Small Amount Of Hydrogen Research Articles

Silver Electrodes Are Highly Selective for CO in CO2 Electroreduction due to Interplay between Voltage Dependent Kinetics and Thermodynamics.

Electrochemical reduction is a promising way to make use of CO2 as feedstock for generating renewable fuel and valuable chemicals. Several metals can be used as the electrocatalyst to generate CO and formic acid, but hydrogen formation is an unwanted side reaction that can even be dominant. The lack of selectivity is, in general, a significant problem, but silver-based electrocatalysts have been shown to be highly selective, with faradaic efficiency of CO production exceeding 90%, when the applied voltage is below -1 V vs RHE. In this voltage range, only a small amount of hydrogen and formate is formed. We present calculations of the activation free energy for the various elementary steps as a function of applied voltage at the three low index facets, Ag(111), Ag(100) and Ag(110), as well as experimental measurements on polycrystalline electrodes, to identify the reason for this high selectivity. The formation of formic acid is suppressed, even though it is thermodynamically favored, because of the low coverage of adsorbed hydrogen and kinetic hindrance to the formation of the HCOO* intermediate, while *COOH, a key intermediate in CO formation, is thermodynamically unstable until the applied voltage reaches -1 V vs RHE, at which point the kinetics for its formation are more favorable than for hydrogen. The calculated results are consistent with experimental measurements carried out for acidic conditions and provide an atomic scale insight into the high CO selectivity of silver-based electrocatalysts.

Hydrodynamic simulations of white dwarf–white dwarf mergers and the origin of R Coronae Borealis stars

ABSTRACT We study the properties of double white dwarf (DWD) mergers by performing hydrodynamic simulations using the new and improved adaptive mesh refinement code octo-tiger. We follow the orbital evolution of DWD systems of mass ratio $q=0.7$ for tens of orbits until and after the merger to investigate them as a possible origin for R Coronae Borealis (RCB) type stars. We reproduce previous results, finding that during the merger, the helium WD donor star is tidally disrupted within 20–80 min since the beginning of the simulation onto the accretor carbon–oxygen WD, creating a high temperature shell around the accretor. We investigate the possible helium burning in this shell and the merged object’s general structure. Specifically, we are interested in the amount of oxygen-16 dredged-up from the accretor to the hot shell and the amount of oxygen-18 produced. This is critical as the discovery of very low oxygen-16 to oxygen-18 ratios in RCB stars pointed out the merger scenario as a favourable explanation for their origin. A small amount of hydrogen in the donor may help keep the oxygen-16 to oxygen-18 ratios within observational bounds, even if moderate dredge-up from the accretor occurs. In addition, we perform a resolution study to reconcile the difference found in the amount of oxygen-16 dredge-up between smoothed-particle hydrodynamics and grid-based simulations.

Probabilistic Analysis of Low-Emission Hydrogen Production from a Photovoltaic Carport

This article presents a 3D model of a yellow hydrogen generation system that uses the electricity produced by a photovoltaic carport. The 3D models of all key system components were collected, and their characteristics were described. Based on the design of the 3D model of the photovoltaic carport, the amount of energy produced monthly was determined. These quantities were then applied to determine the production of low-emission hydrogen. In order to increase the amount of low-emission hydrogen produced, the usage of a stationary energy storage facility was proposed. The Metalog family of probability distributions was adopted to develop a strategic model for low-emission hydrogen production. The hydrogen economy of a company that uses small amounts of hydrogen can be based on such a model. The 3D modeling and calculations show that it is possible to design a compact low-emission hydrogen generation system using rapid prototyping tools, including the photovoltaic carport with an electrolyzer placed in the container and an energy storage facility. This is an effective solution for the climate and energy transition of companies with low hydrogen demand. In the analytical part, the Metalog probability distribution family was employed to determine the amount of monthly energy produced by 6.3 kWp photovoltaic systems located in two European countries: Poland and Italy. Calculating the probability of producing specific amounts of hydrogen in two European countries is an answer to a frequently asked question: In which European countries will the production of low-emission hydrogen from photovoltaic systems be the most profitable? As a result of the calculations, for the analyzed year 2023 in Poland and Italy, specific answers were obtained regarding the probability of monthly energy generation and monthly hydrogen production. Many companies from Poland and Italy are taking part in the European competition to create hydrogen banks. Only those that offer low-emission hydrogen at the lowest prices will receive EU funding.

