Sm-Nd Isotope Systematics Research Articles

Origins of the terrestrial Hf-Nd mantle array: Evidence from a combined geodynamical-geochemical approach

The formation and segregation of oceanic and continental crust from the mantle, and its return to the mantle via subduction and/or delamination, leads to the development of distinct geochemical reservoirs in the terrestrial mantle. Fundamental questions remain regarding the location, nature, and residence time of these reservoirs, as well as the respective roles of oceanic and continental crust in the development of the mantle's geochemical endmembers. The Lu-Hf and Sm-Nd isotope systems behave similarly in magmatic systems and together form the terrestrial mantle Hf-Nd isotopic array. Here we combine a geodynamic model of mantle convection with isotope and trace element (TE) geochemistry to investigate the evolution of the Hf-Nd mantle array. This study examines the sensitivity to: TE partition coefficients used in the formation of oceanic crust; density contrasts between subducting oceanic crust and the mantle; and the formation and recycling of continental crust. We show that the fractionation between the parent (Lu and Sm) and daughter (Hf and Nd) species needs to be higher than is indicated by partition coefficients determined from the present-day melting environment. This is consistent with the suggestion of deeper mantle melting earlier in Earth history and an increased role for residual garnet. Subduction and accumulation of dense oceanic crust produces a large mass of incompatible TE enriched material in the deep mantle. This deep mantle enrichment appears to play a more significant role than the extraction and recycling of continental crust in developing the Hf and Nd isotope and TE compositions of the mid-ocean ridge mantle source. The corollary of this result is that the formation of the continental crust plays a secondary role, contrary to the currently accepted paradigm. Nevertheless, the inclusion of continental crust formation and recycling produces a broader model mantle array, which better reproduces the spread in the natural data set. This model also produces the Hf and Nd isotope and TE compositions of the upper mantle and continental crust, as well as deep mantle compositions similar to those of plume-fed ocean island basalts. Our model is consistent with continental growth models based on the Lu-Hf isotopic composition of zircon, which suggest that 50–70% of the present-day mass of the continental crust is produced prior to 3 Ga, and that the recycling of continental crust becomes more prevalent after this time.

Contrasting isotopic sources (Sm-Nd) of Late Ediacaran series in the Iberian Massif: Implications for the Central Iberian-Ossa Morena boundary

In the Iberian Massif, westernmost sector of the Variscan Orogen, the nature of the boundary between the Central Iberian Zone and the Ossa Morena Complex has been largely discussed. Peri-Gondwanan Ediacaran series similar in age (c. 565 Ma) but different in composition occur at both sides of that boundary. The Lower Alcudian Series (Central Iberian Zone) is located to the north, while the Serie Negra (Ossa-Morena Complex) can be found to the south of the boundary. Major and trace element compositions and Sm-Nd isotopic systematics of siliciclastic rocks from both series suggest a common active margin setting for their deposition, the Serie Negra likely occupying a more external (fore-arc) position within the arc-system relative to the Lower Alcudian Series, which would have been deposited within a large back-arc domain. TDM ages for these two series are notably different, yielding values of 1421–2040 Ma and 1256–1334 Ma for the Serie Negra and Lower Alcudian, respectively. These values suggest higher input from old cratonic sources in the Ossa Morena Complex, with probable participation of the West African Craton, which would be less prominent in the Central Iberia Zone. The whole data set indicate deposition of the Ediacaran series in separated basins, probably far away from each other along/across the margin of Gondwana. Current juxtaposition of these basins is explained by Variscan and probably also pre-Variscan tectonics. Similar conclusions could be also be extended to other similar boundaries in the Variscan Orogen.

Carbonatites as recorders of mantle-derived magmatism and subsequent tectonic events: An example of the Gifford Creek Carbonatite Complex, Western Australia

The Gifford Creek Carbonatite Complex (GCCC), Western Australia contains a diverse suite of alkaline igneous rocks, including magnesiocarbonatites, ferrocarbonatites, phoscorites, fenites, magmatic-hydrothermal peralkaline dykes, and ironstones. This study employs U-Pb, Sm-Nd, and Lu-Hf radiogenic isotope techniques on monazite – (Ce), fluorapatite, and zircon to determine the origin, age, and history of the GCCC.Zircon crystals found in glimmerite alteration selvages adjacent to ferrocarbonatites exhibit pyramidal crystal morphologies, εHf values of −1.8 to −4.3, high Th/U, and variable Zr/Hf, all of which are indicative of carbonatitic zircon sourced from an enriched mantle component. Uranium-Pb dating of these zircons returned a definitive magmatic age of ~1370 Ma for the GCCC. Monazite hosted in the ferrocarbonatites, phoscorites, and fenite alteration assemblages yielded variable U-Pb ages ranging from ca. 1250 Ma to 815 Ma. Neodymium isotope isochrons determined from coexisting monazite and apatite gave ages between ca. 1310 Ma to ca. 1190 Ma, but all with similar initial 143Nd/144Nd values of 0.51078–0.51087.The 1370 Ma age of the GCCC does not correspond to any known mantle plume activity, but does broadly correlate with the separation of the North China Craton from the West Australian Craton as part of the greater breakup of Nuna. The monazite and apatite εNd data illustrate that the multiple younger U-Pb monazite and Nd isotope isochron ages are not recording multiple magmatic intrusions into the complex, but rather represent partial recrystallisation/resetting of REE-bearing minerals during the protracted tectonic history of the Western Australia Craton from ~1300 Ma to 815 Ma and its involvement in the breakup of Nuna and assembly and disassembly of Rodinia.The age variability in the U-Pb and the Sm-Nd isotope systems in monazite and apatite reveal that tectonically-induced hydrothermalism can contribute to the isotopic resetting of phosphate minerals. This age resetting, if properly identified, can be used as a thorough geochronological record of tectonism affecting alkaline igneous complexes after initial magmatic emplacement.

