Site U1313 Research Articles

Late quaternary sea-ice and sedimentary redox conditions in the eastern Bering Sea – Implications for ventilation of the mid-depth North Pacific and an Atlantic-Pacific seesaw mechanism

On glacial-interglacial and millennial timescales, sea ice is an important player in the circulation and primary productivity of high latitude oceans, affecting regional and global biogeochemical cycling. In the modern North Pacific, brine rejection during sea-ice freezing in the Sea of Okhotsk drives the formation of North Pacific Intermediate Water (NPIW) that ventilates the North Pacific Ocean at 300 m–1000 m water depth. Glacial intervals of the late Quaternary, however, experienced a deepening of glacial NPIW to at least 2000 m, with the strongest ventilation observed during cold stadial conditions of the last deglaciation. However, the origin of the shifts in NPIW ventilation is poorly understood. Numerical simulations suggest an atmospheric teleconnection between the North Atlantic and the North Pacific, in response to a slowdown or shutdown of the Atlantic meridional overturning circulation. This leads to a build-up of salinity in the North Pacific surface ocean, triggering deep ventilation. Alternatively, increased sea-ice formation in the North Pacific and its marginal seas may have caused strengthened overturning in response to enhanced brine rejection.Here we use a multi-proxy approach to explore sea-ice dynamics, sedimentary redox chemistry, and benthic ecology at Integrated Ocean Drilling Program Site U1343 in the eastern Bering Sea across the last 40 ka. Our results suggest that brine rejection from enhanced sea-ice formation during early Heinrich Stadial 1 locally weakened the halocline, aiding in the initiation of deep overturning. Additionally, deglacial sea-ice retreat likely contributed to increased primary productivity and expansion of mid-depth hypoxia at Site U1343 during interstadial conditions, confirming a vital role of sea ice in the deglacial North Pacific carbon cycle.

Combination of insolation and ice-sheet forcing drive enhanced humidity in northern subtropical regions during MIS 13

Marine Isotope Stage (MIS) 13, ∼533–478 ka, has received particular attention due to the unexpected enhancement of monsoon systems under a cool climate characterized by lower atmospheric CO2 and larger ice volume than many other interglacials. Key questions remain about its regional expression (intensity, climate variability, length), and underlying forcing factors, in particular at the mid-latitudes. Here we examine the SW Iberian vegetation, terrestrial climate and sea surface temperature (SST) variability during MIS 13 by combining pollen and biomarker data from IODP Site U1385 with climate-model experiments. We show, for the first time, that despite strong precessional forcing, MIS 13 stands out for its large forest expansions with a reduced Mediterranean character alternating with muted forest contractions, indicating that this stage is marked by a cool-temperate climate regime with high levels of humidity. Results of our data-model comparison reveal that MIS 13 orbitally driven SW Iberian climate and vegetation changes are modulated by the relatively strong ice-sheet forcing. We find that the Northern Hemisphere ice-sheets prescribed at the MIS 13 climate optimum reinforce the insolation effect by increasing the tree fraction and both winter and summer precipitation. We propose that the interactions between ice-sheets and major atmospheric circulation systems may have resulted in the persistent influence of the mid-latitude cells over the SW Iberian region, which led to intensified moisture availability and reduced seasonality, and, in turn, to a pronounced expansion of the temperate forest.

A new perspective of the Alboran Upwelling System reconstruction during the Marine Isotope Stage 11: A high-resolution coccolithophore record