Characterizing the Rapid Hydrogen Disappearance in SN 2022crv: Evidence of a Continuum between Type Ib and IIb Supernova Properties

We present optical and near-infrared (NIR) observations of SN 2022crv, a stripped-envelope supernova in NGC 3054, discovered within 12 hr of explosion by the Distance Less Than 40 Mpc Survey. We suggest that SN 2022crv is a transitional object on the continuum between Type Ib supernovae (SNe Ib) and Type IIb supernovae (SNe IIb). A high-velocity hydrogen feature (∼ −20,000 to −16,000 km s−1) was conspicuous in SN 2022crv at early phases, and then quickly disappeared. We find that a hydrogen envelope of ∼10−3 M ⊙ can reproduce the observed behavior of the hydrogen feature. The lack of early envelope cooling emission implies that SN 2022crv had a compact progenitor with an extremely low amount of hydrogen. A nebular spectral analysis shows that SN 2022crv is consistent with the explosion of a He star with a final mass of ∼4.5–5.6 M ⊙ that evolved from a ∼16 to 22 M ⊙ zero-age main-sequence star in a binary system with ∼1.0–1.7 M ⊙ of oxygen finally synthesized in the core. In order to retain such a small amount of hydrogen, the initial orbital separation of the binary system is likely larger than ∼1000 R ⊙. The NIR spectra of SN 2022crv show a unique absorption feature on the blue side of the He i line at ∼1.005 μm. This is the first time such a feature has been observed in SNe Ib/IIb, and it could be due to Sr II. Further detailed modeling of SN 2022crv can shed light on the progenitor and the origin of the mysterious absorption feature in the NIR.

Microstructures, hydrogen concentrations, and seismic properties of a tectonically exhumed sliver of oceanic mantle lithosphere, Moa Island, Timor-Tanimbar outer-arc, eastern Indonesia

We characterize and quantify the microstructure, hydrogen concentrations, and seismic properties of a tectonically exhumed sliver of oceanic lithospheric mantle outcropping in the Moa Island (Leti archipelago, Timor-Tanimbar outer-arc). The 18 spinel peridotites (lherzolites and harzburgites) have coarse-porphyroclastic microstructures and olivine crystal-preferred orientations (CPO) with axial-[010] (also known as AG-type) or [100](010) (A-type) patterns, similar to those observed in peridotitic xenoliths from oceanic mantle lithosphere. These coarse-porphyroclastic microstructures are variably overprinted by growth of strain-free olivine neoblasts and crystallization of secondary pyroxenes. Recrystallized fractions vary from 6.9 up to 31.3%. The interstitial (cuspate) shapes and CPOs of clinopyroxene, uncorrelated with the olivine CPOs, indicate that refertilization by a reactive melt percolation post-dated deformation. Seismic properties are calculated based on the modal compositions and CPOs of all samples. Increase in the recrystallized olivine fraction decreased the seismic anisotropy, since static recrystallization produced some dispersion of the CPO, but did not change drastically the texture acquired during deformation. Mean seismic velocities (mean Vp = 7.9 km.s−1; mean Vs = 4.5 km.s−1) and anisotropy (mean maximum S wave polarization anisotropy = 4.5%), estimated by considering coherent orientation of the foliation and lineation of all samples, are within the range of typical values for the uppermost mantle. The nominally anhydrous minerals contain small amounts of hydrogen (olivine: 13–18 ppm H2O by weight; orthopyroxene: 58–175 wt ppm H2O and clinopyroxenes: 244–288 wt ppm H2O). A bulk water content of 50 wt ppm H2O is estimated based on nomminally anhydrous minerals for the Moa peridotites, in agreement with previous estimates for the oceanic mantle lithosphere based on peridotitic xenoliths. This is the first direct measurement of hydrogen concentrations in peridotites from an oceanic mantle lithosphere which experienced melt extraction.

