Size Roughness Research Articles

Relative size matters: Spawning substrate roughness size and spacing affect egg dislodgement and retention in the benthos

AbstractThe consequences of hydrodynamic effects on survival of embryonic benthic organisms remain unknown. This is because the interaction of hydrodynamics and substrate roughness is complex, but it can be conceptualized in two dimensions by roughness flow regimes (isolated, wake interference, and skimming flow) or roughness types (k‐ and d‐type). We examined the effect of different roughness flow regimes/roughness types and roughness heights (k) on the dislodgement of walleye (Sander vitreus) eggs (2 mm diameter, ⌀) using a wall jet apparatus. We expected that lower wall shear stress (τw) would be required for dislodgement in more‐exposed/less‐sheltered roughness type/flow regimes (i.e., k‐type/isolated roughness flow) and when k ≤ ⌀. Surprisingly, the opposite was found, indicating that other mechanism(s) are also responsible for egg dislodgement on these rough surfaces. Hydrodynamic sheltering occurred when flow was directed over exposed eggs (k ≤ ⌀) adjacent to roughness elements effectively increasing their width, and thus requiring higher τw for rolling and then ejection. When k > ⌀, eggs dislodgement likely occurred via the lower pressure in the eddies recirculating in the groove width between roughness elements, rather than due to τw. These results indicate the relevance of heterogeneous sorting and sizing of substrate elements to provide suitable spawning habitats in benthic environments.

Effect of Dual Shot Peening on Microstructure and Wear Performance of CNT/Al-Cu-Mg Composites.

This work systematically investigated the effect of dual shot peening (DSP) and conventional shot peening (CSP) on the microstructure, residual stress and wear performance of the CNT/Al-Cu-Mg composites. The results indicated that compared with CSP, DSP effectively reduced surface roughness (Rz) from 31.30 to 12.04 μm. In parallel, DSP introduced a smaller domain size (33.1 nm) and more dislocations, higher levels compressive residual stress and a stiffer deformation layer with deeper affected zones. Moreover, DSP effectively improved the uniformity of the surface layer's microstructure and residual stress distribution. The improvement is mainly due to secondary impact deformation by microshots and fine grain strengthening. In addition, the transformation of the hard second phases such as Al4C3 and CNT and its effects on improving the surface strength and deformation uniformity were discussed. Significantly, DSP improved the wear resistance by 31.8% under the load of 6 N, which is attributed to the synergistic influence of factors including hardness, compressive residual stress, surface roughness, and grain size. In summary, it can be concluded that DSP is an effective strategy to promote the surface layer characteristics for CNT/Al-Cu-Mg composites.

Scaling Heat Transfer and Pressure Losses of Novel Additively Manufactured Rib Designs

Abstract Rib turbulators are a key cooling feature that enables increased heat transfer on the interior of gas turbine components. As metal additive manufacturing becomes available for developing turbine parts, it is becoming increasingly important to understand how the surface roughness intrinsic to this manufacturing method impacts the performance of rib turbulators. To explore what impact roughness has on rib turbulator performance, several relevant scale test coupons were manufactured on two different additive machines out of IN718. Additionally, several coupons were built at large scales to effectively reduce the relative roughness size impacts and determine scale effects. A range of different wavy broken rib designs, varying both rib wavelength and orientation within a channel were evaluated. Coupon geometry and surface roughness were characterized using both computed tomography scans and optical profilometry. Variations between the print methods were found to have limited impact on the surface roughness, but significant impact on the accuracy to meet the design intent with rib heights varying by 30%. Following characterization, coupons were flow tested and it was found that the ribs that more regularly disturbed the flow as a function of their geometry most significantly enhanced heat transfer and pressure drop. The performance index of the broken wavy ribs was similar to other advanced rib designs, such as broken or V shaped ribs, but augmentations to heat transfer and pressure drop were generally lower. The rib performance was compared as a function of relative roughness, and it was found that increases in relative roughness resulted in increased friction factor and heat transfer, especially at higher Reynolds numbers.

