Small Fraction Of Particles Research Articles

Carbon Cycling in Marine Particles Based on Inorganic and Organic Stable Isotopes

The marine carbon cycle has a central role in biogeochemical cycling and a close interaction with the climate system. Here, we use the stable carbon isotope (δ13C) of particulate inorganic carbon (PIC) and particulate organic carbon (POC) in marine particles to diagnose carbonate dissolution and organic matter respiration processes in the ocean water column. We show PIC dissolution both in the euphotic zone, potentially driven by POC remineralization, and a preferential dissolution of coccoliths compared to foraminifera below the saturation horizon in the water column. Within the oxygen deficient zone (ODZ), POC remineralization and consequent respiration-driven PIC dissolution are both significantly diminished. We also demonstrate that POC remineralization preferentially removes a 13C-enriched component compared to isotopically-light bulk POC in both the large size fraction (LSF, > 51μ m) and small size fraction (SSF, 0.5 – 51μ m) of the pump particles, but exhibits a greater impact on the large particles because of its smaller inventory. Simultaneously, addition of a 13C-enriched heterotrophic or chemoautotrophic component to the SSF further increases the isotopic offset between SSF and LSF POC. Overall, this study uses δ13C to provide novel evidence for different biogeochemical processes in marine particles, and demonstrates carbonate dissolution in the ocean water column, both driven by bulk seawater chemistry and organic matter respiration within particles. The absence of O2 in the ODZ likely protects carbonate from dissolving by severely limiting organic matter respiration, thus reducing shallow PIC dissolution within the ODZs.

Long-range velocity correlations from active dopants

Active matter systems display collective behaviors that are impossible in thermodynamic equilibrium. One such feature, observed in in dense active matter systems is the appearance of long-range velocity correlations without explicit aligning interaction. However, the conditions for the appearance of these correlations remain largely unexplored. Here we show that such long-range velocity correlations can also be generated in a dense athermal passive system by the inclusion of a very small fraction of active Brownian particles. We develop a continuum theory to explain the emergence of velocity correlations generated via such active dopants. We validate the predictions for the effects of magnitude and persistence time of the active force and the area fractions of active and passive particles using extensive Brownian dynamics simulation of a canonical active-passive mixture. Our work decouples the roles that density and activity play in generating long-range velocity correlations in such exotic non-equilibrium steady states.

Effects of Alpha Particle Fraction on Kinetic Plasma Turbulence

Solar activities have an extraordinary impact on interplanetary space, enriching the plasma dynamics including turbulent heating of various species. The small fraction of alpha particles is believed to play a significant role in the turbulent dynamics of the solar wind. Here we present fully kinetic particle-in-cell simulations to reveal the influences of the alpha particles in decaying plasma turbulence. Multiple run cases with different controlled variations of proton and alpha density are performed to compare and evaluate the energy conversion processes. It is found that the alpha particles can suppress the energy conversion rate with increasing density. Besides, the alpha particles show more heating intermittency than the proton species. Interestingly, on the other hand, the electrons do not show any change in their dynamics, including overall heating. These two positive charge species have more correlation in temperature anisotropy as their densities are comparable. Our results provide valuable insights on the turbulence with different species compositions to a certain extent, especially with abundant heavy particles.

Characterization of refractory aerosol particles collected in the tropical upper troposphere–lower stratosphere (UTLS) within the Asian tropopause aerosol layer (ATAL)

Abstract. Aerosol particles with diameters larger than 40 nm were collected during the flight campaign StratoClim 2017 within the Asian tropopause aerosol layer (ATAL) of the 2017 monsoon anticyclone above the Indian subcontinent. A multi-impactor system was installed on board the aircraft M-55 Geophysica, which was operated from Kathmandu, Nepal. The size and chemical composition of more than 5000 refractory particles/inclusions of 17 selected particle samples from seven different flights were analyzed by use of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) combined with energy dispersive X-ray (EDX) microanalysis. Based on chemical composition and morphology, the refractory particles were assigned to the following particle groups: extraterrestrial, silicates, Fe-rich, Al-rich, Hg-rich, other metals, C-rich, soot, Cl-rich, and Ca-rich. Most abundant particle groups within the refractory particles are silicates and C-rich (non-volatile organics). In samples taken above the tropopause, extraterrestrial particles are becoming increasingly important with rising altitude. The most frequent particle sources for the small (maximum in size distribution DP-max=120 nm) refractory particles carried into the ATAL are combustion processes at the ground (burning of fossil fuels/biomass burning) and the agitation of soil material. The refractory particles in the ATAL represent only a very small fraction (< 2 % by number for particles > 40 nm) of the total aerosol particles, which are dominated by species like ammonium, sulfate, nitrate, and volatile organics. During one flight, a large number of very small (DP-max=25 nm) cinnabar particles (HgS) were detected, which are supposed to originate from a ground source such as coal combustion or underground coal fires.