Investigations on a Spark Ignition Engine, Part II: Impact of Hydrogen Addition and Compression Ratio on a Biogas-Fuelled Engine

Performance, emissions and combustion were studied using a spark ignition engine modified from a single-cylinder diesel engine with varying compression ratios and hydrogen addition. When the compression ratio increases, there is a slight increase in brake power and thermal efficiency. There is a small increase in brake power and brake thermal efficiency when the compression ratio is above 13:1. Increased emissions of nitric oxide, hydrocarbon, and carbon monoxide were observed at compression ratios above 13:1. Leaner mixtures, brake power and brake thermal efficiency are lowered. Spark timing is retarded as the compression ratio rises which results in high peak pressure and rate of heat release. At a compression ratio of 13:1, a small amount of hydrogen (15% on an energy basis) was added along with biogas. The lean limit of biogas combustion and the combustion rate are greatly increased by the addition of hydrogen. In addition, there was a rise in brake power and thermal efficiency. The levels of hydrocarbons were significantly reduced. Nitric oxide emissions did not rise as a result of the use of the retarded ignition timing. The effect of two throttle conditions on spark ignition engines using biogas as fuel is presented as Part I of this study.

Experimental Study of Influence of the Gas Flux on Urotropine Gasification in the Low-Temperature Gas Generator

The experimental study was carried out to investigate the gasification of urotropine (hexamethylenetetramine) in a low-temperature solid fuel gas generator under varying inlet gas flows. Nitrogen was applied as the filter gas. The filter gas flow was varied from 0.6 to 1.4 L/s with a step of 0.2 L/s. The inlet gas's initial temperature was equal to 910 K. It was shown that with an increase in the nitrogen flow, the fuel gasification time decreased. Increasing the flux of inlet nitrogen from 0.6 to 1.4 L/s results in an increase in the average urotropine gasification mass rate from 0.63 to 1.61 g/s. When the initial nitrogen flow is raised, the rate of fuel gasification increases almost linearly. Studies have demonstrated that the proportion of mass flows between urotropine gasification products and nitrogen remains constant regardless of the incoming gas flow. The mass flow ratio remains steady at approximately 0.9 g/g when the incoming gas flow is altered. It has been shown that the gaseous products of urotropine gasification consist of nitrogen with a small amount of hydrogen and hydrocarbons. The content of simple gaseous products does not exceed 4% vol.

Effect of the Degree of Hybridization and Energy Management Strategy on the Performance of a Fuel Cell/Battery Vehicle in Real-World Driving Cycles

The study utilizes open-access data to generate power demand curves for a hybrid automotive system, testing twelve configurations with three different energy management strategies and four values for the degree of hybridization (DOH), the latter representing the share of the total power of the vehicle powertrain supplied by the battery. The first control logic (Battery Main—BTM) uses mainly batteries to satisfy the power demand and fuel cells as backup, while in the other two controllers, fuel cells operate continuously (Fuel Cell Main—FCM) or within a fixed range (Fuel Cell Fixed—FCF) using batteries as backup. The results are assessed in terms of H2 consumption, overall system efficiency, and fuel cell predicted lifespan. The battery is heavily stressed in the BTM and FCF logics, while the FCM logic uses the battery only occasionally to cover load peaks. This is reflected in the battery’s State of Charge (SOC), indicating different battery stress levels between the BTM and FCF modes. The FCF logic has higher stress levels due to load demand, reducing battery lifetime. In the BTM and FCM modes, the fuel cell operates with variable power, while in the FCF mode, the fuel cell operates in a range between 90 and 105% of its rated power to ensure its lifetime. In the BTM and FCM modes, hydrogen consumption decreases at almost the same rate as the DOH increases, due to a decrease in battery capacity and a smaller amount of hydrogen being used to recharge it. In contrast, the FCF control logic results in a larger fuel consumption when the DOH decreases. In terms of FC durability, the FCF control logic performs better, with a predicted lifetime ranging from 1815 h for DOH = 0.5 to 2428 h for DOH = 0.1. The FCM logic has the worst performance, with a predicted lifetime of 800 to 808 h, being almost insensitive to the DOH variation. Simulations were performed on two different driving cycles, and similar trends were observed. Simulations taking into account fuel cell (FC) performance degradation showed an increase in hydrogen consumption of approximately 38% after 12 years. Overall, this study highlights the importance of optimizing control systems to improve the performance of fuel cell hybrid vehicles, also taking into account the component of performance degradation.

