SO2 Values Research Articles

Statistical Analysis of Air Pollutants and Meteorological Parameters in Afyon, Turkey

In this study, the relation between sulfur dioxide (SO2) and particulate matter (PM) concentrations periodically measured in the city of Afyon’s atmosphere with meteorological factors such as precipitation, humidity, temperature, wind velocity, and inversion were investigated. The mean values of SO2 and PM concentrations measured during the winter months of October–March 1990–1999 were correlated with the meteorological parameters of the same period. Simple and multiple linear regression analysis were utilized to evaluate the contribution of meteorological variables. The statistical results show that the pollutants, i.e., SO2 and PM are dependent upon humidity, temperature, and inversion at the 1% significance level; while the dependence of both pollutants with temperature is negative when those of humidity and inversion are positive. Two models in which temperature and inversion are dependent with multiple variables are recommended for predicting the contribution of meteorological parameters on SO2 and PM. In addition, the relationship between humidity, temperature, and inversion with pollutants is also determined using nonlinear (polynomial) models.

Blood-Gas and Acid–Base Parameters in Nontranquilized Arabian Oryx (Oryx leucoryx) in the United Arab Emirates

Arterial and venous blood-gas and acid-base values were established from a herd (n = 19; 14 male, 5 female) of semi-free-ranging Arabian oryx (Oryx leucoryx) in the United Arab Emirates. The animals were restrained with the use of a modified raceway incorporating a commercially available handling crate. Statistically significant differences were found between arterial and venous values for PO2 (p < 0.001), PCO2 (p = 0.0141), SO2 (p < 0.001), pH (p = 0.0494), and glucose (p < 0.0001). The results are similar to those reported for the same species under field anesthetic conditions, and to those reported from other species of wild bovidae, both tranquilized and nontranquilized, established under similar methods of restraint. In addition, Bland and Altman plots suggest adequate levels of clinical agreement between venous and arterial pH but not between arterial and venous PCO2.

Anomalous Emissions of SO2 During the Recent Eruption of Santa Ana Volcano, El Salvador, Central America

Santa Ana volcano in western El Salvador, Central America, had a phreatic eruption at 8:05 am (local time) on October 1, 2005, 101 years after its last eruption. However, during the last one hundred years this volcano has presented periods of quiet degassing with fumarolic activity and an acidic lake within its crater. This paper presents results of frequent measurements of SO2 degassing using the MiniDOAS (Differential Optical Absorption Spectroscopy) system and a comparison with the volcanic seismicity prior to the eruption, during, and after the eruption. Vehicle measurements of SO2 flux were taken every hour during the first nine days of the eruption and daily after that. The period of time reported here is from August to December, 2005. Three periods of degassing are distinguished: pre-eruptive, eruptive, and post-eruptive periods. The intense activity at Santa Ana volcano started in July 2005. During the pre-eruptive period up to 4306 and 5154 ton/day of SO2 flux were recorded on October 24 and September 9, 2005, respectively. These values were of the same order of magnitude as the recorded values just after the October 1st eruption (2925 ton/day at 10:01 am). Hourly measurements of SO2 flux taken during the first nine days after the main eruptive event indicate that explosions are preceded by an increase in SO2 flux and that this parameter reaches a peak after the explosion took place. This behavior suggests that increasing accumulation of exsolved magmatic gases occurs within the magmatic chamber before the explosions, increasing the pressure until the point of explosion. A correlation between SO2 fluxes and RSAM (Real Time Seismic Amplitude Measurements) is observed during the complete sampling period. Periodic fluctuations in the SO2 and RSAM values during the entire study period are observed. One possible mechanism explaining these fluctuations it that convective circulation within the magmatic chamber can bring fresh magma periodically to shallow levels, allowing increasing degasification and then decreasing degasification as the batch of magma lowers its gas content, becomes denser, and sinks to give space to a new magma pulse. These results illustrate that the measurements of SO2 flux can provide important warning signals for incoming explosive activity in active volcanoes.