Conversion of Natural Soil to Paddy Promotes Soil Organic Matter Degradation in Small-Particle Fractions: δ13C and Lipid Biomarker Evidence

The stabilization mechanism of soil organic matter (SOM) has received considerable attention. It is widely accepted that mineral sorption/protection is important for SOM stabilization. However, it remains unclear which organic carbon component is beneficial for mineral protection. We collected soil samples from a paddy field (TP) to compare with natural soil (NS). To illustrate the behavior of different SOM pools and their protection by particles, we separated the soils into different particle-size fractions and then removed the active minerals using an acid mixture (1 M HCl/10% HF). The different carbon pools were analyzed using stable carbon isotopes and lipid biomarkers. Our study showed that acid treatment evidently increased the extractability of free lipids, usually over 60%, which confirmed the predominant role of minerals in SOM protection. For NS, the δ13C values increased with decreasing soil particle sizes and soil depths, indicating that 13C-enriched SOM was selectively preserved. However, this trend disappeared after cultivation, which was mainly attributed to the combined effects of the input of 13C-depleted fresh SOM and decomposition of the preserved 13C-enriched SOM. Meanwhile, based on the degradation parameters of the overall lipid biomarkers, SOM showed higher degradation states in clay and silt fractions than in the sand fraction before cultivation. It is possible that the small particle-size fractions could selectively absorb highly degraded SOM. The clay-associated SOM showed a low degradation state, but its carbon content was low after cultivation. We propose that the previously protected SOM was degraded after cultivation and was replaced by relatively fresh SOM, which should be carefully monitored during SOM management.

Abstract 1588: Identification of new signaling pathways between fibroblasts & tumor cells in pancreatic cancer

Abstract We explore the unstudied role of nanoparticles (NPs), recently discovered secreted non-vesicular nanoparticles, in signaling between pre-cancer associated fibroblasts (preCAF), CAFs, and tumor cells. We generated two novel primary lines preCAF PFUM1 from a patient with high-grade intraductal papillary mucinous neoplasms and CAF FUM2 from a patient with pancreatic ductal adenocarcinoma, all tests performed between passages 2 and 3, fibroblast purity validated by RT-PCR and ACTA2 immunofluorescence. Small extracellular vesicles (sEVs), exomeres, and supermeres (the two main forms of NPs) were isolated by the ultracentrifugation method from PF-UM1 and F-UM2 with n=2-3 experiments. To validate the isolation, we used nanoparticle tracking, electron, and fluid-phase atomic force microscopy. Proteins were quantified by BCA assay. Liquid chromatography-mass spectrometry characterized the cargo from each fraction. Human cancer lines MIAPACA2 and SU8686 were treated with 10 μg of each fraction and cell proliferation was tested by phase-contrast images (Cytation 5), analyzed by Ilastik-based 1.4.0 machine-learning. We performed fluorescent Ki-67 and vimentin staining and quantified in QuPath 0.4.3. Non-parametric statistics were performed in Prism GraphPad. NPs constitute the major fraction of small particles released by fibroblasts, containing 80.5% (PFUM1) and 77.5% (FUM2) of the protein load by quantification. Mass spectrometry reveals enrichment of growth factors, epithelial-to-mesenchymal (EMT) transition, and metabolism-associated proteins in the NPs compared to sEVs. At 72 hours, cell proliferation for Su8686 reveals a proliferative effect for all fractions from both PFUM1 and FUM2 (19-63% increase compared to controls, p=0.049 to <0.0001). For MIAPACA2, only supermeres from PFUM1 and FUM2 consistently increased proliferation (9.5-35% increase, p=0.0051 to <0.0001). Ki-67 expression in MIAPACA2, increased by 9.6-23.0% following treatment by NPs (all p<0.0001) and by 2.9-9.2% with sEVs (p=0.011 to <0.0001). EMT was estimated by vimentin in MIAPACA2, as all preCAF fractions from PFUM1 reduced vimentin expression (p<0.001), while CAF FUM2 NPs increased vimentin expression (p<0.0001) while sEVs had no effect (p=0.075). In conclusion, the majority of pancreatic tumor-associated fibroblast small secretome is composed of NPs, exhibiting significant functional pro-tumoral effects. Citation Format: Ayman Al Shoukari, Maelle Batardiere, Nooshin Movahed, Camille beaussier, Jumanah Baig, Melissa gonzalez, Patricia Moraille, Eric Bonneil, Louise Rousseau, Simon turcotte, Kathleen Delgiorno, Marcus Tan, Anna Means, Elham Dianati Ajibisheh, Quoc-huy Trinh. Identification of new signaling pathways between fibroblasts & tumor cells in pancreatic cancer [abstract]. In: Proceedings of the American Association for Cancer Research Annual Meeting 2024; Part 1 (Regular Abstracts); 2024 Apr 5-10; San Diego, CA. Philadelphia (PA): AACR; Cancer Res 2024;84(6_Suppl):Abstract nr 1588.