A high-resolution study of the MIS 12/MIS 11 transition and the MIS 11 (430–376 kyr) coccolithophore assemblages at Ocean Drilling Program Site 977 was conducted to reconstruct the palaeoceanographic and climatic changes in the Alboran Sea from the variability in surface water conditions. The nannofossil record was integrated with the planktonic oxygen and carbon stable isotopes, as well as the Uk'37 Sea Surface Temperature (SST) at the studied site during the investigated interval. The coccolithophore primary productivity, reconstructed from the PPP (primary productivity proxy = absolute values of Gephyrocapsa caribbeanica + small Gephyrocapsa group) revealed pronounced fluctuations, that were strongly associated with variations in the intensity of the regional Alboran Upwelling System. The comparison of the nannoplankton record with opal phytolith content for the studied site and the already available pollen record at the nearby Integrated Ocean Drilling Program Site U1385, suggests an association of the upwelling dynamics with the variability of the North Atlantic Oscillation-like (NAO-like) phase. High PPP during positive (+) NAO-like phases is the result of intensified upwelling, owing to the complete development of the surface hydrological structures at the Alboran Sea. This scenario was identified during the MIS 12/MIS 11 transition (428-422 kyr), the late MIS 11c (405-397 kyr), and MIS11 b to MIS 11a (397-376 kyr). Two short-term minima in the PPP and SST were observed during MIS 11 b and were coeval with the North Atlantic Heinrich-type (Ht) events Ht3 (∼390 kyr) and Ht2 (∼384 kyr). Increased abundance of the subpolar Coccolithus pelagicus subsp. pelagicus and Gephyrocapsa muellerae was consistent with the inflow of cold surface waters into the Mediterranean Sea during the Ht events. Lowered PPP during negative (−) NAO-like phases is the result of moderate upwelling by the incomplete development of surface hydrological structures at the Alboran Sea. This scenario is expressed during the early MIS 11c (422-405 kyr). Overall, the results of our study provide evidence of the important role of atmospheric circulation patterns in the North Atlantic region for controlling phytoplankton primary production and oceanographic circulation dynamics in the Western Mediterranean during MIS 11.

Exploring the importance of authigenic clay formation in the global Li cycle

Lithium isotopic (δ7Li) and elemental concentrations of pore fluids and carbonates from IODP Site U1338 Hole A (eastern equatorial Pacific Ocean) suggest that clay authigenesis (i.e., in situ precipitation) is a significant sink for Li in carbonate-rich sedimentary sections. Systematic variations in pore fluid δ7Li with depth in the section suggest that clay authigenesis can (i) strongly decrease pore fluid Li concentrations with depth and (ii) fractionate Li isotopically to a considerable degree (Δ ∼ 5–21‰ relative to seawater). We hypothesize that clay authigenesis in carbonate-rich sections occurs due to the presence of reactive biogenic silica, and reactive transport modeling supports the contention that the pore fluid δ7Li depth profile at Site U1338 is best explained by faster authigenesis at depth. The significance of clay authigenesis in carbonate-rich sediments is two-fold: if global in scale, (i) it can generate sizeable output fluxes in the global Li cycle, and (ii) the evolution of the sedimentary system over time can markedly impact the isotopic composition of the global Li output flux. We compile ODP and IODP pore fluid Li data from 267 sites; of these, 207 have Li pore fluid concentration gradients in the upper 50–100 meters that indicate the sites as diffusive sinks of Li. We then estimate that clay authigenesis in carbonate-rich sediments could reasonably generate a Li output flux on the order of ∼1.2·1010 moles/year, which is comparable to the gross input fluxes in the modern Li cycle. A series of reactive transport simulations illustrate how clay authigenesis might impact the isotopic composition of the output flux of Li from the global ocean. The suggestion is that applying a constant fractionation factor from the global ocean over time is likely incorrect, and that secular changes in the δ7Li of the output flux will be driven by rates of authigenesis, burial rates, and the depth extent of authigenesis in the sedimentary section. Utilizing a time-dependent, depositional diagenetic model, the δ7Li values of bulk carbonate are shown to be a consequence not of recrystallization alone, but recrystallization in the presence of clay authigenesis. Further, our model results are used to illustrate how carbonate δ7Li may be used to constrain the temporal evolution of clay authigenesis in the sedimentary section. Ultimately, this work suggests that the Li isotopic composition of bulk carbonates can be altered diagenetically. However, such alteration is not a detriment, but provides useful information on those diagenetic processes in the sedimentary column that impact the global Li cycle. Thus, Li isotopes in bulk carbonates have the potential to elucidate diagenetic controls on the global Li cycle over long time scales.

A Reassessment of the Chronostratigraphy of Late Miocene C3–C4 Transitions

AbstractCombining magnetostratigraphic and carbon isotopic data for the late Miocene can provide a temporal framework for an isotopic shift first documented in soil carbonate nodules of northern Pakistan. The shift has been interpreted as a change in vegetation from trees and shrubs (using the C3 photosynthetic pathway) to grassland (using the C4 pathway). The cause of the event has been hotly debated and its timing is close to a shift in carbon isotopes in the marine realm. Further understanding depends critically on chronology. Unfortunately, temporal calibration of the various records published over decades relied on different time scales. To address the lack of a consistent chronology, we have reevaluated the constraints for the carbon isotopic shifts recorded from the Indian subcontinent. These show a diachronous transition ranging in age from about 7.8 Ma in Pakistan to as late at 6 Ma in Nepal. The record from IODP Expedition 355 Site U1457, drilled on the Indus fan shows that the transition in peninsular India began at about 7.2 Ma. Similar records from the African margin saw an earlier shift to C4 dominance starting around 10 Ma and those from Australia and South America transitioned later, during the Pliocene. The diachroneity around the globe does not invalidate pCO2 as a driver, but is consistent with it being one of several drivers of the global C4 expansion.