Technological aspects of Russian hydrogen energy development

Russian hydrogen industry exists more than 100 years and is one of the biggest in the world. In 2021 Russia produced more than 5 mln tons of hydrogen (the 5th place in the world after China, US, EU-27, India), more than 1 mln tons of hydrogen were exported as hydrogen-contained production (ammonia, methanol, fertilizers).Following the global trends in the growth of production and use of hydrogen as an energy carrier, which plays the role of an important tool for reducing greenhouse gas emissions, decarbonization of energy, as well as the use of hydrogen in the transport sector and industry, the analysis of the current state and prospects for the development of hydrogen energy in Russia is carried out, the technologies of low-carbon hydrogen production at electric power, oil- and gas processing, logistics and technologies of transportation and storage of hydrogen, the world's leading and promising Russian developments are analyzed, the feasibility of their application in Russia is assessed.The main technology for hydrogen production in Russia remains SMR: by using this technology more than 95 % of hydrogen is produced. At the same time, electrolyzers are present in many industries (oil refineries, power generation, hydrometeorology, microelectronics, food industry etc.). Russian nuclear power plant giant Rosatom is seriously studying the possibility of producing hydrogen in nuclear power plants by using high-temperature technologies.There are no main hydrogen pipelines in Russia (only internal technological pipelines) because big industrial plants that use hydrogen construct their hydrogen facilities on-site. Smaller amounts of hydrogen are delivered to the customers in a compressed state and stored in steel cylinders or reservoirs. Currently, Russian companies and organizations process development in hydrogen transportation and storage in compressed (up to 700 bars, including polymer reservoirs), liquid and bound states.In addition to traditional hydrogen consumers (hydrocarbon refineries, chemical plants) and metallurgy (7 furnaces for iron production) Russian companies and organizations develop hydrogen energy storage units, and there are pilot projects in the commercial and heavy vehicles, buses, river boats).

In Situ Measurement of Hydrogen Absorption into Copper-Coated Titanium Using Neutron Reflectometry and Electrochemical Impedance Spectroscopy

We set out to investigate the possibility that a small amount of hydrogen, generated by sulfide-driven corrosion or radiolytic processes, might be absorbed into the copper coating proposed for use as corrosion protection for the used nuclear fuel containers (UFCs) to be stored in a deep geological repository (DGR) in Canada. Hydrogen absorption may have the potential to alter the mechanical properties of the copper coating. This contribution discusses our initial study, using in situ neutron reflectometry (NR) and electrochemical impedance spectroscopy (EIS), of hydrogen absorption into a 50-nm layer of copper coated onto 4 nm of Ti on a Si single-crystal substrate. In situ NR-EIS experiments detected no increase in the hydrogen content within the copper layer of the copper-titanium thin film following 55 h of polarization in deoxygenated 0.1 M NaCl solution at pH 9, at potentials ranging from −444 mV/SCE to −1300 mV/SCE (detection limit ~2 at.%). However, these NR results showed that hydrogen can be absorbed into copper when the latter is cathodically polarized below about ─900 mV/SCE, which is the experimentally measured potential threshold for the hydrogen evolution reaction (HER) under these conditions. Although hydrogen did not accumulate in the outer Cu layer, our experiments revealed that the absorbed hydrogen quickly traversed the Cu layer to concentrate in the underlying titanium layer, which favours absorbed hydrogen. This observation is consistent with hydrogen uptake measured using inert gas fusion analysis on oxygen-free, phosphorus-doped (OFP) copper, which showed that in the absence of hydrogen recombination inhibitors (e.g., As(III)), only a small increase of 22 wt. ppm hydrogen was absorbed into the copper after 24 h at E = −1300 mV/SCE, and no increase in absorbed hydrogen occurred at potentials of −1100 mV/SCE or more positive. The initial absorption efficiency for electrolytically produced hydrogen atoms at the copper surface was determined to be 3.2%, suggesting that there may be an upper limit for hydrogen uptake by the copper coating of the UFC, although studies on 3 mm copper-coated steel samples representative of UFC materials will be required to confirm that. This result supports the prediction that hydrogen absorption is unlikely to lead to any failure of the copper barrier within a proposed DGR, in which it will not be possible to achieve such negative electrochemical potentials. Intended future research using in situ NR-EIS to study hydrogen absorption during the corrosion of copper thin films by HS⁻ ions and further studies on hydrogen absorption into 3-mm-thick copper-coated steel samples will help to validate these conclusions.