Petrogenesis and geodynamic setting of the Neoarchaean Haines Gabbroic Complex and Shebandowan greenstone belt, southwestern Superior Province, Ontario, Canada

The 2722 ± 2 Ma Archaean megacrystic anorthosite-bearing Haines Gabbroic Complex in the Wawa subprovince of the western Superior Province formed contemporaneously with the spatially associated Greenwater Assemblage of the Shebandowan greenstone belt, Ontario, Canada. Both field and petrographic observations indicate that the Haines Gabbroic Complex and the spatially and temporally associated ultramafic to intermediate volcanic and intrusive rocks of the Greenwater and Burchell assemblages experienced extensive metamorphic recrystallization and alteration as a consequence of greenschist-facies metamorphism. These metamorphic processes resulted in pervasive replacement of igneous minerals by metamorphic counterparts. Metamorphic alteration also mobilised LILE and transition metals and slightly reset the U-Th-Pb and Sm-Nd isotope systems. Consequently, the Haines Gabbroic Complex and Greenwater Assemblage have respective Sm-Nd errorchron ages of 2765 +110/‐280 Ma and 3108 +120/‐380 Ma.Major and trace element compositions suggest that the least altered anorthosites, leucogabbros and gabbros of the Haines Gabbroic Complex are not cogenetic with the Greenwater and Burchell assemblages and have distinct parental magmas and depleted mantle sources. The calc-alkaline andesites of the Burchell Assemblage, the tholeiitic basalts and gabbros of the Greenwater and Burchell assemblages, the transitional gabbros of the Greenwater and Burchell assemblages and the picrites, serpentinites and peridotites of the Greenwater Assemblage are all petrogenetically distinct and have different parental magmas and depleted mantle sources. The pyroxenites are genetically distinct from the other Greenwater Assemblage lithologies, the Burchell Assemblage and the Haines Gabbroic Complex. The Haines Gabbroic Complex crystallised from hydrous, Ca- and Al-rich tholeiitic parental magmas that fractionated from more primitive, hydrous boninitic parental magmas.The initial εNd values of the Haines Gabbroic Complex (εNd = +3.0 to +4.1) and the Greenwater (εNd = +1.8 to +4.1) and Burchell (εNd = +2.0 to +3.7) assemblages are indicative of variably depleted mantle sources. The major and trace element characteristics of the Haines Gabbroic Complex and the Greenwater and Burchell assemblages and geological relationships indicate that they formed in a Japan-style mature intra-oceanic continental arc with a large volume of TTGs. Intra-oceanic arc rifting was most likely triggered by slab rollback, followed by mantle plume emplacement. On the basis of rock association and geochemical data, we suggest that the Haines Gabbroic Complex and the Greenwater and Burchell assemblages represent a dismembered subduction-related Archaean ophiolite that marks a Neoarchaean suture zone between the Wawa and Wabigoon subprovinces.

Disturbance of the Sm-Nd isotopic system by metasomatic alteration: A case study of fluorapatite from the Sin Quyen Cu-LREE-Au deposit, Vietnam

The Neoproterozoic (840 Ma) Sin Quyen deposit in northwestern Vietnam contains replacement Cu-LREE-Au orebodies in Proterozoic metasedimentary rocks. In this deposit, LREE-bearing minerals include allanite-(Ce), monazite-(Ce), chevkinite-(Ce), and fluorapatite. Fluorapatite from orebodies has undergone variable degrees of metasomatic alteration. Samarium-neodymium isotopic analyses were conducted on altered fluorapatite, and also on allanite-(Ce) and monazite-(Ce), to investigate whether such metasomatism can affect the Sm-Nd isotope system. Allanite-(Ce) and monazite-(Ce) have Sm-147/Nd-144 ratios ranging from 0.0359 to 0.0549, and Nd-143/Nd-144 ratios from 0.51147 to 0.51172. Their initial Nd-143/Nd-144 values at the time of mineralization range from 0.51126 to 0.51148, but mostly cluster between 0.51135 and 0.51145. Thus, the primary ore-forming fluids were relatively homogeneous in their Sm-Nd isotopic compositions. In the Sm-147/Nd-144 vs. Nd-143/Nd-144 diagram, the compositions of allanite-(Ce) and monazite-(Ce) generally plot along a Sm-Nd isochron of 840 Ma, implying that the Sm-Nd isotopic systems of these minerals were either closed or only slightly modified. In contrast, altered fluorapatite crystals have Sm-147/Nd-144 ratios varying from 0.0667 to 0.1348, and Nd-143/Nd-144 ratios from 0.51160 to 0.51199. The calculated initial Nd-143/Nd-144 ratios range widely from 0.51114 to 0.51141, with most values lower than those of the allanite-(Ce) and monazite-(Ce). In the Sm-147/Nd-144 vs. Nd-143/Nd-144 diagram, their compositions mostly plot below the 840-Ma Sm-Nd isochron. Petrographic observations and trace elemental analyses show that metasomatic modification of fluorapatite grains led to increases of their Sm/Nd ratios. The unaltered domains in the grains have Sm/Nd ratios varying from 0.114 to 0.200, with an average value of 0.161; whereas the altered domains have Sm/Nd ratios varying from 0.111 to 0.254, with an average value of 0.183. The increased Sm/Nd ratios can cause the calculated initial Nd-143/Nd-144 ratios to be lower than actual initial isotopic ratios, and can also result in compositional deviations from the reference Sm-Nd isochron. This study demonstrates that the traditionally assumed inert Sm-Nd isotopic system can be metasomatically disturbed due to changes in the Sm/Nd ratio. Therefore, care must be taken when interpreting the Sm-Nd isotopic data from apatite/apatite-rich rocks that have undergone metasomatic alteration.