Wall-resolved large eddy simulation of mixed-size sand-laden flow

Most of the existing numerical studies on wind-blown sand flow simplify sands into single-size particles, whereas natural wind-blown sand flow is a two-phase flow with mixed-size particles, thus, the simulation of mixed-size sand-laden flow is necessary. In the present work, wall-resolved large eddy simulations of mixed-size sand-laden flows are realized. Each sand in the wind field is tracked using the Lagrangian point-particle model. The transport characteristics of sand particles in mixed-size sand-laden flow are investigated under the premise of considering bed erosion. Considering the significant influence of sand-bed collision on simulation, the splash function is modified in the present simulation according to the previous experimental results. It reveals that in mixed-size sand-laden flow, the fraction of rebound sand particles in all the saltation particles is approximately 0.6, which is twice times of the ejected sand particles, and the modification of the sand rebound angle greatly affects the simulation results of mixed-size sand-laden flow. Meanwhile, the mean size of the saltation sand particles decreases with height and is 20% lower at the top of the saltation layer than that near the sand bed in the present simulation. Further analysis by grouping of sands with their size shows that the sand transport intensity of small sands decreased more rapidly with increasing height. The volume fraction and sand transport intensity of small sand particles exceed those of medium and large sand particles at heights y/δ = 0.05 and y/δ = 0.1.

Multi-Technique Characterization of 3.45 Ga Microfossils on Earth: A Key Approach to Detect Possible Traces of Life in Returned Samples from Mars.

The NASA Mars 2020 Perseverance rover is actively exploring Jezero crater to conduct analyses on igneous and sedimentary rock targets from outcrops located on the crater floor (Máaz and Séítah formations) and from the delta deposits, respectively. The rock samples collected during this mission will be recovered during the Mars Sample Return mission, which plans to bring samples back to Earth in the 2030s to conduct in-depth studies using sophisticated laboratory instrumentation. Some of these samples may contain traces of ancient martian life that may be particularly difficult to detect and characterize because of their morphological simplicity and subtle biogeochemical expressions. Using the volcanic sediments of the 3.45 Ga Kitty's Gap Chert (Pilbara, Australia), containing putative early life forms (chemolithotrophs) and considered as astrobiological analogues for potential early Mars organisms, we document the steps required to demonstrate the syngenicity and biogenicity of such biosignatures using multiple complementary analytical techniques to provide information at different scales of observation. These include sedimentological, petrological, mineralogical, and geochemical analyses to demonstrate macro- to microscale habitability. New approaches, some unavailable at the time of the original description of these features, are used to verify the syngenicity and biogenicity of the purported fossil chemolithotrophs. The combination of elemental (proton-induced X-ray emission spectrometry) and molecular (deep-ultraviolet and Fourier transform infrared) analyses of rock slabs, thin sections, and focused ion beam sections reveals that the carbonaceous matter present in the samples is enriched in trace metals (e.g., V, Cr, Fe, Co) and is associated with aromatic and aliphatic molecules, which strongly support its biological origin. Transmission electron microscopy observations of the carbonaceous matter documented an amorphous nanostructure interpreted to correspond to the degraded remains of microorganisms and their by-products (extracellular polymeric substances, filaments…). Nevertheless, a small fraction of carbonaceous particles has signatures that are more metamorphosed. They probably represent either reworked detrital biological or abiotic fragments of mantle origin. This study serves as an example of the analytical protocol that would be needed to optimize the detection of fossil traces of life in martian rocks.

