Collaborative environmental governance (CEG) is increasingly advocated to address the environmental risk issues in the integrated development of urban agglomerations. Constructing an effective CEG network from the perspective of interdependent multilevel network plays a vital role in promoting the environmental governance of urban agglomerations. To investigate the structure characteristics and formation mechanism of CEG network, this paper takes the Yangtze River Delta urban agglomeration as the research area, and employes the social network analysis and Exponential Random Graph Model (ERGM) methods to analyze the CEG network, which consists of the collaborative network of cities, relationship network of topics, and affiliation network connecting cities to topics. Research results show that the CEG level in the Yangtze River Delta urban agglomeration continues to improve, while the CEG network is still not in a tightly connected state. For the collaborative network of cities, it presents the small world characteristics and forms a cooperative trend of “central-subcentral-peripheral city.“For the relationship network of topics, the evolution of environmental governance topics is characterized by “from aspect to point.” For the affiliation network connecting cities to topics, as the diversity of environmental governance topics increases among cities, cities within the Yangtze River Delta urban agglomeration tend to share the similar topics. In addition, the interactive triangular structures, star structures, open triangular structures and closed triangular structures in the network can promote the formation of new cooperative relationships in CEG network.
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