Small Voltage Research Articles

Effect of Stray and High Voltage Exposure on Livestock: An Overview

Electricity is essential to dairy farming and electrically powered machines are used for milking, automatic feed dispensers and heated water bowls. Leakage of current from these equipments, high voltage lines or faulty connections between the electrical circuit and the earth can lead to an undesirable electrical phenomenon called stray voltage. Stray voltage is a small voltage (<10V) that can be measured between two possible contact points. Cows can sense voltages at approximately one-tenth of a human being. Humans have inherently higher body resistance than cows and generally have shoes or boots while working in barns, which further increases resistance. Consequently, humans do not feel what animals feel. Stray voltages less than 0.5 volts are considered normal. Stray voltages vary, depending on the circuits used and the amount of moisture in the soil around the grounding rod. Impact of stray currents on livestock at current 1 - 3 mA: At current 4 - 6 mA: common behavioral response such as flinching or delaying drinking water. At current > 6 mA (up to 10): Feed intake is reduced, resulting in lower meat and milk production. Common symptoms of stray voltage in cows include hesitation to enter the parlor, they may stampede or rush out of the parlor when released, cows dance or step around constantly while in the milking parlor, Normal milk letdown is interrupted, Increased milking time, Udder irritation caused by residual milk and increased somatic cell count which increases the incidence of mastitis.

Covalent organic framework‐derived Fe, Co‐nitrogen codoped carbon as a bifunctional electrocatalyst for rechargeable efficient Zn–air batteries

AbstractThe development of cathode materials with controllable physicochemical structures and explicit catalytic sites is important in rechargeable Zn–air batteries (ZABs). Covalent organic frameworks (COFs) have garnered increasing attention owing to their facile synthesis methods, ordered pore structure, and selectivity of functional groups. However, the sluggish kinetics of oxygen evolution reaction (OER) or oxygen reduction reaction (ORR) inhibit their practical applications in ZABs. Herein, nucleophilic substitution is adopted to synthesize pyridine bi‐triazine covalent organic framework (denoted as O‐COF), and meanwhile, ionothermal conversion synthesis is employed to load MOx (M=Fe, Co) onto carbon nanosheet (named as FeCo@NC) to modulate the electronic structure. The Fe, Co‐N codoped carbon material possesses a large portion of pyridinic N and M‐N, high graphitization, and a larger BET surface area. An outstanding bifunctional activity has been exhibited in FeCo@NC, which provides a small voltage at 10 mA cm−2 for OER (E10 = 1.67 V) and a remarkable half‐wave voltage for ORR (E1/2 = 0.86 V). More impressively, when assembling ZABs, it displays notable rate performance, significant specific capacity (783.9 mAh gZn−1), and satisfactory long‐term endurance. This method of regulating covalent organic framework and ionothermal synthesis can be extended to design diverse catalysts.

Flash luminescence, resistive switching and metal-insulator transitions in ceramic oxides

A combination of voltage-induced, reversible OFF-ON resistive switching and electroluminescence is reported in two materials that are both mixed conductors of oxide ions and electron holes. This occurs at high temperatures, 450–700 °C in cubic, fluorite-structured hafnia, YxHf1-xO2-x/2 and at more modest temperatures, 200–300 °C in Ca-doped BiFeO3 with a cubic perovskite structure. In both cases, a small voltage in the range 2–40 V is applied across mm-thick ceramic samples. Both effects are influenced greatly by oxygen exchange with the surrounding atmosphere and involve a combination of electron injection at the cathode, hole injection at the anode and generation of internal pn junctions. There are strong similarities between these effects and flash sintering but without the significant sintering, thermoluminescence and Joule heating that may be observed with flash sintering.

Shifting the Oxygen-Evolution Reaction Pathway via Cation Engineering to Activate Lattice Oxygen in Metal-Organic Frameworks.