Differentiation mechanisms of the early Hadean mantle: Insights from combined 176Hf-142,143Nd signatures of Archean rocks from the Saglek Block

Positive 142Nd anomalies in Eoarchean rocks provide evidence for early (4.40 ± 0.03 Ga; Morino et al., 2017) depletion of Earth's mantle. This model age lies within errors of the Pb-Pb “age of the Earth” (Connelly and Bizzarro, 2016), and is similar to model ages inferred for crystallization of the lunar mantle (McLeod et al., 2014), implying that this large-scale event may reflect crystallization of a magma ocean following the Moon-forming impact. However, differentiation mechanisms responsible for the formation of this early depleted mantle reservoir and the depth at which it formed cannot be constrained from the Sm-Nd isotope system alone, because the magnitude of Sm/Nd fractionation during partial melting or fractional crystallization shows little dependence on pressure-controlled changes in mantle mineralogy. In contrast, the Lu-Hf isotope system is highly dependent on mineralogy, notably the presence or absence of garnet, an upper mantle phase, and thus may be used to constrain the pressure of fractionation. This study provides the first 176Lu-176Hf isotopic results on mafic and ultramafic rocks belonging to the Eoarchean (Nulliak) and Mesoarchean suites of the Saglek Block (northern Labrador, 3.2–3.9 Ga). The 176Lu-176Hf dating confirms the distinction between these two groups of rocks and provides ages consistent with those obtained from 147Sm-143Nd dating. The whole rock 176Lu-176Hf errorchrons yield ages and initial epsilon values of 3766 ± 140 Ma, ε176Hfi = 6.0 ± 2.5 and 3023 ± 390 Ma, ε176Hfi = −0.3 ± 2.5 for the Nulliak suite and the Mesoarchean suite respectively. The time-integrated 176Lu/177Hf for the sources of the Nulliak and the Mesoarchean suites considering a time of differentiation at 4.40 ± 0.03 Ga are estimated to be 0.047 ± 0.005 and 0.033 ± 0.005, respectively. For the Mesoarchean samples, the combined 146,147Sm-142,143Nd and 176Lu-176Hf data are consistent with a near-chondritic mantle source. On the other hand, Nulliak ultramafic rocks were derived from a mantle reservoir with superchondritic Lu/Hf and Sm/Nd. The Nulliak parent reservoir, however, does not plot on the ε176Hf-ε143Nd mantle array defined by modern oceanic basalts. Instead, the Nulliak source more likely belongs to a distinct array defined by Eo- and Meso-Archean komatiites. These results are interpreted in the framework of a simple model of crystallization of a primordial magma ocean. It appears that the fractionation observed in the mantle source of Nulliak was most likely generated by crystallization of a garnet-bearing assemblage in the shallow mantle, above the transition zone rather than by perovskite fractionation in the lower mantle. To preserve this depleted reservoir from the rest of the hot and vigorously convecting mantle, the Nulliak mantle source may have been isolated either at the top of the mantle in a buoyant lithosphere or near the core-mantle boundary, with the latter setting being more consistent with the komatiitic nature of the erupted rocks. Given that the garnet signature argues for differentiation of the Nulliak source at relatively shallow depth (few hundred kilometers), its isolation in the deep mantle would require a cumulate overturn following crystallization of the magma ocean.

Late Mesoproterozoic to Early Paleozoic history of metamorphic basement from the southeastern Chiapas Massif Complex, Mexico, and implications for the evolution of NW Gondwana