Investigation of the flotation behavior and interaction characteristics of micro-fine quartz and magnesite in a dodecylamine system under ultrasonic treatment

Ultrasonic treatment, as an important surface modification method, profoundly affects the flotation behavior of minerals. This study examined the impact of ultrasonic treatment on the surface properties and flotation performance of magnesite and quartz in a dodecylamine (DDA) flotation system. Atomic force microscope detection results revealed that the surface roughness and roughness size of both magnesite and quartz increased after ultrasonic treatment. Flotation tests indicated that the recovery rates of magnesite and quartz were lower after ultrasonic treatment. At pH of 10 and DDA of 75 mg/L, ultrasonic treatment led to a 0.66%, 3.46%, and 0.33% decrease in the flotation recovery rates for three different magnesite particle sizes. Following ultrasonic processing, the flotation recovery rates for three different quartz particle sizes decreased by 8.48%, 30.76%, and 43.69%, in that order. X-ray photoelectron spectroscopy detection results showed an increased presence of characteristic Mg and Si sites on the surfaces of magnesite and quartz following ultrasonic treatment. DDA acted on the surfaces of the two minerals through electrostatic adsorption and hydrogen bonding adsorption and repelled the flotation of minerals owing to the same charge as characteristic sites, thereby reducing flotation recovery. Adsorption capacity tests and contact angle measurements demonstrated a decrease in DDA adsorption and contact angle on the surfaces of magnesite and quartz after ultrasonic treatment, explaining the reduced floatability. Extended Derjaguin–Landau–Verwey–Overbeek theoretical calculations indicated that before ultrasonic treatment, there was a repulsive energy between magnesite and fine-grained quartz particles. After ultrasonic treatment, the interaction energy between magnesite and fine quartz particles is mutual attraction.

Functional insights into the interaction of Lactobacillus spp. and potentially protective agents

The research addresses the critical need to explore how potentially protective agents (PPAs) influence the cellular characteristics of probiotic bacteria, with a focus on strain-specific responses. This study aimed to reveal the effect of 48-h exposure of the Lactobacillus spp. strains to selected PPAs on the viability, metabolic activity, stress response, surface properties, and physicochemical stability of bacterial suspensions. Results provide new insights into the potential risks or benefits of using the tested PPAs in probiotic production based on the analyzed strains, offering valuable information on their impacts on bacterial cells. Trehalose (TRE) and vitamin C (VC) notably impact the metabolic activity and surface characteristics of cells, with TRE improving viability and VC changing surface roughness and particle size distribution (PSD), suggesting a delicate balance between stress induction and viability enhancement. Inulin (IN) decreased metabolic changes, pointing the complex interplay between PPAs and bacterial metabolism. Results of zeta potential and PSD measurements revealed that other PPAs can either promote uniformity or induce aggregation of the bacterial suspensions. Findings have shown significant strain-specific effects of PPAs on bacterial viability and functionality, suggesting that their careful selection can improve bacterial health. Future directions include exploring the molecular mechanisms behind PPAs' effects and their practical applicability in real food systems.

Considerations Regarding Sandblasting of Ti and Ti6Al4V Used in Dental Implants and Abutments as a Preconditioning Stage for Restorative Dentistry Works

Sandblasting materials used for dental restoration are a valuable preconditioning technique that enhances the physical properties and promotes osseointegration and cell adhesion. Triplicate groups of Ti medical grade 4 and Ti6Al4V were blasted with 16 series of various naturally occurring and synthetically produced spraying materials of controlled granulometry at three spraying durations each and two spraying pressures, and the results were tested for the determination of the surface roughness taken as an average of 80 points ±5 points for each particular series of operating parameters. SEM analysis and specific tests to see whether or not cell cultures proliferate on the treated materials were also conducted. It was found that in all cases, regardless of the spraying material or working conditions, the roughness profile achieved is a uniformly distributed one. A reduction in the blasting pressure by half led to a decrease in the roughness between 30 and 35%. The use of glass balls as blasting material led to decreased roughness and more uniformly distributed roughness values for Ti as well as for Ti6Al4V, regardless of spraying duration or applied pressure compared to other spraying materials. Blasting with olivine led to increased, as well as uniformly distributed, values, and hence the conclusion that one may control the roughness size by choosing one or another of the above materials without the need to change any other operating parameters. In the case of Ti, the achieved roughness is greater than in the case of Ti4Al6V, regardless of the blasting material; the differences are smaller the softer the sandblasting material due to the fact that Ti alloys have better mechanical properties and increased hardness compared to pure Ti. SEM analysis showed that the use of sintered hydroxyapatite as an additive to the blasting material does not necessarily lead to a substantial deposition of hydroxyapatite on the substrate materials; only traces of it were identified during the analysis. As a general conclusion, this study showed that by sandblasting Ti and Ti6Al4V with different spraying materials, one may control the surface roughness, and this technique may be an attractive method for preconditioning these materials for restorative dentistry.

