulphate and chloride ions indicates their occurrence as sulfates and chlorides. The results signify the role of regional geology in the presence of these ions in water along with the secondary influence of agricultural and anthropogenic activities (human and animal waste) on the quality of shallow groundwater. The Water Quality Index varies greatly, from excellent to unsuitable category in both seasons mainly due to the presence of high Fe and Mn content in shallow handpumps, village pond and a few tubewells located in the agricultural fields. Leaching of fertilizers and fungicides in the agricultural fields may further contribute in deteriorating shallow groundwater quality.

Major ion compositions, sources and risk assessment of karst stream under the influence of anthropogenic activities, Guizhou Province, Southwest China.

To explore the influence of different types of anthropogenic activity on the rivers, we investigate the major ion composition, sources and risk assessment of the karst stream (Youyu stream and Jinzhong stream), which are heavily influenced by mining activities and urban sewage, respectively. The chemical compositions of the Youyu stream water, which is heavily influenced by mining activities, are dominated by Ca2+ and SO42-. However, the chemical compositions of the Jinzhong stream water, which is heavily influenced by urban sewage, are dominated by Ca2+ and HCO3-. The Ca2+, Mg2+ and HCO3- in Jinzhong stream are mainly derived from rock weathering, while the Youyu stream is affected by acid mine drainage, and sulfuric acid is involved in the weathering process. Ion sources analysis indicates that the Na+, K+, NO3-, and Cl- in the Jinzhong stream mainly derive from urban sewage discharge; but NO3- and Cl- of the Youyu stream mainly derive from agricultural activities, and Na+, K+ are mainly from natural sources. The element ratios analysis indicates the ratio of SO42-/Mg2+ in Youyu stream (4.61) polluted by coal mine is much higher than that in Jinzhong stream (1.29), and the ratio of (Na++K++Cl-)/Mg2+ in Jinzhong stream (1.81) polluted by urban sewage is higher than Youyu stream (0.64). Moreover, the ratios of NO3-/Na+, NO3-/K+, and NO3-/Cl- in the agriculturally polluted Youyu stream were higher than those in the Jinzhong stream. We can identify the impact of human activities on streams by ion ratios (SO42-/Mg2+, (Na++K++Cl-)/Mg2+, NO3-/Na+, NO3-/K+, and NO3-/Cl-). The health risk assessment shows the HQT and HQN for children and adults are higher in Jinzhong stream than in Youyu stream and the total HQ value (HQT) of children was higher than one at J1 in the Jinzhong stream, which shows that children in Jinzhong stream basin are threatened by non-carcinogenic pollutants. Each HQ value of F- and NO3- for children was higher than 0.1 in the tributaries into Aha Lake, indicating that the children may also be potentially endangered.

Quantifying BrO and SO2 distributions in volcanic plumes—Recent advances in imaging Fabry-Pérot interferometer correlation spectroscopy

Bromine monoxide (BrO) and sulphur dioxide (SO2) are two gases frequently observed in volcanic plumes by spectroscopic techniques capable of continuous gas monitoring like, e.g., Differential Optical Absorption Spectroscopy (DOAS). The spatio-temporal resolution of DOAS measurements, however, only allows to determine average gas fluxes (minutes to hours resolution). In particular, it is insufficient to record two-dimensional images of SO2 and BrO in real-time (seconds time resolution). Thus, it is impossible to resolve details of chemical conversions of reactive plume constituents. However, these details are vital for further understanding reactive halogen chemistry in volcanic plumes. Therefore, instruments that combine high spatio-temporal resolution and high gas sensitivity and selectivity are required. In addition, these instruments must be robust and compact to be suitable for measurements in harsh and remote volcanic environments. Imaging Fabry-Pérot interferometer (FPI) correlation spectroscopy (IFPICS) is a novel technique for atmospheric trace gas imaging. It allows measuring atmospheric gas column density (CD) distributions with a high spatial and temporal resolution, while at the same time providing selectivity and sensitivity comparable to DOAS measurements. IFPICS uses the periodic transmission spectrum of an FPI, that is matched to the periodic narrowband (vibrational) absorption features of the target trace gas. Recently, IFPICS has been successfully applied to volcanic SO2. Here we demonstrate the applicability of IFPICS to much weaker (about two orders of magnitude) trace gas optical densities, such as that of BrO in volcanic plumes. Due to its high reactivity, BrO is extremely difficult to handle in the laboratory. Thus, based on the similarity of the UV absorption cross sections, we used formaldehyde (HCHO) as a spectral proxy for BrO in instrument characterization measurements. Furthermore, we present recent advances in SO2 IFPICS measurements and simultaneous measurements of SO2 and BrO from a field campaign at Mt Etna in July 2021. We find photon shot-noise limited detection limits of 4.7 × 1017 molec s0.5 cm−2 for SO2 and of 8.9 × 1014 molec s0.5 cm−2 for BrO at a spatial resolution of 512 × 512 pixels and 200 × 200 pixels, respectively. Furthermore, an estimate for the BrO to SO2 ratio (around 10–4) in the volcanic plume is given. The prototype instrument presented here provides spatially resolved measurements of the reactive volcanic plume component BrO. The temporal resolution of our approach allows studies of chemical conversions inside volcanic plumes on their intrinsic timescale.

