Particle number concentrations and size distribution of atmospheric aerosol particles were measured in the range 6560nm by a fast mobility particle sizer in Toledo, Spain, and in the outskirts of nearby small villages within the area of influence of a cement factory, quarries and ceramic industries. Several measurement campaigns have been carried out in different days in Toledo (April, May and July) and one campaign in “Comarca de la Sagra” in July. In each campaign, measurement of 10–15 min has been achieved in several different points. In addition, a campaign of continuous measurements has been carried out in Toledo. The average number concentration in Toledo are consistent with other urban measurements, with lower values during the night–time ranging from 3×103 to 1×104 particles/cm3 and higher average levels during daytime ranging from 5×103 to 4×104 particles/cm3 depending on the measurement site and date. The measurement sites show similar background profiles of the particle size distributions with two clear particle modes centered in the sizes ranges 10–15 and 40–50nm. Road traffic is postulated as the main source of submicron particles, giving lower level of particles during the summer time. Results from continuous measurements have been analyzed. On the other hand, the low total concentrations obtained in the “Comarca de la Sagra” campaign, ranging from 1.5×103 to 3.1×103 particles/cm3 with an average value of 2.3×103 particles/cm3, show a negligible influence of the different building materials industries on the total submicron particle concentration in the surrounding area and in Toledo.