Lithogeochemistry of the Mid-Ocean Ridge Basalts near the Fossil Ridge of the Southwest Sub-Basin, South China Sea

Mid-ocean ridge basalts (MORB) in the South China Sea (SCS) record deep crust-mantle processes during seafloor spreading. We conducted a petrological and geochemical study on the MORBs obtained from the southwest sub-basin of the SCS at site U1433 and U1434 of the International Ocean Discovery Program (IODP) Expedition 349. Results show that MORBs at IODP site U1433 and U1434 are unaffected by seawater alteration, and all U1433 and the bulk of U1434 rocks belong to the sub-alkaline low-potassium tholeiitic basalt series. Samples collected from site U1433 and U1434 are enriched mid-ocean ridge basalts (E-MORBs), and the U1434 basalts are more enriched in incompatible elements than the U1433 samples. The SCS MORBs have mainly undergone the fractional crystallization of olivine, accompanied by the relatively weak fractional crystallization of plagioclase and clinopyroxene during magma evolution. The magma of both sites might be mainly produced by the high-degree partial melting of spinel peridotite at low pressures. The degree of partial melting at site U1434 was lower than at U1433, ascribed to the relatively lower spreading rate. The magmatic source of the southwest sub-basin basalts may be contaminated by lower continental crust and contributed by recycled oceanic crust component during the opening of the SCS.

Image processing techniques to improve characterization of composite ichnofabrics

Image processing techniques, including the Analyze Particles tool offered by Fiji software and the Intensity Profile by ICY (IP-ICY), were applied in core and outcrop examples to improve characterization of autocomposite ichnofabrics. Analyze Particles gives information about particle shape and size in the studied image. This tool was applied to Chondrites assemblages in composite ichnofabrics in view of selected images of modern marine hemipelagic cores from Site U1385 of IODP Expedition 339. Differences in size, relative abundance, density and distribution of Chondrites were interpreted as related to variations within the population of Chondrites tracemakers. Intensity Profile quantifies pixel values of the infilling material of traces, proving helpful to discriminate between specimens, evaluate the horizon of colonization, and approach the penetration depth. Its application to the analysis of Zoophycos improves characterization of composite ichnofabrics from deep-sea pelagic calcilutites of the Petra Tou Romiou section (Eocene Lefkara Formation; southern Cyprus). Some suites of Zoophycos were interpreted as associated with different phases of colonization from several horizons. Moreover, it was possible to discriminate structures pertaining to different specimens, as opposed to those from the same specimen.

Geochemical Records of the Provenance and Silicate Weathering/Erosion From the Eastern Arabian Sea and Their Responses to the Indian Summer Monsoon Since the Mid‐Pleistocene

AbstractWe present a multiproxy record of Sr‐Nd isotopes and major and trace elements for clay‐sized (<2 μm) siliciclastic sediment fractions from the International Ocean Discovery Program Site U1456 in the eastern Arabian Sea to extract reliable chemical indicators not influenced by the grain‐size effect, quantitatively estimate detrital provenance, and constrain silicate weathering/erosion in response to the Indian summer monsoon over orbital timescales. A provenance analysis of fine‐grained siliciclastic sediments indicates a two end‐member mixture from the Indus River (20–90%) and rivers draining the Deccan Traps (10–80%). A prominent increase in terrigenous input from the Indus River occurred at ~0.5 Ma, probably resulting from an intensive erosional event in the Himalayan region. Moreover, αAlK at Site U1456, which is calculated as Al/K ratio of the study sample versus Al/K ratio of the upper continental crust, can be generally used to reflect the chemical weathering intensity in the source regions. During most interglacial and even certain glacial periods, the Indian summer monsoon reinforcement is closely coupled with enhanced continental chemical weathering and physical erosion. Wavelet and spectral analyses of the αAlK record display strong 125‐, 35‐, 29‐, and 23‐kyr periodicities since 1.2 Ma with significant ~100‐kyr cycles established at the end of the Mid‐Pleistocene Transition (~0.7 Ma), suggesting forcing mechanisms linked with both Northern and Southern Hemispheric processes. Significant fluctuations observed in silicate weathering/erosion during ~1.2–0.7 Ma indicate an enhancement of the Indian summer monsoon with increased variability in association with the Mid‐Pleistocene Transition.

