Ambient Intelligence and Smart Home Automation systems are currently emerging as feasible and ready to exploit solutions to support more intelligent features inside future and current homes. Thanks to increased availability of off-the-shelf components and to relatively easy to implement solutions we are experiencing a steady evolution of households, causing an ever-increasing users’ awareness of the capabilities of such innovative environments. To foster effective adoption of Smart Home Automation technologies in our home environments, traditional architectural and plant design must be complemented by sound design methodologies and tools, supporting the whole environment design cycle, including for example modeling, simulation and emulation, as well as, when feasible, formal model-checking and verification. Several research efforts have already addressed the design of expressive modeling tools, mostly based on Semantic Web technologies, as well as of suitable platforms for adding interoperation and rule-based intelligence to home environments. This paper proposes a new modeling methodology designed to fit the different phases of Intelligent Environments design, with a particular focus on validation and verification of the whole system. Carefully designed separation of modeled entities permits to exploit the DoMAIns framework during all phases of the environment design, from early abstract conception to the final in-field deployment. The DoMAIns design methodology is applied to a sample use case that involves comprehensive modeling and simulation of a Bank Security Booth, including the environment, the control algorithms, the automation devices and the user. Results show that the approach is feasible and that can easily handle different types of environment modeling, required in the different design phases, and for each of them it may support simulation, emulation, or other verification techniques.