Transport and retention of micro-polystyrene in coarse riverbed sediments: effects of flow velocity, particle and sediment sizes

Riverbed sediments have recently been found to be an important reservoir for microplastics. But the hydrogeological factors that control the abundance of microplastics are complex and conceptual frameworks priorising the parameters affecting their transport and retention during deep riverbed filtration are still missing. In this study a series of saturated column experiments was conducted to investigate the vertical distribution patterns of secondary polystyrene fragments (100–2000 μm) in dependence on their particle size, grain size of the sediment, seepage velocity and duration of infiltration flow. The columns with a length of 50 cm were operated with flow velocities between 1.8 m d−1 and 27 m d−1. Invasive samples obtained after the experiments were density separated and then depth profiles of microplastic concentrations were retrieved using fluorescence imaging analysis. Most polystyrene particles were retained in the upper 20 cm and 15 cm of the medium gravel and coarse sand sediments, respectively. Through the high particle retention riverbed sediments can act as a temporary sink or long term retention site for the transport of microplastic particles (MPPs) from streams to oceans. A small fraction of particles ranging from 100 to 500 μm in size was observed down to infiltration depths of 50 cm suggesting that MPPs at the pore scale have the potential to be advectively transferred via hyporheic exchange or induced bank filtration into coarse riverbed sediments and alluvial aquifers. MPP abundance over column depth follows an exponential relationship with a filter coefficient that was found to depend significantly on the flow rate, MPP and sediment grain size, as indicated by multiple linear regression (R2 = 0.92). The experimentally derived empirical relation allows to estimate particle abundances of initially negatively buoyant MPP in riverbed sediments by surface water infiltration.

Differentiation of prokaryotic community composition in suspended sediment size-fractionation in a small loess watershed

The transfer of particle-bound prokaryotes and substrates from slopes to rivers during soil erosion is a crucial dynamic process that greatly influences terrestrial biological and geochemical cycles. Particle size strongly affects the transport distance of suspended sediments and likely induces prokaryote and substrate variations along the course of the river. Previous studies have mainly focused on the spatial redistribution of soil prokaryotes, whereas the variation in prokaryotic diversity and community composition among different particle size-fractions in suspended sediments remain unclear. In this study, suspended sediments were collected at four plots (upstream, middle stream, downstream, and dam) along a river that runs through a valley. Sampled sediments were size-fractionated into > 63 μm and < 63 μm particles (referred to as small and large particle fractions hereafter), to identify the corresponding prokaryotic community composition, interactions, and functions. The richness index (Chao1 and observed species) and the diversity index (Shannon) of sediment-associated prokaryotic communities significantly decreased from upstream towards dam plots, except in the small particle fraction in downstream and dam plots. The highest β-diversity index value was found for the large particle fractions, while the geospatial contribution to β-diversity varied. The concentration of Proteobacteria in downstream (41.39 %) and dam (34.86 %) plots was lower than that in the upstream (47.65 %) and middle stream (45.90 %) plots. In contrast, Cyanobacteria (4.89 % and 6.75 %) and Verrucomicrobiota (5.98 % and 11.00 %) concentrations were greater in the downstream and dam plots, respectively, than those in the upstream (0.93 % and 2.43 %) and middle stream (3.37 % and 3.11 %) plots, respectively. Additionally, the concentrations of Verrucomicrobiota and Bacteroidota were significantly higher in the small particle fractions (2.26–8.12 % and 4.33–7.72 %) than those in the large particle fractions (2.03–5.94 % and 3.70–7.11 %). Compared to the other plots, upstream plots had a larger clustered network and a greater number of co-occurrences within the prokaryotic community in the bulk sediment and in the small particle fraction, whereas more complex interactions among prokaryotic communities were found in the large particle fraction from the dam plots. Soil organic carbon (SOC), total nitrogen (TN), and Olsen phosphorus were the three most influential factors, explaining 67.41 % of the variation in prokaryotic community. Proteobacteria and Myxococcota correlated negatively with SOC, TN, and Olsen P but positively with C = O. Conversely, Cyanobacteria and Verrucomicrobiota correlated positively with SOC, TN, and Olsen P but negatively with C = O. Functional groups linked to the biogeochemical cycling of carbon (methanol oxidation and methylotrophy) were found in high concentrations, whereas those linked to nitrogen (nitrogen and nitrate respiration) were found in low concentrations in upstream and middle stream plots. Reassembly of the sediment physicochemical characteristics among geospatial plots along the transport transect significantly altered the prokaryotic community composition and metabolic functional groups.