Regional and temporal (1992–2004) evolution of air-borne sulphur isotope composition in Saxony, southeastern Germany, central Europe†

The isotopic composition of air-borne sulphur was investigated in Saxony, Southeast Germany – a region with formerly very high atmospheric SO2 concentrations. In addition, data from various authors were compiled for different Saxonian locations, spanning from 1992 to 2004, i.e., a time of decreasing SO2 concentrations in the atmosphere. There were no obvious temporal changes in the mean δ34S value of bulk precipitation. However, the variability of monthly mean δ34S values decreased. The mean sulphur isotope composition of sulphate from bulk precipitation after the year 2000 converges in Saxony towards 4–5‰, with similar values for different locations. Mean values of different forms of sulphur show the following enrichment order: δ34S of SO2 < δ34S of weathering crusts ≤δ34S of sulphate from bulk precipitation ≤δ34S of dust. Judging from local differences on sulphate crusts and corresponding isotope values of sources, the δ34S value of SO2 as well as for crusts mainly reflects local point sources. The mean δ34S value of bulk precipitation represents more regionally well-mixed SO2 sources and is therefore an ideal tool for monitoring regional atmospheric change. †Revised version of a paper presented at the 27th Annual Meeting of the German Association for Stable Isotope Research (GASIR), October, 4–6, 2006, Freiberg, Germany.

Effects of wavelength-dependent fluence attenuation on the noninvasive photoacoustic imaging of hemoglobin oxygen saturation in subcutaneous vasculature in vivo

Quantitative measurements of the oxygen saturation of hemoglobin (sO2) in a blood vessel in vivo presents a challenge in photoacoustic imaging. As a result of wavelength-dependent optical attenuation in the skin, the local fluence at a subcutaneous vessel varies with the optical wavelength in spectral measurement and hence needs to be compensated for so that the intrinsic absorption coefficient can be recovered. Here, by employing a simplified double-layer skin model, we demonstrate that although the absolute value of sO2 in a vessel is seriously affected by the volume fraction of blood and the spatially averaged sO2 in the dermis, the difference of sO2 between neighboring vessels is minimally affected. Experimentally, we acquire compensational factors for the wavelength-dependent optical attenuation by measuring the PA spectrum of a subcutaneously inserted 25 µm thick black film using our PA microscope. We demonstrate in vivo that the difference in sO2 between a typical artery and a typical vein is conserved before and after spectral compensation. This conservation holds regardless of the animal's systemic physiological state.

Air pollution impact assessment on agroecosystem and human health characterisation in the area surrounding the industrial settlement of Milazzo (Italy): a multidisciplinary approach

In order to evaluate the impact of atmospheric pollutants emitted by the industrial settlement of Milazzo (Italy) on agriculture, sulphur dioxide and ozone levels in air were monitored and the data were used to estimate yield losses of the most widespread cultures. Trace element concentrations in crops and soils were also detected and metabolic profiles of soil microbial communities were considered. Vibrio fischeri test was used to appraise airborne pollutant ecotoxicity and epidemiological studies on causes of death distribution were carried out to characterize health state of people living in the area. All the sampling points were selected in farms on the basis of a theoretical meteo-diffusive model of industrial air pollutants. Experimental SO2 and O3 values mainly exceeded the threshold established by Italian and EU regulations to protect vegetation and they correspond to estimated significant crop losses. Conversely toxic element residues in soils and in agroalimentary products were generally lower than the fixed values. SO2 and O3 concentrations, toxic element contents and ecotoxicity levels of airborne pollutants were not related only to industrial site emissions, while the fluctuations on metabolic profiles of soil microbial communities seem to agree with the predicted deposition of xenobiotic compounds from the industrial plants. The epidemiological study evidenced a better health state of populations living in the investigated area than in the Messina province and the Sicily region but, inside the area, males living in the municipalities closest to the industrial settlement exhibited a worst health state than those in the very far ones.

Boosting for real and functional samples: an application to an environmental problem

In this paper, boosting techniques are given in order to forecast SO2 levels near a power plant. We use boosting with neural networks to forecast real values of SO2 concentration. Then, the data are considered as a time series of curves. Assuming a lag one dependence, the predictions are computed using the functional kernel and the linear autoregressive Hilbertian model. Boosting techniques are developed for those functional models. We compare results of functional boosting with different starting points and iterate models. We carry out the estimation, in real and functional cases, with the information given by a historical matrix, which is a subsample that emphasizes relevant SO2 values.

