In this paper, we introduce a groundbreaking modification to a K-band substrate integrated waveguide (SIW) Longitudinal Slot Array Antenna for Vehicle-to-Everything (V2X) applications, particularly long-range radar (LRR) in the automotive industry. Our approach harnesses an elliptic metasurface capable of distinguishing between TE and TM modes in relation to radiation direction. By utilizing metasurfaces, we effectively address the issue of mutual coupling between antenna elements, which often results in subpar antenna performance. This modification focuses on improving various antenna characteristics, including frequency bandwidth (expanded by approximately four times), sidelobe level (reduced by 4 dB), aperture efficiency (increased to about 44%), and cross-polarization (reduced by an average of 10 dB). In essence, the results demonstrate that the increased number of longitudinal elements can be effectively enhanced by utilizing the metasurface structure, while maintaining an acceptable level of efficiency. As an illustrative case, we design a 1 × 32-element Longitudinal Slot Array Antenna using the Elliott method operating at 24.3 GHz, with the antenna size measuring 12.5 × 154 mm2. Experimental measurements validate our design, showcasing a 10 dB return loss bandwidth of 24.05–24.45 GHz, a maximum gain of 14.45 dBi, a sidelobe level of 24.5 dB, cross-polarization exceeding 30 dB, and an impressive aperture efficiency of 65%.