Multivariate lognormal mixture for pulp particle characterization

AbstractWe present a method for pulp particle characterization based on a truncated lognormal mixture (TLM) model, as motivated by size statistics of organisms. We use an optical fiber analyzer to measure the length–width distribution of kraft-cooked roundwood or sawmill sources, of chemi-thermomechanical pulp (CTMP) samples from roundwood or sawmill sources, and the same CTMP samples after kraft post-processing. Our results show that bimodal TLMs capture salient features of the investigated pulp particle distributions, by decomposition into a large-particle and a small-particle fraction. However, we find that fibers from sawmill sources, which have not undergone mechanical treatment, cannot be described by TLM, likely due to non-random sampling. Within the confines of our dataset, the TLM characterization predicts laboratory sheet properties more effectively than conventional averaging methods for pulp particle size distributions. The TLM characterization is intended as a tool for controlling the pulp production process towards higher product quality, uniformity, and energy efficiency, pending further mill trials for validation.

Change in dispersion of synthetic magnetite particles from the conditions of precipitation from iron sulfate-containing solutions

The paper analyzes the problems of the reagent method of wastewater treatment of machine–building enterprises, and the advantages of the magnetic sorption method in comparison with the reagent method are presented. The magnetosorption method, based on the treatment of a liquid with particles of a ferromagnetic material with the aim of sorption on their surface of substances to be extracted, has proven itself well not only in the purification of wastewater from impurities of heavy metals, but also from petroleum products, surfactants, radioisotopes, and suspended substances. The efficiency of water purification processes depends on the properties of the sorbent particles, such as dispersion, sorption capacity and magnetic properties of the particles. The paper presents the results on the dispersion of particles. Changes in the dispersion of synthetic magnetite particles obtained under various conditions, such as storage time, temperature, pH, K=[Fe2+]:[Fe3+] ratio, salt content, and nature of the precipitant, were studied. It is shown that with an increase in storage time, the number of small particles less than 10 μm decreases, and the number of large particles increases due to recrystallization processes. It has been determined that at 20 ℃ without the influence of a magnetic field, a suspension with a maximum content of particles with a diameter of 10 μm is formed, at a temperature of 40 – 70 ℃ particles with a size of 8 – 10 μm prevail in the suspension, and with an increase in the pH of the solution, the number of small particles in the suspension increases. Conversely, with an increase in salt content, the particle size increases with a decrease in the fraction of small particles by almost half. It is noted that at K = 0.8; 2.0, the largest number of particles (about 60 %) with a size of 10 μm are formed in the solution. It is shown that the maximum number of particles larger than 20 μm is formed using NaOH.

Athermal quasistatic cavitation in amorphous solids: Effect of random pinning.

Amorphous solids are known to fail catastrophically via fracture, and cavitation at nano-metric scales is known to play a significant role in such a failure process. Micro-alloying via inclusions is often used as a means to increase the fracture toughness of amorphous solids. Modeling such inclusions as randomly pinned particles that only move affinely and do not participate in plastic relaxations, we study how the pinning influences the process of cavitation-driven fracture in an amorphous solid. Using extensive numerical simulations and probing in the athermal quasistatic limit, we show that just by pinning a very small fraction of particles, the tensile strength is increased, and also the cavitation is delayed. Furthermore, the cavitation that is expected to be spatially heterogeneous becomes spatially homogeneous by forming a large number of small cavities instead of a dominant cavity. The observed behavior is rationalized in terms of screening of plastic activity via the pinning centers, characterized by a screening length extracted from the plastic-eigenmodes.

Mitigating the Recrystallization of a Cold-Worked Cu-Al2O3 Nanocomposite via Enhanced Zener Drag by Nanocrstalline Cu-Oxide Particles.