In this paper, U-Pb zircon geochronology, Lu-Hf and Sm-Nd isotope systematics, geochemistry and geothermobarometry of metaigneous basement rocks exposed in the southeastern Chiapas Massif Complex are presented. Geologic mapping of the newly defined “El Triunfo Complex” located at the southeastern edge of the Chiapas Massif reveals (1) partial melting of a metamorphic basement mainly constituted by mafic metaigneous rocks (Candelaria unit), (2) an Ediacaran metasedimentary sequence (Jocote unit), and (3) occurrence of massif-type anorthosite. All these units are intruded by undeformed Ordovician plutonic rocks of the Motozintla suite. Pressure and temperature estimates using Ca-amphiboles, plagioclase and phengite revealed prograde metamorphism that reached peak conditions at ~650°C and ~6kbar, sufficient for partial melting under water saturated conditions. Relict rutile in titanite and clinopyroxene in amphibolite further indicate a previous metamorphic event at higher P-T conditions. U-Pb zircon ages from felsic orthogneiss boudins hosted in deformed amphibolite and migmatite yield crystallization ages of ~1.0Ga, indicating that dry granitic protoliths represent remnants of Rodinia-type basement. Additionally, a mid-Tonian (~920Ma) metamorphic overprint is suggested by recrystallized zircon from a banded gneiss. Zircon from folded amphibolite samples yield mainly Ordovician ages ranging from ~457 to ~444Ma that are indistinguishable from the age of the undeformed Motozintla plutonic suite. Similar ages between igneous- and metamorphic- zircon suggest a coeval formation during a high-grade metamorphic event, in which textural discrepancies are explained in terms of differing zircon formation mechanisms such as sub-solidus recrystallization and precipitation from anatectic melts. In addition, some amphibolite samples contain inherited zircon yielding Stenian-Tonian ages around 1.0Ga. Lu-Hf and Sm-Nd isotopes and geochemical data indicate that the protoliths of the amphibolite have E-MORB characteristics and were derived from a depleted mantle source younger than the Rodinia-type basement. Inasmuch as similar amphibolites also occur in the Ediacaran metasedimentary rocks as dykes or lenses, Late Neoproterozoic magmatism in a rift setting is suggested. Hence, the geologic record of the El Triunfo Complex includes evidences for Rodinia assemblage, Tonian circum-Rodinia subduction, and breakup during the Late Neoproterozoic. Metamorphism, and partial melting are interpreted in terms of a convergent margin setting during the Ordovician. The results place the southern Chiapas Massif along with Oaxaquia and similar Northern Andes terranes on the NW margin of Gondwana interpreted as the extension of the Famatinian orogen that evolved during the closure of the Iapetus Ocean.

Comment on “Reconciliation of the excess 176Hf conundrum in meteorites: Recent disturbances of the Lu-Hf and Sm-Nd isotope systematics” [Geochim. Cosmochim. Acta 212 (2017) 303–323

Comment on “Reconciliation of the excess 176Hf conundrum in meteorites: Recent disturbances of the Lu-Hf and Sm-Nd isotope systematics” [Geochim. Cosmochim. Acta 212 (2017) 303–323

Clastic metasediments of the Khamar-Daban Group (Central Asian Orogenic Belt): chemical composition and isotope systematics

New data have been obtained on major- and trace-element compositions and Sm-Nd isotope systematics of clastic metasediments that belong to the Kornilova and Shubutui Formations in the Khamar-Daban terrane. The Kornilova Formation flysch derived from felsic mature crust, while the Shubutui Formation, with 4.5-7.5 wt.% MgO and higher Cr and Ni contents, had a mafic-ultramafic protolith of an island-arc setting. Isotope data indicate significant inputs of Precambrian crustal material (£Nd(T = -10 to -6.2) to the protolith of the Kornilova rocks and of high amounts of synsedimentary juvenile material to the protolith of the Shubutui Formation (£Nd(T = -2.9 to -1.5). Different model ages (1.7-2.0 and 1.3-1.4 Ga, respectively), compositions, and provenances of the Kornilova and Shubutui rocks, as well as a prolonged deposition gap (>100 Myr), evidence that the two formations were deposited in different basins and tectonic settings. The rock compositions and Nd isotope signatures suggest an island arc setting for the Shubutui deposition in the Dzhida terrane and a continental-margin setting for the deposition of the Kornilova Formation, which is the uppermost straton of the Khamar-Daban terrane.

∼2.1 Ga intraoceanic magmatism in the Central India Tectonic Zone: Constraints from the petrogenesis of ferropicrites in the Mahakoshal supracrustal belt

Picrites with anomalous high-Fe (ferropicrites), have erupted from the Archean to recent, however, their incidences are extremely limited. Particularly, post-Archean occurrences are scarce. Experimental studies indicate that ferropicrites are derived from partial melting of the upper mantle at moderate pressures (≤4GPa). The origin of the anomalous Fe-enrichment in their source, however, remains elusive, and in part attributed to the presence of silica-deficient pyroxenite.In this contribution we present a detailed account of ferropicrites in the Chitrangi Formation of the Paleoproterozoic Mahakoshal supracrustal belt in the Central India Tectonic Zone. The Lu-Hf isotope systematics of these rocks imply an age between ∼2.3Ga and ∼1.8Ga. Compared to the Lu-Hf isotopic system, the Sm-Nd isotopic system appears to be disturbed. Nevertheless, the combined Hf and Nd depleted mantle model ages of these lavas are consistent at ∼2.1Ga, which we propose as the maximum age.Geochemically, the rocks have moderate to high concentrations of Fe2O3(T) (13–19wt%) and MgO (6–18wt%), with moderate to low SiO2 (49–42wt%) and Al2O3 (14–9wt%) contents, and low Al2O3/TiO2 (<8) ratio. They exhibit fractionated chondrite normalized rare earth element patterns (La/Yb)N ∼10. The primitive mantle normalized positive Nb anomalies in combination with key trace element ratios, and their Hf, Nd isotope systematics preclude contamination by Archean upper continental crust. Further, their juvenile Hf, Nd isotope systematics are inconsistent with long lived recycled crustal or sedimentary components in the mantle source of the Mahakoshal ferropicrites. In contrast, the enrichments in the incompatible lithophile elements suggest that the source of the Mahakoshal ferropicrites was refertilized by melts, possibly from an upwelling mantle plume shortly prior to eruption.The preserved pillow structures imply that magmatism took place in an ocean basin. Therefore, we argue for the existence of a proto-ocean prior to the amalgamation of the northern cratonic block consisting of Aravalli and Bundelkhand proto-continents, and the southern cratonic block consisting of Singhbhum, Bastar and Dharwar proto-continents, which were still adrift at ∼2.1Ga.