Temporal Evolution of Proto-Izu–Bonin–Mariana Arc Volcanism over 10 Myr: Constraints from Statistical Analysis of Melt Inclusion Compositions

AbstractInternational Ocean Discovery Program (IODP) Expedition 351 ‘Izu–Bonin–Mariana (IBM) Arc Origins’ drilled Site U1438, situated in the northwestern region of the Philippine Sea. Here volcaniclastic sediments and the igneous basement of the proto-IBM volcanic arc were recovered. To gain a better understanding of the magmatic processes and evolution of the proto-IBM arc, we studied melt inclusions hosted in fresh igneous minerals and sampled from 30–40 Myr old deposits, reflecting the maturation of arc volcanism following subduction initiation at 52 Ma. We performed a novel statistical analysis on the major element composition of 237 representative melt inclusions selected from a previously published dataset, covering the full age range between 30 and 40 Ma. In addition, we analysed volatiles (H2O, S, F and Cl) and P2O5 by secondary ion mass spectrometry for a subset of 47 melt inclusions selected from the dataset. Based on statistical analysis of the major element composition of melt inclusions and by considering their trace and volatile element compositions, we distinguished five main clusters of melt inclusions, which can be further separated into a total of eight subclusters. Among the eight subclusters, we identified three major magma types: (1) enriched medium-K magmas, which form a tholeiitic trend (30–38 Ma); (2) enriched medium-K magmas, which form a calc-alkaline trend (30–39 Ma); (3) depleted low-K magmas, which form a calc-alkaline trend (35–40 Ma). We demonstrate the following: (1) the eruption of depleted low-K calc-alkaline magmas occurred prior to 40 Ma and ceased sharply at 35 Ma; (2) the eruption of depleted low-K calc-alkaline magmas, enriched medium-K calc-alkaline magmas and enriched medium-K tholeiitic magmas overlapped between 35 and 38–39 Ma; (3) the eruption of enriched medium-K tholeiitic and enriched medium-K calc-alkaline magmas became predominant thereafter at the proto-IBM arc. Identification of three major magma types is distinct from the previous work, in which enriched medium-K calc-alkaline magmas and depleted low-K calc-alkaline magmas were not identified. This indicates the usefulness of our statistical analysis as a powerful tool to partition a mixture of multivariable geochemical datasets, such as the composition of melt inclusions in this case. Our data suggest that a depleted mantle source had been replaced by an enriched mantle source owing to convection beneath the proto-IBM arc from >40 to 35 Ma. Finally, thermodynamic modelling indicates that the overall geochemical variation of melt inclusions assigned to each cluster can be broadly reproduced either by crystallization differentiation assuming P = 50 MPa (∼2 km deep) and ∼2 wt% H2O (almost saturated H2O content at 50 MPa) or P = 300 MPa (∼15 km deep) and ∼6 wt% H2O (almost saturated H2O content at 300 MPa). Assuming oxygen fugacity (fO2) of log fO2 equal to +1 relative to the nickel–nickel oxide (NNO) buffer best reproduces the overall geochemical variation of melt inclusions, but assuming more oxidizing conditions (log fO2 = +1 to +2 NNO) probably reproduces the geochemical variation of enriched medium-K and calc-alkaline melt inclusions (30–39 Ma).

Across‐Arc Diversity in Rhyolites From an Intra‐oceanic Arc: Evidence From IODP Site U1437, Izu‐Bonin Rear Arc, and Surrounding Area

AbstractFelsic magmas from the Izu‐Bonin rear arc have compositions that resemble average continental crust in some respects. In order to understand their origin, we studied 1.1–4.4 Ma tephras in a rear‐arc drill core from International Ocean Discovery Program Expedition 350, Site U1437. They provide a well‐dated record of changing magmatic compositions during the early stages of the most recent episode of Izu‐Bonin arc rifting. Based on our comprehensive recontextualization of published analyses of <7 Ma regional dredged rocks across the arc, basalts to rhyolites are shown to vary in coherent chronological and spatial trends and can be classified into three series: light rare earth element‐depleted volcanic front series; a rift‐related series with nearly flat rare earth element patterns; and light rare earth element‐enriched rear‐arc seamount chain‐type (RASC‐type) series, which are abundant in the studied Site U1437 tephra record. All three series erupted simultaneously between 4.4 and 1.1 Ma, including the RASC‐type rhyolites which erupted until 1.1 Ma in significant quantities. Remarkably, trace element and radiogenic isotope ratios are similar between rhyolites and basalts from the same region. This recontextualization of rhyolite affinity represents a significant departure from existing frameworks. Geochemical modeling shows that fractional crystallization can largely explain <4.4 Ma RASC‐type rhyolites with some additional open system processing evident in rhyolites with >73% SiO2. However, trace element and Hf isotope ratios preclude rear‐arc rhyolite derivation by partial melting of the Oligocene‐Eocene arc basement. Thus, we favor a model where fractional crystallization is more important than crustal melting in producing intra‐oceanic arc rhyolites in this region.