Metal-organic frameworks (MOFs) as promising electrocatalysts have been widely studied, but their performance is limited by conductivity and coordinating saturation. This study proposes a cationic (V) modification strategy and evaluates its effect on the electrocatalytic performance of CoFe-MOF nanosheet arrays. The optimal V-CoFe-MOF/NF electrocatalyst exhibits excellent oxygen-evolution reaction (OER)/hydrogen-evolution reaction (HER) performance (231 mV at 100 mA cm-2/86 mV at 10 mA cm-2) in alkaline conditions, with its OER durability exceeding 400 h without evident degradation. Furthermore, as a bifunctional electrocatalyst for water splitting, a small cell voltage is achieved (1.60 V at 10 mA cm-2). The practicability of the catalyst is further evaluated by membrane electrode assembly (MEA), showing outstanding activity (1.53 V at 10 mA cm-2) and long-term stability (at 300 mA cm-2). Moreover, our results reveal the apparent reconstruction properties of V-CoFe-MOF/NF in alkaline electrolytes, where the partially dissolved V promotes the formation of more active β-MOOH. The mechanism study shows the OER mechanism shifts to a lattice oxygen oxidation mechanism (LOM) after V doping, which directly avoids complex multistep adsorption mechanism and reduces reaction energy. This study provides a cation mediated strategy for designing efficient electrocatalysts.

Toward low-power-consumption source-gated phototransistor

The power consumption is challenging the next-generation electronic and optoelectronic devices. In this Letter, the n-type source-gated transistor (SGT) enabled by CdS nanobelt is investigated in detail, demonstrating the expected low power consumption, along with impressive photodetection performance. The SGT is realized by deliberately introducing the Schottky barrier at the source of the staggered-electrode transistor, exhibiting a small saturated voltage (VSAT) of 0.84 ± 0.21 V and a remarkably low power consumption of 7.56 ± 4.01 nW. Under illumination, the as-constructed SGT also shows a low power consumption of 7.58 nW, which is much lower than that of the most reported phototransistors operating in the saturated region. Moreover, the source-gated phototransistor also shows a high responsivity of 2.54 × 103 A W−1 and a high detectivity of 6.72 × 1012 Jones. All results imply that the as-constructed low-power-consumption source-gated phototransistor promises next-generation high-performance electronic and optoelectronic devices.

Three‐dimensional interconnected graphene network‐based high‐performance air electrode for rechargeable zinc‒air batteries

AbstractAlthough zinc‒air batteries (ZABs) are regarded as one of the most prospective energy storage devices, their practical application has been restricted by poor air electrode performance. Herein, we developed a free‐standing air electrode that is fabricated on the basis of a multifunctional three‐dimensional interconnected graphene network. Specifically, a three‐dimensional interconnected graphene network with fast mass and electron transport ability, prepared by catalyzing growth of graphene foam on nickel foam and then filling reduced graphene oxide into the pores of graphene foam, is used to anchor iron phthalocyanine molecules with atomic Fe‒N4 sites for boosting the oxygen reduction during discharging and nanosized FeNi hydroxides for accelerating the oxygen evolution during charging. As a result, the obtained air electrode exhibited an ultra‐small electrocatalytic overpotential of 0.603 V for oxygen reactions, a high peak power density of 220.2 mW cm‒2, and a small and stable charge‒discharge voltage gap of 0.70 V at 10 mA cm‒2 after 1136 cycles. Furthermore, in situ Raman spectroscopy together with theoretical calculations confirmed that phase transformation of FeNi hydroxides takes place from α‐Ni(OH)x to β‐Ni(OH)x to γ‐Ni(3+δ)+OOH for the oxygen evolution reaction and Ni is the active center while Fe enhances the activity of Ni active sites.

Anisotropic tribology and electrification properties of sliding-mode triboelectric nanogenerator with groove textures

Sliding-mode triboelectric nanogenerator (S-TENG) is based on the coupling of triboelectrification and electrostatic induction, converting electrical energy from sliding motion. Introducing micro-textures into the sliding surface, and adjusting the angle between the texture and sliding direction (direction angle) may achieve performance anisotropy, which provides novel ideas for optimizing the tribology and electrification performance of S-TENG. To guide the performance optimization based on the anisotropy, in this paper, groove micro-textures were fabricated on the surface of S-TENG, and anisotropic tribology and electrification performance were obtained through changing the direction angle. Based on the surface analysis and after-cleaning tests, the mechanism of the anisotropy was explained. It is shown that the anisotropy of friction coefficient can be attributed to the changes of texture edge induced resistance and groove captured wear debris, while the voltage anisotropy is due to the variations of debris accumulated on the sliding interface and the resulting charge neutralization. Among the selected 0°–90° direction angles, S-TENG at angle of 90° exhibits relatively small stable friction coefficient and high open-circuit voltage, and thus it is recommended for the performance optimization. The open-circuit voltage is not directly associated with the friction coefficient, but closely related to the wear debris accumulated on the sliding interface. This study presents a simple and convenient method to optimize the performance of S-TENG, and help understand the correlation between its tribology and electrical performance.