Reconciliation of the excess 176Hf conundrum in meteorites: Recent disturbances of the Lu-Hf and Sm-Nd isotope systematics

The long-lived 176Lu-176Hf and 147Sm-143Nd radioisotope systems are commonly used chronometers, but when applied to meteorites, they can reveal disturbances. Specifically, Lu-Hf isochrons commonly yield dates up to ∼300Myr older than the solar system and varying initial 176Hf/177Hf values. We investigated this problem by attempting to construct mineral and whole rock isochrons for eucrites and angrites. Meteorites from different parent bodies exhibit similar disturbance features suggesting that a common process is responsible. Minerals scatter away from isochron regressions for both meteorite classes, with low-Hf phases such as plagioclase and olivine typically being most displaced above (or left of) reference isochrons. Relatively Hf-rich pyroxene is less disturbed but still to the point of steepening Lu-Hf errorchrons. Using our Lu-Hf and Sm-Nd data, we tested various Hf and Lu redistribution scenarios and found that decoupling of Lu/Hf from 176Hf/177Hf must postdate the accumulation of significant radiogenic 176Hf. Therefore early irradiation or diffusion cannot explain the excess 176Hf. Instead, disturbed meteorite isochrons are more likely caused by terrestrial weathering, contamination, or common laboratory procedures. The partial dissolution of phosphate minerals may predominantly remove rare earth elements including Lu, leaving relatively immobile and radiogenic Hf behind. Robust Lu-Hf (and improved Sm-Nd) meteorite geochronology will require the development of chemical or physical methods for removing unsupported radiogenic Hf and silicate-hosted terrestrial contaminants without disturbing parent-daughter ratios.

Evaluating crustal contributions to enriched shergottites from the petrology, trace elements, and Rb-Sr and Sm-Nd isotope systematics of Northwest Africa 856

The origin of the incompatible trace element (ITE) characteristics of enriched shergottites has been critical for examining two contradicting scenarios to explain how these Martian meteorites form. The first scenario is that it reflects ITE enrichment in an early-formed mantle reservoir whereas the second scenario attributes it to assimilation of ancient Martian crust (∼4–4.5Ga) by ITE-depleted magmas. Strongly differentiated shergottite magmas may yield added constraints for determining which scenario can best explain this signature in enriched shergottites. The meteorite Northwest Africa (NWA) 856 is a basaltic shergottite that, unlike many enriched shergottites, lacks olivine and has undergone extensive differentiation from more primitive parent magma. In similarity to other basaltic shergottites, NWA 856 is comprised primarily of compositionally zoned clinopyroxenes (45% pigeonite and 23% augite), maskelynite (23%) and accessory minerals such as ulvöspinel, merrillite, Cl-apatite, ilmenite, pyrrhotite, baddeleyite and silica polymorph. The CI-chondrite normalized rare earth element (REE) abundance patterns for its maskelynite, phosphates, and its whole rock are flat with corresponding light-REE depletions in clinopyroxenes. The 87Rb-87Sr and 147Sm-143Nd internal isochron ages are 162±14 (all errors are ±2σ) Ma and 162.7±5.5Ma, respectively, with an initial εNdI=−6.6±0.2. The Rb-Sr isotope systematics are affected by terrestrial alteration resulting in larger scatter and a less precise internal isochron age. The whole rock composition is used in MELTS simulations to model equilibrium and fractional crystallization sequences to compare with the crystallization sequence from textural observations and to the mineral compositions. These models constrain the depth of initial crystallization to a pressure range of 0.4–0.5GPa (equivalent to 34–42km) in anhydrous conditions at the Fayalite-Magnetite-Quartz buffer, and consistently reproduce the observed mineralogy throughout the sequence with progressive crystallization. The Ti/Al ratios in the clinopyroxenes are consistent with initial crystallization occurring at these depths followed by polybaric crystallization as the parent magma ascended to the surface. The REE abundances in the clinopyroxenes and maskelynite are consistent with progressive crystallization in a closed system.The new results for NWA 856 are combined with other shergottite data and are compared to mixing and assimilation and fractional crystallization (AFC) models using depleted shergottite magmas and ancient Martian crust as end-members. The models indicate that the range of REE abundances and ratios, when taken in isolation, can be successfully explained for all shergottites by crustal contamination. However, no successful crustal contamination model can explain the restricted εNdI of −6.8±0.2 over the wide range of Mg# (0.65–0.25), and corresponding trace element variations from enriched shergottites to depleted shergottites. The findings indicate that the origin of the long-term ITE-enriched signature in enriched shergottites and the geochemical variability seen in shergottites is not a result of crustal contamination but instead reflects ancient mantle heterogeneity.

Age and origin of rocks of the Daldyn Group of the Anabar Shield: Evidence from U-Pb zircon dating, Sm-Nd and Lu-Hf isotope systematics

The Hf-Nd isotope systematics was used to determine the genesis of zircons from granulites of the Daldyn Group of the Anabar Shield. Obtained age of magmatic crystallization for biotite–hypersthene crystalline schists and garnet amphibolites agree with position of zircons within terrestrial array. Magmatic genesis of plagiogranite neosome under granulite conditions was established for leucocratic plagiogneisses.