Sulfur isotope ratios in co-occurring barite and carbonate from Eocene sediments: A comparison study

In order to investigate the utility of bulk carbonate as a recorder of seawater sulfate sulfur isotope ratios (δ34Ssw), co-existing pelagic barite and bulk carbonate in Eocene sediments from the Equatorial Pacific Ocean (IODP Exp. 320/321 Sites U1331 to U1333) were analyzed for their sulfur isotope ratios (δ34S). The δ34S from both minerals showed parallel fluctuation throughout the Eocene with carbonate associated sulfate (CAS) values about 0.8‰ heavier than those of barite. A similar offset was observed in CAS δ34S obtained using species-specific cleaned planktonic foraminifers in a previous study. The consistent results from two distinct minerals suggest that the original δ34Ssw can be derived from bulk CAS analysis, if post deposition carbonate recrystallization is minimal.The combined data set showed a ~5‰ increase of δ34Ssw during the Eocene (from 53 Ma to 36 Ma) with the majority of the shift within 7 myr between 53 and 46 Ma. This change is more gradual than previously reported. The timing of this δ34Ssw shift coincides with extensive pyrite burial in the Arctic Ocean, supporting the hypothesis that the 5‰ increase in Eocene δ34Ssw has been caused by 34S-enriched water outflow from the Arctic Ocean.

The earliest stage of Izu rear‐arc volcanism revealed by drilling at Site U1437, International Ocean Discovery Program Expedition 350

AbstractThe International Ocean Discovery Program Expedition 350 drilled between two Izu rear‐arc seamount chains at Site U1437 and recovered the first complete succession of rear‐arc rocks. The drilling reached 1806.5 m below seafloor. In situ hyaloclastites, which had erupted before the rear‐arc seamounts came into existence at this site, were recovered in the deepest part of the hole (∼15–16 Ma). Here it is found that the composition of the oldest rocks recovered does not have rear‐arc seamount chain geochemical signatures, but instead shows affinities with volcanic front or some of the extensional zone basalts between the present volcanic front and the rear‐arc seamount chains. It is suggested that following the opening of the Shikoku back‐arc Basin, Site U1437 was a volcanic front or a rifting zone just behind the volcanic front, and was followed at ~ 9 Ma by the start of rear‐arc seamount chains volcanism. This geochemical change records variations in the subduction components with time, which might have followed eastward moving of hot fingers in the mantle wedge and deepening of the subducting slab below Site U1437 after the cessation of Shikoku back‐arc Basin opening.

Planktic Foraminiferal Test Size and Weight Response to the Late Pliocene Environment

AbstractAtmospheric carbon dioxide (pCO2atm) is impacting the ocean and marine organisms directly via changes in carbonate chemistry and indirectly via a range of changes in physical parameters most dominantly temperature. To assess potential impacts of climate change on carbonate production in the open ocean, we measured size and weight of planktic foraminifers during the late Pliocene at pCO2atm concentrations comparable to today and global temperatures 2 to 3 °C warmer. Size of all foraminifers was measured at Atlantic Ocean Deep Sea Drilling Project (DSDP) Site 610, Ocean Drilling Program (ODP) Site 999, and Integrated Ocean Drilling Program (IODP) Site U1313. Test size was smaller during the Pliocene than in modern assemblages under the same environmental conditions. During the cold marine isotope stage (MIS) M2, size increased at Site 999, potentially linked to intensified stratification of the surface ocean in response to the closure of the Central American Seaway. At Site U1313, test size tracks the warming throughout the late Pliocene. Size‐normalized weight (SNW) of Globigerina bulloides at Site U1313 decreased during warmer temperature intervals. SNW of Globigerinoides ruber (white) at Site 999 displays high‐frequency variability not correlated to temperature. Yet during the glacial period within MIS M2, test weight was higher during higher temperatures. Our results support studies in the modern ocean, which challenge the view that carbonate chemistry is the primary driver for calcification. To better understand processes driving changes in SNW, computer tomography was used to quantify calcite to volume ratios. During interglacial periods, lower calcite volume but higher test volume suggests less suitable conditions for calcification. As this signal is not evident in SNW, subtle changes in calcification might not be observed by the weight‐based method.