Construction of MOF-derived hollow sugar gourd-like Ni-Co-S@NiMoO4•xH2O nanocage arrays for efficient solar-powered overall water splitting

In situ growth of nanoarrays on conductive substrates is an efficient strategy for designing electrocatalysts. However, preparing array with excellent catalytic activities for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) remains a challenge. Here, we construct a novel hollow sugar gourd-like Ni-Co-S@NiMoO4·xH2O/NF nanocage array through MOF derivation strategy for stable solar-driven overall water splitting. Due to the hollow core–shell structure and multi-component advantages, the Ni-Co-S@NiMoO4·xH2O/NF presents high density of active sites and fast charge transfer rate. Therefore, Ni-Co-S@NiMoO4·xH2O/NF exhibits attractive electrocatalytic activity in alkaline electrolytes for HER (90 mV@10 mA cm−2) and OER (208 mV@10 mA cm−2, 245 mV@100 mA cm−2). The corresponding two-electrode electrolytic cell demonstrates small cell voltage (1.515 V @ 10 mA cm−2) and shows durability over 50 h at 10 mA cm−2, exhibiting excellent overall water splitting performance. It is worth noting that the solar-assisted electrolysis cell reaches a high solar-to-hydrogen (STH) conversion rate of 19.4 %. The construction of this unique hollow structure gives a fascinating method for improving the HER and OER performance of transition metal sulfide electrocatalysts.

Molybdenum oxide/nickel molybdenum oxide heterostructures hybridized active platinum co-catalyst toward superb-efficiency water splitting catalysis

A new catalyst has been developed that utilizes molybdenum oxide (MoO3)/nickel molybdenum oxide (NiMoO4) heterostructured nanorods coupled with Pt ultrafine nanoparticles for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) toward industrial-grade water splitting. This catalyst has been synthesized using a versatile approach and has shown to perform better than noble-metals catalysts, such as Pt/C and RuO2, at industrial-grade current level (≥1000 mA·cm−2). When used simultaneously as a cathode and anode, the proposed material yields 10 mA·cm−2 at a remarkably small cell voltage of 1.55 V and has shown extraordinary durability for over 50 h. Density functional theory (DFT) calculations have proved that the combination of MoO3 and NiMoO4 creates a metallic heterostructure with outstanding charge transfer ability. The DFT calculations have also shown that the excellent chemical coupling effect between the MoO3/NiMoO4 and Pt synergistically optimize the charge transfer capability and Gibbs free energies of intermediate species, leading to remarkably speeding up the reaction kinetics of water electrolysis.

Single Crystal Seed Induced Epitaxial Growth Stabilizes α-FAPbI3 in Perovskite Solar Cells.

FAPbI3 stands out as an ideal candidate for the photoabsorbing layer of perovskite solar cells (PSCs), showcasing outstanding photovoltaic properties. Nonetheless, stabilizing photoactive α-FAPbI3 remains a challenge due to the lower formation energy of the competitive photoinactive δ-phase. In this study, we employ tetraethylphosphonium lead tribromide (TEPPbBr3) single crystals as templates for the epitaxial growth of PbI2. The strategic use of TEPPbBr3 optimizes the evolution of intermediates and the crystallization kinetics of perovskites, leading to high-quality and phase-stable α-FAPbI3 films. The TEPPbBr3-modified perovskite exhibits optimized carrier dynamics, yielding a champion efficiency of 25.13% with a small voltage loss of 0.34 V. Furthermore, the target device maintains 90% of its initial PCE under maximum power point (MPP) tracking over 1000 h. This work establishes a promising pathway through single crystal seed based epitaxial growth for achieving satisfactory crystallization regulation and phase stabilization of α-FAPbI3 perovskites toward high-efficiency and stable PSCs.