Optimizing sheet metal edge quality with laser-polishing: surface characterization and performance evaluation

Dual-phase (DP) steels are widely used in the automotive industry due to their exceptional performance. It offers excellent strength, ductility, formability, and weldability. However, there is a high risk of edge cracking, particularly in materials like DP1000 steel, caused by residual damage from blanking, such as microcracks and burrs, which needs further investigation. In this study, the transformative potential of laser-polishing on DP1000 steel was investigated. The goal was to reduce edge crack sensitivity and enhance edge formability. In this work, laser-polished samples produced by various pre-manufacturing techniques such as sawing, punching, and waterjet cutting were examined. Various evaluations were performed on laser-polished samples. Those included white-light-confocal microscopy, scanning electron microscopy, and Electron Backscatter Diffraction (EBSD) analysis. Those evaluations aimed to analyze the microstructural transformation, surface roughness, and micro grain size distribution resulting from laser-polishing. Laser-polishing is a process in which the edge of the sample is remelted locally. Hence, residual damage vanishes, and surface defects disappear, which should be beneficial for edge formability. On the other hand, the cooling rate during re-solidification is high, leading to high strength and reduced ductility compared to the initial DP steel. Therefore, hole expansion tests were conducted to evaluate the edge formability of the steel. The results indicated a significant improvement in the hole expansion ratio of the laser-polished samples compared to samples with conventional manufactured edges. These findings will help to assess the advantages and limitations of laser-polishing in sheet material manufacturing.

Correlations between Skin Condition Parameters and Ceramide Profiles in the Stratum Corneum of Healthy Individuals.

Ceramides are essential lipids for skin barrier function, and various classes and species exist in the human stratum corneum (SC). To date, the relationship between skin conditions and ceramide composition in healthy individuals has remained largely unclear. In the present study, we measured six skin condition parameters (capacitance, transepidermal water loss, scaliness, roughness, multilayer exfoliation, and corneocyte cell size) for the SC of the cheeks and upper arms of 26 healthy individuals and performed correlation analyses with their SC ceramide profiles, which we measured via liquid chromatography-tandem mass spectrometry. In the cheeks, high levels and/or ratios of two free ceramide classes containing an extra hydroxyl group in the long-chain moiety and a protein-bound ceramide class containing 6-hydroxysphingosine correlated with healthy skin conditions. In contrast, the ratios of two other free ceramide classes, both containing sphingosine, and a protein-bound ceramide class containing 4,14-sphingadiene correlated with unhealthy skin conditions, as did shortening of the carbon chain of the fatty acid portion of two ceramide classes containing non-hydroxy fatty acids. Thus, our findings help to elucidate the relationship between skin conditions and ceramide composition.

Research on production of microgroove arrays on TiAl intermetallic alloy by micro milling

TiAl intermetallic alloy is a superior lightweight material with excellent performance, and its micro features or components have promising applications in manufacturing fields. In this work, an investigation of micro milling of microgroove arrays on TiAl alloy was studied. The effects of cutting parameters including the feed per tooth (fz) and depth of cut ( ap) on the milling force, surface morphology, surface roughness and burr size of the micro-slots were investigated. The wear types and mechanisms of the micro end mills were also studied. The results showed that the optimal cutting parameters were fz = 3.5 μm/z and ap = 4 μm, which provided the best surface roughness Sa of 152 nm, top-burr heights on up- and down-milling sides of 19 and 19.5 μm respectively. Using the optimized cutting parameters, microgrooves with a width of 500 μm, aspect ratio of 5 and array period of 10 were fabricated successfully. Surface topography, dimensional accuracy and perpendicularity of the microgroove arrays were characterized. Results demonstrated that an increase in the microgroove number, microgroove edge chipping as well as burrs of the entrance and exit increased gradually. The dimensional error between the obtained width and the designed width of the microgroove was less than 2%, and the slope of the sidewalls reached more than 89°. The wear mechanisms of the micro end mills were abrasive wear and adhesive wear, and wear types were coating delamination, cutting edge chipping, and tool nose breakage.