Late Miocene changes in C3, C4 and aquatic plant vegetation in the Indus River basin: evidence from leaf wax δ13C from Indus Fan sediments

AbstractVegetation changes in the Indus River basin within the past 10.8 million years were investigated based on the analysis of n-fatty acids and their carbon isotopes in sediments from IODP Site U1457 in the Laxmi Basin of the Arabian Sea. The δ13C of long-chain n-C32 fatty acid shifted from −34 to −22 ‰ from 10 to 6.3 Ma, while the δ13C of mid-chain n-C24 fatty acid was nearly constant at around −23 to −22 ‰ over the same period. This large difference in the δ13C values suggests that the mid-chain fatty acids reflect the contribution of aquatic vascular C3 plants. Before 6.3 Ma, the average chain length of n-fatty acids and the δ13C values of long-chain fatty acids were negatively correlated, suggesting that the δ13C values reflected the relative abundance of terrestrial C3 versus aquatic C3 plants in the Indus River basin and western India. After 5.8 Ma, the average chain length was variable, but the δ13C values remained nearly the same, suggesting that the δ13C values reflected heavier δ13C values of both aquatic C3 and C4 plants. A three-end-member model calculation suggests that terrestrial C3 plants were replaced by C4 plants in the Indus River basin and western India from 9.7 or 8.2 to 6.3 Ma. Aridification in those areas during the late Miocene period may have driven the replacement of terrestrial C3 plants by C4 plants. An episodic increase in the abundance of terrestrial plants around 8 Ma is attributed to elevated precipitation by regionally enhanced moisture transport.

Radiolarian Biostratigraphy and Faunal Turnover across the Early/Middle Miocene Boundary in the Equatorial Pacific

Sedimentary sequences obtained from drilling during Integrated Ocean Drilling Program (IODP) Expedition 320/321, “Pacific Equatorial Age Transect (PEAT)” at eight sites (Sites U1331–1338) in the equatorial Pacific offer an ideal record for reconstructing the evolution of the ocean/climate system throughout the Cenozoic. The sediments drilled at Site U1335 record short-term events of paleoceanographic significance, including the early Miocene climatic optimum (MCO) and the middle Miocene climatic transition (MMCT). Abundant well preserved radiolarians were recovered from the lower Miocene radiolarian Zone RN2 through middle Miocene Zone RN5 at IODP Site U1335. A total of 46 radiolarian datum levels consisting of 20 first occurrences (FOs), 25 last occurrences (LOs), and one evolutionary transition (ET) was recognized within the studied interval at Site U1335. Of these datum levels, 36 radiolarian datum levels were directly tied to the geomagnetic polarity time scale (GPTS) across the early/middle Miocene boundary. The general magnitude of evolutionary change was estimated based on the total turnover rate (the sum of FOs and LOs per 0.5 m.y.) of tropical radiolarians, and two minor faunal turnovers of radiolarian species were recognized between 16.5 and 14.7 Ma and between 13.9 and 13.4 Ma. These faunal turnovers were associated with regional environmental changes such as the increased biological productivity in the equatorial Pacific during the MCO and the MMCT.

Multi-elemental composition of authigenic carbonates in benthic foraminifera from the eastern Bering Sea continental margin (International Ocean Discovery Program Site U1343)