Modulation of energy barrier of reaction steps over S-doped Ni(OH)2/Cu composites to achieve high-performance urea electrolysis catalysts

Ni(OH)2 has been found a cost-effective and promising electrocatalyst for urea oxidation reaction (UOR). However, HER activity is challenging due to its weak adsorption of active H atoms, poor water dissociation, and low conductivity. In this study, heteroatomic S-doped Ni(OH)2/Cu composite has been synthesized using the one-pot electrodeposition process. The incorporation of S atoms significantly enhanced the electron transfer rate and adsorption of active H atoms, which promoted the UOR and HER process. Similarly, the metallic Cu with S-doped Ni(OH)2 also exhibited the synergistic effect and promoted water dissociation, adsorption of active H atoms. As expected, S-doped Ni(OH)2/Cu composites exhibit remarkable urea electrolysis activity with a small cell voltage of 1.35 V to approach the current density of 10 mA cm−2. Results indicate that the adopted strategy has been found effective and the prepared composite is a good bifunctional urea electrolysis catalyst.

J-MISFET Hybrid Dual-Gate Switching Device for Multifunctional Optoelectronic Logic Gate Applications.

High-performance and low operating voltage are becoming increasingly significant device parameters to meet the needs of future integrated circuit (IC) processors and ensure their energy-efficient use in upcoming mobile devices. In this study, we suggest a hybrid dual-gate switching device consisting of the vertically stacked junction and metal-insulator-semiconductor (MIS) gate structure, named J-MISFET. It shows excellent device performances of low operating voltage (<0.5 V), drain current ON/OFF ratio (∼4.7 × 105), negligible hysteresis window (<0.5 mV), and near-ideal subthreshold slope (SS) (60 mV/dec), making it suitable for low-power switching operation. Furthermore, we investigated the switchable NAND/NOR logic gate operations and the photoresponse characteristics of the J-MISFET under the small supply voltage (0.5 V). To advance the applications further, we successfully demonstrated an integrated optoelectronic security logic system comprising 2-electric inputs (for encrypted data) and 1-photonic input signal (for password key) as a hardware security device for data protection. Thus, we believe that our J-MISFET, with its heterogeneous hybrid gate structures, will illuminate the path toward future device configurations for next-generation low-power electronics and multifunctional security logic systems in a data-driven society.

The Transfer Dehydrogenation Method Enables a Family of High Crystalline Benzimidazole-linked Cu (II)-phthalocyanine-based Covalent Organic Frameworks Films.

Heterocycle-linked phthalocyanine-based COFs with close-packed π-π conjugated structures are a kind of material with intrinsic electrical conductivity, and they are considered to be candidates for photoelectrical devices. Previous studies have revealed their applications for energy storage, gas sensors, and field-effect transistors. However, their potential application in photodetector is still not fully studied. The main difficulty is preparing high-quality films. In our study, we found that our newly designed benzimidazole-linked Cu (II)-phthalocyanine-based COFs (BICuPc-COFs) film can hardly formed with a regular aerobic oxidation method. Therefore, we developed a transfer dehydrogenation method with N-benzylideneaniline (BA) as a mild reagent. With this in hand, we successfully prepared a family of high crystalline BICuPc-COFs powders and films. Furthermore, both of these new BICuPc-COFs films showed high electrical conductivity (0.022-0.218 S/m), higher than most of the reported COFs materials. Due to the broad absorption and high conductivity of BICuPc-COFs, synaptic devices with small source-drain voltage (VDS=1 V) were fabricated with response light from visible to near-infrared. Based on these findings, we expect this study will provide a new perspective for the application of conducting heterocycle-linked COFs in synaptic devices.

A Green High-k Dielectric from Modified Carboxymethyl Cellulose-Based with Dextrin.

Many crucial components inside electronic devices are made from non-renewable, non-biodegradable, and potentially toxic materials, leading to environmental damage. Finding alternative green dielectric materials is mandatory to align with global sustainable goals. Carboxymethyl cellulose (CMC) is a bio-polymer derived from cellulose and has outstanding properties. Herein, citric acid, dextrin, and CMC based hydrogels are prepared, which are biocompatible and biodegradable and exhibit rubber-like mechanical properties, with Young modulus values of 0.89 MPa. Hence, thin film CMC-based hydrogel is explored as a suitable green high-k dielectric candidate for operation at low voltages, demonstrating a high dielectric constant of up to 78. These fabricated transistors reveal stable high capacitance (2090 nF cm-2) for ≈±3V operation. Using a polyelectrolyte-type approach and poly-(2-vinyl anthracene) (PVAn) surface modification, this study demonstrates a thin dielectric layer (d ≈30 nm) with a small voltage threshold (Vth ≈-0.8 V), moderate transconductance (gm ≈65 nS), and high ON-OFF ratio (≈105). Furthermore, the dielectric layer exhibits stable performance under bias stress of ± 3.5 V and 100 cycles of switching tests. The modified CMC-based hydrogel demonstrates desirable performance as a green dielectric for low-voltage operation, further highlighting its biocompatibility.