Migration of natural organic matter and Pseudomonas fluorescens-associated polystyrene on natural substrates in aquatic environments

This study investigated the migration behavior of microplastics (MPs) covered with natural organic matter (NOM) and biofilm on three substrates (silica, Pseudomonas fluorescent and Pseudomonas aeruginosa biofilms) in various ionic strengths, focusing on the alterations in surface properties based on surface energy theory that affected their deposition and release processes. Peptone and Pseudomonas fluorescens were employed to generate NOM-attached and biofilm-coated polystyrene (PS) (NOM-PS and Bio-PS). NOM-PS and Bio-PS both exhibited different surface properties, as increased roughness and particle sizes, more hydrophilic surfaces and altered zeta potentials which increased with ionic strength. Although the deposition of NOM-PS on biofilms were enhanced by higher ionic strengths and the addition of Ca2+, while Bio-PS deposited less on biofilms and more on the silica surface. Both types exhibited diffusion-driven adsorption on the silica surface, with Bio-PS also engaging in synergistic and competitive interactions on biofilm surfaces. Release tests revealed that NOM-PS and Bio-PS were prone to release from silica than from biofilms. The Extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory furtherly demonstrated that mid-range electrostatic (EL) repulsion had significantly impacts on NOM-PS deposition, and structural properties of extracellular polymeric substances (EPS) and substrate could affect Bio-PS migration.

Microstructure, electrochemical corrosion and corrosion mechanism of electroplated Ni–W alloy coating by DFT calculation

ABSTRACT A Ni–W alloy coating with a thickness of 5 μm was electroplated on N80 steel, and its electrochemical performance in a 3.5% NaCl solution was investigated. The atomic models of passive films and corrosion mechanism were analysed with the density functional theory calculation. The results show that the electroplated Ni–W alloy coating is composed of W atoms in the Ni lattice, and its surface roughness and particle size are 66.1 and 640.4 nm, respectively. The corrosion current density of Ni–W coating is lower than that of the substrate, indicating better corrosion resistance, while the corrosion potential is opposite, which is more passive than the substrate. The total impedance of Ni–W coating is higher than that of the substrate, which is attributed to the formation of NiO passive film during the corrosion process.

Improved Reversibility of Thin-Film Solid Oxide Cells at 500 °C by Tailoring Sputtering Processes for Depositing Yttria-Stabilized Zirconia Electrolyte.

The present study investigates the impact of sputtering configurations on the microstructure and crystallinity of thin-film yttria-stabilized zirconia electrolytes for anodized aluminum oxide-supported all-sputtered thin-film reversible solid oxide cells. Employing various sputtering parameters, such as target-substrate distance and substrate rotation speed, the present study reveals distinct surface characteristics and crystalline structures of thin-film yttria-stabilized zirconia. The microstructure analysis includes scanning electron microscopy and atomic force microscopy examinations, uncovering the influence of the process parameters on the surface morphology, roughness, and grain size. X-ray diffraction data illustrate the texture preferences and crystallite characteristics. The electrochemical characterization of the reversible solid oxide cells demonstrates that the optimized sputtering configuration significantly outperforms the others in both SOFC and SOEC modes, showing exceptional current densities of 964 mA/cm2 at 1.3 V in electrolysis mode at 500 °C. Electrochemical impedance spectroscopy further reveals improved charge transfer reactions at the interface of the electrolyte. The enhanced electrochemical performance is attributed to the unique microstructure and crystallinity of the thin film of yttria-stabilized zirconia. The record-breaking electrolysis performance of this work at 500 °C underscores the potential of tailored sputtering parameters in optimizing the reversible solid oxide cell performance.

Study on the reduction of residual stress in laser cladding layers through groove texture

In order to develop a method for the production of crack-free cladding layers, we combined surface texturing technology with laser cladding, establishing a multi-field coupled numerical simulation model. A separate investigation was conducted into the temperature, stress, and fluid fields in laser cladding processes with and without texturing, seeking optimal cladding parameters, and conducted experiments. The results of the numerical simulations indicate that pre-set texturing effectively reduces the temperature gradient during the cladding process, thereby making the thermal cycle curve smoother. The residual stresses in the X, Y, and Z directions are reduced by 34.84%, 3.94%, and 50.22%, respectively. The introduction of texturing reduces the internal flow velocity of the melt pool, preventing the occurrence of a double vortex effect. Experimental results show that the residual stresses in the X, Y, and Z directions of the predefined textured cladding layer are reduced by approximately 41%, 8%, and 47%, respectively, compared to the non-textured cladding layer. This effectively improves the surface roughness and internal grain size of the cladding layer, with no significant defects at the metallurgical bonding positions, providing a reference for future improvements in cladding layer quality.