Local metabolic, pathophysiological and histological changes in venous ulcers

The pathogenesis of venous ulceration is not completely understood. The aim of this research was to measure and compare various parameters in ulcers caused by abnormalities in superficial venous (SU) versus deep venous flow (DU), to determine possible differences in their pathogenesis. Analysis of venous blood gases and levels of anaerobic metabolites from the ulcer site were measured in SU (n=8) and DU patients (n=8) and compared with control samples from the contralateral healthy limb. Histological examination via electron microscopy was also performed in tissue samples from the ulcer sites in SU (n=2) and DU (n=2) patients. The SU group had significantly lower values of partial oxygen pressure (pO2) and oxygen saturation (sO2), and significantly higher values of partial pressure of carbon dioxide, bicarbonate concentration and total carbon dioxide versus control samples. The DU group had significantly higher values of pO2 and sO2 versus controls. Elevated levels of pyruvate (P < 0.01) and lactate (P < 0.05) were found in DU ulcer blood samples taken after 30 min of passive standing (static shear), as compared with control blood samples. However, no significant histological differences between SU and DU samples could be distinguished via electron microscopy. Differences in levels of venous blood gases and anaerobic metabolites indicate a potential difference in the causation and development of superficial versus deep venous caused ulcers. This may have clinical significance for the diagnosis and treatment of these conditions.

Imaging of hemoglobin oxygen saturation variations in single vessels in vivo using photoacoustic microscopy

Photoacoustic microscopy was used to noninvasively image variations in hemoglobin oxygen saturation (SO2) in the subcutaneous microvasculature of rats in vivo. In phantom tests, the calculated concentration fractions of red ink in double-ink mixtures matched the actual values with a 1% error. In ex vivo studies, the calculated SO2 in bovine blood agreed with the standard spectrophotometric measurements within a 4% systematic difference. In in vivo studies, arteries and veins were separated based on the measured SO2 values and variations in SO2 between different physiological states (hyperoxia, normoxia, and hypoxia) were imaged in single blood vessels.

A Water Model for Water and Environmental Management at Mae Moh Mine Area in Thailand

It is revealed that the water quality in Mae Moh Reservoir, Thailand, has been deteriorated by lignite mine drainage and power station effluent. This study aims to manipulate water quantity and quality to reduce environmental impacts in Mae Moh area through a model for water management. The model was constructed on the basis of materials balance to predict water flow, which includes concentrations of TDS and SO2–4. Data collected during 1996–2000 were used. Model validation showed that the mean of predicted and actual values of TDS and SO2–4 load were significantly similar at 95% confidence limit. The test result is acceptable and the water model can be used as a tool for water system management in the area. In 2006, Mae Moh mine excess water will be discharged at 10.76 Mm3, with a pH of 7.3, TDS and SO2–4 concentrations of 2,547 and 1,803 mg/l, respectively. Mae Moh power station effluent will be 14.59 Mm3, with pH of 7.1, TDS and SO2–4 concentrations of 610 and 358 mg/l, respectively. Predicted results showed that the outflow of Mae Moh Reservoir will be 83.67 Mm3 and the concentrations of TDS and SO2–4 will be as high as 1,501 and 822 mg/l, respectively. Mine excess water management measures are recommended according to the following strategy. All mine excess water should be stored during dry season. During wet season, 50% of the excess water should be stored and the remaining treated at 90% of TDS removal before being discharged. The end result would be a significant improvement in water quality in the Mae Moh Reservoir over the 4-year period to 2010. Pollutants in terms of TDS would be reduced by 35% from 1,501 mg/l in the beginning of 2006 to 975 mg/l at the end of 2009.

Measurements of atmospheric parameters during Indian Space Research Organization Geosphere Biosphere Program Land Campaign II at a typical location in the Ganga Basin: 2. Chemical properties

This paper attempts to analyze the chemical compositions of the near surface aerosols at a typical location in the Ganga basin with an emphasis on delineating the source of aerosols in foggy/hazy conditions. Collocated measurements of a number of atmospheric and aerosol parameters along with simultaneous sampling of near surface aerosols of size less than 10 μm (PM10) were made as part of an intense field campaign launched under the Indian Space Research Organization Geosphere Biosphere Program (ISRO‐GBP) in December 2004. PM10 and black carbon (BC) mass concentration was found to be significantly higher during the foggy/hazy period. Much of the PM10 mass (∼81%) was due to fine/accumulation mode particles (0.1–0.95 μm). Significant proportions of water soluble ions such as NH4+, K+, Na+, Cl−, NO3− and SO42− were present in the fine mode particles while considerable amounts of Ca2+ and Mg2+ along with NH4+, K+, Na+, Cl−, NO3− and SO42− were found in the coarse mode particles. Also, water soluble ions NH4+ and NO3− were significantly higher; however, Na+, K+, SO42− and Cl− did not show significant difference between foggy/hazy and clear days. In contrast, Ca2+, Mg2+ and acid soluble metals were significantly lower during foggy/hazy days as compared to the clear days. Presence of higher amounts of NH4+, K+, NO3− and SO42− associated with very low values (&lt;5 ppmv) of SO2 despite considerable plausible emissions due to fossil fuel and biomass burning in the region suggests that loading of fine mode aerosols in the region could have been enhanced through reactions of gaseous pollutants on the solid surfaces. These results along with the findings presented in the companion paper indicate that prolonged foggy/hazy conditions in the region may be due to the increased anthropogenic emissions.