Ultraselective Extraction Reprocessing of 99TcO4-/ReO4- with a Promising Carbamic Acid Extractant System.

With the development of nuclear energy, the reprocessing of 99TcO4-/ReO4- has become a very difficult problem due to environmental issues such as high output, long life, and easy leakage. In this study, three extraction systems containing carbamic acid were introduced into the reprocessing of 99TcO4-/ReO4- for the first time. The results involving one of the three results show that N-[N,N-di(2-ethylhexyl) aminocarbonylmethyl] glycine (D2EHAG) has ultrahigh selectivity for removal to 99TcO4-/ReO4-. When the extreme concentration ratio of SO42- and Cl- to ReO4- of D2EHAG is 10,000:1, the distribution coefficient of ReO4- still reaches 12.73 and 2.67, respectively. Additionally, the most hydrophilic NO3-, when the extreme concentration ratio of NO3- and ReO4- is 1000:1, still has a distribution coefficient close to 2.33, which is more than the most reported MOF adsorption materials. Moreover, the reaction kinetics, stripping rate, and reuse rate were studied. After five cycles, the removal rate is still 98.12%, with a decrease of less than 0.7%. The system containing carbamic acid is a potential extraction removal system to remove 99TcO4-/ReO4- from nuclear radioactive wastewater.

Investigating the hygroscopicities of calcium and magnesium salt particles aged with SO2 using surface plasmon resonance microscopy

The hygroscopicities of calcium and magnesium salts strongly affect the environment and climate, but the aging products of these salts at high relative humidities (RHs) are still poorly understood. In this study, surface plasmon resonance microscopy (SPRM) was used to determine the hygroscopic growth factors (GFs) of Ca(NO3)2 and Mg(NO3)2 separately or mixed with galactose at different mass ratios at different RHs before and after aging. For all particles, the measured GFs showed no indication of deliquescence across the range of RHs tested, and overall hygroscopicity was clearly lower after than before aging. The Ca(NO3)2 and Mg(NO3)2 GFs at 90 % RH were 1.80 and 1.66, respectively, before aging and 1.33 and 1.42, respectively, after 4 h aging, meaning aging decreased the GFs by 26.11 % and 14.46 %, respectively. Aging decreased the hygroscopicity because insoluble or sparingly soluble substances (CaSO3, CaSO4, MgSO3) formed and strongly changed the overall hygroscopicity. For bicomponent aerosols with different mass ratios, the GFs (calculated using the Zdanovskii-Stokes-Robinson method) of the other components except galactose at 90 % RH after 1 h aging were all lower, respectively, than the measured GFs of pure Ca(NO3)2 and Mg(NO3)2 after aging for 1 h, especially with the mass ratio of 1:2, their GFs have decreased by 14.63 % and 7.50 %, respectively. Subsequently, Ion chromatograms indicated that the peak area ratio of SO42− to NO3− ratios were higher for the aged bicomponent particles than aged single-component particles, possibly because adding galactose improved the gas–liquid state stability during drying after the aging process and therefore promoted nitrate consumption and sulfate formation. The results indicated that organic components may play important roles in heterogeneous reactions between trace gases and multicomponent aerosols and should be considered in evaluating the impacts on submicron aerosol composition of high atmospheric SO2 concentrations at high humidities.

Quantitative sustainability assessment and sensitivity analysis for a solar-driven combined heating and power system integrated with organic Rankine cycle and ground source heat pump

Integrating renewable energy and combined heating and power (CHP) systems saves fossil energy, reduces greenhouse gas emissions, and increases system efficiency. This study proposes a solar-driven CHP system integrated with an organic Rankine cycle (ORC) and a ground source heat pump (GSHP). A quantitative sustainability assessment method is used to evaluate the sustainability performance of the CHP system. This method aggregates the technical, economic, environmental, and social performance of the solar-driven CHP system through an information entropy approach to obtain a composite sustainability index. The results indicate that the solar-driven CHP system scenario with a heat distribution ratio of 75% has a higher composite sustainability index (0.768). A sensitivity analysis of the sustainability performance of the solar-driven CHP system under the optimal scenario shows that the emissions reduction ratio of SO2, CO2, NOx, and PM2.5 are positively correlated with solar irradiation, and the annual cost-saving ratio is more influenced by electricity prices, the job opportunity is more sensitive to job factors of the concentrated solar power. The above results indicate that the quantitative sustainability assessment method is helpful for the selection of CHP systems.

