Abstract An automated micropitting test rig was applied to study the effect of slide to roll ratio (SRR) on micropitting behaviour in rolling-sliding contacts lubricated with Zinc Dialkyl Dithiophosphate (ZDDP) containing lubricants. The tested specimen surface was examined under an optical microscope and Scanning Electron Microscope(SEM) to study the micropitting behavior of the surface, followed by applying X-ray Photoelectron Spectroscopy(XPS) to study the related tribochemistry behavior. The results show that the increase of SRR can reduce the number of micropits on the worn surface while wear increased and friction did not change much. XPS results indicate that the increase of SRR resulted in the increase of oxide concentration while the decrease of film thickness on the worn surface.