SO2 modeling in İzmit Gulf, Turkey during the winter of 1997: 3 cases

In this study, SO2 dispersion over Izmit Gulf is simulated by California Puff (CALPUFF) model for three air pollution cases, which occurred on January 28, February 12, and February 26, 1997. These days are generally characterized by dominant high-pressure systems – pressure values reaching 1032 mb, low wind speeds and sometimes calm conditions, and low temperatures with a minimum of 0°C. Hourly simulations during those critical cases were carried out and results revealed very high concentrations of SO2 transported to the downwind regions of Tupras and Gebze, and values sometimes exceeded 1,000 μg/m3. Nighttime and morning simulations associated with inversion produced considerably higher values of SO2 than the afternoon simulations associated with breeze. Model verification was conducted by comparing the measured daily average values of eight stations with the model predicted values at the same receptor points. Results showed that the model well predicted the values at station Gebze in all three cases. The model sometimes underestimated and sometimes overestimated the concentrations at other receptor stations.

Comparison of modelled and monitored deposition fluxes of sulphur and nitrogen to ICP-forest sites in Europe

Abstract. The EMEP MSC-W Eulerian chemical transport model, and its predictions of deposition of acidifying and eutrophying pollutants over Europe, play a key role in the development of emission control strategies for Europe. It is important that this model is tested against observational data. Here we compare the results of the EMEP model with measured data from 160 sites of the European Union/ICP Forest (Level II) monitoring network, for the years 1997 and 2000. This comparison comprises: (a) Precipitation amount, (b) Total deposition of SO2−4 to coniferous and deciduous forests, (c) Wet deposition of SO2−4, NO3− and NH4+ in open field sites, and (d) Concentrations of SO2−4, NO3− and NH4+ in precipitation. Concerning precipitation, the EMEP model and ICP network showed very similar overall levels (within 4% for 1997 and 11% for 2000). The correlation was, however, poor (r2=0.15–0.23). This can be attributed largely to the influence of a few outliers, combined with a small range of rainfall amounts for most points. Correlations between modelled and observed deposition values in this study were rather high (r2 values between 0.4–0.8 for most components and years), with mean values across all sites being within 30%. The EMEP model tends to give somewhat lower values for SO2−4, NO3− and NH4+ wet deposition to ICP, but differences in mean values were within 20% in 1997 and 30% in 2000. Modelled and observed concentrations of SO2−4, NO3− and NH4+ in precipitation are very similar on average (differences of 0–14%), with good correlation between modelled and observed data (r2=0.50–0.78). Differences between the EMEP model and ICP measurements are thought to arise from a mixture of problems with both the observations and model. However, the overall conclusion is that the EMEP model performs rather well in reproducing patterns of S and N deposition to European forests.

The reliability of the i-STAT clinical portable analyser

The purpose of this investigation was to assess the reliability of the i-STAT clinical portable analyser and CG(4)(+) cartridge measures of blood pH, partial pressures of O(2) (pO(2)) and CO(2) (pCO(2)), bicarbonate ([HCO(3)(-)]), base excess (BE), total carbon dioxide (TCO(2)), oxygen saturation (sO(2)) and blood lactate ([BLa(-)]) at various exercise intensities. A comparison between [BLa(-)] measured by the i-STAT and the Accusport lactate analysers during an intermittent treadmill run was also undertaken. The technical error of measurement (TEM%) at rest, at moderate (200W) and maximal exercise (V O(2)max) was acceptable (<15%) for all parameters. The intra-class correlation coefficients for each analyte ranged from weak-to-strong across resting (ICC=0.19-0.96) and moderate (ICC=0.30-0.96) exercise intensities. The ICC for all analytes were observed to be strong following maximal intensity exercise (ICC=0.77-0.95). The comparison of the [BLa(-)] measures between the i-STAT and Accusport showed that the difference between measures was acceptable at both low (<4mmolL(-1)) (-0.39+/-0.27mmolL(-1)), moderate to high concentrations (>4mmolL(-1)) (0.58+/-1.22mmolL(-1)), and across all [BLa(-)] data (0.36+/-1.13mmolL(-1)). In conclusion, the i-STAT clinical analyser and CG(4)(+) cartridge provides reliable measures of a number of blood parameters across exercise intensities. The [BLa(-)] measures from the i-STAT analyser are consistent with that of the Accusport lactate analyser.