A novel interdisciplinary model for optimizing coalbed methane recovery and carbon dioxide sequestration: Fracture dynamics, gas mechanics, and its application

The Carbon Dioxide Enhanced Coalbed Methane (CO2-ECBM) technique significantly enhances clean energy extraction and mitigates climate change. Central to this process is the dynamic evolution of rough fracture networks within coal seams, influencing the migration of CO2 and natural gas. However, existing research lacks a comprehensive, quantitative approach to examining the micro-evolution of these fractures, including fracture roughness, fracture density, fracture touristy, and fracture size, particularly under thermo-hydro-mechanical effects. Addressing this gap, our study introduces an innovative, fractal model for quantitative analysis. This model intricately characterizes fracture networks in terms of number, tortuosity, length, and roughness, integrating them with fluid dynamics affected by external disturbances in CO2-ECBM projects. Upon rigorous validation, the finite element method analysis reveals significant impacts of micro-parameters on permeability and natural gas extraction. For instance, increasing CO2 injection pressure from 4 to 6 MPa changes fracture network density by up to 6.4%. A decrease in fracture density (Df) from 1.6 to 1.5 raises residual gas pressure by 2.7% and coal seam stress by 9.5%, indicating crucial considerations for project stability. Applying the proposed interdisciplinary model to assess CO2 emissions in Australia, it is can be obtained that when Df decreases from 1.6 to 1.5, the total amount of CO2 storage reduces by 17.71%–18.04%. Our results demonstrate the substantial influence of micro-fracture behaviors on CO2-ECBM projects, offering a ground-breaking solution for efficient greenhouse gas reduction and clean energy extraction, with practical implications for the energy sector's sustainability.

Modeling powder spreadability in powder-based processes using the discrete element method

Powder-bed fusion (PBF) processes refer to a subset of Additive Manufacturing (AM) techniques where powder is spread on the build-plate before melting (by a laser or electron beam). While PBF processes are attractive due to their ability for realizing complex structures that are either difficult or impossible to create through conventional means, the parts fabricated with these techniques can exhibit defects such as pores, inclusions, and excessive surface roughness. To minimize these defects, much research has been dedicated towards process maturation by optimizing laser or electron beam parameters. However, these developmental efforts typically do not address the recoating process where achieving dense and uniform layers of powder is a necessity for ensuring process repeatability and part quality. While the recoating process can be studied through experimentation, the dynamics of particle movement are difficult to analyze experimentally. Therefore, in this study, powder spreading in PBF was simulated through the Discrete Element Method (DEM) to elucidate the mechanisms that control powder-bed quality. Utilizing the Buckingham Pi theorem, a dimensionless metric referred to as the spreading index is developed that combines powder-bed density, roughness, and particle size to assess the quality of powder layers. The formulated spreading index is then related to several dimensionless quantities that provide insight into the mechanisms dominating powder spreading in PBF. The DEM simulations conducted in this work focused on the scenario where powder is spread onto an existing powder bed and revealed that a reduction in the recoating velocity causes an increase in the spreading index while little to no impact on the spreading index was observed when varying layer thickness from 30 µm to 75 µm. Particle size effects on the powder-bed quality were also investigated.

Unveiling enhanced sound absorption in coconut wood through hemicellulose and lignin modification

Coconut wood (Cocos nucifera L.) is lightweight and has variable quality, making it a potential candidate for manufacturing sound absorption boards. However, its sound absorption coefficient needs enhancement to optimize its effectiveness in this application. This study aims to enhance its sound absorption properties using eco-friendly hydrogen peroxide and acetic acid treatments. This treatment modified the carbohydrate polymers (hemicellulose and cellulose) and lignin structures in the wood cell wall. The novelty of this approach lies in using these chemicals to improve acoustic performance significantly. Coconut wood samples were treated with a 1:1 acetic acid and hydrogen peroxide mixture for 20, 40, 60, and 80 min. Characterization techniques such as FTIR, XPS, and XRD, and 3D optical profilometry analyzed changes in chemical functionalities, crystallinity, and surface roughness. Sound absorption coefficients were measured using the impedance tube method. Results showed a significant improvement in sound absorption for all treated samples, especially at 60 min. The treatment also enhanced surface roughness, air permeability, porosity, and pore sizes, contributing to better sound absorption. This proposed treatment method addresses environmental consciousness and enhances the sustainable use and utilization of coconut wood.