Geochemistry, Nd-Pb Isotopes, and Pb-Pb Ages of the Mesoproterozoic Pea Ridge Iron Oxide-Apatite–Rare Earth Element Deposit, Southeast Missouri

Iron oxide-apatite and iron oxide-copper-gold deposits occur within ~1.48 to 1.47 Ga volcanic rocks of the St. Francois Mountains terrane near a regional boundary separating crustal blocks having contrasting depleted-mantle Sm-Nd model ages (TDM). Major and trace element analyses and Nd and Pb isotope data were obtained to characterize the Pea Ridge deposit, improve identification of exploration targets, and better understand the regional distribution of mineralization with respect to crustal blocks. The Pea Ridge deposit is spatially associated with felsic volcanic rocks and plutons. Mafic to intermediate-composition rocks are volumetrically minor. Data for major element variations are commonly scattered and strongly suggest element mobility. Ratios of relatively immobile elements indicate that the felsic rocks are evolved subalkaline dacite and rhyolite; the mafic rocks are basalt to basaltic andesite. Granites and rhyolites display geochemical features typical of rocks produced by subduction. Rare earth element (REE) variations for the rhyolites are diagnostic of rocks affected by hydrothermal alteration and associated REE mineralization. The magnetite-rich rocks and REE-rich breccias show similar REE and mantle-normalized trace element patterns. Nd isotope compositions (age corrected) show that: (1) host rhyolites have ɛ Nd from 3.44 to 4.25 and TDM from 1.51 to 1.59 Ga; (2) magnetite ore and specular hematite rocks display ɛ Nd from 3.04 to 4.21 and TDM from 1.6 to 1.51 Ga, and ɛ Nd from 2.23 to 2.81, respectively; (3) REE-rich breccias have ɛ Nd from 3.04 to 4.11 and TDM from 1.6 to 1.51 Ga; and (4) mafic to intermediate-composition rocks range in ɛ Nd from 2.35 to 3.66 and in TDM from 1.66 to 1.56. The ɛ Nd values of the magnetite and specular hematite samples show that the REE mineralization is magmatic; no evidence exists for major overprinting by younger, crustal meteoric fluids, or by externally derived Nd. Host rocks, breccias, and magnetite ore shared a common origin from a similar source. Lead isotope ratios are diverse: (1) host rhyolite has 206Pb/204Pb from 24.261 to 50.091; (2) Pea Ridge and regional galenas have 206Pb/204Pb from 16.030 to 33.548; (3) REE-rich breccia, magnetite ore, and specular hematite rock are more radiogenic than galena; (4) REE-rich breccias have high 206Pb/204Pb (38.122–1277.61) compared to host rhyolites; and (5) REE-rich breccias are more radiogenic than magnetite ore and specular-hematite rock, having 206Pb/204Pb up to 230.65. Radiogenic 207Pb/206Pb age estimates suggest the following: (1) rhyolitic host rocks have ages of ~1.50 Ga, (2) magnetite ore is ~1.44 Ga, and (3) REE-rich breccias are ~1.48 Ga. These estimates are broadly consistent and genetically link the host rhyolite, REE-rich breccia, and magnetite ore as being contemporaneous. Alteration style and mineralogical or textural distinctions among the magnetite-rich rocks and REE-rich breccias do not correlate with different isotopic sources. In our model, magmatic fluids leached metals from the coeval felsic rocks (rhyolites), which provided the metal source reflected in the compositions of the REE-rich breccias and mineralized rocks. This model allows for the likelihood of contributions from other genetically related felsic and intermediate to more mafic rocks stored deeper in the crust. The deposit thus records an origin as a magmatic-hydrothermal system that was not affected by Nd and Pb remobilization processes, particularly if these processes also triggered mixing with externally sourced metal-bearing fluids. The Pea Ridge deposit was part of a single, widespread, homogeneous mixing system that produced a uniform isotopic composition, thus representing an excellent example of an igneous-dominated system that generated coeval magmatism and REE mineralization. Geochemical features suggest that components in the Pea Ridge deposit originated from sources in an orogenic margin. Basaltic magmatism produced by mantle decompression melting provided heat for extracting melts from the middle or lower crust. Continual addition of mafic magmas to the base of the subcontinental lithosphere, in a back-arc setting, remelted calc-alkaline rocks enriched in metals that were stored in the crust. The St. Francois Mountains terrane is adjacent to the regional TDM line (defined at a value of 1.55 Ga) that separates ~1600 Ma basement to the west, from younger basements to the east. Data for Pea Ridge straddle the TDM values proposed for the line. The Sm-Nd isotope system has been closed since formation of the deposit and the original igneous signatures have not been affected by cycles of alteration or superimposed mineralizing events. No evidence exists for externally derived Nd or Sm. The source region for metals within the Pea Ridge deposit had a moderate compositional variation and the REE-rich breccias and mineralized rocks are generally isotopically homogeneous. The Pea Ridge deposit thus constitutes a distinctive isotopic target for use as a model in identifying other mineralized systems that may share the same metal source in the St. Francois Mountains terrane and elsewhere in the eastern Granite-Rhyolite province.