Hydrogen, Oxygen and Sulfur Isotope Studies of Seafloor Hydrothermal System at the Desmos Caldera, Manus Back‐arc Basin, Papua New Guinea: An Analogue of Terrestrial Acid Hot Crater‐lake

Abstract. The Onsen site is an active submarine hydrothermal system hosted by the Desmos caldera in the Eastern Manus Basin, Papua New Guinea. The hydrothermal fluid is very acidic (pH=1.5) and abundant native sulfur is deposited around the vent. The δ34S values of native sulfur range from ‐6.5 to ‐9.3 %o. δ34S values of H2S and SO4 in the hydrothermal fluid are ‐4.3 to ‐9.9 %o and +18.6 to +20.0 %o, respectively. These δ34S values are significantly lower than those of the other hydrothermal systems so far reported. These low δ34S values and the acidic nature of the vent fluids suggest that volcanic SO2 gas plays an important role on the sulfur isotope systematic of the Onsen hydrothermal system. Relationship among the δ34S values of S‐bearing species can be successively explained by the model based on the disproportionation reaction starting from the volcanic SO2 gas. The predicted δ34S values of SO2 agree with the measured whole rock δ34S values. δD and δ18O values of clay minerals separated from the altered rock samples also suggest the contribution of the magmatic fluid to the hydrothermal system. Present stable isotopic study strongly suggests that the Onsen hydrothermal site in the Desmos caldera is a magmatic submarine hydrothermal system.

Estudo comparativo entre a pressão positiva intermitente (Reanimador de Müller) e contínua no pós-operatório de cirurgia de revascularização do miocárdio

To compare the effect of the use of intermittent and continuous positive airway pressure in postoperative patients undergoing coronary artery bypass grafting. This study included forty patients divided into two groups: one undergoing continuous positive airway pressure (CPAP Group), and the other undergoing intermittent pressure (Müller Resuscitator Group). The patients were evaluated in relation to the several study variables at the following time points: preoperative, 3rd, 24th, and 48th hours. The patient groups were homogeneous in relation to the several demographic and clinical variables. The values of pO2, pCO2 and sO2 were within normal limits and no significant differences were found between the groups. Regarding respirometry, the groups showed significant differences in the tidal volume and respiratory rate at the 48th postoperative hour. Dyspnea and use of accessory muscle in postoperative assessments were found with a significantly higher frequency in patients undergoing CPAP. Patients undergoing Müller Resuscitator had a normal chest radiograph more frequently than did patients undergoing CPAP. Both devices were shown to be able to keep pO2, pCO2, and sO2 values within normal limits. However, when the objective was pulmonary reexpansion with less imposed workload, the Müller Resuscitator was more effective because of its prompter action and consequently lower levels of dyspnea, respiratory rate (RR) and use of accessory muscle were observed.

Measurement of hemoglobin saturation and hematocrit by a multispectral imaging approach

Determination of the local oxygen saturation in microvessels is relevant for intravital studies including angiogenesis, angioadaptation, tumor development or ischemia reperfusion injury. We adapted a multispectral approach, based on differences in absorption spectra between oxygenated and deoxygenated hemoglobin, for oxygen saturation (SO2) and hematocrit measurement during trans- and epi-ilumination intravital microscopy. Data can be obtained as 2D images of the observed area. For validation we performed in vivo experiments in rat mesentery under: hyperoxia (inspiratory O2concentration 100%, mesentery exposed to pure oxygen), normoxia (breathing room air, mesentery covered with oxygen-impermeable film), hypoxia (inspiratory O2 conc. 9% in N2, mesentery exposed to pure nitrogen), anoxia (superfusion of mesentery with Na-dithionite). Using data obtained under hyperoxic and anoxic conditions as references, SO2 values under normoxic control conditions averaged ~95% in arterioles and ~87% in venules. In conclusion, the presented method allows generation of intravascular SO2 and hematocrit images for all vessels in a microscopic field of view during trans- and epi-ilumination and in different tissues.

