This paper describes a detailed investigation which was specifically aimed at providing a simple practical assessment procedure which identified reverse temper embrittlement (RTE) in a series of high-pressure (HP) and intermediate-pressure (IP) CrMoV steel turbine bolts from two separate 120 MW sister units which had been subjected to 120 000 h of service. A small section of material was removed from a non-critical location from all 182 bolts. From this section the chemical composition, average hardness and prior austenite grain size were assessed. The toughness of selected bolts was measured by either (i) Charpy impact testing or (ii) Auger electron spectroscopy. It was established that grain size and bulk phosphorus content were the primary factors which consistently correlated with the embrittled condition. An embrittlement estimative diagram was established by plotting grain size d versus percentage phosphorus. This portrayed two distinct regions, namely an embrittled region and a non-embrittled regio...
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