Solid oxide fuel cell (SOFC) is attracting attention for its high efficiency and low environmental impact. By integrating them into cogeneration systems, which harness the waste heat produced during power generation, significant overall efficiency gains can be achieved. Trigeneration systems (TGS), which extend this concept by incorporating exhaust gases alongside cogeneration, hold promise for reducing overall cost and energy required for the process. In this study, TGS was considered to utilize the exhaust gas from the SOFC cathode as a lean oxygen gas. Conventionally, nitrogen used as lean oxygen gas is obtained through energy-intensive deep cooling separation of air, and the process requires significant cost and energy. They are expected to be reduced by using SOFC exhaust gas to obtain lean oxygen gas. However, employing SOFC in TGS requires consideration of the tradeoff between oxygen concentration and power density. Consequently, this study aims to elucidate the impact of operating SOFC at high oxygen utilization on power generation characteristics. The influence of flow conditions on power generation characteristics was examined through experimental investigations under integral reactor conditions, where air was supplied to the cathode at a small flow rate, and under differential reactor conditions, where gas with a different composition was supplied at a larger flow rate. Additionally, simulations of oxygen concentration distribution within the flow channel were conducted.Under integral reactor conditions, power generation characteristics of the SOFC exhibited voltage drops in the low current density region at lower flow rates. To investigate variations in oxygen utilization under different flow conditions, concentration and current density distributions within the cell were obtained from numerical analysis using the finite volume method1). A 1-D model was established for analysis, considering mass balance of gas flow in the channel direction. The distribution was calculated by correlating current density with overvoltage and oxygen concentration, as determined from results obtained under differential reactor conditions. The analysis revealed that as flow rates decreased, current density diminished towards the cell outlet, and at lower flow rates, with slight current flow observed near the outlet, indicating little oxygen is consumed there. Consequently, optimizing operating conditions to minimize the portion of the system where oxygen consumption is low are required for effective utilization of SOFC in TGS.AcknowledgementThis work was supported by F. C. C. Co.References1) Y. Inui et al., IEEJ Trans. PE, 123(1), 66 (2003)
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