Few‐Hydrogen Metal‐Bonded Perovskite Superconductor MgHCu3 with a Critical Temperature of 42 K under Atmospheric Pressure

AbstractSince the prediction of multi‐hydrogen high‐temperature superconductor by Ashcroft in 2004, many possible candidates have been proposed, e.g., LaH10 showing the highest superconducting transition temperature (Tc) around 250–260 K at 170‐200 GPa hitherto. However, this pressure is too large to be taken into practical use. To address this challenge, it proposes a few‐hydrogen metal‐bonded perovskite superconductor, MgHCu3, by combining a novel design idea with first‐principles calculations. Different from multi‐hydrogen hydrides, whose high Tc relies on extreme pressure, the metallic bond in few‐hydrogen superconductor MgHCu3 improves the structural stability and ductility at atmospheric pressure. Here, the small amount of hydrogen is found to be vital for Tc. After the incorporation of hydrogen, the electron–phonon coupling constant of MgHCu3 is increased to 0.83, which is larger than that of the well‐known MgB2. Moreover, the anisotropy of MgHCu3 also plays an important role in enhancing Tc. Based on the Migdal‐Eliashberg theory, it predicts that the phonon‐mediated metal‐bonded perovskite MgHCu3 is a superconductor with Tc of 42 K. The first predicted ternary metal‐bonded perovskite, MgHCu3, enriches the family of perovskite and will promote further investigation on few‐hydrogen superconductors under atmospheric pressure.

Visualization and simulation study of ammonia blending with hydrogen as combustion application in lean-burn condition

Ammonia (NH3), as one of the two zero-carbon fuels, has attracted lots of attention. However, its poor properties, including slow laminar burning velocity (LBV), high ignition energy, and low flammability, make it unfavorable for use in engines. On the other hand, hydrogen (H2), another zero-carbon fuel, has a much higher LBV and flammability. Adding a certain amount of hydrogen to ammonia mixture has the potential to improve the combustion process and extend the lean-burn limit of ammonia. This paper investigates the combustion and emission improvements of ammonia blended with a small amount of hydrogen under lean-burn conditions, both experimentally and numerically. A new NH3/H2 chemical reaction mechanism was developed to accurately predict ignition delay time (IDT), LBV and NO generation under a wide range of initial conditions. The flame propagation schlieren and NO chemiluminescence measurements with a homogenous NH3/H2 mixture ignited by a spark plug in constant volume combustion chamber (CVCC) were conducted. The 3D numerical simulations in CVCC, coupled with the new mechanism, were validated with the experimental results. The hydrogen energy fraction up to 30 % (X30) and ER down to 0.4 (ER0.4) were studied in experiments and simulations. The results showed that, in comparison to pure ammonia (X0) at ER1.0, lean-burn conditions can be extended to ER0.6 and ER0.4 for X10 and X30, respectively, while still achieving a shorter combustion duration. NO is initially increased and then decreased with decreasing ER, regardless of hydrogen addition. Comparatively, X30ER0.4 can achieve relatively low NOx emissions, and maintaining an equivalent combustion rate with a low combustion temperature.

Effectiveness of hydrogen enrichment strategy for Wankel engines in unmanned aerial vehicle applications at various altitudes

This study investigates the effectiveness of the hydrogen-enrichment strategy on a Wankel engine for unmanned aerial vehicles (UAVs). The primary motivation behind this study is to contribute to the Wankel-type rotary engine designs by revealing the influences of the hydrogen enrichment method on the Wankel engine performance at various altitudes. To achieve these objectives, CFD simulations were conducted by applying a hydrogen enrichment method to a neat gasoline Wankel engine model at sea level, 5000 ft and 15,000 ft altitudes. The hydrogen energy fraction at the intake was gradually increased from 0% to 10%. The decrease in ambient air temperature, pressure, density, and insufficient fresh charge with the increase in altitude leads to the reduced reference chamber temperature and pressure of the Wankel engine. Thus, the combustion worsens, the heat release rate (HRR) and performance decrease, also emissions deteriorate in these colder operating conditions. On the other hand, the unique physicochemical properties of hydrogen such as wide flammability limits, high homogeneity, relatively small quenching distance and high flame speed allow hydrogen-enriched mixture flames to propagate toward the narrower gaps in the combustion chamber and make up for some drawbacks of Wankel engines. As a result, flame propagation is accelerated and fuel burning rate, peak pressure and temperature values in the reference chamber are increased by hydrogen addition. For the cases at sea level with 5% and 10% hydrogen energy fraction, IMEP is increased by 6.59%, 8.50%, and the indicated power is increased by 35.51% and 52.47%. In the cases with the same energy fraction at 15,000 ft, IMEP is increased by 26.61% and 48.75%, and the indicated power is reduced by 26.61% and 48.75%, respectively. It has been proven that a small amount of hydrogen by energy fraction improves combustion efficiency and performance. The findings show that hydrogen has excellent compatibility with Wankel engines and hydrogen enrichment is a very practical concept for the improvement of the performance of these engines for UAVs. Thus, Wankel engines, which are already a very favorable power source for UAVs, become even more favorable by the hydrogen-blending strategy.