The strength of metals and alloys at elevated temperatures typically decreases due to the recovery, recrystallization, grain growth, and growth of second-phase particles. We report here a cold-worked Cu-Al2O3 composite did not recrystallize up to a temperature of 0.83Tm of Cu. The composite was manufactured through the internal oxidation process of dilute Cu-0.15 wt.% Al alloy and was characterized by transmission electron microscopy to study the nature of oxide precipitates. As a result of internal oxidation, a small volume fraction (1%) of Al2O3 particles forms. In addition, a high density of extremely fine (2-5 nm) Cu2O particles has been observed to form epitaxially within the elongated Cu grains. These finely dispersed second-phase Cu2O particles enhance the Zener drag significantly by three orders of magnitude as compared to Al2O3 particles and retain their original size and spacing at elevated temperatures. This limits the grain boundary migration and the nucleation of defect-free regions of different orientations and inhibits the recrystallization process at elevated temperatures. In addition, due to the limited grain boundary migration, a bundle of stacking faults appears instead of annealing twins. This investigation has led to a better understanding of how to prevent the recrystallization process of heavily deformed metallic material containing oxide particles.

Hybrid Emission Modeling of GRB 221009A: Shedding Light on TeV Emission Origins in Long GRBs

Observations of long-duration gamma-ray bursts (GRBs) with TeV emission during their afterglow have been on the rise. Recently, GRB 221009A, the most energetic GRB ever observed, was detected by the Large High Altitude Air Shower Observatory experiment in the energy band 0.2–7 TeV. Here, we interpret its afterglow in the context of a hybrid model in which the TeV spectral component is explained by the proton-synchrotron process while the low-energy emission from optical to X-ray is due to synchrotron radiation from electrons. We constrained the model parameters using the observed optical, X-ray, and TeV data. By comparing the parameters of this burst and of GRB 190114C, we deduce that the VHE emission at energies ≥1 TeV in the GRB afterglow requires large explosion kinetic energy, E ≳ 1054 erg and a reasonable circumburst density, n ≳ 10 cm−3. This results in a small injection fraction of particles accelerated to a power law, ∼10−2. A significant fraction of shock energy must be allocated to a near equipartition magnetic field, ϵ B ∼ 10−1, while electrons should only carry a small fraction of this energy, ϵ e ∼ 10−3. Under these conditions required for a proton-synchrotron model, namely ϵ B ≫ ϵ e , the SSC component is substantially subdominant over proton-synchrotron as a source of TeV photons. These results lead us to suggest that proton-synchrotron process is a strong contender for the radiative mechanisms explaining GRB afterglows in the TeV band.

Nanosized LiFePO4 Reveals the Electrochemical Kinetics of Electrolytes in Porous Li-Ion Battery Electrodes

