The mechanical and physical properties of amorphous alloys depend on their time, temperature, and stress history. Due to their out-of-thermodynamic-equilibrium nature, describing the nonelastic deformation while considering the evolution of the structural state poses a significant challenge. We address this challenge by incorporating a parameter for structural state changes into a conventional deformation theory. This allows us to account for aging-induced ordering and deformation-induced disordering in the description of the mechanical deformation. In the apparent elastic regime (small strain), aging dominates while disorder caused by deformation can be disregarded. In this context, we have also made modifications to the widely used stretched exponential function, incorporating in-situ aging during deformation. This modification successfully describes the stress relaxation behavior under small deformation conditions and provides insights into parameter evolution in this process. Under large deformation conditions, both aging and deformation induced rejuvenation effects on the structural state must be considered simultaneously. By analyzing the evolution of defect concentration during this process, we describe relevant experimental results within the framework of the free volume theory, effectively separating the contributions of aging and rejuvenation to the structural state during the deformation process.
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