Qualification Approach Detailed for Offshore Hydrogen Pipeline Systems

_ This article, written by JPT Technology Editor Chris Carpenter, contains highlights of paper OTC 32158, “Offshore Hydrogen Pipeline System Qualification: Design and Materials/Welds Testing in Hydrogen Environment,” by Angelo Santicchia, Elvira Aloigi, and Salvatore Terracina, Saipem, et al. The paper has not been peer reviewed. Copyright 2023 Offshore Technology Conference. Reproduced by permission. _ The qualification of a pipeline system for hydrogen transport, important in the transition to a decarbonized energy system even if strictly related to offshore pipelines, is a broad field that requires a systematic approach from basic material knowledge to complex physical models and fracture and fatigue assessments. The authors’ analysis of qualification requirements, including available test types and testing protocols, led to a matrix of potential tests, detailed in the complete paper, to be conducted in hydrogen and air environments for the steel base material, seam weld, and girth weld of offshore pipelines. Offshore Pipeline Materials Requirements vs. Hydrogen Transportation The authors’ work outlines many challenges, including the following: - Although hydrogen pipelines installed and operating onshore are common, at the time of writing, none exist in the offshore environment. - The blending percentage of hydrogen into natural gas in the future-transport scenario is still under discussion. - Small amounts of hydrogen can have a substantial effect on fatigue and fracture on high-strength materials. - The effect of hydrogen on pipe-material fatigue and fracture properties correlates directly to the specificity of the offshore environment, which will be very demanding in terms of longitudinal stress and fatigue. Another important aspect to consider is the effect of hydrogen on weldments both longitudinal and circumferential that are part of pipe-material fabrication and pipeline fabrication. A dedicated engineering team analyzed key standards and the available literature in terms of theoretical studies and experimental tests of materials in hydrogen environments. This activity indicated that, in addition to theoretical and design considerations, characterization of primary material and welding properties in hydrogen environments that will affect the failure modes of offshore pipeline design is a critical step. Testing Protocols and Equipment Slow Strain Rate Test (SSRT). Smooth cylindrical specimens were tested in inert gas (nitrogen), pure hydrogen, and a hydrogen/natural gas mixture for comparative purposes. This testing was aimed at evaluating the susceptibility of the pipeline materials (base material and weld metals) to hydrogen embrittlement when subjected to typical conditions envisaged for future hydrogen service. Tensile cylindrical specimens were tested at room temperature (24°C) in a high-pressure gaseous atmosphere. Tests were carried out in displacement control mode. In the initial part of the tensile test, in the plastic regime, after attainment of material yielding but before reaching the maximum tensile strength of the specimen, the strain distribution along the specimen was approximately uniform.

Experimental Investigation of Spark-Assisted Compression-Ignition with Ammonia-Hydrogen Blends