Electrified transportation is critical for a decarbonized future, but high cost and range anxiety hamper the adoption of electric vehicles (EV). For low-cost EVs, extreme fast charging of lithium-ion batteries (LIB) is an ideal solution to range anxiety, but this requires significant improvements to rate performance. The measurement of electrochemical kinetics in LIBs is central to understanding and optimizing their rate performance. However, while LIB rate performance is typically limited by the electrolyte, the behaviors of electrolytes during high-rate (dis)charge remain elusive to electrochemical characterization. It is commonly assumed that the effects of ion transport in the electrolyte are negligible in sufficiently thin electrodes (e.g., ≤ 5 μm), allowing measurement of the intrinsic electrochemical kinetics of LIB active materials (AM). On the contrary, we suggest that when the AM is not rate limiting (i.e., with nanosized AMs), electrochemical characterization of LIB electrodes reveals only the kinetics of the electrolyte, making the AM kinetics impossible to measure. In this work, we use LiFePO4 (LFP) as a model system to investigate the fundamental electrochemical kinetics of porous battery electrodes in which the electrolyte is the sole rate limiting component.We first synthesize a nanosized, carbon-coated LFP active material (LFP-C) and fabricate electrodes with both a practical composition (95% AM) and extremely low electronic resistance. Electrochemical impedance spectroscopy shows that charge-transfer resistance is immeasurably small compared to pore resistance, while cyclic voltammetry proves that semi-infinite Li+ diffusion in the electrolyte is the rate limiting process. We develop a novel pseudo-steady-state extrapolation (S3E) technique for quantification of charge-transfer kinetics in porous battery electrodes, which shows that LFP obeys Butler-Volmer kinetics, even at a current density of > 100 mA cm-2. Unexpectedly, we find that the apparent transfer coefficient of LFP-C is ~ 1.5, rather than the commonly assumed value of 0.5. Furthermore, the remarkably low electrode-level exchange current (< 1 mA cm-2) suggests that only a small fraction of particles (~ 1%) are actively reacting, even at extreme rates. These results show that a moving reaction front resulting from rapid interfacial kinetics is the root cause of the widely observed electrode-level reaction heterogeneity of phase-separating AMs. Using LFP three-electrode cells, we conducted rate performance testing on the electrolyte, comparing the conventional LP57 electrolyte to highly conductive 2M LiFSI in acetonitrile (LiFSI-AN). LiFSI-AN achieves up to 70% charge capacity at a 600C rate and 35% discharge capacity at a 3000C rate, exceeding all other reports of LIB rate performance. A novel resistance vs. capacity analysis of the rate performance data enables direct measurement of electrolyte resistance growth, revealing how the complex interaction between a moving reaction front (i.e., increase in conduction path length) and concentration polarization (i.e., decrease in electrolyte conductivity) controls electrolyte rate performance in LFP electrodes.Overall, this work shows that the electrochemical kinetics of nanosized AMs in porous battery electrodes can only be understood by explicitly accounting for the behaviors of the electrolyte. Consequently, the common a priori assumption that the effects of the electrolyte are negligible for electrochemical kinetic measurements in thin electrodes is shown to be, in many cases, fundamentally misleading. Nanosized AMs are, therefore, a powerful tool to investigate the electrochemical kinetics of electrolytes in porous battery electrodes. Particularly, all-LFP three-electrode cells were developed as an ideal platform for rate performance testing of electrolytes, enabling direct measurement of electrolyte resistance growth during high-rate battery operation.

Study on the transport and deposition of micron-sized particles with different densities in the coal mine environment in miners

To address the health problems caused by the long-term intrusion of high-concentration dust generated in coal mining operations into the human respiratory tract, this study reconstructed a 3D digital model of the upper airway based on fine industrial CT scanning images, and established the micron particle migration calculation model by Euler-Lagrange method. The transport and deposition mechanisms of dust with different densities under different inspiratory intensities were simulated and analyzed. The simulated results were compared with the results of dust exposure experiments in the upper airway combined with 3D printing technology, and the relative errors obtained were in the range of 2.9% to 6.3%. The results showed that the airflow volume peaked in the nasopharynx, oropharynx, epiglottis, and larynx, leading to the airflow separation and formation of circulation that tend to cause dust deposition in these regions. As the dust density and inspiratory airflow volume increased, the deposition fraction of small dust particles (<1μm) in the upper airway slightly changed, and most of them escaped to the lung. For 7.07 μm dust particles, as the dust density increased from 1210 kg/m3 to 2750 kg/m3, the escape rate decreased from 31.43% to 0.48%, and this trend can be seen in the fitting function of escape rate and inspiratory airflow volume Y7.07μm=(80–1.37ν + 0.0064ν2) × 100%. When the dust particle diameter exceeded 20 μm, the impact of dust density was weakened by the large size of the dust, and the escape rate was close to 0% when the inspiratory airflow volume was 50–110 L/min. This study can provide theoretical support for the research and development of respiratory dust sensors and targeted dust prevention technologies.

How Pt Influences H2 Reactions on High Surface-Area Pt/CeO2 Powder Catalyst Surfaces.