Response of Soil Respiration to Simulated Acid Rain with Different Ratios of SO42− to NO3− in Cunninghamia lanceolata (Lamb.) Hook. and Michelia macclurei Dandy Plantations

Acid rain is one of the most serious environmental issues in Southern China. The composition of acid rain has gradually changed from sulfuric acid rain (SAR) to nitric acid rain (NAR) due to the rapid development of industry, and controls on SO2 emissions. However, a comprehensive understanding of how changes in the type of acid rain affect soil respiration (Rs) in forest ecosystems is still lacking. In this study, we investigated the influence of simulated acid rain with different SO42−/NO3− ratios, namely, SAR (4:1), MAR (mixed acid rain, 1:1), and NAR (1:4), on Rs in Cunninghamia lanceolata (Lamb.) Hook. (CL) and Michelia macclurei Dandy (MM) plantations from 2019 to 2020. A trenching method was used to partition Rs into heterotrophic respiration (Rh) and autotrophic respiration (Ra). The results showed that acid rain did not significantly influence Rs in the two plantations, which could be mainly attributed to the unchanged soil pH. Neither SAR, MAR, nor NAR affected Ra in the two plantations, possibly due to the unchanged root biomass. The SAR treatment only significantly increased Rh in the MM plantation, not in the CL plantation. The temperature sensitivity (Q10) of Rs and its components was not significantly different among different acid rain types in either of the plantations. Our results suggest that the impact of acid rain on Rs and its components depends on the forest ecosystem and the type of acid rain. Different biological processes complicate the response of soil CO2 emissions to acid rain pollution.

Efficient removal of arsenic and phosphate contaminants by diatomite-modified schwertmannite

Schwertmannite (Sch) has been proved to be a promising and efficient adsorbent for the removal of various metal ions. However, how to further improve the adsorption capacity and stability of Sch to As(III), As(V) and P(V) is always a problem. In this study, we developed a method to synthesize various Schs with different initial ratios of SO42-:Fe(III). Our results show that Schs can be used to remove As(III), As(V) and P(V) in a wide concentration range of pH 3.0–7.0, and negligible difference can be observed in the adsorption capacities of various Schs towards As(III), As(V) and P(V), indicating that increasing initial concentrations of SO42- does not necessarily increase the adsorption capacity of Sch. In addition, the maximum adsorption capacities (Qmax) of Sch-0.75 towards As(V) and P(V) increases with decreasing pHs, whereas increase with increasing pHs towards As(III). The Qmax values of As(III), As(V) and P(V) are 80.5, 161.5 and 139.9 mg g−1 at pH 3.0, respectively, and are 214.5, 107.6 and 86.5 mg g−1 at pH 7.0, respectively, indicating that the strong dependence of Qmax on pH values. Besides, we also successfully developed a method to synthesize the diatomite-modified Sch (DMS). The synthesized DMS with the ratio of Fe(III) salts and diatomite of 4:1 (DMS-4) shows the maximum adsorption capacities of As(III), As(V) and P(V) of 59.81, 151.52 and 236.97 mg g−1 at pH 3.0, respectively, and of 282.49, 126.58 and 165.02 mg g−1 at pH 7.0, respectively. DMS-4 also shows high stability during repeated experiments, and the removal efficiencies of DMS-4 to As(III), As(V) and P(V) maintain 97.42 %, 88.39 % and 94.72 % after five cycles, whereas the removal efficiencies of Sch-0.75 rapidly decrease to 63.61 %, 31.12 % and 50.71 % towards As(III), As(V) and P(V) after five cycles. This study provides a new method to synthesize stable DMS with high adsorption capacities towards As(III), As(V) and P(V).

Preparation of Cex-Mn0.8Fe0.2O2 Catalysts and Its Anti-Sulfur Denitration Performance

In order to meet the industrial denitrification demands, inexpensive ferrous metals Mn and Fe have been chosen as the raw materials for the catalysts of CO-SCR, and the anti-sulfur denitrification performance of ferromanganese catalysts can be greatly enhanced by Ce doping. In this study, Cex-Mn0.8Fe0.2O2 catalysts were prepared by co-precipitation, and the effects of Ce addition on the structure and morphology of prepared catalysts and their anti-sulfur denitration performance were investigated with X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results showed that the Cex-Mn0.8Fe0.2O2 catalysts consisted of nanoparticles sized 20–100 nm. Specifically, the Ce0.2-Mn0.8Fe0.2O2 catalyst had more active sites and the best anti-sulfur denitration performance, with a denitration rate of 90.36% at 350 °C, while the denitrification performance of the Mn0.8Fe0.2O2 catalyst was only 85%. Furthermore, the denitrification rate of the catalyst was maintained above 80% when the CO:NO:SO2 ratio was 3:1:1 for 4 h at 350 °C.