Carbon-free emissions and stable operation of ammonia-fueled internal combustion engines have been demonstrated in recent studies through combustion strategies suited to the fuel’s unique properties. High ignition energy and slow flame speed of ammonia are typically compensated for by hydrogen addition and/or enhanced ignition systems while the high octane rating of ammonia allows high compression ratio. The experimental study in this work investigates the performance of ammonia in spark-assisted compression-ignition (SACI) mode, where the cylinder charge is spark ignited and a subsequent auto-ignition event results in a faster burn and more ideal combustion phasing. The high-compression ratio engine was fueled by 100% anhydrous ammonia or blends with small quantities of hydrogen (2.5% and 5% by volume). Fuels were port-injected for a homogeneous intake charge mixture at stoichiometric equivalence ratio. Two different engine speeds were tested at several intake temperatures and spark timings. All cases showed an inflection point in the apparent heat release rate (AHRR) followed by more rapid rate of heat release, signaling the onset of auto-ignition. Blending hydrogen in the fuel benefited gross indicated mean effective pressure (gIMEP) at maximum brake torque (MBT) timing, but pure ammonia fuel was more stable across a wide range of spark timings and intake temperatures. Burn durations in the present study were similar to those of conventional SI engines fueled by gasoline indicating that the combustion enhancement of SACI compensated for the lower flame speed of ammonia. The control of SI percent, defined as the fraction of heat release before auto-ignition compared to the total heat release, is shown to be strongly related to the sensitivity of auto-ignition timing to spark timing. Unburned ammonia emissions are hypothesized to be primarily driven by unburned gases trapped in the crevices and are mitigated slightly through blending hydrogen in the fuel or by increasing intake temperature. However, the addition of hydrogen and increasing intake temperature led to increased nitric oxide (NO) emissions. Of primary concern because of its potent global warming potential, nitrous oxide (N2O) did not show a clear trend with fuel hydrogen content or intake temperature, but definitively increased for the higher engine speed.

Comparative study on methane/air deflagration with hydrogen and ethane additions: Investigation from macro and micro perspectives

Natural gas usually contains a small amount of hydrogen and ethane in addition to methane, which would pose a threat to the safety of natural gas production and utilization by affecting its explosion risk. In order to reveal the effect mechanism of hydrogen and ethane on methane deflagration, the deflagration behaviors of methane-hydrogen/ethane-air mixtures([CH4]=7.0, 9.5, 11.0 vol. %; [H2]=0–2.0 vol. %; [C2H6]=0–2.0 vol. %) at normal temperature and pressure are compared and analyzed from macro and micro perspectives. The results indicate that the deflagration pressure and the spectral intensity of free radicals (H* and OH*) show different change trends depending on equivalent state of the system with adding hydrogen or ethane to methane/air mixtures. There is a parabolic relationship between the average rising rates of deflagration pressure (VP) and spectral intensity (VI) and they are positively correlated. The contribution of H* to deflagration pressure gradually decreases while the promotion of OH* to it increases with the volume fraction of methane changing from 7.0 % to 11.0 %. Besides, the top 10 most significant elementary reactions were obtained in the methane deflagration process with adding hydrogen and ethane. Hydrogen promotes methane deflagration by reacting with OH and O, while ethane contributes to it by reacting with OH and CH3.

Hydrogen Absorption into Copper-Coated Titanium Measured by In Situ Neutron Reflectometry and Electrochemical Impedance Spectroscopy

One concern regarding the used nuclear fuel containers proposed for use in a Canadian deep geological repository (DGR) is the possibility that a small amount of hydrogen might be absorbed into their copper coating, potentially altering its mechanical properties. Reported herein is a study of hydrogen absorption into 50 nm of copper, coated on 4 nm of Ti using in situ neutron reflectometry (NR) and electrochemical impedance spectroscopy (EIS). NR results show that hydrogen is absorbed when the copper is cathodically polarized below the threshold for the hydrogen evolution reaction (HER), but that the hydrogen concentrates in the underlying titanium layer rather than concentrating in the copper coating. The hydrogen concentration in titanium rapidly rose when the HER was initiated and was observed to reach a steady state at TiH1.5. Over the course of 55h of cathodic polarization, the concentration of hydrogen in the copper remained below the NR detection limit (2 at %). The portion of hydrogen atoms produced that diffused through the copper layer was initially 3.2%, suggesting a possible upper limit for hydrogen uptake by the copper coating of the UFC, although definitive conclusions can only be drawn from studies on 3 mm copper-coated steel samples.