The addition of platinum-group metals (PGMs, e.g., Pt) to CeO2 is used in heterogeneous catalysis to promote the rate of redox surface reactions. Well-defined model system studies have shown that PGMs facilitate H2 dissociation, H-spillover onto CeO2 surfaces, and CeO2 surface reduction. However, it remains unclear how the heterogeneous structures and interfaces that exist on powder catalysts influence the mechanistic picture of PGM-promoted H2 reactions on CeO2 surfaces developed from model system studies. Here, controlled catalyst synthesis, temperature-programmed reduction (TPR), in situ infrared spectroscopy (IR), and in situ electron energy loss spectroscopy (EELS) were used to interrogate the mechanisms of how Pt nanoclusters and single atoms influence H2 reactions on high-surface area Pt/CeO2 powder catalysts. TPR showed that Pt promotes H2 consumption rates on Pt/CeO2 even when Pt exists on a small fraction of CeO2 particles, suggesting that H-spillover proceeds far from Pt-CeO2 interfaces and across CeO2-CeO2 particle interfaces. IR and EELS measurements provided evidence that Pt changes the mechanism of H2 activation and the rate limiting step for Ce3+, oxygen vacancy, and water formation as compared to pure CeO2. As a result, higher-saturation surface hydroxyl coverages can be achieved on Pt/CeO2 compared to pure CeO2. Further, Ce3+ formed by spillover-H from Pt is heterogeneously distributed and localized at and around interparticle CeO2-CeO2 boundaries, while activated H2 on pure CeO2 results in homogeneously distributed Ce3+. Ce3+ localization at and around CeO2-CeO2 boundaries for Pt/CeO2 is accompanied by surface reconstruction that enables faster rates of H2 consumption. This study reconciles the materials gap between model structures and powder catalysts for H2 reactions with Pt/CeO2 and highlights how the spatial heterogeneity of powder catalysts dictates the influence of Pt on H2 reactions at CeO2 surfaces.

Interplay between thermal and magnetic properties of polymer nanocomposites with superparamagnetic Fe3O4 nanoparticles

Magnetic nanoparticles embedded in polymer matrices have excellent potential for multifunctional applications like magnetic remote heating, controlled drug delivery, hyperthermia, and thermally functionalized biomedical devices. A solvent-based processing method was developed to produce magnetic composites consisting of magnetite (Fe3O4) superparamagnetic nanoparticles embedded in a biomedical-grade polyurethane (ChronoFlex® C). The particles had a log-normal size distribution spanning from 4−16 nm, with a mean-size of 9.5 ± 2 nm. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy with elemental mapping were used to assess the phase purity, surface morphology, particle size, and homogeneity of the resulting nanocomposite. The magnetic properties of composites with 7–13 wt% of Fe3O4 were studied between 5 and 300 K using vibrating sample magnetometry. Room temperature magnetic attraction was observed, with a saturation magnetization of up to 5 emu/g and a low coercive field (Hc < 50 Oe), where the non-zero coercive field was attributed to a small fraction of larger particles that are ferromagnetic at room temperature. Field-cooled and zero-field-cooled magnetometry data were fitted to a numerical model to determine the superparamagnetic mean blocking temperature (TB = 90 K) of the embedded magnetite particles, and an effective magnetic anisotropy of 6×105 erg/cm3. Using an AC magnetic field operating at 85 kHz, we demonstrate that remote heating of the base polyurethane material is greatly enhanced by compositing with Fe3O4 nanoparticles, leading to temperatures up to 45 °C within 18 min for composites submerged in water. This work demonstrates the fundamental principles of a custom-designed thermomagnetic polymer composite that could be used in applications, including medical and heat management.

Gold recovery improvements in grinding and flash flotation circuit

Grinding and a flash flotation cell are frequently installed to recover fast floatability coarse particles avoiding their regrinding. However, the ore textural characteristics, such as grain size, change during mine operation and consequently the recovery of valuable particles in the flash flotation cell decreases. This article proposes and validates an interesting method of solving the problem of low gold recovery, making relevant and well thought out changes in a grinding and flash flotation circuit. This was done by optical ore characterisation (Leica DM2700 P microscope using 20X and 40X lens), mathematical modelling, and steady state process simulation (evaluating the original circuit (simulation I) and two proposed circuits (simulation II, and III)). The mineralogical characterisation indicates that, liberated gold (Au), electrum (Au-Ag), and acanthite (Ag2S) particles of less than 100 µm were the desired particles in the flash concentrate. Additionally, true flotation was identified as the predominant mechanism in gold and silver recovery, but mathematical model suggests that a small fraction of fine particles with gold could be recovered by entrainment. Both analyses led to the proposed installation of a re-grinding mill with recirculation to a flash cell (simulation III). After its commissioning, gold recovery in the flash cell increased 27.0%, reaching a maximum of 48.3%. This represents a clear improvement in gold recovery in a single stage. A significant increase in the global gold recovery was also observed (from 78.9% to 90.6%).