Petrogenesis of a Neoproterozoic magmatic arc hosting porphyry Cu-Au mineralization at Jebel Ohier in the Gebeit Terrane, NE Sudan

The ca. 730Ma porphyry Cu-Au deposit at Jebel Ohier in the Red Sea Hills of northeastern Sudan represents a rare example of a preserved Neoproterozoic magmatic-hydrothermal system which bears many similarities to major mineral-hosting (‘productive’) Tertiary–Cenozoic porphyries in circum-Pacific metallogenic belts. Petrographic, lithogeochemical and Sm-Nd isotope systematics confirm that the deposit formed in a supra-subduction setting and during the constructional stage of an evolving intra-oceanic magmatic arc. The calc-alkaline melts were sourced predominantly from juvenile reservoirs and received comparatively little input from continental-character material. Comparison with igneous rocks from barren intrusions elsewhere in the region point to the absence of major crustal breaks but indicate that the ore-forming granodiorite-dacite porphyry complex at Jebel Ohier is the result of ‘abnormal’ and prolonged multi-phase arc plutonism. This process involved the formation of relatively hydrous and oxidized melts via the fractionation of magmas, which possibly had ponded at the bottom of the thickening lithosphere for a protracted period prior to their ascent. The tectonic trigger for the emplacement of the productive pluton into a pre-existing volcanic edifice at Jebel Ohier remains unconstrained. Preservation of what is considered the first documented porphyry Cu-Au deposit in the NE African portion of the Arabian Nubian Shield can probably be related to the accretion of the magmatic arc to a stable continental margin within a few million years of mineralization, thus enabling the deposit to escape excessive uplift, erosion and structural dismemberment.

Multiple sulfur isotope and mineralogical constraints on the genesis of Ni-Cu-PGE magmatic sulfide mineralization of the Monchegorsk Igneous Complex, Kola Peninsula, Russia

We present the results of a pilot investigation of multiple sulfur isotopes for the Ni-Cu-PGE sulfide mineralization of the ∼2.5 Ga Monchegorsk Igneous Complex (MIC). Base Metal Sulfide (BMS) compositions, Platinum Group Element (PGE) distributions, and Platinum Group Mineral (PGM) assemblages were also studied for different types of Ni-Cu-PGE mineralization. The uniformly low S content of the country rocks for the MIC as well as variable Sm-Nd isotope systematics and low-sulfide, PGE-rich mineralization of the MIC suggest that S saturation was reached via assimilation of silicates rather than assimilation of sulfur-rich lithologies. R-factor modeling suggests that the mixing ratio for silicate-to-sulfide melt was very high, well above 15,000 for the majority of our mineralized samples, as might be expected for the low-sulfide, PGE-rich mineralization of the MIC. Small, negative Δ33S values (from −0.23 to −0.04 ‰) for sulfides in strongly metamorphosed MIC-host rocks indicate that their sulfur underwent mass-independent sulfur isotope fractionation (MIF) in the oxygen-poor Archean atmosphere before it was incorporated into the protoliths of the host paragneisses and homogenized during metamorphism. Ore minerals from the MIC have similar Δ33S values (from −0.21 to −0.06 ‰) consistent with country rock assimilation contributing to sulfide saturation, but, also importantly, our dataset suggests that Δ33S values decrease from the center to the margin of the MIC as well as from early to late magmatic phases, potentially indicating that both local assimilation of host rocks and S homogenization in the central part of the large intrusion took place.

Genesis and age of zircon from alkali and mafic rocks of the Elet’ozero Complex, North Karelia

The paper presents a study of zircon from the Middle Paleoproterozoic Elet’ozero high-Ti layered ultramafic-mafic-alkaline intrusive complex with carbonatites and Sm-Nd isotope system of rock-forming minerals in ferrogabbro sample from this complex. Zircons extracted from syenite and ferrogabbro samples have similar pattern and experienced two main independent episodes of secondary transformation. The first episode was accompanied by the partial or complete replacement of the magmatic zircon with oscillatory zoning by porous zircon with a complex irregular inner structure, while a rim of CL-homogenous zircon around primary and porous zircons was produced during the second episode. The primary magmatic zircon is characterized by the elevated HREE, lowered LREE contents and positive Ce anomaly. The porous zircon is enriched in LREE, Ca, Ti, and frequently, in Th. While both varieties are mainly depleted in U. The REE distribution pattern in a homogenous zircon shell is similar to that of the magmatic zircon, but differs in much lower REE, especially HREE and MREE contents. The porous zircon contains microinclusions of thorite, barite, yttrialite, as well as other rare-metal and rare-earth minerals (calciosamarskite, pyrochlore, and hatchettolite), which indicates it was reworked by fluids containing not only F and Th, but also Y, U, Nb, Ta, Ba, Fe, Ti, and Ca. These components were presumably released during metamorphism-related replacement of magmatic minerals by metamorphic assemblages with fairly limited isomorphic capacity. U-Pb SHRIMP-II geochronological study of zircon showed its age varies within a wide range and correlates with peculiarities of its inner structure, which is explained by a style of superimposed processes. However, age estimations, especially for the domains dispersed alongside with porous zircon or “penetration” of shell material, often have younger values. The oldest ages (2086 ± 53 and 2086 ± 30 Ma for syenites and 2070 ± 24 Ma for ferrogabbroids) are presumably closest to the crystallization age of the intrusion. According to geological data, syenites intrude gabbroids. Therefore, the age obtained for syenites (2086 ± 30 Ma) seems to be the more preferable for the real formation age of the intrusion. Age values of porous zircon also widely vary, which is explained by the presence of relics (domains) of primary zircon in a porous matrix. We suggest that the minimum obtained dates (1.8–1.9 Ga) are the closest to the crystallization age of porous zircon. This age coincides with the Svecofennian tectonometamorphic processes, which presumably spanned the rocks of the Elet’ozero Complex, caused the metamorphism of all kind of rocks under the epidote-amphibolite facies conditions and formation of porous zircon. CL-light zircon shells were presumably formed later by interaction of zircon with a crustal fluid during the Meso- and Neoproterozoic, and even Caledonian events. The age of ferrogabbroids determined by Sm-Nd isochron method (1988 ± 63 Ma) is comparable within error with results of U-Pb dating of porous zircon, thus confirming that magmatic rocks of the complex underwent intense secondary transformations during the Svecofennian orogeny. The Middle Paleoproterozoic Elet’ozero Complex is the oldest manifestation of the high-Ti moderately alkaline magmatism at the Karelian Craton.