Highly Efficient Light‐Driven CO2 to CO Reduction by an Appropriately Decorated Iron Porphyrin Molecular Catalyst

AbstractThe photocatalytic CO2 reduction into value‐added chemicals is regarded as one promising technology to mitigate environmental issues and the energy crisis of the modern world due to the extended CO2 emissions. Recent advances have shown that iron porphyrins are considered as one of the most efficient molecular catalysts in the activation and reduction of molecules like CO2. Thus, a suitably modified FeIII porphyrin ([FeIII(TF4TMAP)](CF3SO3)5) was prepared and its catalytic activity in terms of photocatalytic reduction of CO2 was studied. This iron catalyst possesses four fluorine substituents in the ortho and the meta position of each meso‐phenyl group of the porphyrin, while trimethylammonium groups were placed in the para position. Photocatalytic studies were performed in the presence of an iridium complex as a chromophore and have shown that [FeIII(TF4TMAP)](CF3SO3)5 can effectively reduce CO2, achieving excellent turnover numbers (up to 5500 TONs) and high turnover frequencies. The main reduction product of this photocatalytic system was CO, and only a small amount of hydrogen was detected, presenting a maximum selectivity of 86 % for CO.

Analysis of low emission characteristics of NH3/H2/air mixtures under low temperature combustion conditions

The complex dynamics of NH3/H2/air mixtures have been numerically investigated in an idealized reactor environment of fast fuel/air mixing represented by perfectly stirred reactors (PSR). The complete steady state “S-curve” solutions are obtained with eigenvalue analysis for quantifying the stable/unstable characteristics of different branches. With four different chemical mechanisms, stable cool flame branches are observed for NH3/H2/air mixtures. The reactions involving species NH2, H2NO and NNH are found important for both fuel consumption and NOx formation on the cool flame branch. The parametric study further shows that with less than 5 % hydrogen addition in ammonia (in volume), stable cool flames exist over a wide range of inlet temperature, equivalence ratio and pressure. For the states in the cool flame branch, although hydrogen is almost consumed completely, only portion of the ammonia is consumed resulting in low NOx emission due to the reduction effects of remaining ammonia and high N2O emission resulting from low temperature. Inspired by the observed stable cool flame characteristics, a multi-staged low-temperature model system is formulated for low NOx emission of NH3/H2/air combustion, in which small amount of hydrogen is sequentially injected to homogeneous reactors of lean NH3/H2/air mixture. With the representative high inlet temperature of 850 K, pressure of 20 atm, fuel lean of ϕ=0.7 and critical fuel efficiency of 99.7 %, results with the 28-species Li reduced mechanism show that less than 75 ppm of NOx and 98 ppm of N2O can be achieved with two-staged homogenous combustion operating at low temperature of 1300 K and 2 % H2 addition in each stage. With three-staged homogenous combustion, less than 70 ppm of NOx and 10 ppm of N2O can be achieved at 1300 K. NOx emission is lower than those of direct NH3/H2/air combustion without aftertreatment, demonstrating the opportunity of utilizing low temperature combustion to achieve high fuel conversion, low NOx and N2O formation for lean NH3/H2/air mixtures.

Hydrogen enrichment enhances soot formation in swirl-stabilized non-premixed turbulent combustion of ethylene in a model gas turbine combustor

A switch from fossil fuels to hydrogen is currently not feasible mostly due to supply and infrastructure issues. One of the possible approaches, and this is now practiced to a limited extent in industrial gas turbines, is to blend relatively small amounts of hydrogen with fossil fuels curbing the carbon dioxide emissions. However, studies assessing the influence of modest amounts of hydrogen blending with hydrocarbon fuels on soot processes yielded contradictory results. Most of these experimental and numerical studies were performed on laminar diffusion flames and studies on turbulent flames are scarce. One of the confounding factors in assessing the influence of hydrogen is selection of a control experiment in which the fossil fuel is blended with the same amount of an inert diluent. Using helium in the control experiment is preferable because of its similar transport properties and heat capacity to those of hydrogen. Hence, we studied the soot processes in a model gas turbine combustor in which the flame is stabilized by an air swirl. Swirl-stabilized platform ensures that with and without hydrogen/helium dilution, the hydrodynamics of the combustor stays fixed. Base fuel ethylene is supplemented with hydrogen or helium by the same amount to separate the dilution affects and assess the direct chemical interaction of hydrogen related to soot formation. Soot volume fraction and primary soot particle diameters were measured by auto-compensating laser induced-incandescence for all cases. Flow field data obtained using stereoscopic particle image velocimetry is utilized to ascertain the hydrodynamic effects on soot distribution due to addition of lighter species. Soot formation was found to be enhanced by the addition of hydrogen when allowance was made for the dilution effect using the helium doped flame experiments. Possible causes of this observation including the molecular diffusivities of hydrogen and helium, and chemical interaction are discussed.