Simulation of liquid cone formation on the tip apex of indium field emission electric propulsion thrusters

Field emission electric propulsion (FEEP) thrusters possess excellent characteristics, such as high specific impulse, low power requirements, compact size and precise pointing capabilities, making them ideal propulsion devices for micro-nano satellites. However, the detection of certain aspects, such as the evolution process of the liquid cone and the physical quantities at the cone apex, proves challenging due to the minute size of the needle tip and the vacuum environment in which they operate. Consequently, this paper introduces a computational fluid dynamics (CFD) model to gain insight into the formation process of the liquid cone on the tip apex of indium FEEP. The CFD model is based on electrohydrodynamic (EHD) equations and the volume of fluid (VOF) method. The entire cone formation process can be divided into three stages, and the time-dependent characteristics of the physical quantities at the cone apex are investigated. The influences of film thickness, apex radius size and applied voltage are compared. The results indicate a gradual increase in the values of electrostatic stress and surface tension stress at the cone apex over an initial period, followed by a rapid escalation within a short duration. Apex configurations featuring a small radius, thick film and high voltage exhibit a propensity for liquid cone formation, and the cone growth time decreases as the film thickness increases. Moreover, some unstable behavior is observed during the cone formation process.

Peculiarities of the SCLC Effect in Gate‐All‐Around Silicon Nanowire Field‐Effect Transistor Biosensors

AbstractHigh‐quality liquid gate‐all‐around (LGAA) silicon nanowire (NW) field‐effect transistor (FET) biosensors are fabricated and studied their properties in 1 mm phosphate‐buffered saline solution with pH = 7.4 using transport and noise spectroscopy. At small VDS, the conventional current behavior of FET with a linear dependence on voltage is registered in the output current‐voltage (I‐VM) characteristics with M = 1. At drain‐source voltage VDS &gt; 0.6 V, the I‐V characteristics with stronger power M are revealed. It is shown that the current in LGAA NW FETs follows current proportional to voltage in power M = 4 dependence on small liquid gate voltages. Transport and noise spectroscopy analyses demonstrate that the obtained results are associated with the space‐charge‐limited current (SCLC) effect. Moreover, a strong two‐level random telegraph signal (RTS) is found in the region corresponding to SCLC at VDS values exceeding 0.6 V. The RTS related to single trap phenomena results in a well‐resolved Lorentzian component of noise spectra. The results demonstrate that the SCLC and two‐level RTS phenomenon are correlated effects. They should be taken into account during the development of single‐trap‐based devices, including biosensors.

Hetero-Diatomic CoN4-NiN4 Site Pairs with Long-Range Coupling as Efficient Bifunctional Catalyst for Rechargeable Zn-Air Batteries.

In this study, Co/Ni-NC catalyst with hetero-diatomic Co/Ni active sites dispersed on nitrogen-doped carbon matrix is synthesized via the controlled pyrolysis of ZIF-8 containing Co2+ and Ni2+ compounds. Experimental characterizations and theoretical calculations reveal that Co and Ni are atomically and uniformly dispersed in pairs of CoN4-NiN4 with an intersite distance ≈0.41nm, and there is long-range d-d coupling between Co and Ni with more electron delocalization for higher bifunctional activity. Besides, the in situ grown carbon nanotubes at the edges of the catalyst particles allow high electronic conductivity for electrocatalysis process. Electrochemical evaluations demonstrate the superior ORR and OER bifunctionality of Co/Ni-NC catalyst with a narrow potential gap of only 0.691V and long-term durability, significantly prevailing over the single-atom Co-NC and Ni-NC catalysts and the benchmark Pt/C and RuO2 catalysts. Co/Ni-NC catalyzed Zn-air batteries achieve a high specific capacity of 771 mAh g-1 and a long continuous operation period up to 340 h with a small voltage gap of ≈0.65V, also much superior to Pt/C-RuO2.