Solid solution of zirconium on the M-site in Ti2AlC MAX phase coatings: Synthesis, structure and mechanical properties

Ti2AlC MAX phase is considered an ideal candidate for surface protective coatings in harsh environments due to its excellent resistance to oxidation and corrosion, yet poor mechanical properties are a key bottleneck for practical applications. In this work, taking the conception of solid solution, high-purity and high-hardness (Ti, Zr)2AlC coatings were synthesized on Ti-6Al-4V substrates using a multiple-target magnetron sputtering technique combined with subsequent annealing. The as-deposited Ti-Zr-Al-C coating was partially crystalline containing TiAlx phase, and MAX phases formed after annealing at 750 °C for 90 min. Comprehensive X-ray diffraction and high-resolution TEM analysis identified the formation of solid solution (Ti0.9Zr0.1)2AlC. The incorporation of Zr reduced the surface roughness and grain size of the coatings due to the increased nucleation sites and the suppressed atomic diffusion. Comparing with pristine Ti2AlC coating, the hardness of the (Ti0.9Zr0.1)2AlC coating was enhanced by 30 % from 12.8 GPa to 16.6 GPa. This enhancement can be ascribed to the synergistic strengthening from solid solution and grain refinement. However, fracture toughness slightly deteriorated in the (Ti0.9Zr0.1)2AlC coating due to the preferential crack path along the refined-grain boundaries.

Interfacial design of support substrate for a continuous mesophase-templated active layer with adjustable pore size

Nano-porous active layers templated by hexagonal lyotropic liquid crystal (HLLC) offer a continuous water pathway, rendering them promising for membrane separation applications of high performance. The surface properties, such as surface roughness, hydrophilicity and pore size, of commercially available ultrafiltration membranes usually need to be optimized to better support the active layer. Here, we apply a facile yet potent thermal treatment process to a polyacrylonitrile ultrafiltration (UPAN) substrate and form a continuous HLLC separation layer. The enhancement in water filtration performance is largely influenced by the surface roughness of the substrates. As the temperature increases, the UPAN substrates become rougher due to approaching the glass transition temperature of polyacrylonitrile. This leads to a denser HLLC active layer with smaller pores. For the membranes treated at a temperature of 100 °C, their water flux reaches 17 L/m2h, which is 10 times higher than that of the membranes treated at 85 °C, and the PEG4000 rejection increases by almost 50 % from 42 % to 59 %. This heat treatment process offers a novel approach to fabricate mesophase-templated active layers with adjustable pore sizes, thus advancing membrane separation techniques.

Studying the Effect of Magnetron Copper Deposition on the Surface Topography of Biodegradable Antibacterial Coating.

The surface properties of the materials used significantly influence the success and longevity of medical implants. Increasing surface roughness promotes osteoblast activity and osseointegration, while biodegradable materials such as copper have shown potential for antimicrobial applications. However, the effect of coating parameters on surface topography is not well investigated. Sputtering of copper was performed using EPOS-PVD-440 system (Zeleno-grad, Russia). The samples were examined by Scanning Electron Microscopy (SEM) with subsequent image processing in Mountains software (Digital Surf). Antibacterial efficacy was evaluated against Staphylococcus aureus by measuring the zone of inhibition. Additionally, copper ion release was monitored over time to assess its correlation with changes in surface topography. Higher sputtering currents increased surface roughness and particle size, with a significant release of copper ions within the first 24 hr of immersion. Samples sputtered at higher currents exhibited coarser grain structures. The release of copper ions in the simulated biological environment led to further changes in surface topography, highlighting the critical influence of sputtering parameters on coating properties. Optimizing magnetron copper deposition parameters enhances the surface topography and antibacterial effectiveness of biodegradable coatings on implants.

Effect of Annealing Process on the Morphological, Optical and Electrical Properties of Cu:MnO Films Prepared by PLD Technique

In this study, Nd:YAG laser pulses with a wavelength of 1064 nm, a power of 500 mJ, a pulse width of 9 ns, and a repetition frequency of 6 Hz were used to hit a manganese oxide (MnO) target surface 300 times. Pure MnO and copper Cu-doped MnO (Cu:MnO) with different amounts of Cu (0.03, 0.05, 0.07, and 0.09 wt%) produced by PLD were studied. Cu:MnO thin films were annealed at 473 K, and their morphological, optical, and electrical characteristics were studied. The results of the atomic force microscopic (AFM) investigation of morphological properties showed that Cu dopant impacted the creation of roughness and particle size in MnO2 films. The optical transmission was examined using a UV-Vis spectrophotometer. The highest optical absorption was noted at 0.09 dopant content. The dielectric constants' real (εr) and imaginary (εi) components, as well as the extinction coefficient (k), refractive index (n), and other optical constants, were studied. At an annealing temperature of (473 K), Hall effect studies demonstrate that all produced films exhibit a P-type conductivity.