Bering Sea sediments represent exceptional archives, offering the potential to study past climates and biogeochemistry at a high resolution. However, abundant hydrocarbons of microbial origin, especially along the eastern Bering Sea continental margin, can hinder the applicability of palaeoceanographic proxies based on calcareous foraminifera, due to the formation of authigenic carbonates. Nonetheless, authigenic carbonates may also bear unique opportunities to reconstruct changes in the sedimentary redox environment.Here we use a suite of visual and geochemical evidence from single-specimens of the shallow infaunal benthic foraminiferal species Elphidium batialis Saidova (1961), recovered from International Ocean Discovery Program (IODP) Site U1343 in the eastern Bering Sea, to investigate the influence of authigenic carbonates on the foraminiferal trace metal composition. Our results demonstrate that foraminiferal calcite tests act as a nucleation template for secondary carbonate precipitation, altering their geochemistry where organoclastic sulphate reduction and anaerobic oxidation of methane cause the formation of low- and high-Mg calcite, respectively. The authigenic carbonates can occur as encrusting on the outside and/or inside of foraminiferal tests, in the form of recrystallization of the test wall, or as banding along natural laminations within the foraminiferal test walls. In addition to Mg, authigenic carbonates are enriched in U/Ca, Mn/Ca, Fe/Ca, and Sr/Ca, depending on the redox environment that they were formed in. Our results demonstrate that site-specific U/Ca thresholds are a promising tool to distinguish between diagenetically altered and pristine foraminiferal samples, important for palaeoceanographic reconstructions utilising the primary foraminiferal geochemistry. Consistent with previous studies, U/Mn ratios of foraminifera at IODP Site U1343 increase according to their degree of diagenetic alteration, suggesting a potential response of authigenic U/Mn to the microbial activity in turn linked to the sedimentary redox environment.

Late Miocene to Holocene high-resolution eastern equatorial Pacific carbonate records: stratigraphy linked by dissolution and paleoproductivity

Abstract. Coherent variation in CaCO3 burial is a feature of the Cenozoic eastern equatorial Pacific. Nevertheless, there has been a long-standing ambiguity in whether changes in CaCO3 dissolution or changes in equatorial primary production might cause the variability. Since productivity and dissolution leave distinctive regional signals, a regional synthesis of data using updated age models and high-resolution stratigraphic correlation is an important constraint to distinguish between dissolution and production as factors that cause low CaCO3. Furthermore, the new chronostratigraphy is an important foundation for future paleoceanographic studies. The ability to distinguish between primary production and dissolution is also important to establish a regional carbonate compensation depth (CCD). We report late Miocene to Holocene time series of XRF-derived (X-ray fluorescence) bulk sediment composition and mass accumulation rates (MARs) from eastern equatorial Pacific Integrated Ocean Drilling Program (IODP) sites U1335, U1337, and U1338 and Ocean Drilling Program (ODP) site 849, and we also report bulk-density-derived CaCO3 MARs at ODP sites 848, 850, and 851. We use physical properties, XRF bulk chemical scans, and images along with available chronostratigraphy to intercorrelate records in depth space. We then apply a new equatorial Pacific age model to create correlated age records for the last 8 Myr with resolutions of 1–2 kyr. Large magnitude changes in CaCO3 and bio-SiO2 (biogenic opal) MARs occurred within that time period but clay deposition has remained relatively constant, indicating that changes in Fe deposition from dust is only a secondary feedback to equatorial productivity. Because clay deposition is relatively constant, ratios of CaCO3 % or biogenic SiO2 % to clay emulate changes in biogenic MAR. We define five major Pliocene–Pleistocene low CaCO3 % (PPLC) intervals since 5.3 Ma. Two were caused primarily by high bio-SiO2 burial that diluted CaCO3 (PPLC-2, 1685–2135 ka, and PPLC-5, 4465–4737 ka), while three were caused by enhanced dissolution of CaCO3 (PPLC-1, 51–402 ka, PPLC-3, 2248–2684 ka, and PPLC-4, 2915–4093 ka). Regional patterns of CaCO3 % minima can distinguish between low CaCO3 caused by high diatom bio-SiO2 dilution versus lows caused by high CaCO3 dissolution. CaCO3 dissolution can be confirmed through scanning XRF measurements of Ba. High diatom production causes lowest CaCO3 % within the equatorial high productivity zone, while higher dissolution causes lowest CaCO3 percent at higher latitudes where CaCO3 production is lower. The two diatom production intervals, PPLC-2 and PPLC-5, have different geographic footprints from each other because of regional changes in eastern Pacific nutrient storage after the closure of the Central American Seaway. Because of the regional variability in carbonate production and sedimentation, the carbonate compensation depth (CCD) approach is only useful to examine large changes in CaCO3 dissolution.