Analysis of an underlimiting and overlimiting current regime in a single electrodialysis channel

Overlimiting ionic transfer is considered a mechanism to intensify transport processes in electrodialysis, potentially providing a smaller required footprint of electromembrane units. However, its applicability in desalination is still questionable. To address this aspect of electrodialysis, we characterized desalination in a single-channel electrodialysis unit operated under various current densities, yielding various diluate desalination degrees. Our analysis revealed that the conditions providing <100 % desalination were pertinent to an underlimiting regime with no indication of overlimiting processes. Specifically, no (electro-) convective structures intensifying ionic transfer occurred in the channel under these conditions. Applying electric current densities yielding theoretical desalination larger than 100 % significantly increased the necessary voltage, driving electroconvective vortices. The observation suggested that overlimiting phenomena occur upon setting conditions corresponding to complete desalination and, thus, do not positively contribute to desalination. Notably, the partial loss of membrane ion selectivity was associated with an operation in the overlimiting regime, worsening desalination efficiency. Our results imply that the overlimiting regime is, at least with the tested membranes, unsuitable for enhancing ionic transfer. Conversely, the small voltage required to remove ions in the underlimiting regime was attributed to the effect of natural convection, which readily occurs in the model system.

One-step achieving high performance all-solid-state and all-in-one flexible electrochromic supercapacitor by polymer dispersed electrochromic device strategy

Electrochromic devices (ECD) are widely used to regulate the transmittance of sunlight by applying a small voltage, but the drawbacks like complex layer-by-layer preparation procedures and inconvenient assembling process still exist. To address these problems, gel or solution-type all-in-one ECDs were recently developed for the simple structure, however, the leakage risk and absence of flexible large-area production have limited real applications. Herein, a novel all-solid-state and all-in-one flexible ECD was reported by originally developed polymer dispersed electrochromic device (PDECD) strategy. This all-solid-state flexible ECD could be efficiently prepared only by one step of phase separation without any extra treatment, and demonstrated outstanding stability (92.1 % of original ΔT remained after 10,000 cycles), high coloration efficiency (197 cm2/C), low power consumption (86.4 μW/cm2) and satisfied response time (≤12 s). Meanwhile, the stored power in ECD during coloring process could drive a LED with excellent cyclic stability (93 % of original capacity remained after 3000 cycles), implying that ECD could also serve as an idea electrochromic supercapacitor. What’more, a reported largest viologen-based all-solid-state flexible ECD (17.8 × 13.2 cm2) with robust bending resistance (up to 1000 bending cycles) was successfully fabricated with industrial roller coating technique, which indicated the huge potential in real world.

ИМПЕДАНСНЫЙ АНАЛИЗ ПРОЦЕССОВ ПЕРЕНОСА ЗАРЯДА В СТРУКТУРЕ МЕТАЛЛ/ПОЛИМЕР/МЕТАЛЛ

The reaserch is devoted to the experimental study of charge transfer processes in thin films of an electroactive polymer from the class of polyarylene phthalides – poly (diphenylene phthalide). The method of impedance analysis of thin polymer films was used in this work. The material is quite well studied using other methods, such as thermally stimulated methods, optical spectroscopy, etc. However, frequency measurements were carried out mainly only in the field of determining capacitance-voltage characteristics. And since the polymer is electroactive, we should expect to identify features associated with charge transfer in the alternating field mode. In this regard, the work carried out an impedance analysis of thin films of poly (diphenylene phthalide) in the frequency range from 0.1 to 106 Hz. Typically, in impedance analysis, in addition to an ac field, a small DC bias voltage is applied to the metal/polymer/metal structure. This makes it possible to obtain data on surface polarization, charge carrier mobility, and the Maxwell-Wagner effect in the case of studying multilayer films. However, taking into account the electrical activity of the studied material, even impedance analysis in an alternating field, but with an effective voltage range from 0.1 to 10 V, made it possible to evaluate some of the electrophysical characteristics of the behavior of thin films. It was found that the slope of the impedance curve depends on the mechanism of transport of charge carriers in the polymer film. As the voltage increases from 0.1 to 10 V, an increase in the slope of the graph is observed. With an increase in the magnitude of the effective voltage, a transition occurs from the ohmic to the injection mechanism of transport of charge carriers limited by traps. When reaching 2 V, a mode of complete filling of the traps is observed, as a result of which an increase in voltage ceases to affect the slope of the frequency response. The dependence of the transition frequency fc on voltage has been plotted. This frequency corresponds to the transition from the predominance of the active to the reactive component of the impedance. Here, an exponential dependence on the magnitude of the applied voltage is observed, which also indicates the dependence of the mechanisms of transport of charge carriers in the polymer film on voltage (electric field).