Determination of the peak thermal condition is vital in order to understand tectono-thermal evolution of the Himalayan belt. The Lesser Himalayan Sequence (LHS) in the Western Arunachal Pradesh, being rich in carbonaceous material (CM), facilitates the determination of peak metamorphic temperature based on Raman spectroscopy of carbonaceous material (RSCM). In this study, we have used RSCM method of Beyssac et al. (J Metamorph Geol 20:859–871, 2002a) and Rahl et al. (Earth Planet Sci Lett 240:339–354, 2005) to estimate the thermal history of LHS and Siwalik foreland from the western Arunachal Pradesh. The study indicates that the temperature of 700–800 °C in the Greater Himalayan Sequence (GHS) decreases to 650–700 °C in the main central thrust zone (MCTZ) and decreases further to 600 and 12 km) than the upper Siwalik sediments to its south at depths <8 km before they were exhumed. The 40Ar/39Ar ages suggest that the upper zones of Se La evolved ~13–15 Ma. The middle zone exhumed at ~11 Ma and lower zone close to ~8 Ma indicating erosional unroofing of the MCT sheet. The footwall of MCTZ cooled between 6 and 8 Ma. Analyses of P–T path imply that LHS between MCT and U.MBT zone falls within the kyanite stability field with near isobaric condition. At higher structural level, the temperatures increase gradually with P–T conditions in the sillimanite stability field. The near isothermal (700–800 °C) condition in the GHS, isobaric condition in the MCTZ together with T–t path evidence of GHS that experienced relatively longer duration of near peak temperatures and rapid cooling towards MCTZ, compares the evolution of GHS and inverted metamorphic gradient closely to channel flow predictions.