Geochronological (U–Pb, U–Th–total Pb, Sm–Nd) and geochemical (REE, 87Sr/86Sr, δ18O, δ13C) tracing of intraplate tectonism and associated fluid flow in the Warburton Basin, Australia

The Warburton Basin of central Australia has experienced a complex tectonic and fluid-flow history, resulting in the formation of various authigenic minerals. Geochemical and geochronological analyses were undertaken on vein carbonates from core samples of clastic sediments. Results were then integrated with zircon U–Pb dating and uraninite U–Th–total Pb dating from the underlying granite. Stable and radiogenic isotopes (δ18O, Sr and eNd), as well as trace element data of carbonate veins indicate that >200 °C basinal fluids of evolved meteoric origin circulated through the Warburton Basin. Almost coincidental ages of these carbonates (Sm–Nd; 432 ± 12 Ma) with primary zircon (421 ± 3.8 Ma) and uraninite (407 ± 16 Ma) ages from the granitic intrusion point towards a substantial period of active tectonism and an elevated thermal regime during the mid Silurian. We hypothesise that such a thermal regime may have resulted from extensional tectonism and concomitant magmatic activity following regional orogenesis. This study shows that the combined application of geochemical and geochronological analyses of both primary and secondary species may constrain the timing of tectonomagmatic events and associated fluid flow in intraplate sedimentary basins. Furthermore, this work suggests that the Sm–Nd-isotopic system is surprisingly robust and can record geologically meaningful age data from hydrothermal mineral species.

Duration of the formation and sources of the granitoids of the Litsk-Araguba Complex, Kola Peninsula

Postorogenic granitoids of the Litsk-Araguba Complex compose a chain of intrusive bodies around 850 km2 in area, which are confined to the NE-trending deep-seated fault zone. Results of U-Pb zircon dating indicate that the formation of granitoids of the Litsk-Araguba Complex lasted 28 ± 9 Ma. Note that the rocks of the first-fourth phases have similar age within (1774–1762 Ma), while quartz syenites of the fifth phase were formed much later (1746 ± 8 Ma). The study of Sm-Nd isotopic system revealed that the quartz syenites plot in the field of the Nd isotopic evolution of the lower crust represented mainly by the Paleoproterozoic garnet granulites with model ages TNd(DM) = 2.4–2.7 Ga and ɛNd(T) from −5.6 to −6.3. It was found that the near-contact syenites of the Litsk Massif contain composite zircons with an age of 1758 ± 9Ma. They differ from zircons in coeval porphyraceous granites in lowered U and Th concentrations, which are close to those in zircons from the lower crustal garnet granulites of this region. These data in combination with internal structure of the crystals determine xenogenic lower-crustal origin of zircons from syenites and confirm geochemical data on the lower crustal input in the formation of granitoid melts.

Petrogenesis of the Kulyk Lake monazite-apatite-Fe(Ti)-oxide occurrence revealed using in-situ LA-(MC)-ICP-MS trace element mapping, U-Pb dating, and Sm-Nd isotope systematics on monazite

The high-grade metamorphic metasedimentary rocks that comprise the Wollaston Domain, northern Saskatchewan, are host to numerous REE-mineralized pegmatite bodies, including the Kulyk Lake monazite-apatite-Fe(Ti)-oxide occurrence. This occurrence, which is defined by a 3-5 cm wide sinouous zone of granoblastic monazite, apatite, and titanomagnetite, is enclosed within aplitic monzonite and granitic pegmatite dikes. Monazite in this dike was studied in detail using in situ laser ablationinductively coupled plasma-mass spectrometry (LA-ICP-MS) and LA-multi-collector (MC)-ICP-MS. A combination of in situ LA-ICP-MS trace element mapping, trace-element quantification, and U-Pb dating were used to identify a significant volume of partial resorbed xenocyrstic monazite and zircon cores within the monazite-apatite-Fe(Ti)-oxide zone. This xenocrystic monazite is locally characterized by anomalously high As, V, Mo, and Eu concentrations and high (La/Yb) CN (i.e., &gt;1000) consistent with their derivation from metalliferous black shales. The U-Pb age distribution of the inherited monazite and zircon populations matches that of the middle- to upper-Wollaston Group sedimentary succession. The latter was confirmed by in situ Sm-Nd isotope systematics measured by LA-MCICP- MS that yielded εNd (1830Ma) between -5.0 and -5.7 consistent with derivation from Wollaston Group metasediment. The crystallization of ~1830 Ma anatectic overgrowths on xenocrystic cores is indistinguishable from monazite crystallization in the aplitic monzonite dike hosting the monaziteapatite- Fe(Ti)-oxide bodies. This study reveals the potential importance of metalliferous monazite-rich lithologies in the anatectic zone to these pegmatite-hosted REE occurrences and suggests that entrainment and magmatic segregation mechanisms may have helped to concentrate monazite, apatite, and Fe(Ti)-oxide prior to final emplacement of the aplite-pegmatite dikes. Similar processes may have occurred regionally and in other high-grade metamorphic terrains worldwide that are endowed with metalliferous metasedimentary protoliths.