Depositional History and Indian Summer Monsoon Controls on the Silicate Weathering of Sediment Transported to the Eastern Arabian Sea: Geochemical Records From IODP Site U1456 Since 3.8 Ma

AbstractSystematic variation in elemental and Sr‐Nd isotopic compositions of the clay‐sized (<2 μm) siliciclastic fraction from the International Ocean Discovery Program (IODP) Site U1456 (Laxmi Basin) provides valuable insights into dynamic changes in continental weathering intensity in the western Himalayas and sediment inputs from the Indus River and Deccan Traps to the eastern Arabian Sea. Long‐term, high‐resolution proxy records from the sediment core reveal that the main sources (i.e., Indus River and Deccan Trap basalts) of the fine‐grained detrital sediments have significantly changed with Indian summer monsoon variation over the studied time interval. During two depositional periods (3.8–3.3 and 2.7–1.2 Ma) corresponding to a weak Indian summer monsoon, the Indus River contributed fine‐grained sediments with high K/Al, high 87Sr/86Sr, and low εNd to the study site. Between 3.3 and 2.7 Ma and between 1.2 and 0 Ma, deposition in the eastern Arabian Sea was governed by large inputs of Deccan Trap‐derived basaltic sediments, characterized by high Mg/Al and Fe/Al, low 87Sr/86Sr and chemical index of alteration values, and high εNd values, associated with a change to a stronger Indian summer monsoon driving stronger chemical weathering. Synchronous changes in the geochemical proxies since 3.8 Ma highlight that variations in the inputs of siliciclastic sediments and Indian summer monsoon development are closely coupled.

Integrating heavy-mineral, geochemical and biomarker analyses of Plio-Pleistocene sandy and silty turbidites: a novel approach for provenance studies (Indus Fan, IODP Expedition 355)

AbstractA multidisciplinary mineralogical, geochemical and biomarker study of Indus Fan sediments cored during International Ocean Discovery Program (IODP) Expedition 355 to the Laxmi Basin was carried out to define the different compositional signatures of sand, silt and clay. Upper Pliocene – lower Pleistocene turbidites from sites U1456 and U1457 were selected as the best candidates for this study. The integrated dataset presented here was obtained by coupling traditional and innovative bulk-sediment and single-mineral techniques on the same samples. Turbiditic deposits mostly consist of medium to fine silt, including rich and diverse heavy-mineral assemblages. Such a fine grain size forced us to push the limits of high-resolution quantitative heavy-mineral analysis down to as low as 5 μm. Heavy-mineral analysis allowed us to establish a Himalayan origin of the detritus in the studied turbidites. Heavy-mineral concentrations are higher in channel-fill than in overbank deposits. Mineralogical and geochemical data concur in revealing that fast-settling ultradense minerals such as zircon are preferentially concentrated in channel-fill deposits, whereas the top of overbank deposits are notably enriched with slow-settling platy phyllosilicates. Biomarker analysis represents a most suitable complementary technique that is able to investigate the provenance signature of the finer sediment fraction, largely consisting of clay. This technique allowed us to identify a largely terrigenous origin of organic matter at Site U1456 and an open marine origin at Site U1457. The latter site lies closer to the Laxmi Ridge, where thermal maturity increases with depth to reach the early oil window (127°C at c. 320 m below the seafloor).

Spatiotemporal variation of organic geochemical properties since the mid-Miocene in the deep South China Sea (IODP Expedition 349)

We performed an extensive survey of total organic carbon (OC) and stable OC composition of in the deep South China Sea sediments from the International Ocean Discovery Program (IODP) Expedition 349 Sites U1431, U1433 and Ocean Drilling Program (ODP) Leg 184 Site 1148. Our results reveal dramatic spatial and temporal variations in organic geochemical characteristics among the three Sites. Before ~8 Ma, OC deposited at Site U1431 may be predominantly terrigenous, whereas OC deposited at Sites U1433 and 1148 is mainly of marine origin. After ~8 Ma, OC accumulation at the three Sites progressively increases, mainly due to enhancement of marine primary productivity and input of terrestrial organic matter; the three sites receive mainly marine OC, whereas Sites U1433 and 1148 receive relatively more terrestrial OC compared with Site 1431. Additionally, methane concentrations vary from ~20 to ~100,000 ppmv at Site U1433 and from ~10 to ~600 ppmv at Site 1148 with higher geothermal gradients (78 and 84 °C/km, respectively). In contrast, methane concentrations are <5 ppmv at Site U1431 with lower geothermal gradient (14.8 °C/km). Such high methane concentrations and ratios of methane to ethane at Site U1433 suggest that the gaseous hydrocarbons in the southwestern sub-basin (deep water depth, >4000 km) are primarily sourced from microbial production. Our findings suggest that the sources, trajectories, and fates of OC buried in the deep South China Sea since the mid-Miocene are spatially and temporally variable, controlled by sedimentological processes in the sub-basins, and regional tectonic evolution and long-term paleoenvironmental changes.