Sensitivities of gas‐phase dimethylsulfide oxidation products to the assumed mechanisms in a chemical transport model

The gas‐phase products of dimethylsulfide (DMS) oxidation are simulated in the global 3D Model of Atmospheric Transport and Chemistry (MATCH). The focus is on the sensitivities to the assumed mechanisms of DMS oxidation chemistry in large‐scale models, and hence volcanic and anthropogenic sources of SO2 are ignored. Four representations of DMS chemistry are considered, including two comprehensive mechanisms (about 50 reactions) and two parameterized schemes (four and five reactions). The gas‐phase yields of DMS, SO2, methanesulfonic acid (MSA) and H2SO4 are compared between these four cases as a measure of the sensitivity to uncertain DMS chemistry. Among the four cases, DMS is largely invariant, while SO2 using parameterized chemistry is three times higher than its levels using comprehensive chemistry in the tropical upper troposphere. For MSA and H2SO4, there are order‐of‐magnitude inter‐mechanistic differences at high and low altitudes in the extratropics, respectively. The differences are attributed to fixed branching yields and the absence of important intermediate species and pathways in the parameterized mechanisms. Regional budgets are also analyzed within the remote Southern Ocean and central tropical Pacific. While the DMS budget varies primarily between the regions, the SO2, MSA and H2SO4 budgets vary strongly between the regions and mechanisms. The DMS oxidation products, therefore, are as sensitive to the assumed mechanisms as to the external conditions between the tropics and extratropics. To distinguish between the mechanism cases, the MATCH simulations are also compared to campaign measurements. The simulated values of DMS and SO2 are found to approximate the observations, but do not provide mechanism differentiation. The gas‐phase H2SO4 and MSA simulations differ more extensively from the observations, yet the comprehensive chemistry cases give a better fit to the MSA measurements. Better fits to the MSA observations are also achieved for the two mechanisms that consider dimethylsulfoxide (DMSO) as an MSA precursor.

RELATION OF POLLUTANT CONCENTRATIONS TO THE PÉCZELY’S LARGE SCALE WEATHER SITUATIONS IN SZEGED, SOUTHERN HUNGARY

The aim of the study is to determine how contaminating gases are concentrated during various weather conditions which are closely related to various large-scale weather situations in the town of Szeged. The data are derived from an automatic meteorological station in the downtown, beside a highway. Measurements taken every 30 minutes between 1996-1998 are used in the paper. Values of CO, NO, NO2, NOx, O3, SO2 and dust are analysed as functions of various large-scale weather situations, established by Peczely for the Carpathian Basin.

General Outlook of World Main Energy Resources and Numerical Approach for Prediction of SO2 Emission Value

It is stated in the report of the World Energy Committee that coal will be the first energy source in the year of 2000 because of reserve capacity and widespread existence of the coal geographic region. Solid fuels especially are increasingly dominated inputs for primary electricity generation (54% total input in 1980, and increasing to 66% in 1997) and in a few key industrial sectors, such as steel, cement and chemical. However, since 1990, coal consumption in the European Union was declining due to the restructuring coal industry. It was the only part of the world, except for the “CIS and Central—Eastern Europe” for other reasons (economical and political reforms), in which the trend was observed. These scientific evidences and observations indicated that coal would be the most favored energy source of the next century in spite of decreasing economic petroleum reserves. Besides of this, according to environmental problems, the technologies of coal preparing, washing, and combustion for obtaining appropriate methods and limits progressed fast. Based on these aspects, to provide numerical information on fundamental SO2 value, two different equations are derived and showed in nomogram based on coal technological parameters (according to coal [hard and brown coal] consumption [C, tons] lower heat value [LHV, GJ/tons], moisture content [N, %], sulphur content [S, %] and sulphur content in ash [K s , %]). These equations and nomograms contain data of 17 different Central and Eastern Western countries of Europe from 1997. It is obvious that large coal consumer's countries are also large amount SO2 value producer countries. For instance, CIS (8.85 × 106 ton), Ukraine (4.26 × 106 ton), Poland (3.11 × 106 ton), Germany (2.36 × 106 ton), and Czechoslovakia (2.27 × 106 ton.).